CN114085584A - Litchi surface multicolor paint and preparation method and application thereof - Google Patents

Litchi surface multicolor paint and preparation method and application thereof Download PDF

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Publication number
CN114085584A
CN114085584A CN202111565644.1A CN202111565644A CN114085584A CN 114085584 A CN114085584 A CN 114085584A CN 202111565644 A CN202111565644 A CN 202111565644A CN 114085584 A CN114085584 A CN 114085584A
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parts
multicolor paint
weight
agent
litchi
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CN114085584B (en
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邱奉玲
杨勇
田新阳
李金钟
其他发明人请求不公开姓名
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ASIA PAINT (SHANGHAI) CO LTD
Asia Cuanon Technology Shanghai Co Ltd
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ASIA PAINT (SHANGHAI) CO LTD
Asia Cuanon Technology Shanghai Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The invention relates to a litchi surface multicolor paint and a preparation method and application thereof, wherein the litchi surface multicolor paint comprises a base material, a granulation liquid and a continuous phase material; the base material comprises water, protective glue, first emulsion, first auxiliary agent, filler and ectoine; the granulating liquid comprises water, protective glue and a suspending agent; the continuous phase material comprises water, a second emulsion and a second auxiliary agent. The litchi surface multicolor paint disclosed by the invention has excellent texture, the color point heat storage stability is good, and the size change of color points constructed in different time periods in the same engineering is small.

Description

Litchi surface multicolor paint and preparation method and application thereof
Technical Field
The invention relates to the technical field of coatings, in particular to litchi surface multicolor paint and a preparation method and application thereof.
Background
In the sand-in-water coating, especially the litchi surface multicolor paint has higher requirements on the texture and the storage stability of color dots. However, most of strong-quality multi-color paints realize thickening of the paint through the strong association effect of the hydrophobic modified cellulose, the strong reaction type wetting agent and the protective glue, the strong quality of the existing litchi surface multi-color paint is realized by using the idea, but the color point size change of the same engineering construction in different time periods is obvious due to the color point heat storage shrinkage.
CN112940556A discloses a sand-in-water coating and a preparation method thereof, belonging to the technical field of sand-in-water coatings. The sand-in-water coating and the preparation method thereof are simple and reasonable, and the synthetic materials are mixed and stirred in sequence to obtain a finished product with good quality; the environment is protected, and the harm to the health of people is small; the paint has the advantages of good stability, good adhesiveness and film-forming property, difficult peeling, good water resistance and long service life. But that is still faced with the problem of poor heat storage stability of the color dots.
CN112662224A discloses a sand-in-water multicolor paint with high stability, which comprises a sand-containing base paint, a continuous phase emulsion and a second part of protective adhesive, wherein the sand-containing base paint comprises: a first part of protective gum, anionic surfactant, nonionic surfactant, filler, cellulose, emulsion, water and sand; the continuous phase emulsion comprises: an emulsion and water; the protective adhesive comprises: lithium magnesium silicate or modified lithium magnesium silicate, and water; the first part of protective glue and the second part of protective glue are both magnesium silicate or modified magnesium silicate aqueous solutions. Due to the adoption of the mixed surfactant, three colloids of the sand-containing base paint, the continuous phase emulsion and the second part of protective glue in the multicolor paint can interact more uniformly and orderly, and can exist in a finished product more stably; in addition, the surfactant can improve the selection tolerance of the sand-in-water multicolor paint in main raw materials such as protective glue, emulsion, cellulose and the like, and enhance the compatibility. But still faces the problem that the color point heat storage shrinkage causes the color point size of the same project to change obviously in different construction time periods.
In view of the above, there is an urgent need for litchi surface multicolor paint with strong texture and good color point heat storage stability.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a litchi surface multicolor paint and a preparation method and application thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the invention provides litchi surface multicolor paint which comprises a base material, a granulating liquid and a continuous phase material;
the base material comprises water, protective glue, first emulsion, first auxiliary agent, filler and ectoine;
the granulating liquid comprises water, protective glue and a suspending agent;
the continuous phase material comprises water, a second emulsion and a second auxiliary agent.
According to the litchi surface multicolor paint, the ectoin is arranged in the base material, and reacts with the protective adhesive to thicken and plasticize, so that thixotropy is improved, and the reaction speed is high, so that the litchi surface multicolor paint has excellent texture, the color point thermal storage stability is good, and the change of the color point size in the construction of the same engineering in different time periods is small.
Preferably, the litchi surface multicolor paint comprises a base material, a granulating liquid and a continuous phase material in a weight ratio of 1 (0.4-0.6) to (0.4-0.6), wherein 0.4-0.6 are respectively and independently 0.42, 0.44, 0.46, 0.48, 0.5, 0.52, 0.54, 0.56, 0.58 and the like.
Preferably, the base material comprises the following components in parts by weight:
Figure BDA0003421906720000021
Figure BDA0003421906720000031
the ectoin is 0.2-0.4 part by weight, and the reason for controlling the ectoin within the range is to provide a proper texture strength, the addition amount is too high, and the colorful paint dots are too convex or even hardened; the addition amount is too low, and the color dots are not enough for the design requirement of the concave-convex texture of the product.
The water accounts for 20-30 parts by weight, such as 22 parts, 24 parts, 26 parts, 28 parts and the like.
The weight portion of the first emulsion is 4-8 parts, such as 5 parts, 6 parts, 7 parts and the like.
The first auxiliary agent is 0.1-5.5 parts by weight, such as 0.1 part, 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts and the like.
The filler is present in an amount of 0 to 4 parts by weight, and not 0 part, such as 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, and the like.
The sand is 40-50 parts by weight, such as 42 parts, 44 parts, 46 parts, 48 parts and the like.
The weight portion of the ectoin is 0.2-0.4 portion, such as 0.25 portion, 0.3 portion, 0.35 portion and the like.
Preferably, the ectoin has a solid content of 8% to 12%, such as 9%, 10%, 11%, etc., preferably 10%.
The reason why the solid content of the ectoin is preferably 10% in the invention is that the viscosity after dissolution can be transported and added in a way suitable for the general requirements of multicolor paint technology.
Preferably, the solid content of the protective gum is 5% to 10%, such as 6%, 7%, 8%, 9%, etc.
Preferably, the first auxiliary agent comprises any one of or a combination of at least two of hydroxyethyl cellulose, ammonium salt dispersant, bactericide, anionic wetting agent, mineral oil defoamer, amine auxiliary agent, antifreeze agent or film forming auxiliary agent, wherein typical but non-limiting combinations include: the combination of hydroxyethyl cellulose and an ammonium salt dispersant, the combination of a bactericide, an anionic wetting agent and a mineral oil defoamer, the combination of a bactericide, an anionic wetting agent, a mineral oil defoamer, an amine auxiliary agent and an antifreeze agent, the combination of hydroxyethyl cellulose, an ammonium salt dispersant, a bactericide, an anionic wetting agent, a mineral oil defoamer, an amine auxiliary agent, an antifreeze agent and a film forming auxiliary agent, and the like.
Preferably, the amine adjuvant comprises AMP 95.
Preferably, the hydroxyethyl cellulose is present in an amount of 0.5 to 0.8 parts by weight, such as 0.55 parts, 0.6 parts, 0.65 parts, 0.7 parts, 0.75 parts, etc.
Preferably, the weight portion of the ammonium salt dispersant is 0.2-0.6 parts, such as 0.3 parts, 0.4 parts, 0.5 parts, and the like.
Preferably, the bactericide is present in an amount of 0.1 to 0.7 parts by weight, such as 0.2 parts, 0.3 parts, 0.4 parts, 0.5 parts, 0.6 parts, etc.
Preferably, the anionic wetting agent is present in an amount of 0.1 to 0.4 parts by weight, such as 0.15 parts, 0.2 parts, 0.25 parts, 0.3 parts, 0.35 parts, etc.
Preferably, the mineral oil defoamer is present in an amount of 0.3 to 0.6 parts by weight, such as 0.35 parts, 0.4 parts, 0.45 parts, 0.5 parts, 0.55 parts, and the like.
Preferably, the amine adjuvant is present in an amount of 0.1 to 0.2 parts by weight, such as 0.12 parts, 0.14 parts, 0.16 parts, 0.18 parts, etc.
Preferably, the antifreeze agent is 0.1-0.2 parts by weight, such as 0.1 parts, 0.15 parts, etc.
Preferably, the film-forming aid is present in an amount of 1 to 2 parts by weight, such as 1.2 parts, 1.4 parts, 1.6 parts, 1.8 parts, and the like.
Preferably, the filler comprises titanium dioxide and/or kaolin.
Preferably, the weight portion of the titanium dioxide is 0-1 part, such as 0.2 part, 0.4 part, 0.6 part, 0.8 part and the like, and when the filler is titanium dioxide, it is not 0 part.
Preferably, the kaolin is present in an amount of 1 to 3 parts by weight, such as 1.2 parts, 1.4 parts, 1.6 parts,. 8 parts, 2 parts, 2.2 parts, 2.4 parts, 2.6 parts, 2.8 parts, and the like.
Preferably, the granulation liquid comprises the following components in parts by weight:
87-94 parts of water
6-8 parts of protective adhesive
0.2-1 part of suspending agent.
The water accounts for 87-94 parts by weight, such as 88 parts, 89 parts, 90 parts, 91 parts, 92 parts, 93 parts and the like.
The weight portion of the protective glue is 6-8 portions, such as 6 portions, 6.5 portions, 7 portions, 7.5 portions and the like.
The suspending agent is 0.2-1 part by weight, such as 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part and the like.
Preferably, the solid content of the protective gum is 5% to 10%, such as 6%, 7%, 8%, 9%, etc.
Preferably, the continuous phase material comprises the following components in parts by weight:
20-40 parts of water
50-80 parts of second emulsion
0.1-10 parts of a second auxiliary agent.
The water accounts for 20-40 parts by weight, such as 25 parts, 30 parts, 35 parts and the like.
The second emulsion is 50-80 parts by weight, such as 55 parts, 60 parts, 65 parts, 70 parts, 75 parts and the like.
The second auxiliary agent is 0.1-10 parts by weight, such as 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts and the like.
Preferably, the second adjuvant comprises any one of, or a combination of at least two of, a bactericide, a film-forming adjuvant, a neutralizing agent, an anti-freeze agent, or a thickener, wherein typical but non-limiting combinations include: combinations of bactericides and coalescing agents, combinations of coalescing agents, neutralizers and anti-freezing agents, combinations of bactericides, coalescing agents, neutralizers, anti-freezing agents and thickeners, and the like.
Preferably, the continuous phase material of the litchi surface multicolor paint comprises a thickening agent, and the continuous phase thickening agent is used as a universal method in the multicolor paint industry.
Preferably, the weight portion of the bactericide is 0.1-0.2 parts, such as 0.12 parts, 0.14 parts, 0.15 parts, 0.16 parts, 0.18 parts, etc.
Preferably, the film-forming aid is present in an amount of 5 to 8 parts by weight, such as 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, and the like.
Preferably, the neutralizing agent is present in an amount of 0.1 to 0.3 parts by weight, such as 0.15 parts, 0.2 parts, 0.25 parts, 0.3 parts, etc.
Preferably, the antifreeze is present in an amount of 0.2 to 0.5 parts by weight, such as 0.25 parts, 0.3 parts, 0.35 parts, 0.4 parts, 0.45 parts, etc.
Preferably, the thickener is present in an amount of 0.8 to 1 part by weight, such as 0.85 part, 0.9 part, 0.95 part, and the like.
In a second aspect, the invention provides a preparation method of the litchi surface multicolor paint, which comprises the following steps:
mixing water, protective adhesive, first emulsion, first auxiliary agent, filler, sand and ectoin to obtain a base material;
mixing water, protective glue and a suspending agent to obtain a granulation liquid;
mixing water, the second emulsion and the second auxiliary agent to obtain a continuous phase material;
and mixing the base material, the granulating liquid and the continuous phase material to obtain the litchi surface multicolor paint.
In a third aspect, the invention provides the litchi surface multicolor paint in the first aspect, or the litchi surface multicolor paint prepared by the method in the second aspect, and an application of the litchi surface multicolor paint in buildings.
In a fourth aspect, the invention provides an application of ectoin in improving the texture and the color point heat storage stability of litchi surface multicolor paint.
In the invention, the ectoin can be used for improving the texture and the color point heat storage stability of the litchi surface multicolor paint, and is characterized by reacting with the protective adhesive to thicken and plasticize, so that the thixotropy is improved and the reaction speed is high.
Preferably, the litchi surface multicolor paint comprises the litchi surface multicolor paint of the first aspect.
Compared with the prior art, the invention has the following beneficial effects:
the litchi surface multicolor paint disclosed by the invention has excellent texture, the color point heat storage stability is good, and the size change of color points constructed in different time periods in the same engineering is small.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments. It should be understood by those skilled in the art that the examples are only for the understanding of the present invention and should not be construed as the specific limitations of the present invention.
In a specific embodiment, the kinds and purchase information of the components are shown in table 1:
TABLE 1
Figure BDA0003421906720000071
Figure BDA0003421906720000081
Examples 1 to 3
The litchi surface multicolor paint comprises the following components in parts by weight as shown in Table 2:
TABLE 2
Figure BDA0003421906720000091
Figure BDA0003421906720000101
In examples 1-3, the respective parts by weight of the base, granulating liquid and continuous phase material are not necessarily equivalent.
In example 1, base stock: granulating liquid: continuous phase material 1: 0.5: 0.5;
in example 2, base stock: granulating liquid: continuous phase material 1: 0.4: 0.6;
in example 3, base stock: granulating liquid: continuous phase material 1: 0.6: 0.4.
the preparation method of the litchi surface multicolor paint comprises the following steps:
mixing water, protective glue, first emulsion, hydroxyethyl cellulose, ammonium salt dispersant, bactericide, anionic wetting agent, mineral oil defoamer, amine assistant, antifreeze, film forming assistant, filler, sand and ectoin to obtain base material;
mixing water, protective glue and a suspending agent to obtain a granulation liquid;
mixing water, the second emulsion, a bactericide, a film-forming aid, a neutralizer, an antifreezing agent and a thickening agent to obtain a continuous phase material;
and mixing the base material, the granulating liquid and the continuous phase material in proportion to obtain the litchi surface multicolor paint.
Examples 4 to 7
Examples 4-7 differ from example 1 in the parts by weight of ectoin in the base material as follows:
example 4: 0.2 part of ectoin, 15.1 parts of first emulsion and the balance of the emulsion are the same as in example 1;
example 5: 0.4 part of ectoin, 14.9 parts of first emulsion and the balance of the emulsion are the same as in example 1;
example 6: 0.15 part of ectoin, 15.15 parts of first emulsion and the balance of the emulsion are the same as in example 1;
example 7: the contents of ectoin 0.45 part and first emulsion 14.85 parts are the same as in example 1.
Comparative example 1
This comparative example differs from example 1 in that the base used contains no ectoine and 0.2% hydrophobically modified cellulose (yastran HE-3KB) is added, all as in example 1.
Comparative example 2
This comparative example differs from example 1 in that the base does not contain ectoin and is otherwise the same as example 1.
Comparative example 3
This comparative example differs from example 1 in that no ectoin was present in the base, 0.2% wetting agent (grid 399) was added, and the rest was the same as example 1.
Performance testing
The litchi-surface multicolor paints described in examples 1-7 and comparative examples 1-2 were tested as follows:
(1) texture:
the texture is described as the concave-convex feeling of the color dots after the finished product is dried, the color dots are judged by visual observation and the use of slightly rubbing the paint surface by touch, the shape of the color dots is prominent, the color dots are qualified if the color dots are obviously convex, and the color dots are too hard if the color dots are broken and the color dots are obviously stabbing.
(2) Color point shrinkage:
and (3) spraying the prepared finished paint on the same day after the color point shrinkage is carried out, recording the spraying amount, spraying the same amount after the heat storage at 50 ℃ for 14 days, and comparing the initial value with a sample plate after the heat storage, wherein the qualified rate is no obvious difference, and the unqualified rate is obvious difference.
The test results are summarized in table 3.
TABLE 3
Figure BDA0003421906720000121
Analysis table 3 shows that the litchi surface multicolor paint has excellent texture, the color point heat storage stability is good, and the size change of color points constructed in different time periods in the same engineering is small.
As can be seen from the analysis of comparative example 1 and example 1, the comparative example 1 is different from the example 1, and the fact that the texture is improved by using the hydrophobic modified cellulose is proved, the storage stability of the color dots is poor, and the color dot shrinkage is serious, so that the litchi surface multicolor paint formed by adding the ectoin into the base material has better performance than the litchi surface multicolor paint formed by adding the hydrophobic modified hydroxyethyl cellulose.
The comparative example 2 and the example 1 are analyzed to know that the performance of the comparative example 2 is inferior to that of the example 1, and the fact that the litchi surface multicolor paint formed by adding the ectoin into the base material can improve the texture and can meet the technical requirements of strong-quality water-coated sand and litchi surface water-coated sand is proved.
As can be seen from the analysis of comparative example 3 and example 1, the shrinkage of the color point heat storage of comparative example 3 is inferior to that of example 1, and the litchi-surface multicolor paint formed by adding ectoin to the base stock is proved to have better performance than that of the litchi-surface multicolor paint added with the wetting agent.
As can be seen from the analysis of examples 4-7, examples 6-7 are inferior to examples 4-5 in performance, and the litchi-surface multicolor paint formed by the fact that the parts by weight of ectoin is in the range of 0.2-0.4 is proved to have better performance.
The present invention is illustrated in detail by the examples described above, but the present invention is not limited to the details described above, i.e., it is not intended that the present invention be implemented by relying on the details described above. It should be understood by those skilled in the art that any modification of the present invention, equivalent substitutions of the raw materials of the product of the present invention, addition of auxiliary components, selection of specific modes, etc., are within the scope and disclosure of the present invention.

Claims (10)

1. The litchi surface multicolor paint is characterized by comprising a base material, a granulating liquid and a continuous phase material;
the base material comprises water, protective glue, first emulsion, first auxiliary agent, filler and ectoine;
the granulating liquid comprises water, protective glue and a suspending agent;
the continuous phase material comprises water, a second emulsion and a second auxiliary agent.
2. The litchi surface multicolor paint of claim 1, wherein the litchi surface multicolor paint comprises a base material, a granulating liquid and a continuous phase material in a weight ratio of 1 (0.4-0.6) to (0.4-0.6).
3. The litchi surface multicolor paint as claimed in claim 1 or 2, wherein the base material comprises the following components in parts by weight:
Figure FDA0003421906710000011
preferably, the solid content of the ectoine is 8% -12%;
preferably, the solid content of the protective glue is 5% -10%.
4. The litchi-surface multicolor paint according to any one of claims 1 to 3, wherein the first auxiliary agent comprises any one or a combination of at least two of hydroxyethyl cellulose, an ammonium salt dispersant, a bactericide, an anionic wetting agent, a mineral oil defoamer, an amine auxiliary agent, an antifreeze agent or a film forming auxiliary agent;
preferably, the weight portion of the hydroxyethyl cellulose is 0.5-0.8 portion;
preferably, the weight portion of the ammonium salt dispersant is 0.2-0.6 portion;
preferably, the weight portion of the bactericide is 0.1-0.7;
preferably, the anionic wetting agent is 0.1-0.4 part by weight;
preferably, the mineral oil defoamer accounts for 0.3-0.6 part by weight;
preferably, the weight portion of the amine assistant is 0.1-0.2 portion;
preferably, the weight portion of the antifreezing agent is 0.1-0.2;
preferably, the film-forming assistant is 1-2 parts by weight;
preferably, the filler comprises titanium dioxide and/or kaolin;
preferably, the weight portion of the titanium dioxide is 0-1, and when the filler is titanium dioxide, the weight portion is not 0;
preferably, the kaolin is 1 to 3 parts by weight.
5. The litchi surface multicolor paint according to any one of claims 1 to 4, wherein the granulation liquid comprises the following components in parts by weight:
87-94 parts of water
6-8 parts of protective adhesive
0.2-1 part of suspending agent;
preferably, the solid content of the protective glue is 5% -10%.
6. The litchi-surface multicolor paint according to any one of claims 1 to 5, wherein the continuous phase material comprises the following components in parts by weight:
20-40 parts of water
50-80 parts of second emulsion
0.1-10 parts of a second auxiliary agent.
7. The litchi surface multicolor paint according to any one of claims 1 to 6, wherein the second auxiliary agent comprises any one or a combination of at least two of a bactericide, a film forming auxiliary agent, a neutralizing agent, an antifreezing agent or a thickening agent;
preferably, the weight portion of the bactericide is 0.1-0.2;
preferably, the film-forming assistant is 5-8 parts by weight;
preferably, the neutralizing agent is 0.1-0.3 part by weight;
preferably, the weight portion of the antifreezing agent is 0.2-0.5;
preferably, the weight part of the thickening agent is 0.8-1 part.
8. The preparation method of the litchi surface multicolor paint as claimed in any one of claims 1 to 7, wherein the preparation method comprises the following steps:
mixing water, protective adhesive, first emulsion, first auxiliary agent, filler, sand and ectoin to obtain a base material;
mixing water, protective glue and a suspending agent to obtain a granulation liquid;
mixing water, the second emulsion and the second auxiliary agent to obtain a continuous phase material;
and mixing the base material, the granulating liquid and the continuous phase material to obtain the litchi surface multicolor paint.
9. The litchi surface multicolor paint as claimed in any one of claims 1 to 7, or the litchi surface multicolor paint prepared by the method as claimed in claim 8, and application of the litchi surface multicolor paint in buildings.
10. The application of ectoin in improving the texture and the color point heat storage stability of the litchi surface multicolor paint;
preferably, the litchi surface multicolor paint comprises the litchi surface multicolor paint of any one of claims 1 to 7.
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