CN114231325A - Preparation and application of new energy multifunctional emulsifier - Google Patents

Preparation and application of new energy multifunctional emulsifier Download PDF

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Publication number
CN114231325A
CN114231325A CN202111451591.0A CN202111451591A CN114231325A CN 114231325 A CN114231325 A CN 114231325A CN 202111451591 A CN202111451591 A CN 202111451591A CN 114231325 A CN114231325 A CN 114231325A
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group
agent
reduction
preparation
multifunctional emulsifier
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张平
刘少君
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Yixin Sannong Shenyang Petrochemical Co ltd
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Yixin Sannong Shenyang Petrochemical Co ltd
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Priority to CN202111451591.0A priority Critical patent/CN114231325A/en
Publication of CN114231325A publication Critical patent/CN114231325A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1233Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1266Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The invention discloses a preparation method and application of a new energy multifunctional emulsifier, which is characterized by comprising the following steps: the multifunctional emulsifier is a compound type and comprises a group A agent and a group B agent, the ratio of the group A agent to the group B agent in parts by weight is 4:6, and the preparation steps of the multifunctional emulsifier are as follows: s1: and respectively weighing the group A agent and the group B agent according to the weight part ratio. The invention has the advantages that: the emulsified oil produced by using the new energy multifunctional emulsifier has the advantages of strong stability, high temperature resistance, long shelf life, environmental protection, small addition amount, sufficient combustion, great reduction of smoke dust and harmful gas emission, reduction of smoke dust amount by more than 55-90%, reduction of carbon emission by more than 20-50%, reduction of nitrogen oxide by more than 25%, reduction of sulfur oxide by more than 30-55%, oil saving rate by more than 5-18%, price reduction by 400-800 yuan/ton, and mass production cost saving for oil units.

Description

Preparation and application of new energy multifunctional emulsifier
Technical Field
The invention relates to the technical field of petroleum additives, in particular to preparation and application of a new energy multifunctional emulsifier.
Background
At present, the shortage of petroleum energy and environmental protection are important problems facing the world, and how to effectively utilize petroleum energy also becomes a focus of attention of all countries in the world, wherein heavy oil has low price, wide source and certain calorific value, so the heavy oil is a main fuel for industrial boilers and large ships. The heavy oil, also called residual oil, is residual oil obtained by extracting distillate oil from crude oil by an atmospheric or vacuum distillation device, or cracked residual oil extracted from the bottom of a high-temperature pressure cracking evaporation tower, or heavy petroleum fuel prepared by mixing the two or adding a proper amount of cracked residual oil. The heavy oil has the outstanding defects of high content of colloid and asphaltene, high viscosity and poor fluidity, and great difficulty is brought to application; in addition, heavy oil is residual oil, so that the viscosity is high, the content of harmful impurities is high, the components are complex, when the residual oil is used as fuel, the combustion is insufficient, carbon deposition is generated in the combustion process, and the corrosion to equipment can cause serious damage to the metal surface.
Disclosure of Invention
The technical problem to be solved by the invention is to provide the preparation and the application of the novel energy multifunctional emulsifier which is simple to prepare and environment-friendly.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: the preparation and application of the new energy multifunctional emulsifier are characterized in that: the multifunctional emulsifier is a compound type and comprises a group A agent and a group B agent, the ratio of the group A agent to the group B agent in parts by weight is 4:6, and the preparation steps of the multifunctional emulsifier are as follows:
s1: respectively weighing a group A agent and a group B agent according to the weight part ratio;
s2: respectively adding the weighed group A agent and the weighed group B agent into a stirring kettle with a heating function;
s3: and starting the stirring kettle, heating the stirring kettle to 60-70 ℃, stirring for 20-60 minutes, and taking out to obtain the multifunctional emulsifier.
As an improvement, the group A agent comprises the following components: the sodium nitrite solution, the potassium permanganate solution, the fatty acid methyl ester and the polyol resin solution are 5-15% of the sodium nitrite solution, 7-12% of the potassium permanganate solution, 1-5% of the fatty acid methyl ester and 8-15% of the polyol resin solution according to the weight part ratio.
As an improvement, the group B agent comprises the following components: the composite material comprises, by weight, 5% -15% of methanol, 3% -10% of ethanolamine, 3% -8% of cyclopropylamine and 0.01% -0.1% of hydrazine hydrate.
Compared with the prior art, the invention has the advantages that: the emulsified oil produced by using the new energy multifunctional emulsifier has the advantages of strong stability, high temperature resistance, long shelf life, environmental protection, small addition amount, sufficient combustion, great reduction of smoke dust and harmful gas emission, reduction of smoke dust amount by more than 55-90%, reduction of carbon emission by more than 20-50%, reduction of nitrogen oxide by more than 25%, reduction of sulfur oxide by more than 30-55%, oil saving rate by more than 5-18%, price reduction by 400-800 yuan/ton, and mass production cost saving for oil units.
Detailed Description
The present invention is described in further detail below.
Example one
The preparation and application of the new energy multifunctional emulsifier are characterized in that the multifunctional emulsifier is a compound type and comprises a group A agent and a group B agent, the ratio of the group A agent to the group B agent in parts by weight is 4:6, and the preparation steps of the multifunctional emulsifier are as follows:
s1: respectively weighing a group A agent and a group B agent according to the weight part ratio;
s2: respectively adding the weighed group A agent and the weighed group B agent into a stirring kettle with a heating function;
s3: and starting the stirring kettle, heating the stirring kettle to 60 ℃, stirring for 20 minutes, and taking out to obtain the multifunctional emulsifier.
The group A agent comprises the following components: the polyurethane resin comprises a sodium nitrite solution, a potassium permanganate solution, fatty acid methyl ester and a polyol resin solution, wherein the sodium nitrite solution, the potassium permanganate solution, the fatty acid methyl ester and the polyol resin solution are prepared from 5% of the sodium nitrite solution, 7% of the potassium permanganate solution, 1% of the fatty acid methyl ester and 8% of the polyol resin solution in parts by weight.
The group B agent comprises the following components: the composite material comprises, by weight, 5% of methanol, 3% of ethanolamine, 3% of cyclopropylamine and 0.01% of hydrazine hydrate.
Example two
The preparation and application of the new energy multifunctional emulsifier are characterized in that the multifunctional emulsifier is a compound type and comprises a group A agent and a group B agent, the ratio of the group A agent to the group B agent in parts by weight is 4:6, and the preparation steps of the multifunctional emulsifier are as follows:
s1: respectively weighing a group A agent and a group B agent according to the weight part ratio;
s2: respectively adding the weighed group A agent and the weighed group B agent into a stirring kettle with a heating function;
s3: and starting the stirring kettle, heating the stirring kettle to 70 ℃, stirring for 60 minutes, and taking out to obtain the multifunctional emulsifier.
The group A agent comprises the following components: the sodium nitrite solution, the potassium permanganate solution, the fatty acid methyl ester and the polyol resin solution are 15% of the sodium nitrite solution, 12% of the potassium permanganate solution, 5% of the fatty acid methyl ester and 15% of the polyol resin solution according to the weight part ratio.
The group B agent comprises the following components: the composite material comprises, by weight, 15% of methanol, 10% of ethanolamine, 8% of cyclopropylamine and 0.1% of hydrazine hydrate.
EXAMPLE III
The preparation and application of the new energy multifunctional emulsifier are characterized in that the multifunctional emulsifier is a compound type and comprises a group A agent and a group B agent, the ratio of the group A agent to the group B agent in parts by weight is 4:6, and the preparation steps of the multifunctional emulsifier are as follows:
s1: respectively weighing a group A agent and a group B agent according to the weight part ratio;
s2: respectively adding the weighed group A agent and the weighed group B agent into a stirring kettle with a heating function;
s3: starting the stirring kettle, heating the stirring kettle to 65 ℃, stirring for 40 minutes, and taking out to obtain the multifunctional emulsifier.
The group A agent comprises the following components: the sodium nitrite solution, the potassium permanganate solution, the fatty acid methyl ester and the polyol resin solution are 10% of the sodium nitrite solution, 9% of the potassium permanganate solution, 3% of the fatty acid methyl ester and 12% of the polyol resin solution in parts by weight.
The group B agent comprises the following components: the composite material comprises, by weight, 10% of methanol, 6% of ethanolamine, 5% of cyclopropylamine and 0.05% of hydrazine hydrate.
The present invention and the embodiments thereof have been described above, but the description is not limited thereto, and the embodiment shown is only one of the embodiments of the present invention, and the actual structure is not limited thereto. In summary, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (3)

1. The preparation and application of the new energy multifunctional emulsifier are characterized in that: the multifunctional emulsifier is a compound type and comprises a group A agent and a group B agent, the ratio of the group A agent to the group B agent in parts by weight is 4:6, and the preparation steps of the multifunctional emulsifier are as follows:
s1: respectively weighing a group A agent and a group B agent according to the weight part ratio;
s2: respectively adding the weighed group A agent and the weighed group B agent into a stirring kettle with a heating function;
s3: and starting the stirring kettle, heating the stirring kettle to 60-70 ℃, stirring for 20-60 minutes, and taking out to obtain the multifunctional emulsifier.
2. The preparation and application of the new energy multifunctional emulsifier according to claim 1 are characterized in that: the group A agent comprises the following components: the sodium nitrite solution, the potassium permanganate solution, the fatty acid methyl ester and the polyol resin solution are 5-15% of the sodium nitrite solution, 7-12% of the potassium permanganate solution, 1-5% of the fatty acid methyl ester and 8-15% of the polyol resin solution according to the weight part ratio.
3. The preparation and application of the new energy multifunctional emulsifier according to claim 1 are characterized in that: the group B agent comprises the following components: the composite material comprises, by weight, 5% -15% of methanol, 3% -10% of ethanolamine, 3% -8% of cyclopropylamine and 0.01% -0.1% of hydrazine hydrate.
CN202111451591.0A 2021-12-01 2021-12-01 Preparation and application of new energy multifunctional emulsifier Pending CN114231325A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126750A (en) * 1995-01-09 1996-07-17 袁光海 Light fuel oil
CN101058747A (en) * 2007-06-21 2007-10-24 刘同元 Emulsification diesel fuel additive, emulsification diesel fuel using the same and preparation method thereof
CN102206518A (en) * 2010-03-31 2011-10-05 张朝斌 Environment-friendly and energy-saving emulsification clean diesel oil
CN102643692A (en) * 2012-05-08 2012-08-22 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN102676249A (en) * 2012-06-05 2012-09-19 广州埃尔辟能源科技有限公司 High-efficiency environment-friendly energy-saving emulsifier for heavy oil, diesel oil or fuel oil and preparation method of emulsifier

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126750A (en) * 1995-01-09 1996-07-17 袁光海 Light fuel oil
CN101058747A (en) * 2007-06-21 2007-10-24 刘同元 Emulsification diesel fuel additive, emulsification diesel fuel using the same and preparation method thereof
CN102206518A (en) * 2010-03-31 2011-10-05 张朝斌 Environment-friendly and energy-saving emulsification clean diesel oil
CN102643692A (en) * 2012-05-08 2012-08-22 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN102676249A (en) * 2012-06-05 2012-09-19 广州埃尔辟能源科技有限公司 High-efficiency environment-friendly energy-saving emulsifier for heavy oil, diesel oil or fuel oil and preparation method of emulsifier

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