CN104130808A - Clean liquid fuel and preparation method thereof - Google Patents
Clean liquid fuel and preparation method thereof Download PDFInfo
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- CN104130808A CN104130808A CN201410418091.0A CN201410418091A CN104130808A CN 104130808 A CN104130808 A CN 104130808A CN 201410418091 A CN201410418091 A CN 201410418091A CN 104130808 A CN104130808 A CN 104130808A
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- acetone
- nitric acid
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- 239000000446 fuel Substances 0.000 title claims abstract description 60
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 117
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 90
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 83
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 58
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 30
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 30
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000003756 stirring Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 19
- 239000012467 final product Substances 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 238000002485 combustion reaction Methods 0.000 abstract description 22
- 239000002994 raw material Substances 0.000 abstract description 15
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000013068 control sample Substances 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 229940001516 sodium nitrate Drugs 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention provides a clean liquid fuel and a preparation method thereof. The clean liquid fuel is composed of the following components in percentage by weight: 50-75% of methanol, 10-15% of waste alcohol, 13-35% of water, 0.5-1% of methylbenzene, 0.05-0.1% of n-hexane, 0.05-0.1% of ammonium nitrate, 0.5-1.5% of glycerol, 0.1-0.5% of nitric acid and 0.5-1.5% of acetone. The clean liquid fuel has the advantages of high fuel combustion flame temperature, high fuel value, easily available raw materials, environmental friendliness and cleanness, and low cost.
Description
Technical field
The present invention relates to a kind of liquid fuel and preparation method thereof, especially a kind of clean fuel liquid for Industrial Boiler and preparation method thereof.
Background technology
Along with colliery, petroleum-based energy are in the world fewer and feweri, the imbalance between supply and demand of oil becomes increasingly conspicuous, and the demand of the substitute of the fossil class A fuel As such as exploitation oil is also just more and more outstanding.In prior art, mostly be equipped with other raw material with methyl alcohol and make methanol fuel, as the substitute of oil fuel, methanol fuel is to utilize industrial methanol or fuel methanol, add modified alcohol additive, with existing GB petrol and diesel oil (or component oil), allocate a kind of Novel clean-fuel of making through strict scientific technology by certain volume (or weight ratio).Its alternative petrol and diesel oil, for various motor vehicles, pot and stove stove uses.Development of Coal methanol fuel processed, supplements and part petroleum replacing fuel, is the important channel of alleviating energy shortage situation, improving comprehensive utilization of resources.For example Chinese patent literature CN 102504888 A disclose a kind of composite clean liquid fuel and production method thereof, it is iron standby by methyl alcohol, water, ethanol, acetic acid, sodium oxide, ammoniacal liquor, xylidene(s), SODIUMNITRATE and two cyclic diolefines, the combustion flame temperature of the fuel after preparation is 750 ~ 800 DEG C, is exactly this kind of example.
Above-mentioned composite clean liquid fuel of the prior art, because the flame temperature of fuel combustion is 750 ~ 800 DEG C, the temperature that visible fuel can reach is lower, the calorific value of fuel is also just on the low side, therefore, this composite clean liquid fuel just can not meet the demand in the field that some needs fuel flame temperature are higher, and range of application is also just narrow; In addition, because its main batch mixing is methyl alcohol and ethanol, therefore supplied materials is more single, and in contrast, high expensive, does not meet the principle of economic environmental protection to the temperature that can reach with described composite clean liquid fuel combustion heat value and fuel combustion flame.
Summary of the invention
In order to overcome the problems referred to above, the present invention provides clean fuel liquid that a kind of fuel combustion flame temperature is high, fuel value is high, raw material is easy to get environment protection clean and cost is low and preparation method thereof to society.
Technical scheme of the present invention is: design a kind of clean fuel liquid, be made up of the component of following weight per-cent: methyl alcohol 50 ~ 75%, useless alcohol 10 ~ 15%, water 13 ~ 35%, toluene 0.5 ~ 1%, normal hexane 0.05 ~ 0.1%, ammonium nitrate 0.05 ~ 0.1%, glycerol 0.5 ~ 1.5%, nitric acid 0.1 ~ 0.5%, acetone 0.5 ~ 1.5%.
As the further improvement of technique scheme, each composition weight percentage composition is: methyl alcohol 55 ~ 70%, useless alcohol 11 ~ 14%, water 16 ~ 32%, toluene 0.6 ~ 0.9%, normal hexane 0.06 ~ 0.09%, ammonium nitrate 0.06 ~ 0.09%, glycerol 0.7 ~ 1.3%, nitric acid 0.18 ~ 0.42%, acetone 0.7 ~ 1.3%.
As the further improvement of technique scheme, each composition weight percentage composition is: methyl alcohol 60 ~ 65%, useless alcohol 12 ~ 13%, water 19 ~ 29%, toluene 0.7 ~ 0.8%, normal hexane 0.07 ~ 0.08%, ammonium nitrate 0.07 ~ 0.08%, glycerol 0.9 ~ 1.1%, nitric acid 0.26 ~ 0.34%, acetone 0.9 ~ 1.1%.
A kind of preparation method of clean fuel liquid, 0.05 ~ 0.1% ammonium nitrate is added to stirring and dissolving in 13 ~ 35% water, then add 0.5 ~ 1.5% glycerol to continue again stirring and dissolving, finally add 0.1 ~ 0.5% nitric acid, leave standstill the first solution after 10 ~ 25 minutes; 0.5 ~ 1% toluene, 0.05 ~ 0.1% normal hexane are added successively in 0.5 ~ 1.5% acetone and stir to obtain the second solution; Take 10 ~ 15% useless alcohol as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into respectively successively in 50 ~ 75% the methyl alcohol for preparing component, stirred and get final product to obtain finished product.
A kind of preparation method of clean fuel liquid, 0.06 ~ 0.09% ammonium nitrate is added to stirring and dissolving in 16 ~ 32% water, then add 0.7 ~ 1.3% glycerol to continue again stirring and dissolving, finally add 0.18 ~ 0.42% nitric acid, leave standstill the first solution after 10 ~ 25 minutes; 0.6 ~ 0.9% toluene, 0.06 ~ 0.09% normal hexane are added successively in 0.7 ~ 1.3% acetone and stir to obtain the second solution; Take 11 ~ 14% useless alcohol as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into respectively successively in 55 ~ 70% the methyl alcohol for preparing component, stirred and get final product to obtain finished product.
A kind of preparation method of clean fuel liquid, 0.07 ~ 0.08% ammonium nitrate is added to stirring and dissolving in 19 ~ 29% water, then add 0.9 ~ 1.1% glycerol to continue again stirring and dissolving, finally add 0.26 ~ 0.34% nitric acid, leave standstill the first solution after 10 ~ 25 minutes; 0.7 ~ 0.8% toluene, 0.07 ~ 0.08% normal hexane are added successively in 0.9 ~ 1.1% acetone and stir to obtain the second solution; Take 12 ~ 13% useless alcohol as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into respectively successively in 60 ~ 65% the methyl alcohol for preparing component, stirred and get final product to obtain finished product.
The present invention is due to by methyl alcohol, useless alcohol, water, toluene, normal hexane, ammonium nitrate, glycerol, nitric acid and acetone preparation, in the clean-burning reaction of methyl alcohol, because described clean fuel liquid exists acetone, normal hexane and toluene, therefore acetone, normal hexane and toluene and then carry out the reactive combustion of chain lock, in the time that temperature reaches 350 DEG C of left and right, by cracking nitric acid, the first explosive combustion region of glycerol, discharge huge energy, temperature of combustion will reach the second explosive combustion region immediately, in the time that temperature of combustion reaches more than 550 DEG C, reach the explosive combustion region of ammonium nitrate fuel, discharge huger energy, temperature is also just brought up to more than 1200 DEG C, thereby the hydrogen-oxygen key in splitting water molecule, molecule is opened, hydrogen molecule participates in burning, oxygen molecule is combustion-supporting, thereby temperature of combustion is reached more than 1500 DEG C.Hence one can see that, and repeatedly blast can make fuel flame temperature of the present invention reach more than 1500 DEG C, and fuel value is high; And whole combustion processes is all to carry out under the oxygen containing environment of richness, therefore the gas after burning is nonpoisonous and tasteless; And useless alcohol in the present invention waits the recovery of the alcohols of place discharge from some industry, therefore supplied materials approach much and can avoid some factories random exhaust emission environment of alcohol that gives up, raw material be easy to get environmental protection and cost low, also can really realize and turning waste into wealth; Therefore, the present invention has advantages of that fuel combustion flame temperature is high, fuel value is high, raw material is easy to get environment protection clean and cost is low.
Embodiment
Following each embodiment all can make by following method, namely first take corresponding methyl alcohol, useless alcohol, water, toluene, normal hexane, ammonium nitrate, glycerol, nitric acid and acetone by the weight content per-cent in following each embodiment, again ammonium nitrate is added to the water to stirring and dissolving, then add glycerol to continue again stirring and dissolving, finally add nitric acid, standing first solution that obtains after 10 ~ 25 minutes; Toluene, normal hexane are added successively respectively and in acetone, stir to obtain the second solution; Useless alcohol is as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into successively respectively and taken in advance in methyl alcohol, stir and get final product to obtain finished product.Described useless alcohol is the alcohols materials such as the factory useless methyl alcohol, ethanol or the propyl alcohol that produce in cleaning course, or the mixture of useless methyl alcohol, ethanol and propyl alcohol etc., and wherein useless alcohol content is being more than or equal to more than 70%.
Embodiment mono-
Take the raw material that contains following weight percentage composition, methyl alcohol 50%, useless alcohol 10.7%, water 35%, toluene 1%, normal hexane 0.1%, ammonium nitrate 0.1%, glycerol 1.3%, nitric acid 0.5% and acetone 1.3%;
Embodiment bis-
Take the raw material that contains following weight percentage composition, methyl alcohol 58%, useless alcohol 10%, water 28%, toluene 0.7%, normal hexane 0.06%, ammonium nitrate 0.09%, glycerol 1.4%, nitric acid 0.45% and acetone 1.3%;
Embodiment tri-
Take the raw material that contains following weight percentage composition, methyl alcohol 60%, useless alcohol 14%, water 22%, toluene 0.5%, normal hexane 0.08%, ammonium nitrate 0.08%, glycerol 1.5%, nitric acid 0.34% and acetone 1.5%;
Embodiment tetra-
Take the raw material that contains following weight percentage composition, methyl alcohol 65%, useless alcohol 13%, water 19%, toluene 0.8%, normal hexane 0.07%, ammonium nitrate 0.07%, glycerol 0.9%, nitric acid 0.26% and acetone 0.9%;
Embodiment five
Take the raw material that contains following weight percentage composition, methyl alcohol 70%, useless alcohol 12%, water 15.4%, toluene 1%, normal hexane 0.05%, ammonium nitrate 0.06%, glycerol 0.8%, nitric acid 0.19% and acetone 0.5%;
Embodiment six
Take the raw material that contains following weight percentage composition, methyl alcohol 75%, useless alcohol 10%, water 13%, toluene 0.6%, normal hexane 0.05%, ammonium nitrate 0.05%, glycerol 0.5%, nitric acid 0.1% and acetone 0.7%;
Embodiment seven
Take the raw material that contains following weight percentage composition, methyl alcohol 53%, useless alcohol 15%, water 29%, toluene 0.9%, normal hexane 0.06%, ammonium nitrate 0.09%, glycerol 0.9%, nitric acid 0.15% and acetone 0.9%;
Embodiment eight
Take the raw material that contains following weight percentage composition, methyl alcohol 64%, useless alcohol 11%, water 21.5%, toluene 0.8%, normal hexane 0.08%, ammonium nitrate 0.07%, glycerol 1.2%, nitric acid 0.35% and acetone 1%;
Embodiment nine
Take the raw material that contains following weight percentage composition, methyl alcohol 55%, useless alcohol 10%, water 32%, toluene 0.6%, normal hexane 0.09%, ammonium nitrate 0.09%, glycerol 0.7%, nitric acid 0.42% and acetone 1.1%;
Embodiment ten
Take the raw material that contains following weight percentage composition, methyl alcohol 57%, useless alcohol 10%, water 29.5%, toluene 0.5%, normal hexane 0.09%, ammonium nitrate 0.08%, glycerol 1.2%, nitric acid 0.43% and acetone 1.2%;
Liquid fuel of the present invention after tested, compare as shown in following table 1, table 2 and table 3 with control sample 1, control sample 2 by indices:
Table 1 nitric acid, ammonium nitrate and the impact of glycerol content on flame temperature:
As shown in Table 1, in the formula of control sample 1 and control sample 2, not containing nitric acid, ammonium nitrate and these three kinds of materials of glycerol, its flame temperature is all below 900 DEG C; And in each embodiment sample, all containing these three kinds of materials, its flame temperature is all more than 1500 DEG C.Illustrate that the present invention is conducive to improve the flame temperature of fuel combustion.
In addition, embodiment 1-6 is compared known, nitric acid, ammonium nitrate and glycerol content are higher, and the flame temperature of fuel combustion is also just higher.
The impact of table 2 alcohol content on combustion heat value:
We know, when the alcohol content of alcohol radical liquid fuel is lower than 75% time, combustion heat value can be lower; As shown in Table 2, the combustion heat value of control sample 2 is far longer than the combustion heat value of control sample 1, and the combustion heat value of embodiment 1-6 sample is all greater than control sample 2, particularly embodiment 1 and embodiment 2 samples, at alcohol content lower than 75% time, still be greater than control sample 2, visible, the present invention is conducive to improve the calorific value of fuel;
In addition, from embodiment 1-6 sample relatively, alcohol content is higher, and the calorific value of fuel is also just higher, and at alcohol content, higher than 75% time, alcohol content raises, and the calorific value of fuel declines to some extent.
The flash-point comparison of table 3 fuel:
Flash-point is too low, and fuel electrodes is inflammable, is unfavorable for the transport of fuel; But flash-point is too high, fuel is just difficult for igniting, and is unfavorable for burning, and therefore flash-point need be in a suitable scope;
As shown in Table 3, the flash-point of contrast file 1, contrast file 2 is to be more than or equal to more than 47 DEG C, and visible flash-point value is too high, is difficult for igniting; And from embodiment 1-10 sample relatively, flash-point, all being more than or equal to 35 DEG C and be less than or equal in the scope of 45 DEG C, is inflammable substance, but it is too low to be unlikely to again flash-point, therefore also convenient transport, hence one can see that, and the present invention is conducive to make fuel flash point in a suitable scope.
Control sample 1 formula in the present invention is:
A kind of composite clean liquid fuel:
Methyl alcohol 60%, water 30%, ethanol 9.2%, acetic acid 0.23%, sodium oxide 0.35%, ammoniacal liquor 0.10%, xylidene(s) 0.05%, SODIUMNITRATE 0.05%, two cyclic diolefine iron 0.02%.
Control sample 2 formulas are:
A kind of alcohol radical liquid fuel:
Each component parts by volume is: 75 parts of methyl alcohol, and 20 parts, aromatic hydrocarbons, 3 parts of many carbon of high heating value hydrocarbon, acetone mutual solvent is 4% of said components cumulative volume.
Above-mentioned control sample 1 and control sample 2 all can be by buying on market.
Claims (6)
1. a clean fuel liquid, it is characterized in that, formed by the component of following weight per-cent: methyl alcohol 50 ~ 75%, useless alcohol 10 ~ 15%, water 13 ~ 35%, toluene 0.5 ~ 1%, normal hexane 0.05 ~ 0.1%, ammonium nitrate 0.05 ~ 0.1%, glycerol 0.5 ~ 1.5%, nitric acid 0.1 ~ 0.5%, acetone 0.5 ~ 1.5%.
2. a kind of clean fuel liquid according to claim 1, it is characterized in that, each composition weight percentage composition is: methyl alcohol 55 ~ 70%, useless alcohol 11 ~ 14%, water 16 ~ 32%, toluene 0.6 ~ 0.9%, normal hexane 0.06 ~ 0.09%, ammonium nitrate 0.06 ~ 0.09%, glycerol 0.7 ~ 1.3%, nitric acid 0.18 ~ 0.42%, acetone 0.7 ~ 1.3%.
3. a kind of clean fuel liquid according to claim 1, it is characterized in that, each composition weight percentage composition is: methyl alcohol 60 ~ 65%, useless alcohol 12 ~ 13%, water 19 ~ 29%, toluene 0.7 ~ 0.8%, normal hexane 0.07 ~ 0.08%, ammonium nitrate 0.07 ~ 0.08%, glycerol 0.9 ~ 1.1%, nitric acid 0.26 ~ 0.34%, acetone 0.9 ~ 1.1%.
4. the preparation method of a clean fuel liquid claimed in claim 1, it is characterized in that: 0.05 ~ 0.1% ammonium nitrate is added to stirring and dissolving in 13 ~ 35% water, then add 0.5 ~ 1.5% glycerol to continue again stirring and dissolving, finally add 0.1 ~ 0.5% nitric acid, leave standstill the first solution after 10 ~ 25 minutes; 0.5 ~ 1% toluene, 0.05 ~ 0.1% normal hexane are added successively in 0.5 ~ 1.5% acetone and stir to obtain the second solution; Take 10 ~ 15% useless alcohol as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into respectively successively in 50 ~ 75% the methyl alcohol for preparing component, stirred and get final product to obtain finished product.
5. the preparation method of a clean fuel liquid claimed in claim 2, it is characterized in that: 0.06 ~ 0.09% ammonium nitrate is added to stirring and dissolving in 16 ~ 32% water, then add 0.7 ~ 1.3% glycerol to continue again stirring and dissolving, finally add 0.18 ~ 0.42% nitric acid, leave standstill the first solution after 10 ~ 25 minutes; 0.6 ~ 0.9% toluene, 0.06 ~ 0.09% normal hexane are added successively in 0.7 ~ 1.3% acetone and stir to obtain the second solution; Take 11 ~ 14% useless alcohol as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into respectively successively in 55 ~ 70% the methyl alcohol for preparing component, stirred and get final product to obtain finished product.
6. the preparation method of a clean fuel liquid claimed in claim 3, it is characterized in that: 0.07 ~ 0.08% ammonium nitrate is added to stirring and dissolving in 19 ~ 29% water, then add 0.9 ~ 1.1% glycerol to continue again stirring and dissolving, finally add 0.26 ~ 0.34% nitric acid, leave standstill the first solution after 10 ~ 25 minutes; 0.7 ~ 0.8% toluene, 0.07 ~ 0.08% normal hexane are added successively in 0.9 ~ 1.1% acetone and stir to obtain the second solution; Take 12 ~ 13% useless alcohol as the 3rd solution; The 3rd solution, the second solution and the first solution are poured into respectively successively in 60 ~ 65% the methyl alcohol for preparing component, stirred and get final product to obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410418091.0A CN104130808B (en) | 2014-08-22 | 2014-08-22 | Clean liquid fuel and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410418091.0A CN104130808B (en) | 2014-08-22 | 2014-08-22 | Clean liquid fuel and preparation method thereof |
Publications (2)
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| CN104130808A true CN104130808A (en) | 2014-11-05 |
| CN104130808B CN104130808B (en) | 2015-06-17 |
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| CN201410418091.0A Expired - Fee Related CN104130808B (en) | 2014-08-22 | 2014-08-22 | Clean liquid fuel and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109971517A (en) * | 2018-12-24 | 2019-07-05 | 江苏盈天化学有限公司 | A kind of alcohol-based fuel and preparation method thereof using useless alcohol azeotropic mixture composition |
| CN112159689A (en) * | 2020-09-09 | 2021-01-01 | 重庆耐燃新能源科技有限公司 | Synthetic environment-friendly clean liquid fuel and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090595A (en) * | 1993-02-05 | 1994-08-10 | 陈志豪 | Industrial fuel |
| CN100545246C (en) * | 2007-02-14 | 2009-09-30 | 何光临 | Molecule and symphysis thing liquid fuel and additive thereof |
-
2014
- 2014-08-22 CN CN201410418091.0A patent/CN104130808B/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109971517A (en) * | 2018-12-24 | 2019-07-05 | 江苏盈天化学有限公司 | A kind of alcohol-based fuel and preparation method thereof using useless alcohol azeotropic mixture composition |
| CN112159689A (en) * | 2020-09-09 | 2021-01-01 | 重庆耐燃新能源科技有限公司 | Synthetic environment-friendly clean liquid fuel and preparation method thereof |
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| Publication number | Publication date |
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| CN104130808B (en) | 2015-06-17 |
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Effective date of registration: 20161128 Address after: 518000, Guangdong, Longgang District, Henggang street, Longgang Avenue (Henggang section), 2999 Lin Heng Plaza Plaza, No. 201, No. 1, Shenzhen Patentee after: Shenzhen Heng Heng Xin Energy Co., Ltd. Address before: 518000, Shenzhen, Guangdong province Luohu District mud Village Hung Wing Building No. 2303 Patentee before: Li Guohuan |
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Effective date of registration: 20170816 Address after: 518000 Guangdong city of Shenzhen province Futian District Jingtian No. 1 North Street in a natural area of D2801 Patentee after: Li Guohuan Address before: 518000, Guangdong, Longgang District, Henggang street, Longgang Avenue (Henggang section), 2999 Lin Heng Plaza Plaza, No. 201, No. 1, Shenzhen Patentee before: Shenzhen Heng Heng Xin Energy Co., Ltd. |
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| TR01 | Transfer of patent right |
Effective date of registration: 20171019 Address after: 518000, No. sixth, No. 602, Fuhua square, six deep street, Henggang street, Longgang District, Shenzhen, Guangdong Patentee after: Shenzhen Heng Heng Xin Energy Co., Ltd. Address before: 518000 Guangdong city of Shenzhen province Futian District Jingtian No. 1 North Street in a natural area of D2801 Patentee before: Li Guohuan |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20150617 Termination date: 20180822 |