CN113845701A - 一种铜金属有机框架改性淀粉基复合膜及其制备方法 - Google Patents
一种铜金属有机框架改性淀粉基复合膜及其制备方法 Download PDFInfo
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- CN113845701A CN113845701A CN202111065424.2A CN202111065424A CN113845701A CN 113845701 A CN113845701 A CN 113845701A CN 202111065424 A CN202111065424 A CN 202111065424A CN 113845701 A CN113845701 A CN 113845701A
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- metal organic
- copper metal
- starch
- parts
- organic framework
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000002131 composite material Substances 0.000 title claims abstract description 32
- 229920000881 Modified starch Polymers 0.000 title claims abstract description 25
- 239000004368 Modified starch Substances 0.000 title claims abstract description 25
- 235000019426 modified starch Nutrition 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229920002472 Starch Polymers 0.000 claims abstract description 43
- 239000008107 starch Substances 0.000 claims abstract description 43
- 235000019698 starch Nutrition 0.000 claims abstract description 43
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000010949 copper Substances 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 39
- 239000000243 solution Substances 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 26
- KBZFDRWPMZESDI-UHFFFAOYSA-N 5-aminobenzene-1,3-dicarboxylic acid Chemical compound NC1=CC(C(O)=O)=CC(C(O)=O)=C1 KBZFDRWPMZESDI-UHFFFAOYSA-N 0.000 claims description 22
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- 229910001868 water Inorganic materials 0.000 claims description 10
- YRGMYJUKFJPNPD-UHFFFAOYSA-N 5-bromopyridine-2,3-diamine Chemical group NC1=CC(Br)=CN=C1N YRGMYJUKFJPNPD-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 7
- 239000004014 plasticizer Substances 0.000 claims description 7
- 238000010992 reflux Methods 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 229920002261 Corn starch Polymers 0.000 claims description 3
- 239000008120 corn starch Substances 0.000 claims description 3
- YDRFJPRPCBJKCM-UHFFFAOYSA-L dichlorocopper ethanol Chemical compound C(C)O.[Cu](Cl)Cl YDRFJPRPCBJKCM-UHFFFAOYSA-L 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 17
- 230000004888 barrier function Effects 0.000 abstract description 5
- 238000004806 packaging method and process Methods 0.000 abstract description 4
- 230000006750 UV protection Effects 0.000 abstract description 3
- 230000003321 amplification Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000003199 nucleic acid amplification method Methods 0.000 abstract description 3
- 239000003607 modifier Substances 0.000 abstract description 2
- 229920008262 Thermoplastic starch Polymers 0.000 description 9
- 239000004628 starch-based polymer Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 4
- 238000011056 performance test Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 208000021386 Sjogren Syndrome Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- MPTQRFCYZCXJFQ-UHFFFAOYSA-L copper(II) chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Cu+2] MPTQRFCYZCXJFQ-UHFFFAOYSA-L 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2487/00—Characterised by the use of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
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CN202111065424.2A CN113845701B (zh) | 2021-09-13 | 2021-09-13 | 一种铜金属有机框架改性淀粉基复合膜及其制备方法 |
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CN202111065424.2A CN113845701B (zh) | 2021-09-13 | 2021-09-13 | 一种铜金属有机框架改性淀粉基复合膜及其制备方法 |
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CN113845701A true CN113845701A (zh) | 2021-12-28 |
CN113845701B CN113845701B (zh) | 2023-04-07 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107698814A (zh) * | 2017-09-23 | 2018-02-16 | 桂林理工大学 | 一种海藻酸钠/铜金属有机框架纳米复合膜的制备方法 |
CN107722375A (zh) * | 2017-09-23 | 2018-02-23 | 桂林理工大学 | 海藻酸钠/淀粉/铜金属有机框架纳米复合膜的制备方法 |
CN109701498A (zh) * | 2019-01-29 | 2019-05-03 | 河南中烟工业有限责任公司 | 一种MOF-Cu@多孔淀粉复合材料及其制备方法和在卷烟中的应用 |
CN110639477A (zh) * | 2019-09-27 | 2020-01-03 | 华南理工大学 | 一种多孔淀粉-金属有机框架复合材料的制备方法 |
-
2021
- 2021-09-13 CN CN202111065424.2A patent/CN113845701B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107698814A (zh) * | 2017-09-23 | 2018-02-16 | 桂林理工大学 | 一种海藻酸钠/铜金属有机框架纳米复合膜的制备方法 |
CN107722375A (zh) * | 2017-09-23 | 2018-02-23 | 桂林理工大学 | 海藻酸钠/淀粉/铜金属有机框架纳米复合膜的制备方法 |
CN109701498A (zh) * | 2019-01-29 | 2019-05-03 | 河南中烟工业有限责任公司 | 一种MOF-Cu@多孔淀粉复合材料及其制备方法和在卷烟中的应用 |
CN110639477A (zh) * | 2019-09-27 | 2020-01-03 | 华南理工大学 | 一种多孔淀粉-金属有机框架复合材料的制备方法 |
Non-Patent Citations (3)
Title |
---|
KUI CHEN等: ""Improved mechanical, water vapor barrier and UV-shielding properties of cellulose acetate films with flower-like metal-organic framework nanoparticles"", 《INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES》 * |
SHETA M. SHETA等: ""Simple synthesis of novel copper metal-organic framework nanoparticles: biosensing and biological applications"", 《DALTON TRANSACTIONS》 * |
刘文勇等: ""淀粉薄膜的研究进展", 《包装学报》 * |
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CN113845701B (zh) | 2023-04-07 |
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Application publication date: 20211228 Assignee: GUILIN XINYU GE INDUSTRY Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044200 Denomination of invention: A copper metal organic framework modified starch based composite film and its preparation method Granted publication date: 20230407 License type: Common License Record date: 20231025 |
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Application publication date: 20211228 Assignee: Guangxi Zaifa Energy Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045075 Denomination of invention: A copper metal organic framework modified starch based composite film and its preparation method Granted publication date: 20230407 License type: Common License Record date: 20231031 Application publication date: 20211228 Assignee: GUANGXI HEYANG ENERGY LTD. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045074 Denomination of invention: A copper metal organic framework modified starch based composite film and its preparation method Granted publication date: 20230407 License type: Common License Record date: 20231031 Application publication date: 20211228 Assignee: Guangxi Wokang Medical Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045070 Denomination of invention: A copper metal organic framework modified starch based composite film and its preparation method Granted publication date: 20230407 License type: Common License Record date: 20231101 |
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Application publication date: 20211228 Assignee: Guangxi manjin Energy Saving Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045248 Denomination of invention: A copper metal organic framework modified starch based composite film and its preparation method Granted publication date: 20230407 License type: Common License Record date: 20231103 |
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