CN114106920A - Lubricating oil for automobile - Google Patents

Lubricating oil for automobile Download PDF

Info

Publication number
CN114106920A
CN114106920A CN202111490161.XA CN202111490161A CN114106920A CN 114106920 A CN114106920 A CN 114106920A CN 202111490161 A CN202111490161 A CN 202111490161A CN 114106920 A CN114106920 A CN 114106920A
Authority
CN
China
Prior art keywords
lubricating oil
antioxidant
oil according
organic molybdenum
automobile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111490161.XA
Other languages
Chinese (zh)
Inventor
杨占辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongying Dongbin Petroleum Technology Service Co ltd
Original Assignee
Dongying Dongbin Petroleum Technology Service Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongying Dongbin Petroleum Technology Service Co ltd filed Critical Dongying Dongbin Petroleum Technology Service Co ltd
Priority to CN202111490161.XA priority Critical patent/CN114106920A/en
Publication of CN114106920A publication Critical patent/CN114106920A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants

Abstract

The invention discloses lubricating oil for automobiles, which relates to the technical field of lubricating oil and comprises the following components in percentage by mass: and (3) anti-foaming agent: 0.1% -3%; organic molybdenum: 1% -5%; compound antioxidant: 0.1% -5%; polyisobutylene succinimide: 2% -4%; detergent: 1% -5%; viscosity index improver: 1% -5%; borate salt: 0.1% -2%; base oil: and (4) the balance. The lubricating oil for the automobile has excellent oxidation resistance and wear resistance, and better high temperature resistance and viscosity-temperature performance. Meanwhile, the addition of the organic molybdenum can effectively replace part of phosphorus-containing additives, and the method has the advantage of environmental protection.

Description

Lubricating oil for automobile
Technical Field
The invention relates to the technical field of lubricating oil, in particular to lubricating oil for an automobile.
Background
The friction causes appearance phenomena such as high temperature, high pressure, noise, abrasion and the like, wherein the most harmful phenomenon is abrasion, and the abrasion directly influences the running condition and the service life of mechanical equipment. In order to alleviate the mechanical friction phenomenon, a lubricating oil technology, a magnetic suspension technology and the like are developed successively.
The lubricating oil can effectively slow down the friction phenomenon, and has the functions of cooling, sealing, isolating and the like. With the development of the automobile industry and the coming of stricter environmental protection laws and regulations, adding clean and efficient automobile lubricating oil becomes an important means for improving the automobile performance and reducing the environmental pollution.
Automobile parts have the characteristics of precision, complexity and large quantity. The combination of the harsh working environment puts higher requirements on the performance of the lubricating oil for the vehicle.
In order to meet the performance requirements of the lubricating oil for vehicles on oxidation resistance, viscosity-temperature property, low-temperature fluidity, extreme pressure wear resistance and the like, a plurality of additives are widely added into the base oil.
However, it is still a technical challenge to reasonably formulate additives to fully and uniformly meet the requirements of the automotive lubricating oil on oxidation resistance, viscosity-temperature property, low-temperature fluidity, extreme pressure wear resistance and the like. Since the automotive lubricating oil is exposed to air for a long time during operation and is subjected to abrasion pressure, it is a development direction to have more excellent oxidation resistance and extreme pressure wear resistance.
Disclosure of Invention
The invention provides lubricating oil for automobiles, which comprises the following components in percentage by mass: and (3) anti-foaming agent: 0.1% -3%; organic molybdenum: 1% -5%; compound antioxidant: 0.1% -5%; polyisobutylene succinimide: 2% -4%; detergent: 1% -5%; viscosity index improver: 1% -5%; borate salt: 0.1% -2%; base oil: and (4) the balance.
The invention is further provided with: the compound antioxidant is compounded by anybase diphenylamine, a phenolic ester antioxidant and a phenolic ashless antioxidant.
The invention is further provided with: the compounding proportion of the aminodiphenylamine, the phenolic ester antioxidant and the phenolic ashless antioxidant is as follows: according to the mass percentage of 3: 1: 1.
the invention is further provided with: the detergent is one or more of magnesium alkyl salicylate, calcium alkyl salicylate and magnesium sulfurized alkyl salicylate.
The invention is further provided with: the organic molybdenum is sulfurized molybdenum oxo dialkyl dithiocarbamate.
The invention is further provided with: the antifoaming agent is methacrylate.
The invention is further provided with: the viscosity index improver is a polyalphaolefin.
The beneficial technical effects of the invention are as follows:
the lubricating oil for the automobile has excellent oxidation resistance and wear resistance, and better high temperature resistance and viscosity-temperature performance. Meanwhile, the addition of the organic molybdenum can effectively replace part of phosphorus-containing additives, and the method has the advantage of environmental protection.
Detailed Description
Preferred embodiments of the present invention are described below. It should be understood by those skilled in the art that these embodiments are only for explaining the technical principle of the present invention, and are not intended to limit the scope of the present invention.
The invention provides lubricating oil for automobiles, which comprises the following components in percentage by mass: and (3) anti-foaming agent: 0.1% -3%; organic molybdenum: 1% -5%; compound antioxidant: 0.1% -5%; polyisobutylene succinimide: 2% -4%; detergent: 1% -5%; viscosity index improver: 1% -5%; borate salt: 0.1% -2%; base oil: and (4) the balance.
The compound antioxidant is compounded by anybase diphenylamine, phenolic ester type antioxidant and phenolic ashless antioxidant. The composite antioxidant has the following effects:
(1) an anyldiphenylamine: the high-temperature antioxidant has excellent high-temperature antioxidant performance, obvious effect of inhibiting the late oxidation of oil products, good compatibility and obvious improvement on the composite use effect of the high-temperature antioxidant and the phenol ester antioxidant;
(2) ester phenol type antioxidant: the auxiliary antioxidant with strong compatibility can inhibit high-temperature oxidation of oil products and formation of oil sludge, improve the compatibility and compatibility among other detergents, dispersants and antioxidants and enhance the synergistic effect;
(3) phenolic ashless antioxidants: the high-temperature antioxidant has excellent high-temperature antioxidant performance, can control the formation of oil sludge, is used in combination with other assistants such as ZDDP and amine antioxidants, and has a coordination effect.
The compounding proportion of the arbitrary diphenylamine, the phenolic ester antioxidant and the phenolic ashless antioxidant is as follows: according to the mass percentage of 3: 1: 1.
the detergent is one or more of magnesium alkyl salicylate, calcium alkyl salicylate and magnesium sulfurized alkyl salicylate.
The organic molybdenum is sulfurized molybdenum oxo dialkyl dithiocarbamate.
The antifoaming agent is methacrylate.
The viscosity index improver is a polyalphaolefin.
Example 1
The embodiment discloses lubricating oil for automobiles, which comprises the following components in percentage by mass: 94.7% of base oil, 0.1% of anti-foaming agent, 1% of organic molybdenum, 0.1% of composite antioxidant, 2% of polyisobutylene succinimide, 1% of detergent, 1% of viscosity index improver and 0.1% of borate. The automobile lubricating oil with the composition has excellent wear resistance and oxidation resistance, but has unbalanced overall performance, higher cost and low overall cost-effectiveness ratio.
Example 2
The embodiment discloses lubricating oil for automobiles, which comprises the following components in percentage by mass: 71% of base oil; 3% of an antifoaming agent; 5% of organic molybdenum; 5% of a composite antioxidant; polyisobutylene succinimide 4%; 5% of a detergent; 5% of viscosity index improver; and 2% of borate. The automobile lubricating oil with the composition has the advantages of good performance, overall balance, moderate cost and high overall efficiency-cost ratio.
Example 3
The embodiment discloses lubricating oil for automobiles, which comprises the following components in percentage by mass: 84.85% of base oil, 1.55% of anti-foaming agent, 2.55% of organic molybdenum, 3% of composite antioxidant, 1% of polyisobutylene succinimide, 3% of detergent, 3% of viscosity index improver and 1.05% of borate. The performance of the automobile lubricating oil with the composition is low, and the overall efficiency-cost ratio is low.
While the invention has been described with reference to a preferred embodiment, various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention, and particularly, features shown in the various embodiments may be combined in any suitable manner without departing from the scope of the invention. It is intended that the invention not be limited to the particular embodiments disclosed, but that the invention will include all embodiments falling within the scope of the appended claims.

Claims (7)

1. A lubricating oil for automobiles, characterized in that: comprises the following components in percentage by mass: and (3) anti-foaming agent: 0.1% -3%; organic molybdenum: 1% -5%; compound antioxidant: 0.1% -5%; polyisobutylene succinimide: 2% -4%; detergent: 1% -5%; viscosity index improver: 1% -5%; borate salt: 0.1% -2%; base oil: and (4) the balance.
2. The automotive lubricating oil according to claim 1, characterized in that: the compound antioxidant is compounded by anybase diphenylamine, a phenolic ester antioxidant and a phenolic ashless antioxidant.
3. The automotive lubricating oil according to claim 2, characterized in that: the compounding proportion of the aminodiphenylamine, the phenolic ester antioxidant and the phenolic ashless antioxidant is as follows: according to the mass percentage of 3: 1: 1.
4. the automotive lubricating oil according to claim 1, characterized in that: the detergent is one or more of magnesium alkyl salicylate, calcium alkyl salicylate and magnesium sulfurized alkyl salicylate.
5. The automotive lubricating oil according to claim 1, characterized in that: the organic molybdenum is sulfurized molybdenum oxo dialkyl dithiocarbamate.
6. The automotive lubricating oil according to claim 1, characterized in that: the antifoaming agent is methacrylate.
7. The automotive lubricating oil according to claim 1, characterized in that: the viscosity index improver is a polyalphaolefin.
CN202111490161.XA 2021-12-08 2021-12-08 Lubricating oil for automobile Pending CN114106920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111490161.XA CN114106920A (en) 2021-12-08 2021-12-08 Lubricating oil for automobile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111490161.XA CN114106920A (en) 2021-12-08 2021-12-08 Lubricating oil for automobile

Publications (1)

Publication Number Publication Date
CN114106920A true CN114106920A (en) 2022-03-01

Family

ID=80367413

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111490161.XA Pending CN114106920A (en) 2021-12-08 2021-12-08 Lubricating oil for automobile

Country Status (1)

Country Link
CN (1) CN114106920A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005041998A (en) * 2003-07-22 2005-02-17 Nippon Oil Corp Internal combustion engine lubricating oil composition
US20100152072A1 (en) * 2008-12-17 2010-06-17 Chevron Oronite Company Llc Lubricating oil compositions
CN102690706A (en) * 2011-03-24 2012-09-26 中国石油化工股份有限公司 Lubricant composition for methanol engine
CN102690711A (en) * 2011-03-24 2012-09-26 中国石油化工股份有限公司 Lubricant composition for gasoline engine
CN106318560A (en) * 2015-06-17 2017-01-11 上海福岛化工科技发展有限公司 Low-phosphor wear-resistant gasoline engine lubricating oil composition
CN107760419A (en) * 2016-08-19 2018-03-06 江西福安路润滑材料有限公司 Lubricant composition for gasoline engine and preparation method thereof
CN108913302A (en) * 2018-06-25 2018-11-30 合肥欧仕嘉机电设备有限公司 A kind of cylinder oil and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005041998A (en) * 2003-07-22 2005-02-17 Nippon Oil Corp Internal combustion engine lubricating oil composition
US20100152072A1 (en) * 2008-12-17 2010-06-17 Chevron Oronite Company Llc Lubricating oil compositions
CN102690706A (en) * 2011-03-24 2012-09-26 中国石油化工股份有限公司 Lubricant composition for methanol engine
CN102690711A (en) * 2011-03-24 2012-09-26 中国石油化工股份有限公司 Lubricant composition for gasoline engine
CN106318560A (en) * 2015-06-17 2017-01-11 上海福岛化工科技发展有限公司 Low-phosphor wear-resistant gasoline engine lubricating oil composition
CN107760419A (en) * 2016-08-19 2018-03-06 江西福安路润滑材料有限公司 Lubricant composition for gasoline engine and preparation method thereof
CN108913302A (en) * 2018-06-25 2018-11-30 合肥欧仕嘉机电设备有限公司 A kind of cylinder oil and preparation method thereof

Similar Documents

Publication Publication Date Title
CN107312598B (en) Low-temperature overweight load synthetic gear oil
JP5703309B2 (en) Additive composition for engine oil
CN103509637B (en) Automobile automatic transmission liquid composition with excellent anti-wear property
JPH0931483A (en) Lubricant composition
CN110408461B (en) Low-smoke long-life environment-friendly strong-shrinkage forming oil and preparation method thereof
CN107353975A (en) A kind of lubricating oil composition for diesel engine composition
CN111394159A (en) Economical gasoline engine oil SN5W/30 and preparation method thereof
EP0304011B1 (en) Lubricating oil composition for internal combustion engine
CN112011387A (en) SN-grade gasoline and engine oil complexing agent and preparation method thereof
JP2016506996A (en) Lubricant compositions based on amine compounds
JPH06336593A (en) Lubricant composition
CN114106920A (en) Lubricating oil for automobile
US20150225665A1 (en) Ashless type engine oil composition
CN101629122A (en) Initial assembling oil composition of diesel engine
CN100460490C (en) Lubricating oil oxidation stability additive composition and preparation method thereof
US4032462A (en) Lubricating oil additive composition
CN114106919A (en) Cleaning lubricating oil
CN113512460A (en) Anti-wear clean type vehicle lubricating oil and preparation process thereof
CN108203615B (en) Low-ash lubricating oil composition
KR100346352B1 (en) Lubricant oil composition
CN110591801A (en) Compressor lubricating oil composition and preparation method thereof
JPH07331269A (en) Lubricating oil composition
CN108570347A (en) A kind of lubricating oil composition for diesel engine composition
JPH06220475A (en) Gear oil composition
CN110484332B (en) Hydraulic oil composite additive, preparation method thereof and hydraulic oil

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220301

RJ01 Rejection of invention patent application after publication