CN108276914A - Aqueous bush-hammered face imitates stone colour-wash containing sand and preparation method thereof - Google Patents
Aqueous bush-hammered face imitates stone colour-wash containing sand and preparation method thereof Download PDFInfo
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- CN108276914A CN108276914A CN201810036607.3A CN201810036607A CN108276914A CN 108276914 A CN108276914 A CN 108276914A CN 201810036607 A CN201810036607 A CN 201810036607A CN 108276914 A CN108276914 A CN 108276914A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/06—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
- C09D201/08—Carboxyl groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- Wood Science & Technology (AREA)
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- Paints Or Removers (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a kind of aqueous bush-hammered faces to imitate stone colour-wash containing sand and preparation method thereof; the aqueous bush-hammered face is imitated stone colour-wash containing sand and is made of base paint, continuous phase emulsion compositions and Protection glue; containing hydroxyethyl cellulose, the sand of grading and containing the lotion of associative groups in the base paint; lotion in continuous phase emulsion compositions containing latent curing agent and containing associative groups, Protection glue are made of organically-modified silicic acid lithium magnalium soap Jia Shui.The aqueous bush-hammered face that the application provides imitates stone colour-wash containing sand because Protection glue, the lotion containing hydroxyethyl cellulose and containing associative groups is made using organically-modified silicic acid lithium magnalium soap; paint film can be made to generate the synergistic effect mutually associated; along with having used latent curing agent, shrink bleeding to solve existing water burnt-in sand multicolor finish particle, sedimentation layering, paint film intensity difference of meeting that water bleaches, paint film is water-fast, compact in paint film degree difference, blistering falls off, can not do the problems such as bush-hammered face imitation stone effect after rainwater impregnates.
Description
Technical field
The present invention relates to paint fields, more specifically, be related to a kind of aqueous bush-hammered face imitate stone colour-wash containing sand and its
Preparation method.
Background technology
It in aqueous, environmental protective, economizes on resources, under the promotion of imitative stone material demand true to nature, water-in-water multicolor coating market demand is got over
Come bigger.Existing water-in-water multicolor coating is substantially to be granulated using base paint in Protection glue first, is then made with lotion
It is made for film forming matter.The production mechanism of Protection glue is roughly the same, most of water-soluble colorful coatings using trade name RD,
The Protection glue of RDS, GTS, but the difference of subsequent processing mode keep Protection glue performance difference larger；And the application kind of cellulose
Various, the kind and quality of lotion are also irregular, cause existing water-in-water multicolor coating easily by the factors shadow such as environment temperature
It rings, multicolor finish system is unstable, has the following problems：
1. particle is easily shunk, bleeding；
2. particle easily contains sand sedimentation, layering；
Easily bleach 3. paint film meets water；
4. paint film is water-fast intensity difference；
5. paint film is because being to squeeze fusion by moisture evaporation to be formed, low density；
After 6. rain drop erosion is impregnated, paint blister falls off；
7. decorative effect can not done imitates marmorean effect as bush-hammered face.
Therefore, it is necessary to be improved to the formula of current aqueous water-in-water multicolor coating, component, to overcome existing skill
The drawbacks described above of art provides quality more preferably aqueous water-in-water multicolor coating, and true to nature can imitate marmorean aqueous litchi
It is very urgent that stone colour-wash containing sand is imitated in branch face.
Applicant is by scientific research and constantly gropes, obtain continuous phase emulsion and dispersed phase particles ingredient, particle contraction,
And the relationship of particle precipitation, the aqueous bush-hammered face for producing the application imitate stone colour-wash containing sand, can solve the prior art
Drawbacks described above.
Invention content
To solve the above-mentioned problems or one of problem, the present invention are changed by selecting different component and its content
The membrane formation mechanism of water-in-water multicolor coating provides a kind of novel aqueous bush-hammered face and imitates stone colour-wash containing sand and its preparation
Method can overcome the above-mentioned technological deficiency of existing aqueous water-in-water multicolor coating.
Specifically, an aspect of of the present present invention provides a kind of aqueous bush-hammered face and imitates stone colour-wash containing sand, by base paint,
Continuous phase emulsion compositions and Protection glue composition, wherein
The component of base paint and the mass content of component are：
The component of continuous phase emulsion compositions and the mass content of component are：
The component of Protection glue and the mass content of component are：
Water 90-95%
Organically-modified silicic acid lithium magnalium soap 5-15%.
Above-mentioned aqueous bush-hammered face provided by the present application imitates stone colour-wash containing sand, because using organically-modified silicic acid lithium magnalium soap
Protection glue is made, hydroxyethyl cellulose is coordinated, makes the lotion containing associative groups that association, shape occur with cellulose, Protection glue
At interpenetrating crossover network structure, colored particles is made more to stablize, reduces Protection glue dosage；And can be in addition system after, glue
Degree automatically ramps up to 80KU, need not in addition add thickener again, save cost, and in turn avoiding thickener water suction keeps system water-fast
Property be deteriorated, particle hardening thicken, particle shrink, sedimentation, adhesion；The sand of rational gradation composition can make the aqueous bush-hammered face of the application imitate stone
Colour-wash containing sand has the fidelity of parian；Latent curing agent is added, whole system is made to form crosslinked three-dimensional knot
Structure, compact in paint film degree significantly improve, and paint film intensity significantly improves, and immersion is soaked will not to whiten, soften, and realizes the application's
Goal of the invention.
The mechanism that specifically the application can solve prior art problem is：
1. Protection glue is made using the lithium metasilicate magnalium soap of water-soluble organic pyrophosphate salt organic matter processing, in conjunction with containing hydroxyl
The synergistic effect of the cellulose of ethyl group and lotion containing associative groups mutually associated forms three-dimensional associative structure, makes body
Set section saves Protection glue, and it is long to solve the prior art production cycle, rear to thicken, and particle hardening thickens, and particle is shunk, sedimentation, adhesion.
May make the aqueous bush-hammered face of the application imitate stone colour-wash containing sand particle be not easy to shrink, bleeding, particle be not easy containing sand sedimentation,
Layering.
2. use the lotion containing associative groups, can with cellulose, Protection glue occur association (so-called " association "
Mechanism is charge attraction), form dimensional network structure, can be in addition system after, viscosity automatically ramps up to 80KU, need not be another
Thickener is added again outside, has saved cost, and in turn avoiding thickener water suction makes system water resistance be deteriorated, and keeps colored particles more steady
It is fixed, compact in paint film.
3. being chemically reacted using the carboxylic group (- COOR) on latent curing agent, with film forming matter lotion, it is
The chemical reaction of hydrogen migration is carried out in carboxylic group double bond, this chemical reaction is exactly in latent curing agent and lotion
Carboxylic group-COOR reacts, and film is made to form fine and close cross-linked structure, thoroughly solves water-soluble colorful coating and meets water mutability
In vain, paint film meets water immersion intensity and is deteriorated, the problem of compact in paint film degree difference.So-called " latent curing agent ", meaning refer to just this
Curing agent does not chemically react in the water-soluble colorful coating of liquid, but after spraying application, with the volatilization of moisture, dive
Volt property curing agent is just chemically crosslinked with the carboxylic group-COOR in lotion, generates fine and close film.Generally, it is exactly
The latent curing agent of addition, does not chemically react in liquid coating, is crosslinked during water volatile dry, generates
Fine and close film, thoroughly solves that film intensity of meeting that water bleaches, paint film is water-fast is deteriorated and compact in paint film degree is poor and rainwater rushes
The problem of paint blister falls off after brush impregnates, resistance to physical and chemical performance is significantly improved.
4. using the sand of rational gradation composition, herein described aqueous bush-hammered face may make to imitate stone colour-wash containing sand and can make
The marmorean fidelity of imitation of the decorative effect as bush-hammered face.
Therefore, it is a kind of novel aqueous crosslinking technological and have that the bush-hammered face of the above-mentioned offer of the application, which imitates stone colour-wash containing sand,
The water-in-water multicolor coating for stablizing protecting colloid, can solve particle existing for water-in-water multicolor coating in the prior art and easily shrink
Bleeding, meets water easily bleaches, paint film is water-fast intensity difference, the problem of compact in paint film degree difference at the layering of coating free settling.
One embodiment of stone colour-wash containing sand is imitated according to bush-hammered face of the present invention, it is preferable that the ethoxy is fine
The plain cellulose to be 2.5 containing ethoxy associative groups, degree of substitution of dimension.The cellulose contains electricity because of its ethoxy associative groups
Lotus, the association easy to implement with Protection glue, lotion.
Another embodiment of stone colour-wash containing sand is imitated according to aqueous bush-hammered face of the present invention, it is preferable that the grade
The sand matched is：80 mesh sand account for 10-20%, and 90 mesh sand account for 15-25%, and 100 mesh sand account for 25-35%, and 110 mesh sand account for 10-20%,
120 mesh sand account for 15-25%.It may make herein described aqueous bush-hammered face to imitate stone colour-wash containing sand, make decorative effect as litchi
The same marmorean simulated effect of imitation in branch face.
Another embodiment of stone colour-wash containing sand is imitated according to aqueous bush-hammered face of the present invention, it is preferable that described to contain
The lotion of associative groups be containing associative groups be anion surfactant (such as 12 polyoxyethylene sulfonate of succinic acid) and
The lotion of carboxyl.With the cellulose of selection, Protection glue association can occur for the lotion, form dimensional network structure.
The further embodiment of stone colour-wash containing sand is imitated according to bush-hammered face of the present invention, it is preferable that the latency
Curing agent is：Poly- carbodiimide.The poly- carbodiimide can during dried coating film with the carboxylic group-COOR on film forming matter
It chemically reacts, film is made to form fine and close cross-linked structure.
The further embodiment of stone colour-wash containing sand is imitated according to bush-hammered face of the present invention, it is preferable that described organic to change
Property lithium metasilicate magnalium soap is：With the lithium metasilicate magnalium soap of water-soluble organic pyrophosphate salt organic matter processing, Protection glue is done, in conjunction with
The synergistic effect of the cellulose of special groups, lotion containing associative groups mutually associated makes system save Protection glue, solves
The problem of prior art production cycle is long, rear to thicken, and particle hardening thickens, particle contraction, sedimentation, adhesion.
Another aspect provides the preparation method that any of the above-described aqueous bush-hammered face imitates stone colour-wash containing sand, institutes
It states the imitative stone colour-wash containing sand of aqueous bush-hammered face to be made of base paint, continuous phase emulsion compositions and Protection glue, including following step
Suddenly：
Step 101, formula described in accordance with the claim 1 produces base paint, continuous phase emulsion compositions and guarantor respectively
Protect glue；
Step 102, the base paint manufactured is granulated in the Protection glue, produces that prepare aqueous bush-hammered face imitative
The required colour particles of stone colour-wash containing sand；
Step 103, the colour particles that will have been manufactured are uniformly mixed with the continuous phase emulsion compositions, produce
The aqueous bush-hammered face imitates stone colour-wash containing sand.
The above-mentioned preparation method that the application provides can produce the aqueous bush-hammered face and imitate stone colour-wash containing sand, this because
Aqueous bush-hammered face imitates stone colour-wash containing sand and makes Protection glue using organically-modified silicic acid lithium magnalium soap, coordinates hydroxy ethyl fiber
Element makes the lotion containing associative groups that association occur with cellulose, Protection glue, forms interpenetrating crossover network structure, make color
Particle more stablize, reduce Protection glue dosage, and can be in addition system after, in addition viscosity automatically ramps up to 80KU, need not be
Add thickener again, saved cost, in turn avoid thickener water suction make system water resistance be deteriorated, particle hardening thicken, particle
It shrinks, settle, adhesion；The sand of rational gradation composition, which can make the aqueous bush-hammered face of the application imitate stone colour-wash containing sand, has parian
Fidelity；Latent curing agent is added, whole system is made to form crosslinked stereochemical structure, compact in paint film degree significantly improves, paint
Film-strength significantly improves, and immersion is soaked will not to whiten, soften, and realizes present invention purpose.
An embodiment of the preparation method of stone colour-wash containing sand is imitated according to aqueous bush-hammered face of the present invention, it is preferable that
The hydroxyethyl cellulose that the aqueous bush-hammered face is imitated in stone colour-wash containing sand is：Exist containing ethoxy associative groups, degree of substitution
2.5 cellulose.The cellulose because its ethoxy associative groups contains charge, make by the association easy to implement with Protection glue, lotion
With.
Another embodiment of preparation method of stone colour-wash containing sand is imitated according to aqueous bush-hammered face of the present invention, it is preferable that
The sand of grading is in the imitative stone colour-wash containing sand of the aqueous bush-hammered face：80 mesh sand account for 10-20%, and 90 mesh sand account for 15-25%,
100 mesh sand account for 25-35%, and 110 mesh sand account for 10-20%, and 120 mesh sand account for 15-25%.It may make herein described aqueous lichee
Stone colour-wash containing sand is imitated in face, makes the marmorean simulated effect of imitation of the decorative effect as bush-hammered face.
The preparation method another embodiment of stone colour-wash containing sand is imitated according to aqueous bush-hammered face of the present invention, it is preferable that
The aqueous bush-hammered face imitates the lotion containing associative groups in stone colour-wash containing sand：It is anion surface active containing associative groups
The lotion of agent (such as 12 polyoxyethylene sulfonate of succinic acid) and carboxyl；Latent curing agent is poly- carbodiimide；It is organic to change
Property lithium metasilicate magnalium soap is：With the lithium metasilicate magnalium soap of water-soluble organic pyrophosphate salt organic matter processing.The lotion can be with choosing
Association occurs for cellulose, Protection glue, forms dimensional network structure；The poly- carbodiimide can be during dried coating film
It is chemically reacted with the carboxylic group-COOR on film forming matter, film is made to form fine and close cross-linked structure；It is organic with water solubility
The lithium metasilicate magnalium soap of pyrophosphate salt organic matter processing does Protection glue, in conjunction with the cellulose of special groups, containing associative groups
The synergistic effect of lotion mutually associated makes system save Protection glue, and it is long to solve the prior art production cycle, rear to thicken, grain
The problem of sub- hardening thickens, particle contraction, sedimentation, adhesion
Additional aspect and advantage according to the present invention will become apparent in following description section, or through the invention
Practice is recognized.
Specific implementation mode
To better understand the objects, features and advantages of the present invention, below to the specific reality of the present invention
The mode of applying illustrates.But in the absence of conflict, the feature in embodiments herein and embodiment can be mutual group
It closes.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still, the present invention may be used also
To be implemented different from other modes described here using other, therefore, protection scope of the present invention is not by described below
Specific embodiment limitation.
Aqueous bush-hammered face of the present invention imitates stone colour-wash containing sand, by base paint, continuous phase emulsion compositions and protection
Glue forms.Wherein, three embodiments of the mass content of the component and component of the base paint are as shown in table 1：
Table 1
Wherein, hydroxyethyl cellulose be 2.5 containing ethoxy associative groups, degree of substitution cellulose；The sand of grading is
80 mesh sand account for 15%, and 90 mesh sand account for 20%, and 100 mesh sand account for 30%, and 110 mesh sand account for 15%, and 120 mesh sand account for 20%；The base containing association
The lotion of group is containing the lotion that associative groups are anion surfactant and carboxyl.
Aqueous bush-hammered face of the present invention is imitated in stone colour-wash containing sand, the component and group of the continuous phase emulsion compositions
Three embodiments of the mass content divided are as shown in table 2：
Table 2
Wherein, the latent curing agent is poly- carbodiimide；Lotion containing associative groups be containing associative groups be it is cloudy from
The lotion of sub- surfactant and carboxyl.
Aqueous bush-hammered face of the present invention is imitated in stone colour-wash containing sand, and the component of the Protection glue and the quality of component contain
Three embodiments of amount are as shown in table 3：
Table 3
Wherein, the organically-modified silicic acid lithium magnalium soap is：With the silicon of water-soluble organic pyrophosphate salt organic matter processing
Sour lithium magnalium soap.
Three embodiments are set forth according to base paint, continuous phase emulsion compositions and Protection glue to table 3 in above-mentioned table 1,
According to the relationship of base paint, continuous phase emulsion compositions and Protection glue, these above-mentioned embodiments can be combined with each other, actually on
It is 27 embodiments for providing herein described aqueous bush-hammered face and imitating stone colour-wash containing sand to state table 1- tables 3.Below with a group
Example is combined into illustrate：
Implemented with Protection glue in continuous phase emulsion compositions embodiment one in base paint embodiment one, table 2 in table 1 and table 3
Example one is made herein described bush-hammered face and imitates stone colour-wash containing sand：
First, according to the formula of its each table illustrated embodiment one produce the base paint, continuous phase emulsion compositions and
Protection glue；
Secondly, the base paint manufactured is granulated in the Protection glue manufactured, produces and prepares bush-hammered face
The required colour particles of imitative stone colour-wash containing sand；
Finally, the colour particles that will have been manufactured are uniformly mixed with the continuous phase emulsion compositions, produce this Shen
It please the imitative stone colour-wash containing sand of the bush-hammered face.
The aqueous bush-hammered face imitates stone colour-wash containing sand after testing, can overcome whole defects of the prior art, real well
The goal of the invention of the present invention is showed.
In the description of this specification, the description of term " one embodiment ", " some embodiments ", " specific embodiment " etc.
Mean that particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one reality of the present invention
It applies in example or example.In the present specification, schematic expression of the above terms are not necessarily referring to identical embodiment or reality
Example.Moreover, description particular features, structures, materials, or characteristics can in any one or more of the embodiments or examples with
Suitable mode combines.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of aqueous bush-hammered face imitates stone colour-wash containing sand, which is characterized in that by base paint, continuous phase emulsion compositions and guarantor
Glue composition is protected, wherein
The component of base paint and the mass content of component are：
The component of continuous phase emulsion compositions and the mass content of component are：
The component of Protection glue and the mass content of component are：
Water 90-95%
Organically-modified silicic acid lithium magnalium soap 5-15%.
2. aqueous bush-hammered face according to claim 1 imitates stone colour-wash containing sand, which is characterized in that the hydroxy ethyl fiber
The plain cellulose to be 2.5 containing ethoxy associative groups, degree of substitution.
3. aqueous bush-hammered face according to claim 1 imitates stone colour-wash containing sand, which is characterized in that the sand of the grading
For：80 mesh sand account for 10-20%, and 90 mesh sand account for 15-25%, and 100 mesh sand account for 25-35%, and 110 mesh sand account for 10-20%, 120 mesh sand
Account for 15-25%.
4. aqueous bush-hammered face according to claim 1 imitates stone colour-wash containing sand, which is characterized in that described to contain associative groups
Lotion be containing the lotion that associative groups are anion surfactant and carboxyl.
5. aqueous bush-hammered face according to claim 1 imitates stone colour-wash containing sand, which is characterized in that the latent curing
Agent is poly- carbodiimide.
6. aqueous bush-hammered face according to claim 1 imitates stone colour-wash containing sand, which is characterized in that the organic modified silicas
Sour lithium magnalium soap is：With the lithium metasilicate magnalium soap of water-soluble organic pyrophosphate salt organic matter processing.
7. the aqueous bush-hammered face of claim 1-6 any one of them imitates the preparation method of stone colour-wash containing sand, the aqueous litchi
It imitates stone colour-wash containing sand and is made of base paint, continuous phase emulsion compositions and Protection glue in branch face, which is characterized in that including following
Step：
Step 101, formula described in accordance with the claim 1 produces base paint, continuous phase emulsion compositions and Protection glue respectively；
Step 102, the base paint manufactured is granulated in the Protection glue, produce prepare aqueous bush-hammered face imitate stone contain
The required colour particles of sand colour-wash；
Step 103, the colour particles that will have been manufactured are uniformly mixed with the continuous phase emulsion compositions, are produced described
Aqueous bush-hammered face imitates stone colour-wash containing sand.
8. aqueous bush-hammered face according to claim 7 imitates the preparation method of stone colour-wash containing sand, which is characterized in that described
The hydroxyethyl cellulose that aqueous bush-hammered face is imitated in stone colour-wash containing sand is：Containing ethoxy associative groups, degree of substitution 2.5
Cellulose.
9. aqueous bush-hammered face according to claim 7 imitates the preparation method of stone colour-wash containing sand, which is characterized in that described
The sand of grading is in the imitative stone colour-wash containing sand of aqueous bush-hammered face：80 mesh sand account for 10-20%, and 90 mesh sand account for 15-25%, 100 mesh
Sand accounts for 25-35%, and 110 mesh sand account for 10-20%, and 120 mesh sand account for 15-25%.
10. aqueous bush-hammered face according to claim 7 imitates the preparation method of stone colour-wash containing sand, which is characterized in that institute
Stating the lotion containing associative groups in the imitative stone colour-wash containing sand of aqueous bush-hammered face is：It is anion surfactant containing associative groups
With the lotion of carboxyl；Latent curing agent is poly- carbodiimide；Organically-modified silicic acid lithium magnalium soap is：With water-soluble organic burnt phosphorus
The lithium metasilicate magnalium soap of acid esters salt organic matter processing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810036607.3A CN108276914B (en) | 2018-01-15 | 2018-01-15 | Water-based litchi surface stone-like sand-containing color coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810036607.3A CN108276914B (en) | 2018-01-15 | 2018-01-15 | Water-based litchi surface stone-like sand-containing color coating and preparation method thereof |
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| CN108276914B CN108276914B (en) | 2020-09-15 |
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| CN110372265A (en) * | 2019-06-21 | 2019-10-25 | 河北晨阳工贸集团有限公司 | A kind of water burnt-in sand coating and preparation method thereof |
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| CN114395302A (en) * | 2022-01-25 | 2022-04-26 | 福州居家逸涂料科技有限公司 | Litchi surface imitated marble paint |
| CN115011231A (en) * | 2022-07-07 | 2022-09-06 | 广东美洲宝实业有限公司 | Stone-like paint coating and preparation method thereof |
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| CN110372265A (en) * | 2019-06-21 | 2019-10-25 | 河北晨阳工贸集团有限公司 | A kind of water burnt-in sand coating and preparation method thereof |
| CN111018474A (en) * | 2019-12-30 | 2020-04-17 | 成都富思特新材料有限公司 | Water-based sand-in-sand multicolor paint and preparation method thereof |
| CN111018474B (en) * | 2019-12-30 | 2022-07-01 | 成都富思特新材料有限公司 | Water-based sand-in-sand multicolor paint and preparation method thereof |
| CN114085584A (en) * | 2021-12-20 | 2022-02-25 | 亚士创能科技(上海)股份有限公司 | Litchi surface multicolor paint and preparation method and application thereof |
| CN114085584B (en) * | 2021-12-20 | 2022-05-13 | 亚士创能科技(上海)股份有限公司 | Litchi surface multicolor paint and preparation method and application thereof |
| CN114395302A (en) * | 2022-01-25 | 2022-04-26 | 福州居家逸涂料科技有限公司 | Litchi surface imitated marble paint |
| CN115011231A (en) * | 2022-07-07 | 2022-09-06 | 广东美洲宝实业有限公司 | Stone-like paint coating and preparation method thereof |
| CN115011231B (en) * | 2022-07-07 | 2024-01-23 | 广东美洲宝实业有限公司 | Stone-like paint and preparation method thereof |
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