CN113797897A - 一种用于捕集co2的改性壳聚糖基碳气凝胶的制备方法 - Google Patents
一种用于捕集co2的改性壳聚糖基碳气凝胶的制备方法 Download PDFInfo
- Publication number
- CN113797897A CN113797897A CN202111206431.XA CN202111206431A CN113797897A CN 113797897 A CN113797897 A CN 113797897A CN 202111206431 A CN202111206431 A CN 202111206431A CN 113797897 A CN113797897 A CN 113797897A
- Authority
- CN
- China
- Prior art keywords
- aerogel
- chitosan
- carbon
- air
- modified chitosan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001661 Chitosan Polymers 0.000 title claims abstract description 81
- 239000004964 aerogel Substances 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 23
- 239000004966 Carbon aerogel Substances 0.000 claims abstract description 34
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000000967 suction filtration Methods 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 4
- 238000007710 freezing Methods 0.000 claims abstract description 3
- 230000008014 freezing Effects 0.000 claims abstract description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical group O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 11
- TZYULTYGSBAILI-UHFFFAOYSA-M trimethyl(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC=C TZYULTYGSBAILI-UHFFFAOYSA-M 0.000 claims description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- 238000004108 freeze drying Methods 0.000 claims description 3
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 2
- 229940015043 glyoxal Drugs 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 9
- 239000002028 Biomass Substances 0.000 abstract description 7
- 230000008929 regeneration Effects 0.000 abstract description 6
- 238000011069 regeneration method Methods 0.000 abstract description 6
- 239000000243 solution Substances 0.000 description 29
- 239000003463 adsorbent Substances 0.000 description 16
- 238000001179 sorption measurement Methods 0.000 description 15
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003090 exacerbative effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229960002442 glucosamine Drugs 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28047—Gels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28095—Shape or type of pores, voids, channels, ducts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111206431.XA CN113797897B (zh) | 2021-10-16 | 2021-10-16 | 一种用于捕集co2的改性壳聚糖基碳气凝胶的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111206431.XA CN113797897B (zh) | 2021-10-16 | 2021-10-16 | 一种用于捕集co2的改性壳聚糖基碳气凝胶的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113797897A true CN113797897A (zh) | 2021-12-17 |
CN113797897B CN113797897B (zh) | 2024-02-06 |
Family
ID=78897766
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111206431.XA Active CN113797897B (zh) | 2021-10-16 | 2021-10-16 | 一种用于捕集co2的改性壳聚糖基碳气凝胶的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113797897B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114506837A (zh) * | 2022-02-15 | 2022-05-17 | 中南大学 | 一种调控碳气凝胶孔道取向的方法和碳气凝胶及应用 |
WO2024133994A1 (es) * | 2022-12-22 | 2024-06-27 | Universidad De La Laguna | Película porosa de quitosano, procedimiento para su fabricacion y uso |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5525710A (en) * | 1991-12-20 | 1996-06-11 | Alliedsignal Inc. | Highly porous chitosan bodies |
WO2009062975A1 (en) * | 2007-11-12 | 2009-05-22 | Cismi | Aerogel compositions |
CN107952415A (zh) * | 2017-11-01 | 2018-04-24 | 西安华泰博源质量检测有限公司 | 一种壳聚糖基二氧化碳吸附气凝胶的制备方法 |
CN111518283A (zh) * | 2019-02-01 | 2020-08-11 | 武汉大学 | 一种壳聚糖在弱碱性水溶液中的溶解方法 |
CN111518305A (zh) * | 2019-02-01 | 2020-08-11 | 武汉大学 | 一种壳聚糖凝胶材料的制备方法 |
CN113214504A (zh) * | 2021-04-20 | 2021-08-06 | 河南工业大学 | 一种基于天然高分子的半互穿网络抑菌凝胶的制备方法 |
-
2021
- 2021-10-16 CN CN202111206431.XA patent/CN113797897B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5525710A (en) * | 1991-12-20 | 1996-06-11 | Alliedsignal Inc. | Highly porous chitosan bodies |
WO2009062975A1 (en) * | 2007-11-12 | 2009-05-22 | Cismi | Aerogel compositions |
CN107952415A (zh) * | 2017-11-01 | 2018-04-24 | 西安华泰博源质量检测有限公司 | 一种壳聚糖基二氧化碳吸附气凝胶的制备方法 |
CN111518283A (zh) * | 2019-02-01 | 2020-08-11 | 武汉大学 | 一种壳聚糖在弱碱性水溶液中的溶解方法 |
CN111518305A (zh) * | 2019-02-01 | 2020-08-11 | 武汉大学 | 一种壳聚糖凝胶材料的制备方法 |
CN113214504A (zh) * | 2021-04-20 | 2021-08-06 | 河南工业大学 | 一种基于天然高分子的半互穿网络抑菌凝胶的制备方法 |
Non-Patent Citations (3)
Title |
---|
UROOJ KAMRAN,SOO-JIN PARK: "Tuning ratios of KOH and NaOH on acetic acid-mediated chitosan-based porous carbons for improving their textural features and CO2uptakes", JOURNAL OF CO2UTILIZATION, pages 1 - 13 * |
朱雪换;杨仁党;刘萧;: "含硫改性壳聚糖气凝胶的合成及对Cu~(2+)吸附的研究", 生物质化学工程, no. 03, pages 5 - 10 * |
王雪源;: "改性壳聚糖重金属生物质吸附剂的制备及表征", 环境科学与技术, no. 12, pages 115 - 120 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114506837A (zh) * | 2022-02-15 | 2022-05-17 | 中南大学 | 一种调控碳气凝胶孔道取向的方法和碳气凝胶及应用 |
CN114506837B (zh) * | 2022-02-15 | 2023-12-15 | 中南大学 | 一种调控碳气凝胶孔道取向的方法和碳气凝胶及应用 |
WO2024133994A1 (es) * | 2022-12-22 | 2024-06-27 | Universidad De La Laguna | Película porosa de quitosano, procedimiento para su fabricacion y uso |
Also Published As
Publication number | Publication date |
---|---|
CN113797897B (zh) | 2024-02-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Wang et al. | Carbon dioxide capture using polyethylenimine-loaded mesoporous carbons | |
Shao et al. | Effective nitrogen and sulfur co-doped porous carbonaceous CO2 adsorbents derived from amino acid | |
Wang et al. | Adsorption and regeneration study of polyethylenimine-impregnated millimeter-sized mesoporous carbon spheres for post-combustion CO2 capture | |
CN109232781B (zh) | 一种含氮多孔有机聚合物的制备方法 | |
CN113797897B (zh) | 一种用于捕集co2的改性壳聚糖基碳气凝胶的制备方法 | |
CN108479710B (zh) | 一种多孔碳材料的制备方法及其应用 | |
CN105195113A (zh) | 室温捕集低浓度co2用固态胺吸附剂及制备方法和应用 | |
CN115779860A (zh) | 吸附燃煤烟气中二氧化碳的壳聚糖与有机胺复合固体吸附剂及其制备方法、应用和再生方法 | |
Shao et al. | Unlocking the potential of N-doped porous Carbon: Facile synthesis and superior CO2 adsorption performance | |
CN115193420A (zh) | 一种石墨烯材料及其制备方法 | |
Chen et al. | Mesoporous silica impregnated with organoamines for post‐combustion CO2 capture: a comparison of introduced amine types | |
KR101918652B1 (ko) | 포름알데히드 가스 제거용 활성탄소 및 그 제조방법 | |
CN110075812B (zh) | 一种氨基化二氧化硅颗粒吸附剂的制备方法及应用 | |
CN102068960B (zh) | 吸附氮氧化物蜂窝活性炭吸附剂的再生方法 | |
JP2002211911A (ja) | 親水性高分子由来水酸基含有炭化物及びその製造方法 | |
CN116459795A (zh) | 一种用于废水除铅的水处理材料及其制备方法和应用 | |
US20240001281A1 (en) | Improved materials for direct air capture and uses thereof | |
Su et al. | Co2-imprinted sustainable carbon derived from sunflower heads for highly effective capture of CO2 from flue gas | |
CN101439282B (zh) | 一种改性膨胀石墨的制备方法及在苯气体处理的用途 | |
CN110743512A (zh) | 一种二氧化碳分子印迹吸附剂的制备与再生方法及其应用 | |
CN112058035A (zh) | 一种除湿剂及其制备方法 | |
CN113856632B (zh) | 一种仿核壳结构co2吸附剂及其制备与应用 | |
CN115475663B (zh) | 一种dabco型高性能二氧化碳吸附剂及其制备方法 | |
WO2021083109A1 (zh) | So 2吸附材料及其制备方法与应用和脱除含so 2烟气中的so 2的方法 | |
CN117339571A (zh) | 一种季铵基修饰聚氨酯co2吸附剂及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20230316 Address after: 250100 725C-1, Floor 7, Building 9, Shandong Hi-Tech Innovation Park, Gangxi Road, Jinan Area, China (Shandong) Pilot Free Trade Zone, Jinan City, Shandong Province Applicant after: Jinan Industrial Research Guoneng Medium Carbon Environmental Protection Technology Co.,Ltd. Address before: 710000 1107-2xa65, building 1, aerospace city center square, Shenzhou fifth road, national civil aerospace industry base, Xi'an, Shaanxi Province Applicant before: Xi'an green carbon resource recycling technology Co.,Ltd. |
|
GR01 | Patent grant | ||
GR01 | Patent grant |