CN114016119A - Electroplating bath solution comprehensive management device - Google Patents

Electroplating bath solution comprehensive management device Download PDF

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Publication number
CN114016119A
CN114016119A CN202111458539.8A CN202111458539A CN114016119A CN 114016119 A CN114016119 A CN 114016119A CN 202111458539 A CN202111458539 A CN 202111458539A CN 114016119 A CN114016119 A CN 114016119A
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pipe
liquid
filter
tank
management device
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CN202111458539.8A
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CN114016119B (en
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姚广一
闫琳
于铁柱
韦金钰
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Xuzhou XCMG Hydraulics Co Ltd
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Xuzhou XCMG Hydraulics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/16Regeneration of process solutions
    • C25D21/18Regeneration of process solutions of electrolytes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The invention belongs to purification equipment, and particularly relates to an electroplating bath solution comprehensive management device which comprises a supporting platform, wherein a circulating tank and a filter are arranged on the supporting platform, and BaCO is placed in the circulating tank3A liquid inlet pipe is arranged between the bottom of the circulating tank and the filter, and a circulating pump is arranged in the liquid inlet pipe; a liquid return pipe is arranged at the bottom of the filter and is simultaneously communicated with the liquid outlet pipe and the clear liquid pipe, one end of the liquid outlet pipe, which is far away from the liquid return pipe, is communicated with the top of the circulating tank, one end of the clear liquid pipe, which is far away from the liquid return pipe, extends towards the outer side of the supporting platform, and valves are arranged on the liquid outlet pipe and the clear liquid pipe; the filter is also communicated with a pure water pipe, the bottom of the circulating tank is also provided with a waste liquid pipe, and the waste liquid pipe is provided with a valve. This electroplating tank liquid integrated management device makes the tank liquid fully contact with the filtering agent through multiple circulating filtration in the filter, has greatly increased the purification area, has improved purification efficiency.

Description

Electroplating bath solution comprehensive management device
Technical Field
The invention belongs to purification equipment, and particularly relates to a comprehensive management device for electroplating bath solution.
Background
Electroplating: the electroplating technology, namely electrodeposition, is to plate a thin layer of other metals or alloys on the surface of some metal materials by utilizing the principle of electrolysis. The electroplating process is a surface processing method in which under the action of DC electric field, a loop is formed by anode and cathode in the salt solution (Ni, Cr solution) containing the metal to be plated, and the metal ions in the solution are deposited on the surface of cathode plating part by utilizing electrolysis action to make the surface of metal or other material product adhere a layer of metal film.
Electroplating management tank: the electroplating process is generally provided with an electroplating bath and a management tank, wherein the management tank aims to ensure that bath solution is always in a circulating state, adjust the liquid level of the electroplating bath and ensure that the concentrations of main salt, conductive salt and the like in each part of the bath solution are uniform. The change of the concentration of each ion in the plating solution can directly affect the electroplating effect, and the Cr of the solution in the plating tank can be changed along with the electroplating process3+And chromic anhydride, and the like, and in order to ensure that the concentration of each ion is in a specified range, supplements such as chromic anhydride, a catalyst, sulfuric acid and the like need to be added, but if a large amount of supplements are directly added into the plating bath, the stability of the plating layer of the running product is influenced. Therefore, the plating tank is usually connected to a buffer-operated control tank, and the both are always in an uninterrupted circulating state, thereby ensuring that the concentration of the plating solution is always within a predetermined range.
Sulfate radical: cr (chromium) component3+Is an important component of the adhesive film, SO4 2-The coating has high content, is easy to dissolve, leads to slow deposition speed, is difficult to form or is thin and porous, has large exposed matrix area and poor coating uniformity, and has no chromium layer in a low current density area, thereby influencing the anti-corrosion capability of the coating; SO (SO)4 2-When the content is low, the glue film is compact, the sulfuric acid is difficult to dissolve, the chromium layer can only grow on the original crystal grains, the crystal is rough, the plating layer is dark and dull, and the plating layer is rough.
The content of sulfate radical has great influence on the electroplating process, and SO in bath solution4 2-When the content is high, unpurified sulfate ions can affect the electroplating efficiency and the plating effect. The over-high concentration of sulfate radical in the hard chromium electroplating bath solution can cause Cr3+The deposition speed is slowed down, so that the plating time is increased under the same time and the plating efficiency is influencedAnd the low current density area has no chromium layer. Therefore, the concentration of sulfate group needs to be adjusted to a predetermined range. According to the traditional treatment technology, only the titanium net is placed in the management tank and contains a certain amount of barium carbonate, so that the generated barium sulfate is deposited at the bottom of the tank body, the method for purifying and recycling the titanium net can not effectively reduce the concentration of sulfate radicals, only the titanium net is placed in the tank liquor, the tank liquor can not be fully contacted with the barium carbonate in the titanium net, the purification area is limited, the purification efficiency is low, and the barium carbonate needs to be repeatedly added for many times. Meanwhile, waste residues are deposited at the bottom of the tank body and are not easy to clean, and a production line cannot normally operate, so that economic benefits are influenced.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides an electroplating bath solution comprehensive management device, which is characterized in that the bath solution in a management tank connected with an electroplating bath is pumped into the electroplating bath solution comprehensive management device and contains BaCO3In the circulating tank, a circulating pump is used for pumping liquid in the circulating tank into the filter through a liquid inlet pipe, and pure water is added properly when liquid is fed; after filtering, the bath solution flows back to the circulating bath through the liquid outlet pipe to complete one circulation; after repeated circulation for many times, when the plating solution reaches a standard value, opening a clear liquid pipe valve, discharging the bath solution from a clear liquid pipe, and sending the bath solution to a management tank for electroplating; and the waste liquid left at the bottom of the circulating tank is discharged through a waste liquid pipe at the bottom of the tank body.
The invention is realized by the following technical scheme: the comprehensive electroplating bath liquid management device comprises a supporting platform, wherein a circulating tank and a filter are arranged on the supporting platform, and BaCO is placed in the circulating tank3A liquid inlet pipe is arranged between the bottom of the circulating tank and the filter, and a circulating pump is arranged in the liquid inlet pipe; a liquid return pipe is arranged at the bottom of the filter and is simultaneously communicated with the liquid outlet pipe and the clear liquid pipe, one end of the liquid outlet pipe, which is far away from the liquid return pipe, is communicated with the top of the circulating tank, one end of the clear liquid pipe, which is far away from the liquid return pipe, extends towards the outer side of the supporting platform, and valves are arranged on the liquid outlet pipe and the clear liquid pipe; the filter is also communicated with a pure water pipe, the bottom of the circulating tank is also provided with a waste liquid pipe, and the waste liquid pipe is provided with a valve.
Furthermore, the waste liquid pipe is arranged on one side of the circulating tank, which is far away from the filter.
Further, the bottom side of the interior of the circulating tank is arranged obliquely downwards from one side of the filter towards the direction of the waste liquid pipe.
Furthermore, a plurality of small moving wheels are arranged at the bottom of the supporting platform.
Further, the small moving wheels are universal wheels.
Further, the supporting platform is also provided with a handle.
The invention has the beneficial effects that: (1) the traditional acid radical complex treatment mode is changed, and integrated purification and cleaning are realized through an electroplating bath solution comprehensive management device; (2) the tank liquor is thoroughly purified, and the concentration of acid radicals is controlled to a standard value, so that good purification is ensured; (3) the tank liquor is fully contacted with the filtering agent, so that the purification area is increased, the purification efficiency is improved, and the purification independence is ensured; (4) waste liquid and waste residue are easy to clean, the working efficiency is improved, and the normal operation of a production line is ensured; (5) be provided with and remove the steamboat, it is convenient to remove, and manual operation is less, guarantees the security.
Drawings
FIG. 1 is a perspective view of the present invention;
FIG. 2 is a front cross-sectional view of the present invention;
FIG. 3 is a top view of FIG. 2;
in the figure, 1, a circulation tank, 2, a pure water pipe, 3, a handle, 4, a filter, 5, a liquid inlet pipe, 6, a liquid outlet pipe, 7, a clear liquid pipe, 8, a movable small wheel, 9, a waste liquid pipe, 10-1, a valve I, 10-2, a valve II, 10-3, a valve III, 10-4, a valve IV, 11 and a supporting platform.
Detailed Description
The invention is further illustrated below with reference to the figures and examples.
As shown in fig. 1 to 3, an integrated management device for electroplating bath solution comprises a supporting platform 11, wherein the supporting platform 11 is used for supporting the main components of the integrated management device for electroplating bath solution. The supporting platform 11 is provided with a circulating groove 1 and a filter 4. The circulating tank 1 is a container for holding tank liquor, and BaCO is placed on the side wall in the circulating tank 13A liquid inlet pipe is arranged between the bottom of the circulation tank 1 and the filter 45, a circulating pump is arranged in the liquid inlet pipe 5; the filter 4 adopts current PTFE bag filter, and the bottom of filter 4 is equipped with back the liquid pipe, returns the liquid pipe and communicates with drain pipe 6 and clear solution pipe 7 simultaneously through tee bend subassembly, and the one end that the liquid pipe 6 was kept away from back the liquid pipe communicates with the top of circulation groove 1, and the one end that the clear solution pipe 7 was kept away from back the liquid pipe extends towards the outside of supporting platform 11, is equipped with valve I10-1 on the drain pipe 6, is equipped with valve II 10-2 on the clear solution pipe 7. The filter 4 is also communicated with a pure water pipe 2, the bottom of the circulating tank 1 is also provided with a waste liquid pipe 9, and the waste liquid pipe 9 is provided with a valve III 10-3. The waste liquid pipe 9 is preferably arranged on one side of the circulating tank 1 far away from the filter 4, the bottom side of the inside of the circulating tank 1 is arranged downwards from one side of the filter 4 towards the waste liquid pipe 9, after purification is completed, the waste liquid left at the bottom of the circulating tank 1 flows to the waste liquid pipe 9 along the inclined plane by gravity, and is discharged through the waste liquid pipe 9 with the valve III 10-3 opened.
The working flow of the comprehensive management device for the electroplating bath solution is as follows: firstly, tank liquor in a management tank connected with an electroplating tank is drained into a circulating tank 1, wherein the circulating tank 1 is connected with a filter 4 through a liquid inlet pipe 5, the liquid is led into the filter 4 through a circulating pump, a valve IV 10-4 is opened during liquid inlet, pure water is added to the filter 4 in a proper amount through a pure water pipe 2, the filtered tank liquor is drained into the circulating tank 1 through a liquid outlet pipe 6 with the valve I10-1 opened, and then the filtered tank liquor is led into the filter 4 again through the liquid inlet pipe 5 for purification. After repeated circulation for many times, when the detected sulfate radical concentration reaches the specified concentration range, the valve II 10-2 is opened, and the bath solution is drained into the management tank through the clear liquid pipe 7 to participate in electroplating circulation. Waste liquid at the bottom of the circulating tank 1 is discharged through a waste liquid pipe 9 with a valve III 10-3 opened.
Preferably, the bottom of the supporting platform 11 is provided with a plurality of movable small wheels 8, so that workers can push the comprehensive electroplating bath solution management device to move, and acid radical management manufacturing can be conveniently carried out at any angle position suitable for the management tank. In order to facilitate a worker to push the comprehensive electroplating bath solution management device to move, the supporting platform 11 is also provided with a handle 3, the small moving wheel 8 is a directional wheel, the handle 3 needs to be arranged along the moving direction of the small moving wheel 8, and the worker can push the comprehensive electroplating bath solution management device to move by pushing the handle 3. Preferably, the small moving wheel 8 is a universal wheel, and when the small moving wheel 8 is a universal wheel, the arrangement direction of the handle 3 is not limited.
This electroplating tank liquid integrated management device makes the tank liquid fully contact with the filtering agent through multiple circulating filtration in the filter, has greatly increased the purification area, has improved purification efficiency. Meanwhile, the filter screen precipitate after purification is easy to clean, the waste liquid is easy to discharge, the workload of personnel is reduced, and the acid radicals in the tank liquid are thoroughly purified.

Claims (6)

1. The utility model provides an electroplating bath solution integrated management device which characterized in that: comprises a supporting platform (11), a circulating tank (1) and a filter (4) are arranged on the supporting platform (11), BaCO is placed in the circulating tank (1)3A liquid inlet pipe (5) is arranged between the bottom of the circulating tank (1) and the filter (4), and a circulating pump is arranged in the liquid inlet pipe (5); a liquid return pipe is arranged at the bottom of the filter (4), the liquid return pipe is simultaneously communicated with the liquid outlet pipe (6) and the clear liquid pipe (7), one end of the liquid outlet pipe (6) far away from the liquid return pipe is communicated with the top of the circulating tank (1), one end of the clear liquid pipe (7) far away from the liquid return pipe extends towards the outer side of the supporting platform (11), and valves are arranged on the liquid outlet pipe (6) and the clear liquid pipe (7); the filter (4) is also communicated with a pure water pipe (2), the bottom of the circulating tank (1) is also provided with a waste liquid pipe (9), and the waste liquid pipe (9) is provided with a valve.
2. The integrated management device for electroplating bath solution according to claim 1, characterized in that: the waste liquid pipe (9) is arranged on one side of the circulating tank (1) far away from the filter (4).
3. The integrated management device for electroplating bath solution according to claim 2, characterized in that: the bottom side in the circulation tank (1) is arranged from one side of the filter (4) to the direction of the waste liquid pipe (9) in an inclined downward mode.
4. The integrated management device for electroplating bath solution according to claim 1, characterized in that: the bottom of the supporting platform (11) is provided with a plurality of movable small wheels (8).
5. The integrated management device for electroplating bath solution according to claim 4, characterized in that: the small moving wheels (8) are universal wheels.
6. An integrated management apparatus for plating bath solution according to claim 4 or 5, characterized in that: the supporting platform (11) is also provided with a handle (3).
CN202111458539.8A 2021-12-02 2021-12-02 Electroplating bath solution comprehensive management device Active CN114016119B (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4054517A (en) * 1974-08-06 1977-10-18 John Cunningham Chrome removal and recovery
GB1537914A (en) * 1976-02-13 1979-01-10 Cunningham J Chrome removal and recovery
JPH07316898A (en) * 1994-05-18 1995-12-05 Chlorine Eng Corp Ltd Removing method of sulfate ion in chromium plating solution
CN101759202A (en) * 2008-12-24 2010-06-30 新疆石河子中发化工有限责任公司 Method for removing sulfate radicals in saline water by using liquid barium chloride
CN103833167A (en) * 2014-03-13 2014-06-04 黄运富 Chromic acid wastewater treatment method and system
CN203807587U (en) * 2014-04-30 2014-09-03 遂宁市维海电子科技有限公司 FPC (Flexible Printed Circuit) board electroplating liquid circulation treatment device
CN105314759A (en) * 2014-07-19 2016-02-10 天津市绿净源环保科技有限公司 Chromium-containing wastewater processing apparatus realizing cycle of sewage and filtrate
CN106315809A (en) * 2016-09-22 2017-01-11 武汉嘉讯源科技有限公司 Novel treatment device of wastewater containing sulfate radicals
CN207143363U (en) * 2017-09-05 2018-03-27 大连新创科技发展有限公司 Electroplate liquid removes lead system
CN211872109U (en) * 2020-01-14 2020-11-06 内蒙古乌海化工有限公司 Device for removing sulfate radical in chlor-alkali production brine

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4054517A (en) * 1974-08-06 1977-10-18 John Cunningham Chrome removal and recovery
GB1537914A (en) * 1976-02-13 1979-01-10 Cunningham J Chrome removal and recovery
JPH07316898A (en) * 1994-05-18 1995-12-05 Chlorine Eng Corp Ltd Removing method of sulfate ion in chromium plating solution
CN101759202A (en) * 2008-12-24 2010-06-30 新疆石河子中发化工有限责任公司 Method for removing sulfate radicals in saline water by using liquid barium chloride
CN103833167A (en) * 2014-03-13 2014-06-04 黄运富 Chromic acid wastewater treatment method and system
CN203807587U (en) * 2014-04-30 2014-09-03 遂宁市维海电子科技有限公司 FPC (Flexible Printed Circuit) board electroplating liquid circulation treatment device
CN105314759A (en) * 2014-07-19 2016-02-10 天津市绿净源环保科技有限公司 Chromium-containing wastewater processing apparatus realizing cycle of sewage and filtrate
CN106315809A (en) * 2016-09-22 2017-01-11 武汉嘉讯源科技有限公司 Novel treatment device of wastewater containing sulfate radicals
CN207143363U (en) * 2017-09-05 2018-03-27 大连新创科技发展有限公司 Electroplate liquid removes lead system
CN211872109U (en) * 2020-01-14 2020-11-06 内蒙古乌海化工有限公司 Device for removing sulfate radical in chlor-alkali production brine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周扬: "硫酸根对离子膜电解工艺影响及处理", 《氯碱工业》 *

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