CN114106918A - 开放式润滑剂组合物 - Google Patents
开放式润滑剂组合物 Download PDFInfo
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- CN114106918A CN114106918A CN202111436373.XA CN202111436373A CN114106918A CN 114106918 A CN114106918 A CN 114106918A CN 202111436373 A CN202111436373 A CN 202111436373A CN 114106918 A CN114106918 A CN 114106918A
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- additive
- base oil
- lubricant composition
- stabilizer
- ester base
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- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000000314 lubricant Substances 0.000 title claims abstract description 28
- 239000000654 additive Substances 0.000 claims abstract description 64
- 230000000996 additive effect Effects 0.000 claims abstract description 59
- 239000002199 base oil Substances 0.000 claims abstract description 35
- 150000002148 esters Chemical class 0.000 claims abstract description 34
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 27
- 239000002270 dispersing agent Substances 0.000 claims abstract description 27
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 27
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 27
- 239000003381 stabilizer Substances 0.000 claims abstract description 27
- 230000001050 lubricating effect Effects 0.000 claims abstract description 25
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 14
- 150000002763 monocarboxylic acids Chemical class 0.000 claims abstract description 13
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 13
- 238000005886 esterification reaction Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 11
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 10
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 5
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 5
- 239000005643 Pelargonic acid Substances 0.000 claims description 5
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 5
- -1 amine phosphate Chemical class 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 239000000600 sorbitol Substances 0.000 claims description 5
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 5
- 229940005605 valeric acid Drugs 0.000 claims description 5
- 239000000811 xylitol Substances 0.000 claims description 5
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 5
- 235000010447 xylitol Nutrition 0.000 claims description 5
- 229960002675 xylitol Drugs 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 235000011148 calcium chloride Nutrition 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 4
- 239000010426 asphalt Substances 0.000 abstract description 4
- 239000000460 chlorine Substances 0.000 abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002574 poison Substances 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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Abstract
本发明提供开放式润滑剂组合物，涉及润滑剂技术领域，所述开放式润滑剂组合物的制备原料是由酯类基础油、润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂构成。本发明，通过多元醇和饱和一元羧酸的酯化反应，形成酯类基础油，从而使成品的组合物为非溶剂、非沥青型产品，不含重金属和氯等有害元素，且基础油可降解，减少操作毒害，然后向酯类基础油内添加润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂，润滑性添加剂能够使成品的组合物在齿轮表面形成一层油膜，且粘度较大，能够有效的防止油膜不足断开的现象，从而达到优异的减磨、抗磨、极压承载性能，能够有效的减缓齿轮损伤，同时防锈添加剂能够使组合物具有良好的防锈性能，突出的抗水、抗剪切能力，使其综合性能优良，以便达到更好的使用效果。
Description
技术领域
本发明涉及润滑剂技术领域，尤其涉及开放式润滑剂组合物。
背景技术
目前市场上用于开放式大齿轮的润滑剂有很多种，而多数是含固体填料的，在使用过程中容易出现油膜不足、齿面拉伤、磨损、点蚀、运行噪音等问题，且一旦齿面发生拉伤，运行异响，平复齿面需要巨大费用，同时导致的停工造成巨大损失，难以达到较好的使用效果。
发明内容
本发明的目的是为了解决现有技术中存在的缺点，而提出的开放式润滑剂组合物。
为了实现上述目的，本发明采用了如下技术方案：开放式润滑剂组合物，所述开放式润滑剂组合物的制备原料是由酯类基础油、润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂构成，且各材料组成成分如下：酯类基础油60-85％，润滑性添加剂7-15％，防锈添加剂5-15％，稳定剂1-3％，羧甲基纤维素钠1-4％，分散剂1-3％。
为了达到润滑的效果，本发明的改进有，所述润滑性添加剂为磷酸酯与磷酸胺的等比例混合物。
为了达到防锈的效果，本发明的改进有，所述防锈添加剂为石油磺酸钙、石油磺酸钠和石油磺酸钡的一种或多种任意比例混合物。
为了使成品组合物能够保存更长时间，本发明的改进有，所述稳定剂为硬脂酸钙、羧甲基纤维素钠、氯化钙或氯化铵中的一种或多种任意比例混合物。
为了使原料能够充分混合，本发明的改进有，所述分散剂为脂肪醇聚氧乙烯醚、多元醇单脂肪酸酯、烷基醇酰胺中的一种。
为了达到不同效果，本发明的改进有，各材料组成成分如下：酯类基础油75％，润滑性添加剂10％，防锈添加剂8.5％，稳定剂1.3％，羧甲基纤维素钠2.7％，分散剂2.5％。
为了达到不同效果，本发明的改进有，各材料组成成分如下：酯类基础油70％，润滑性添加剂13％，防锈添加剂10％，稳定剂1.8％，羧甲基纤维素钠3.2％，分散剂2％。
为了达到不同效果，本发明的改进有，各材料组成成分如下：酯类基础油65％，润滑性添加剂15％，防锈添加剂13.5％，稳定剂1.2％，羧甲基纤维素钠3.8％，分散剂1.5％。
所述开放式润滑剂组合物的制备方法，包括以下步骤：
S1：将多元醇和饱和一元羧酸按体积比为1:4-6加入到反应釜中，进行酯化反应，反应温度为180-260℃，反应时间为5-8小时，在反应过程中，对反应釜进行抽真空处理，使反应釜的真空度为20-50pa，从而制得酯类基础油备用；
S2：然后将S1中得到酯类基础油与润滑性添加剂和分散剂按比例一同倒入调合釜内，然后将调合釜温度调节至110-125℃，进行加热搅拌，搅拌转速为360-480转每分钟，搅拌时间为50-60分钟，从而得到初始混合物；
S3：将调合釜的温度调节至60-80℃，然后加入防锈添加剂、稳定剂与羧甲基纤维素钠，进行搅拌，搅拌转速为240-300转每分钟，搅拌时间为30-40分钟，从而得到成品组合物；
S4：对S3中得到的成品组合物进行检测，组合物在40℃的运动粘度需要在15000-17000mm2/s，且闪点≧300℃，检测合格后，包装入库即可。
为了制备酯类基础油，本发明的改进有，所述步骤S1中的多元醇为甘油、三羟甲基乙烷、季戊四醇、木糖醇、山梨醇中的一种，饱和一元羧酸为戊酸、己酸、壬酸中的一种。
与现有技术相比，本发明的优点和积极效果在于，
本发明中，通过多元醇和饱和一元羧酸的酯化反应，形成酯类基础油，从而使成品的组合物为非溶剂、非沥青型产品，不含重金属和氯等有害元素，且基础油可降解，减少操作毒害，然后向酯类基础油内添加润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂，润滑性添加剂能够使成品的组合物在齿轮表面形成一层油膜，且粘度较大，能够有效的防止油膜不足断开的现象，从而达到优异的减磨、抗磨、极压承载性能，能为超重负荷工作的齿轮啮合部提供可靠的润滑性能，能够有效的减缓齿轮损伤，且不含石墨等固体添加剂，形成透明油膜可在线观测齿轮的磨损状态，检修时便于清理齿面，同时成品组合物具有高粘度指数，具有良好的泵送性和粘度保持性，低温流动性好，便于齿轮散热，同时防锈添加剂能够使组合物具有良好的防锈性能，突出的抗水、抗剪切能力，使其综合性能优良，以便达到更好的使用效果。
附图说明
图1为本发明提出开放式润滑剂组合物的流程图。
具体实施方式
为了能够更清楚地理解本发明的上述目的、特征和优点，下面结合附图和实施例对本发明做进一步说明。需要说明的是，在不冲突的情况下，本申请的实施例及实施例中的特征可以相互组合。
在本发明的描述中，需要理解的是，术语“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系，仅是为了便于描述本发明和简化描述，而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作，因此不能理解为对本发明的限制。此外，在本发明的描述中，“多个”的含义是两个或两个以上，除非另有明确具体的限定。
请参阅图1，本发明提供开放式润滑剂组合物，开放式润滑剂组合物的制备原料是由酯类基础油、润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂构成，且各材料组成成分如下：酯类基础油60-85％，润滑性添加剂7-15％，防锈添加剂5-15％，稳定剂1-3％，羧甲基纤维素钠1-4％，分散剂1-3％，酯类润滑油由于具有粘温特性良好、抗氧化能力强、优越的润滑性和可生物降解性能，能够使成品的组合物为非溶剂、非沥青型产品，不含重金属和氯等有害元素，且基础油可降解，减少操作毒害，同时且粘度较大，能够有效的防止油膜不足断开的现象，从而达到优异的减磨、抗磨、极压承载性能。
润滑性添加剂为磷酸酯与磷酸胺的等比例混合物，润滑性添加剂能够使成品的组合物在齿轮表面形成一层油膜，从而达到优异的减磨、抗磨、极压承载性能，能为超重负荷工作的齿轮啮合部提供可靠的润滑性能，能够有效的减缓齿轮损伤，防锈添加剂为石油磺酸钙、石油磺酸钠和石油磺酸钡的一种或多种任意比例混合物，防锈添加剂能够使组合物具有良好的防锈性能，突出的抗水、抗剪切能力，使其综合性能优良，以便达到更好的使用效果，稳定剂为硬脂酸钙、羧甲基纤维素钠、氯化钙或氯化铵中的一种或多种任意比例混合物，分散剂为脂肪醇聚氧乙烯醚、多元醇单脂肪酸酯、烷基醇酰胺中的一种。
实施例一
各材料组成成分如下：酯类基础油75％，润滑性添加剂10％，防锈添加剂8.5％，稳定剂1.3％，羧甲基纤维素钠2.7％，分散剂2.5％。
开放式润滑剂组合物的制备方法，包括以下步骤：
S1：将多元醇和饱和一元羧酸按体积比为1:5加入到反应釜中，进行酯化反应，反应温度为240℃，反应时间为6小时，在反应过程中，对反应釜进行抽真空处理，使反应釜的真空度为40pa，从而制得酯类基础油备用；
S2：然后将S1中得到酯类基础油与润滑性添加剂和分散剂按比例一同倒入调合釜内，然后将调合釜温度调节至125℃，进行加热搅拌，搅拌转速为480转每分钟，搅拌时间为60分钟，从而得到初始混合物；
S3：将调合釜的温度调节至75℃，然后加入防锈添加剂、稳定剂与羧甲基纤维素钠，进行搅拌，搅拌转速为280转每分钟，搅拌时间为40分钟，从而得到成品组合物；
S4：对S3中得到的成品组合物进行检测，组合物在40℃的运动粘度需要在15000-17000mm2/s，且闪点≧300℃，检测合格后，包装入库即可。
步骤S1中的多元醇为甘油、三羟甲基乙烷、季戊四醇、木糖醇、山梨醇中的一种，饱和一元羧酸为戊酸、己酸、壬酸中的一种。
实施例二
各材料组成成分如下：酯类基础油70％，润滑性添加剂13％，防锈添加剂10％，稳定剂1.8％，羧甲基纤维素钠3.2％，分散剂2％。
开放式润滑剂组合物的制备方法，包括以下步骤：
S1：将多元醇和饱和一元羧酸按体积比为1:5加入到反应釜中，进行酯化反应，反应温度为240℃，反应时间为6小时，在反应过程中，对反应釜进行抽真空处理，使反应釜的真空度为40pa，从而制得酯类基础油备用；
S2：然后将S1中得到酯类基础油与润滑性添加剂和分散剂按比例一同倒入调合釜内，然后将调合釜温度调节至120℃，进行加热搅拌，搅拌转速为420转每分钟，搅拌时间为58分钟，从而得到初始混合物；
S3：将调合釜的温度调节至70℃，然后加入防锈添加剂、稳定剂与羧甲基纤维素钠，进行搅拌，搅拌转速为260转每分钟，搅拌时间为38分钟，从而得到成品组合物；
S4：对S3中得到的成品组合物进行检测，组合物在40℃的运动粘度需要在15000-17000mm2/s，且闪点≧300℃，检测合格后，包装入库即可。
步骤S1中的多元醇为甘油、三羟甲基乙烷、季戊四醇、木糖醇、山梨醇中的一种，饱和一元羧酸为戊酸、己酸、壬酸中的一种。
实施例三
各材料组成成分如下：酯类基础油65％，润滑性添加剂15％，防锈添加剂13.5％，稳定剂1.2％，羧甲基纤维素钠3.8％，分散剂1.5％。
开放式润滑剂组合物的制备方法，包括以下步骤：
S1：将多元醇和饱和一元羧酸按体积比为1:5加入到反应釜中，进行酯化反应，反应温度为240℃，反应时间为6小时，在反应过程中，对反应釜进行抽真空处理，使反应釜的真空度为40pa，从而制得酯类基础油备用；
S2：然后将S1中得到酯类基础油与润滑性添加剂和分散剂按比例一同倒入调合釜内，然后将调合釜温度调节至115℃，进行加热搅拌，搅拌转速为420转每分钟，搅拌时间为54分钟，从而得到初始混合物；
S3：将调合釜的温度调节至68℃，然后加入防锈添加剂、稳定剂与羧甲基纤维素钠，进行搅拌，搅拌转速为240转每分钟，搅拌时间为36分钟，从而得到成品组合物；
S4：对S3中得到的成品组合物进行检测，组合物在40℃的运动粘度需要在15000-17000mm2/s，且闪点≧300℃，检测合格后，包装入库即可。
步骤S1中的多元醇为甘油、三羟甲基乙烷、季戊四醇、木糖醇、山梨醇中的一种，饱和一元羧酸为戊酸、己酸、壬酸中的一种。
本发明，通过多元醇和饱和一元羧酸的酯化反应，形成酯类基础油，从而使成品的组合物为非溶剂、非沥青型产品，不含重金属和氯等有害元素，且基础油可降解，减少操作毒害，然后向酯类基础油内添加润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂，润滑性添加剂能够使成品的组合物在齿轮表面形成一层油膜，且粘度较大，能够有效的防止油膜不足断开的现象，从而达到优异的减磨、抗磨、极压承载性能，能为超重负荷工作的齿轮啮合部提供可靠的润滑性能，能够有效的减缓齿轮损伤，且不含石墨等固体添加剂，形成透明油膜可在线观测齿轮的磨损状态，检修时便于清理齿面，同时成品组合物具有高粘度指数，具有良好的泵送性和粘度保持性，低温流动性好，便于齿轮散热，同时防锈添加剂能够使组合物具有良好的防锈性能，突出的抗水、抗剪切能力，使其综合性能优良，以便达到更好的使用效果。
以上，仅是本发明的较佳实施例而已，并非是对本发明作其它形式的限制，任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或改型为等同变化的等效实施例应用于其它领域，但是凡是未脱离本发明技术方案内容，依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与改型，仍属于本发明技术方案的保护范围。
Claims (10)
1.开放式润滑剂组合物，其特征在于：所述开放式润滑剂组合物的制备原料是由酯类基础油、润滑性添加剂、防锈添加剂、稳定剂、羧甲基纤维素钠和分散剂构成，且各材料组成成分如下：酯类基础油60-85％，润滑性添加剂7-15％，防锈添加剂5-15％，稳定剂1-3％，羧甲基纤维素钠1-4％，分散剂1-3％。
2.根据权利要求1所述的开放式润滑剂组合物，其特征在于：所述润滑性添加剂为磷酸酯与磷酸胺的等比例混合物。
3.根据权利要求1所述的开放式润滑剂组合物，其特征在于：所述防锈添加剂为石油磺酸钙、石油磺酸钠和石油磺酸钡的一种或多种任意比例混合物。
4.根据权利要求1所述的开放式润滑剂组合物，其特征在于：所述稳定剂为硬脂酸钙、羧甲基纤维素钠、氯化钙或氯化铵中的一种或多种任意比例混合物。
5.根据权利要求1所述的开放式润滑剂组合物，其特征在于：所述分散剂为脂肪醇聚氧乙烯醚、多元醇单脂肪酸酯、烷基醇酰胺中的一种。
6.根据权利要求1所述的开放式润滑剂组合物，其特征在于：各材料组成成分如下：酯类基础油75％，润滑性添加剂10％，防锈添加剂8.5％，稳定剂1.3％，羧甲基纤维素钠2.7％，分散剂2.5％。
7.根据权利要求1所述的开放式润滑剂组合物，其特征在于：各材料组成成分如下：酯类基础油70％，润滑性添加剂13％，防锈添加剂10％，稳定剂1.8％，羧甲基纤维素钠3.2％，分散剂2％。
8.根据权利要求1所述的开放式润滑剂组合物，其特征在于：各材料组成成分如下：酯类基础油65％，润滑性添加剂15％，防锈添加剂13.5％，稳定剂1.2％，羧甲基纤维素钠3.8％，分散剂1.5％。
9.根据权利要求1所述的开放式润滑剂组合物的制备方法，其特征在于：包括以下步骤：
S1：将多元醇和饱和一元羧酸按体积比为1:4-6加入到反应釜中，进行酯化反应，反应温度为180-260℃，反应时间为5-8小时，在反应过程中，对反应釜进行抽真空处理，使反应釜的真空度为20-50pa，从而制得酯类基础油备用；
S2：然后将S1中得到酯类基础油与润滑性添加剂和分散剂按比例一同倒入调合釜内，然后将调合釜温度调节至110-125℃，进行加热搅拌，搅拌转速为360-480转每分钟，搅拌时间为50-60分钟，从而得到初始混合物；
S3：将调合釜的温度调节至60-80℃，然后加入防锈添加剂、稳定剂与羧甲基纤维素钠，进行搅拌，搅拌转速为240-300转每分钟，搅拌时间为30-40分钟，从而得到成品组合物；
S4：对S3中得到的成品组合物进行检测，组合物在40℃的运动粘度需要在15000-17000mm2/s，且闪点≧300℃，检测合格后，包装入库即可。
10.根据权利要求9所述的开放式润滑剂组合物的制备方法，其特征在于：所述步骤S1中的多元醇为甘油、三羟甲基乙烷、季戊四醇、木糖醇、山梨醇中的一种，饱和一元羧酸为戊酸、己酸、壬酸中的一种。
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212603A (zh) * | 2014-08-29 | 2014-12-17 | 青岛特瑞信电子科技有限公司 | 一种齿轮油 |
| CN104450094A (zh) * | 2014-12-09 | 2015-03-25 | 芜湖市鸿坤汽车零部件有限公司 | 一种用于火车轮毂的硬膜防锈油 |
| CN105950267A (zh) * | 2016-05-23 | 2016-09-21 | 中国铁道科学研究院金属及化学研究所 | 一种环保型轮轨润滑脂及其制备方法 |
| CN106701284A (zh) * | 2016-12-23 | 2017-05-24 | 上海禾泰特种润滑科技股份有限公司 | 开式齿轮油组合物及其制备方法 |
| CN106833826A (zh) * | 2016-12-10 | 2017-06-13 | 天长市天龙泵阀成套设备厂 | 高温阀门润滑油及其加工方法 |
-
2021
- 2021-11-29 CN CN202111436373.XA patent/CN114106918A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212603A (zh) * | 2014-08-29 | 2014-12-17 | 青岛特瑞信电子科技有限公司 | 一种齿轮油 |
| CN104450094A (zh) * | 2014-12-09 | 2015-03-25 | 芜湖市鸿坤汽车零部件有限公司 | 一种用于火车轮毂的硬膜防锈油 |
| CN105950267A (zh) * | 2016-05-23 | 2016-09-21 | 中国铁道科学研究院金属及化学研究所 | 一种环保型轮轨润滑脂及其制备方法 |
| CN106833826A (zh) * | 2016-12-10 | 2017-06-13 | 天长市天龙泵阀成套设备厂 | 高温阀门润滑油及其加工方法 |
| CN106701284A (zh) * | 2016-12-23 | 2017-05-24 | 上海禾泰特种润滑科技股份有限公司 | 开式齿轮油组合物及其制备方法 |
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