CN113913885B - Nano composite brush plating process for cylindrical surface - Google Patents

Nano composite brush plating process for cylindrical surface Download PDF

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Publication number
CN113913885B
CN113913885B CN202111322569.6A CN202111322569A CN113913885B CN 113913885 B CN113913885 B CN 113913885B CN 202111322569 A CN202111322569 A CN 202111322569A CN 113913885 B CN113913885 B CN 113913885B
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Prior art keywords
plating
plating solution
brush
nano particles
storage tank
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CN113913885A (en
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冯科
王水根
陈欣
易泉秀
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CISDI Research and Development Co Ltd
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CISDI Research and Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/04Electroplating with moving electrodes
    • C25D5/06Brush or pad plating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/16Regeneration of process solutions
    • C25D21/18Regeneration of process solutions of electrolytes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02Electroplating of selected surface areas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

The invention relates to the technical field of metal surface treatment, in particular to a nano composite brush plating process of a cylindrical surface. The method comprises the following steps: introducing the plating solution containing the nano particles in the liquid storage tank into an ultrasonic crushing device for real-time dispersion treatment to obtain the plating solution containing the dispersed nano particles; uniformly spraying the plating solution containing the dispersed nano particles onto an anode sheath through a shunt nozzle so as to enable a brush plating assembly arranged outside a liquid storage tank to brush plate the plating solution containing the dispersed nano particles on a workpiece to be brushed and plated arranged outside the liquid storage tank; the plating solution dropped after spraying falls into a liquid storage tank below the brush plating assembly so as to recycle the plating solution. The beneficial effects are that: the plating solution slurry containing the dispersed nano particles after ultrasonic crushing treatment is directly output to a brush plating assembly for use, so that the dispersed nano particles are immediately subjected to brush plating, the residence time is short, the probability of dynamic re-agglomeration is reduced, the dispersion state of the nano particles in a plating layer is improved, and the plating performance is improved.

Description

Nano composite brush plating process for cylindrical surface
Technical Field
The invention relates to the technical field of metal surface treatment, in particular to a nano composite brush plating process of a cylindrical surface.
Background
The electric brush plating technology is especially suitable for repairing and remanufacturing worn, corroded and scratched parts of mechanical equipment, such as large equipment and weapon armor surfaces, due to the characteristics of convenient operation, low cost, good repairing effect and the like. Nano particles are added into the plating solution for nano composite brush plating, so that the hardness and wear resistance of the plating layer can be further improved, and better protection of a substrate can be realized.
For the nano composite brush plating technology, how to uniformly disperse nano particles in plating solution and plating layer is a key for improving the performance of the plating layer, and is also a difficult point. The existing common particle dispersing methods comprise a chemical modification method, a mechanical stirring method and an ultrasonic dispersing method, and the three methods have advantages and disadvantages and have unsatisfactory using effects. The most notable is the energy-accumulating ultrasonic dispersion method, which utilizes cavitation effect generated by energy-accumulating ultrasonic vibration in liquid to break agglomerated nano particles, and has good particle breaking effect, but the method has the disadvantages of small action range, and the broken and dispersed nano particles still can be dynamically re-agglomerated and cannot be stably dispersed for a long time. The ultrasonic vibration module is arranged in the electrode body, namely the anode, and the dipped composite plating solution can be stirred and dispersed by starting the ultrasonic vibration module, but the method only carries out ultrasonic vibration treatment on the dipped solution, and cannot form an effective cavitation effect, so that a powerful crushing phenomenon cannot be formed, the crushing effect of nano particles is still poor, and stirring and dispersing are still carried out.
Disclosure of Invention
In view of the above drawbacks of the prior art, an object of the present invention is to provide a nanocomposite brush plating process for cylindrical surfaces, which is used for solving the problems of poor dispersion state of nanoparticles in a plating layer and poor plating performance in the prior art.
To achieve the above and other related objects, the present invention provides a nanocomposite brush plating process for cylindrical surfaces, comprising the steps of:
introducing the plating solution containing nano particles in the liquid storage tank into an ultrasonic crushing device;
carrying out real-time dispersion treatment on the nano particles in the plating solution in an ultrasonic crushing device to obtain the plating solution containing dispersed nano particles;
uniformly spraying the plating solution containing the dispersed nano particles onto an anode sheath through a shunt nozzle for a brush plating assembly arranged outside a liquid storage tank to be used, and brushing the plating solution containing the dispersed nano particles on a workpiece to be brushed arranged outside the liquid storage tank through the brush plating assembly;
wherein, the plating solution that drops after spraying falls directly into the liquid storage tank that is located the brush plating subassembly below to make plating solution recovery circulation processing use.
Optionally, the introducing the plating solution containing the nanoparticles in the liquid storage tank into the ultrasonic crushing device comprises:
the plating solution containing nano particles in the liquid storage tank is introduced into the ultrasonic crushing device through the first pipeline, two ends of the first pipeline are respectively connected with the liquid storage tank and the ultrasonic crushing device, a power pump arranged on the first pipeline is started, and a flow regulating valve arranged on the first pipeline is regulated so as to control the flow of the plating solution in the first pipeline to be a preset flow.
Optionally, the preset flow is 0.5L/min-10L/min.
Optionally, a flowmeter is further arranged on the first pipeline.
Optionally, after the flow of the plating solution in the first pipeline displayed by the flowmeter is stable, starting the ultrasonic crushing device to perform real-time dispersion treatment on the nano particles in the plating solution.
Optionally, the ultrasonic crushing device includes:
the crushing kettle is connected with the liquid storage tank through the first pipeline and is used for accommodating plating solution;
the ultrasonic generator is arranged outside the crushing kettle, and an energy-gathering ultrasonic probe extending into the crushing kettle is arranged on the ultrasonic generator; a kind of electronic device with high-pressure air-conditioning system
And the ultrasonic power supply is used for supplying power to the ultrasonic generator.
Optionally, the crushing kettle is connected with the split-flow nozzle through a second pipeline, a split-flow hose is connected to a nozzle outlet of the split-flow nozzle, and an outlet end of the split-flow hose is inserted into the anode sheath.
Optionally, the split nozzle includes a plurality of nozzle outlets, and each nozzle outlet is connected with the split hose respectively, and the exit end of a plurality of split hoses evenly distributes in the positive pole sheath.
Optionally, the brush plating assembly comprises a brush plating pen and a brush plating power supply, the anode sheath is arranged on the brush plating pen and used for contacting with a workpiece to be brush plated, and the anode and the cathode of the brush plating power supply are respectively connected with the brush plating pen and the workpiece to be brush plated; when the plating solution is uniformly sprayed onto the anode sheath through the shunt nozzle, a brush plating pen is started to carry out brush plating operation until the plating thickness of the workpiece to be brush plated reaches a preset thickness.
Optionally, the thickness of the anode sheath is 5 mm-15 mm, the anode sheath is of an arc structure, and the arc radius of the inner side of the anode sheath is the same as the cylindrical surface radius of the workpiece to be brushed.
As described above, the nano composite brush plating process of the cylindrical surface has at least the following beneficial effects: the plating solution slurry containing the dispersed nano particles after ultrasonic crushing treatment is directly output to a brush plating assembly for use, so that the dispersed nano particles are immediately subjected to brush plating, the residence time is short, the probability of dynamic re-agglomeration is reduced, the dispersion state of the nano particles in a plating layer is greatly improved, and the plating performance is improved.
Drawings
FIG. 1 is a schematic diagram of a process for nano-composite brush plating of cylindrical surfaces according to an embodiment of the present invention;
FIG. 2 is a schematic view of the split nozzle of FIG. 1;
FIG. 3 is a scanning electron microscope microstructure of a nanocomposite brush deposit of a product processed by an embodiment of the inventive cylindrical surface nanocomposite brush plating process.
Description of the part reference numerals
1-a liquid storage tank; 2-a first pipeline; 21-a power pump; 22-a flow regulating valve; 23-a flow meter; 31-crushing the kettle; 311-inlet; 312-outlet; 313-opening; 32-an ultrasonic generator; 33-energy-gathering ultrasonic probes; 34-an ultrasonic power supply; 35-connecting wires; 4-a second pipeline; 51-brushing a plating pen; 52-brushing a plating power supply; 53-anode sheath; 6-plating solution; 7-a workpiece; 8-a split-flow nozzle; 81-nozzle inlet; 82-a nozzle outlet; 9-split hose.
Detailed Description
Other advantages and effects of the present invention will become apparent to those skilled in the art from the following disclosure, which describes the embodiments of the present invention with reference to specific examples. The invention may be practiced or carried out in other embodiments that depart from the specific details, and the details of the present description may be modified or varied from the spirit and scope of the present invention.
Please refer to fig. 1 to 3. It should be noted that, the illustrations provided in the present embodiment merely illustrate the basic concept of the present invention by way of illustration, and only the components related to the present invention are shown in the drawings and are not drawn according to the number, shape and size of the components in actual implementation, and the form, number and proportion of the components in actual implementation may be arbitrarily changed, and the layout of the components may be more complex. The structures, proportions, sizes, etc. shown in the drawings attached hereto are for illustration purposes only and are not intended to limit the scope of the invention, which is defined by the claims, but rather by the claims. Also, the terms such as "upper," "lower," "left," "right," "middle," and "a" and the like recited in the present specification are merely for descriptive purposes and are not intended to limit the scope of the invention, but are intended to provide relative positional changes or modifications without materially altering the technical context in which the invention may be practiced.
Before describing embodiments of the present invention in detail, an application environment of the present invention will be described. The technology of the invention is mainly applied to the technical field of metal surface treatment, in particular to a process for synchronously carrying out ultrasonic dispersing agent nano composite brush plating treatment of nano particles. The invention solves the problems of difficult dispersion of nano particles in plating solution and poor plating performance of the surface of a workpiece, and particularly, the problem of inconvenient plating of a cylindrical surface and poor distribution uniformity of the plating solution.
Referring to fig. 1, in an embodiment, the nano-composite brush plating process for cylindrical surfaces provided by the present application includes the following steps: introducing the plating solution 6 containing nano particles in the liquid storage tank 1 into an ultrasonic crushing device; carrying out real-time dispersion treatment on the nano particles in the plating solution in an ultrasonic crushing device to obtain the plating solution containing dispersed nano particles; uniformly spraying the plating solution containing the dispersed nano particles onto the anode sheath 53 through the shunt nozzle 8 for the brush plating assembly arranged outside the liquid storage tank 1 to be used, and brushing the plating solution containing the dispersed nano particles on the workpiece 7 to be brushed arranged outside the liquid storage tank 1 through the brush plating assembly; wherein, the plating solution that drops after spraying falls directly into reservoir 1 that is located the brush plating subassembly below to make plating solution recovery circulation processing use.
The aggregated nano particles in the plating solution are dispersed through simple steps, and a small amount of plating solution slurry containing the dispersed nano particles after ultrasonic crushing treatment is directly output for brush plating, so that the dispersed nano particles stand for brush plating operation, the residence time is short, the probability of dynamic re-aggregation is reduced, the dispersion state of the nano particles in a plating layer is greatly improved, and the plating performance is improved; and the whole process is circularly reciprocated, nano particles are crushed by ultrasound in real time, and nano composite brush plating treatment is carried out in real time, so that a circulation system is formed.
Referring to fig. 1, in one embodiment, introducing a plating solution containing nanoparticles in a reservoir into an ultrasonic disruption device includes:
the plating solution containing nano particles in the liquid storage tank 1 is introduced into the ultrasonic crushing device through the first pipeline 2, two ends of the first pipeline 2 are respectively connected with the liquid storage tank 1 and the ultrasonic crushing device, a power pump 21 arranged on the first pipeline 2 is started, and a flow regulating valve 22 arranged on the first pipeline 2 is regulated so as to control the flow of the plating solution in the first pipeline 2 to be a preset flow.
Optionally, the preset flow is 0.5L/min-10L/min.
Optionally, a flowmeter 23 is further provided on the first pipeline 2.
Referring to fig. 1, in an embodiment, after the flow rate of the plating solution in the first pipeline 2 displayed by the flow meter 23 is stable, the ultrasonic breaking device is turned on to perform real-time dispersion treatment on the nanoparticles in the plating solution.
Referring to fig. 1, in one embodiment, the ultrasonic crushing apparatus includes a crushing tank 31, an ultrasonic power source 34, and an ultrasonic generator 32 disposed outside the crushing tank 31. The ultrasonic power supply 34 is used to supply power to the ultrasonic generator 32 to drive the ultrasonic generator 32 to generate ultrasonic vibrations. Wherein, the crushing kettle 31 is connected with the liquid storage tank 1 through a first pipeline 2 and is used for containing plating solution; the ultrasonic generator 32 is provided with an energy-collecting ultrasonic probe 33 extending into the crushing kettle 31, and the energy-collecting ultrasonic probe 33 amplifies the ultrasonic vibration generated by the ultrasonic generator 32 to enhance the crushing capacity.
Referring to fig. 1, optionally, in one embodiment, an ultrasonic power source 34 is connected to the ultrasonic generator 32 by a connection line 35.
Referring to fig. 1, optionally, in an embodiment, the bottom of the crushing vessel 31 is provided with an inlet 311 connected to the first pipe 2; the upper side wall of the crushing kettle 31 is provided with an outlet 312 connected with the second pipeline 4, the plating solution in the liquid storage tank 1 enters the crushing kettle 31 through the first pipeline 2, and after the ultrasonic treatment of the crushing kettle 31 is completed, the plating solution is output by the second pipeline 4.
Referring to fig. 1, optionally, in an embodiment, an opening 313 is provided at the top of the crushing kettle 31 for inserting the energy-accumulating ultrasonic probe 33, and the energy-accumulating ultrasonic probe 33 extends into the crushing kettle 31 from the opening 313 to perform ultrasonic crushing treatment on the plating solution containing nanoparticles in the crushing kettle 31, so that the agglomerated nanoparticles in the plating solution are dispersed.
Referring to fig. 1, optionally, in an embodiment, a power pump 21 is used to power the plating solution delivery, and the plating solution containing nano particles in the liquid storage tank 1 is sucked out by the power pump 21 and then delivered into the crushing kettle 31 through the first pipeline 2; the flow regulating valve 22 is used for controlling the flow of the plating solution, and the time of ultrasonic crushing treatment of the plating solution in the crushing kettle 31 is controlled by controlling the flow of the plating solution; the flow meter 23 is used for displaying the flow in the first pipeline 2, so as to monitor the real-time flow in the first pipeline 2 in time.
Referring to fig. 1 and 2, in one embodiment, the crushing vessel 31 is connected via a second line 4 to a distribution nozzle 8 through which the plating solution is sprayed evenly onto the anode sheath.
Optionally, in an embodiment, the nozzle inlet 81 of the shunt nozzle 8 is connected to the second pipeline 4, the nozzle outlet 82 of the shunt nozzle 8 is connected to the shunt hose 9, the outlet end of the shunt hose 9 is inserted into the anode sheath 53, the shunt nozzle 8 is connected to the anode sheath 53 through the shunt hose 9, and the shunt hose 9 facilitates adjusting the distribution position, so that the shunt hose 9 is installed at a designated position in the anode sheath 53, so as to improve the uniformity of plating solution distribution.
Optionally, in an embodiment, the split nozzle 8 includes a plurality of nozzle outlets 82, each nozzle outlet 82 being connected with a respective split hose 9, the outlet ends of the plurality of split hoses 9 being evenly distributed within the anode jacket 53. In this embodiment, the plurality of split hoses 9 may be distributed along the axial direction of the workpiece 7 so as to uniformly distribute a single plating solution stream, thereby enabling uniform distribution of the plating solution containing nanoparticles in the anode sheath and preventing excessive concentration of the plating solution in a single area.
Alternatively, the diverting hose may be a rubber hose.
Referring to fig. 1, in one embodiment, the brush plating assembly includes a brush plating pen 51 and a brush plating power source 52, an anode sheath 53 is mounted on the brush plating pen 51, the anode sheath 53 is used to contact the workpiece 7 to be brush plated, and an anode and a cathode of the brush plating power source 52 are respectively connected with the brush plating pen 51 and the workpiece 7 to be brush plated such that the workpiece 7 serves as a cathode terminal and the brush plating pen 51 serves as an anode terminal. When the plating solution is uniformly sprayed onto the anode sheath through the shunt nozzle, a brush plating pen is started to perform brush plating operation until the thickness of a plating layer of a workpiece to be brush plated reaches a preset thickness, and brush plating is performed immediately after the nano particles are uniformly dispersed, so that the nano particles enter the plating layer to maintain a good dispersion state, and the plating performance is improved.
Referring to fig. 1, optionally, in an embodiment, the front end of the brush plating pen 51 is provided with an anode, and the material of the anode may be graphite or stainless steel, etc. An anode sheath 53 is positioned between the workpiece 7 and the brush plating pen 51 to prevent direct contact between the cathode and anode during brush plating.
Referring to fig. 1, alternatively, in an embodiment, the anode sheath 53 may be made of a polyester-cotton fabric, and the anode sheath 53 may also function as a reservoir.
Alternatively, in an embodiment, the thickness of the anode sheath 53 may be 5mm to 15mm, for example, any one of 5mm, 8mm, 10mm, 11mm, 15mm, etc. The anode sheath can be of an arc-shaped structure, and the arc-shaped radius of the inner side of the anode sheath is the same as the radius of the cylindrical surface of the workpiece to be brushed, so that the anode sheath is fully contacted and attached with the cylindrical surface of the workpiece, and the uniform brushing plating of the plating solution on the workpiece is facilitated.
Referring to fig. 1, in one embodiment, at least one of the brush plating pen 51 and the workpiece 7 is movable, i.e., the brush plating pen 51 and the workpiece 7 can move relative to each other, thereby achieving brush plating repair for different areas of the workpiece.
Referring to fig. 1, optionally, in an embodiment, the workpiece 7 is a cylindrical workpiece, such as a roller workpiece or a barrel workpiece, and the surface of the anode sheath 53 facing the workpiece 7 is matched with the workpiece 7 in shape, such as a concave arc surface, so that the anode sheath is in full fitting contact with the workpiece, and the brushing quality is improved. When the brush plating work is performed, the workpiece 7 can be driven to rotate by an external motor, and the brush plating pen 51 is kept relatively fixed, so that the brush plating of the whole cylindrical surface is realized. Especially when the surface of the large-scale equipment workpiece needs to be repaired, the workpiece 7 is driven to move relatively troublesome, and the repair can be realized by driving the anode end to move, namely, the brush plating pen 51 and the anode sheath 53 are driven to move together to repair the appointed surface, and the shunt nozzle sends the plating solution to the anode sheath through the shunt hose, so that the distribution uniformity of the plating solution is improved, and the anode sheath can flexibly move.
In a specific embodiment, a power pump is started, and after the flow is regulated and stabilized, an ultrasonic crushing device is started to perform pre-dispersion treatment of nano particles by regulating a flow regulating valve to the required flow; after pre-dispersing for 1h, uniformly inputting the plating solution subjected to real-time dispersing into an anode sheath to spray on a workpiece through a second pipeline, and naturally refluxing the sprayed plating solution into a liquid storage tank; starting a brush plating pen to perform brush plating on the workpiece, and stopping brush plating after the plating layer reaches the expected thickness; and closing the ultrasonic crushing device and closing the power pump.
According to the nano composite brush plating process for the cylindrical surface, a small amount of plating solution slurry containing dispersed nano particles, which is subjected to ultrasonic crushing treatment, is output in real time for a brush plating assembly to use, the dispersed nano particles are subjected to brush plating in real time, the residence time is short, the probability of dynamic re-agglomeration is reduced, the dispersion state of the nano particles in a plating layer is greatly improved, the plating performance is improved, the nano particles are uniformly dispersed in the plating layer, the nano scale of the particles is basically maintained, and the performance of the nano composite plating layer is greatly improved. The workpiece and the brush plating assembly are arranged outside the liquid storage tank, so that the workpiece to be brush plated can finish brush plating outside the liquid storage tank without being immersed in the liquid storage tank, the influence of plating solution in the liquid storage tank on the uniformity of brush plating of the workpiece is reduced, the workpiece or the brush plating assembly is convenient to rotate, the occupied space is reduced, and the requirement on the size of the liquid storage tank is reduced, particularly, when the brush plating is performed on some large-scale equipment workpieces, the operation is simpler and more convenient; on the other hand, the brush plating of the workpiece is performed outside the liquid storage tank, so that the plating solution acting on the surface of the workpiece is the plating solution after ultrasonic crushing treatment, other plating solutions containing re-agglomerated nano particles in the liquid storage tank are prevented from acting on the workpiece, and the performance of the plating layer on the surface of the workpiece is further improved.
In the description of the present specification, the descriptions of the terms "present embodiment," "example," "specific example," and the like, mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The above embodiments are merely illustrative of the principles of the present invention and its effectiveness, and are not intended to limit the invention. Modifications and variations may be made to the above-described embodiments by those skilled in the art without departing from the spirit and scope of the invention. Accordingly, it is intended that all equivalent modifications and variations of the invention be covered by the claims, which are within the ordinary skill of the art, be within the spirit and scope of the present disclosure.

Claims (6)

1. The nano composite brush plating process of the cylindrical surface is characterized by comprising the following steps of:
introducing the plating solution containing nano particles in the liquid storage tank into an ultrasonic crushing device, wherein the plating solution containing nano particles in the liquid storage tank is introduced into the ultrasonic crushing device through a first pipeline, two ends of the first pipeline are respectively connected with the liquid storage tank and the ultrasonic crushing device, a power pump arranged on the first pipeline is started, and a flow regulating valve arranged on the first pipeline is regulated so as to control the flow of the plating solution in the first pipeline to be a preset flow, and the preset flow is 0.5L/min-10L/min;
carrying out real-time dispersion treatment on the nano particles in the plating solution in an ultrasonic crushing device to obtain the plating solution containing dispersed nano particles;
the plating solution containing the dispersed nano particles is uniformly sprayed onto an anode sheath through a shunt nozzle so as to be used by a brush plating assembly arranged outside a liquid storage tank, the plating solution containing the dispersed nano particles is brush plated on a workpiece to be brush plated arranged outside the liquid storage tank through the brush plating assembly, a nozzle outlet of the shunt nozzle is connected with a shunt hose, an outlet end of the shunt hose is inserted into the anode sheath, the shunt nozzle comprises a plurality of nozzle outlets, each nozzle outlet is respectively connected with the shunt hose, outlet ends of the shunt hoses are uniformly distributed in the anode sheath, the thickness of the anode sheath is 5-15 mm, the anode sheath is of an arc-shaped structure, and the arc-shaped radius at the inner side of the anode sheath is the same as the cylindrical surface radius of the workpiece to be brush plated;
wherein, the plating solution that drops after spraying falls directly into the liquid storage tank that is located the brush plating subassembly below to make plating solution recovery circulation processing use.
2. The process of claim 1, wherein the first pipe is further provided with a flowmeter.
3. The process according to claim 2, wherein after the flow rate of the plating solution in the first pipeline displayed by the flowmeter is stable, the ultrasonic breaking device is turned on to perform real-time dispersion treatment on the nanoparticles in the plating solution.
4. The process of claim 1, wherein the ultrasonic crushing device comprises:
the crushing kettle is connected with the liquid storage tank through the first pipeline and is used for accommodating plating solution;
the ultrasonic generator is arranged outside the crushing kettle, and an energy-gathering ultrasonic probe extending into the crushing kettle is arranged on the ultrasonic generator; a kind of electronic device with high-pressure air-conditioning system
And the ultrasonic power supply is used for supplying power to the ultrasonic generator.
5. The process of claim 4, wherein the crushing kettle is connected to the split nozzle via a second pipeline.
6. The process according to claim 1, wherein the brush plating assembly comprises a brush plating pen and a brush plating power supply, the anode sheath is arranged on the brush plating pen and used for contacting with a workpiece to be brushed, and the anode and the cathode of the brush plating power supply are respectively connected with the brush plating pen and the workpiece to be brushed; when the plating solution is uniformly sprayed onto the anode sheath through the shunt nozzle, a brush plating pen is started to carry out brush plating operation until the plating thickness of the workpiece to be brush plated reaches a preset thickness.
CN202111322569.6A 2021-11-09 2021-11-09 Nano composite brush plating process for cylindrical surface Active CN113913885B (en)

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CN114438565B (en) * 2022-02-21 2023-07-18 湖南昇通新材料科技有限公司 Electromagnetic shielding fabric electric brush nickel plating production equipment and method
CN115012017A (en) * 2022-05-07 2022-09-06 重庆旭华环保工程有限公司 Steel is handled with handling even surface coating device
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CN201024218Y (en) * 2007-01-29 2008-02-20 福州大学 Planar brush plating device
DE102009048669A1 (en) * 2009-09-30 2011-03-31 Siemens Aktiengesellschaft Process for the electrochemical coating of a substrate by brush plating and apparatus for carrying out this process
CN201648540U (en) * 2010-04-22 2010-11-24 重庆理工大学 Brushing electroplating repairing device of thin-wall aluminum products
CN103526241B (en) * 2013-09-23 2016-04-13 中国人民解放军装甲兵工程学院 Component of machine scratches reparation electric brushing coating installation and method
CN109402689B (en) * 2018-12-25 2020-12-01 广东电网有限责任公司 Brush plating pen and preparation method of brush plating layer
CN110653436B (en) * 2019-10-30 2020-07-28 常州工学院 Brush plating-electric spark deposition composite strengthening processing method
CN112410852A (en) * 2020-10-30 2021-02-26 中冶赛迪技术研究中心有限公司 Nano composite electroplating equipment and electroplating process

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