CN113979694A - Exposed fiber concrete material and preparation method thereof - Google Patents

Exposed fiber concrete material and preparation method thereof Download PDF

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Publication number
CN113979694A
CN113979694A CN202111392055.8A CN202111392055A CN113979694A CN 113979694 A CN113979694 A CN 113979694A CN 202111392055 A CN202111392055 A CN 202111392055A CN 113979694 A CN113979694 A CN 113979694A
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fiber
exposed
concrete material
fibers
concrete
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CN113979694B (en
Inventor
潘瑞
董赛阳
瞿威
朱敏涛
吴杰
卞成辉
戴志辉
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Kunshan Shenghua Concrete Co ltd
Shanghai Caiyi Technology Co ltd
Shanghai Construction Building Materials Technology Group Co Ltd
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Kunshan Shenghua Concrete Co ltd
Shanghai Construction Building Materials Technology Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/48Metal
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0625Polyalkenes, e.g. polyethylene
    • C04B16/0633Polypropylene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0641Polyvinylalcohols; Polyvinylacetates
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/88Insulating elements for both heat and sound
    • E04B1/90Insulating elements for both heat and sound slab-shaped
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04HBUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL
    • E04H17/00Fencing, e.g. fences, enclosures, corrals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Architecture (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Acoustics & Sound (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses an exposed fiber concrete material which comprises the following components in percentage by mass: 14.9 to 38.9 percent of cement, 0 to 21.7 percent of admixture, 48.3 to 71.7 percent of fine aggregate, 0.25 to 0.73 percent of synthetic fiber, 0.3 to 0.53 percent of water reducing agent and the balance of water, or 14.9 to 38.9 percent of cement, 0 to 21.9 percent of admixture, 48.3 to 71.7 percent of fine aggregate, 3.55 to 9.13 percent of metal fiber, 0.3 to 0.53 percent of water reducing agent and the balance of water. The exposed fiber concrete material is used in the field of protective walls and protective fence nets, and has more excellent protective effect; the sound insulation board is used in the field of sound insulation boards, can achieve excellent sound insulation effect, and can absorb dust and play a certain protection role; the fiber has the heat preservation function, so that the whole structure has a good heat preservation function; the preparation process of the exposed fiber concrete is simple, the raw materials are easy to obtain, and the economic benefit is high.

Description

Exposed fiber concrete material and preparation method thereof
Technical Field
The invention belongs to the technical field of concrete, and relates to an exposed fiber concrete material and a preparation method thereof.
Background
Concrete is currently the most widely used civil engineering material. Although the compressive strength of concrete is generally high, its tensile properties have been relatively weak. Poor tensile properties can lead to the concrete being prone to cracking, thereby reducing the durability of the concrete and the like, and preventing the structure from reaching the target life. The addition of fibrous materials to concrete to form fibrous concrete materials has been shown to be effective in increasing the tensile strength of concrete.
At present, the fiber plays a bridging role in concrete, can improve the mechanical property of the concrete to a certain extent, and can effectively improve the durability of the concrete. The bionic design principle is adopted, the fibers are exposed on the surface of the concrete board, and the heat insulation performance, the sound insulation performance or the protective performance of the board can be effectively improved by selecting different fiber types, but the application research on exposed fiber concrete materials is lacked at present.
Therefore, a related technical scheme is needed to fill the research blank in the field.
Disclosure of Invention
It has been shown that different types of fibres can give open fibre concrete materials different uses. For example, the exposed steel fiber concrete can play a role in protection because the surface of the exposed steel fiber concrete is fully distributed with steel fibers, and can be used as a protective net in places such as prisons. When the fiber in the exposed fiber concrete is polyvinyl alcohol fiber or polyacrylonitrile fiber, the concrete material has sound insulation effect and can be used as a sound insulation board.
The invention aims to disclose a fiber-exposed concrete material, wherein fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure BDA0003364171800000011
the average length of the fibers exposed from the surface of the fiber-exposed concrete material is 10-20 mm.
The invention also aims to disclose a fiber-exposed concrete material, wherein fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure BDA0003364171800000021
the average length of the fibers exposed from the surface of the fiber-exposed concrete material is 10-35 mm.
Furthermore, the fluidity of the exposed fiber concrete material is more than or equal to 160 mm.
Further, the cement is portland cement or ordinary portland cement.
Further, the admixture comprises one or more of fly ash, silica fume and slag micropowder.
Further, the water reducing agent is a polycarboxylic acid water reducing agent, and the water reducing rate is 30-40%.
Further, the synthetic fiber is selected from one or more of polyvinyl alcohol fiber, polyacrylonitrile fiber, polyester fiber and polypropylene fiber, the length of the synthetic fiber is 25-35mm, and the diameter of the synthetic fiber is more than 0.03 mm.
Further, the metal fiber is steel fiber, the length of the metal fiber is 35-45mm, and the diameter of the metal fiber is 0.2-1.0 mm.
Further, the retarder is selected from one or more of phosphate, gluconate and citric acid.
The invention also aims to disclose a preparation method of the exposed fiber concrete material, which comprises the following steps:
s1, uniformly mixing fine aggregate, cement and an admixture, adding fibers, stirring to be pasty, pouring into a mold, and molding to obtain a coarse product;
s2, leveling the coarse product, spraying a retarder on the surface of the coarse product, and vibrating the coarse product after the retarder penetrates through the surface of the concrete to reach a preset penetration depth;
s3, when the internal concrete reaches a final setting state, removing the formwork to obtain a concrete intermediate product;
s4, washing the concrete intermediate product to enable the fibers to be exposed out of the concrete intermediate product in a specified length;
s5, standing and cleaning the concrete intermediate product to obtain the product.
Further, in step S2, the predetermined penetration depth is 10-20 mm.
Further, in step S4, the specified length is equal to or greater than 15 mm.
The invention also aims to disclose the application of the exposed fiber concrete material in the aspects of protecting walls, protective railings, sound insulation boards and the like.
The invention has the following beneficial effects:
(1) when the fiber is steel fiber, the exposed fiber concrete provided by the invention is used in the field of protective walls and protective fence nets, and the protective effect is more excellent.
(2) When the fiber is synthetic fiber, the exposed fiber concrete is used in the field of sound insulation boards, and the synthetic fiber forms a fiber layer on the surface of the exposed fiber concrete, so that the exposed fiber concrete not only has excellent sound insulation effect, but also can absorb dust and play a certain protection role.
(3) For the exposed fiber concrete, the fiber of the exposed fiber concrete has a heat preservation function, so that the whole structure has a good heat preservation function.
(4) The preparation method of the exposed fiber concrete based on the invention has the advantages of simple preparation process, easily obtained raw materials and high economic benefit.
Detailed Description
In order to more clearly illustrate the technical solution of the present invention, the following examples are given, but the present invention is not limited thereto.
The experimental methods used in the following examples are all conventional methods unless otherwise specified; reagents, materials and the like used in the following examples are commercially available unless otherwise specified.
Examples of the invention
The testing method of the fluidity of the exposed fiber concrete material is carried out according to JGJ/T70-2009.
The cement is Portland cement, and the strength grade is 42.5;
the type of the fine aggregate is natural sand, wherein the mud content of the natural sand is less than or equal to 3 wt%, and the fineness modulus is about 2.2-3.2;
the type of the water reducing agent is a polycarboxylic acid liquid water reducing agent.
Example 1
The fiber-exposed concrete material is characterized in that fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure BDA0003364171800000031
the average length of the fibers exposed from the surface of the fiber-exposed concrete material was 17 mm.
Wherein the diameter of the steel fiber is 0.2mm, and the length is 35 mm;
the fluidity of the exposed fiber concrete material was 200 mm.
The preparation method of the exposed fiber concrete material comprises the following steps:
s1, uniformly mixing the fine aggregate, cement and admixture according to the mass fraction, adding steel fiber, stirring to be pasty, pouring into a mold, and molding to obtain a crude product;
s2, leveling the coarse product by using a tool, uniformly spraying a sodium gluconate retarder on the surface of the coarse product in a high-pressure atomization mode, and vibrating the coarse product in the whole mould to compact the coarse product after the retarder penetrates the surface of the concrete to reach a preset penetration depth (20 mm);
s3, after the internal concrete reaches a final setting state, removing the formwork to obtain a concrete intermediate product;
s4, washing the concrete intermediate product with a high-pressure water gun to enable the fibers to be exposed to a specified length (the average length is about 17 mm);
s5, standing for 2 days, and cleaning the surface of the concrete intermediate product by using a brush to obtain the product exposed fiber concrete material.
Example 2
The fiber-exposed concrete material is characterized in that fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure BDA0003364171800000041
the average length of the fibers exposed from the surface of the fiber-exposed concrete material was 15 mm.
Wherein the diameter of the polypropylene fiber is 0.035mm, and the length is 25 mm;
the fluidity of the open fiber concrete material was 198 mm.
The preparation method of the exposed fiber concrete material comprises the following steps:
s1, uniformly mixing the fine aggregate, cement and admixture according to the mass fraction, adding polypropylene fiber, stirring to be pasty, pouring into a mold, and molding to obtain a crude product;
s2, leveling the crude product by using a tool, uniformly spraying a sodium tripolyphosphate retarder on the surface of the crude product in a high-pressure atomization mode, and vibrating the crude product in the whole mould to compact the crude product after the retarder penetrates the surface of the concrete to reach a preset penetration depth (20 mm);
s3, after the internal concrete reaches a final setting state, removing the formwork to obtain a concrete intermediate product;
s4, washing the concrete intermediate product with a high-pressure water gun to enable the fibers to be exposed to a specified length (the average length is about 15 mm);
s5, standing for 1 day, and cleaning the surface of the concrete intermediate product by using a hairbrush to obtain the product exposed fiber concrete material.
Example 3
The fiber-exposed concrete material is characterized in that fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure BDA0003364171800000051
the average length of the fibers exposed from the surface of the fiber-exposed concrete material was 15 mm.
Wherein, the diameter of the polyvinyl alcohol fiber is 0.3mm, and the length is 30 mm;
the fluidity of the open fiber concrete material was 179 mm.
The preparation method of the exposed fiber concrete material comprises the following steps:
s1, uniformly mixing the fine aggregate, cement and an admixture according to the mass fraction, adding polyvinyl alcohol fiber, stirring to be pasty, pouring into a mold, and molding to obtain a crude product;
s2, leveling the crude product by using a tool, uniformly spraying a sodium tripolyphosphate retarder on the surface of the crude product in a high-pressure atomization mode, and vibrating the crude product in the whole mould to compact the crude product after the retarder penetrates the surface of the concrete to reach a preset penetration depth (20 mm);
s3, after the internal concrete reaches a final setting state, removing the formwork to obtain a concrete intermediate product;
s4, washing the concrete intermediate product with a high-pressure water gun to enable the fibers to be exposed to a specified length (the average length is about 15 mm);
s5, standing for 1 day, and cleaning the surface of the concrete intermediate product by using a hairbrush to obtain the product exposed fiber concrete material.
Test example
The exposed fiber concrete material obtained in example 1 was used for the test of the protection board.
The test method comprises the following steps: visual inspection was carried out.
The test results are: the steel fibers on the surface of the wall body are uniformly distributed and protrude out of the wall body in a spine shape, so that the effective isolation effect is achieved.
The fiber-exposed concrete material obtained in example 2 was used for the test of acoustical panels.
The test method comprises the following steps: according to section 1 of measurement of sound absorption coefficient and sound impedance in an acoustic impedance tube: the sound absorption coefficient was tested by the standard test method of standing wave ratio method (GB/T18696.1).
The test results are: the sound absorption coefficient of the soundproof panel was 60%.
The exposed fiber concrete material obtained in the embodiment 3 is used for testing the insulation board.
The test method comprises the following steps: and testing the heat conductivity coefficient of the heat-insulating board according to a standard test method of the steady-state thermal resistance of the heat-insulating material and a related testing heat-shielding board method (GB/T10294-.
The test results are: the thermal conductivity of the insulation board is 0.43W/m.k.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (10)

1. The fiber-exposed concrete material is characterized in that fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure FDA0003364171790000011
the average length of the fibers exposed from the surface of the fiber-exposed concrete material is 10-20 mm.
2. The fiber-exposed concrete material is characterized in that fibers are exposed on the surface of the fiber-exposed concrete material, and the fiber-exposed concrete material comprises the following components in percentage by mass:
Figure FDA0003364171790000012
the average length of the fibers exposed from the surface of the fiber-exposed concrete material is 10-35 mm.
3. The fiber-exposed concrete material according to claim 1, wherein the fluidity of the fiber-exposed concrete material is not less than 160 mm.
4. The fiber-exposed concrete material according to claim 1, wherein the cement is portland cement or ordinary portland cement.
5. The fiber-exposed concrete material according to claim 1, wherein the admixture comprises one or more of fly ash, silica fume and slag micropowder; the water reducing agent is a polycarboxylic acid water reducing agent, and the water reducing rate is 30-40%.
6. The fiber-exposed concrete material according to claim 1, wherein the synthetic fibers are selected from one or more of polyvinyl alcohol fibers, polyacrylonitrile fibers, polyester fibers and polypropylene fibers, and the synthetic fibers have a length of 25-35mm and a diameter of 0.03mm or more.
7. The fiber-exposed concrete material according to claim 2, wherein the metal fibers are steel fibers,
the length of the metal fiber is 35-45mm, and the diameter is 0.2-1.0 mm.
8. A method of producing the fibre-exposed concrete material according to any one of claims 1 to 7, characterised in that it comprises the following steps:
s1, uniformly mixing fine aggregate, cement and an admixture, adding fibers, stirring to be pasty, pouring into a mold, and molding to obtain a coarse product;
s2, leveling the coarse product, spraying a retarder on the surface of the coarse product, and vibrating the coarse product after the retarder penetrates through the surface of the concrete to reach a preset penetration depth;
s3, after the internal concrete reaches a final setting state, removing the formwork to obtain a concrete intermediate product;
s4, washing the concrete intermediate product to enable the fibers to be exposed out of the concrete intermediate product in a specified length;
s5, standing and cleaning the concrete intermediate product to obtain a final product.
9. The method for preparing fiber-exposed concrete material according to claim 8, wherein in step S2, the predetermined penetration depth is 10-20 mm;
in step S4, the specified length is equal to or greater than 10 mm.
10. Use of the exposed fiber concrete material according to any one of claims 1 to 7 for protective walls, protective barriers, and acoustic panels.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102092996A (en) * 2010-11-30 2011-06-15 南京理工大学 Cement-based composite material with high-temperature resistance and superhigh performance and preparation method thereof
CN103496894A (en) * 2013-09-16 2014-01-08 北京工业大学 Steel fiber and high-performance synthetic fiber mixed toughened RPC (reactive powder concrete) and preparation method
CN110284633A (en) * 2019-04-30 2019-09-27 中国一冶集团有限公司 Embedded thermal-insulating waterproof block shear wall and its construction method
CN112408918A (en) * 2020-12-03 2021-02-26 上海建工建材科技集团股份有限公司 3D printing concrete material added with crushed stone coarse aggregate and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102092996A (en) * 2010-11-30 2011-06-15 南京理工大学 Cement-based composite material with high-temperature resistance and superhigh performance and preparation method thereof
CN103496894A (en) * 2013-09-16 2014-01-08 北京工业大学 Steel fiber and high-performance synthetic fiber mixed toughened RPC (reactive powder concrete) and preparation method
CN110284633A (en) * 2019-04-30 2019-09-27 中国一冶集团有限公司 Embedded thermal-insulating waterproof block shear wall and its construction method
CN112408918A (en) * 2020-12-03 2021-02-26 上海建工建材科技集团股份有限公司 3D printing concrete material added with crushed stone coarse aggregate and preparation method thereof

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