CN113667816B - Annealing process of drywall nail steel semi-finished steel wire - Google Patents
Annealing process of drywall nail steel semi-finished steel wire Download PDFInfo
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- 238000000137 annealing Methods 0.000 title claims abstract description 75
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 62
- 239000010959 steel Substances 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 31
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000007789 gas Substances 0.000 claims abstract description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 230000001681 protective effect Effects 0.000 claims abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000010438 heat treatment Methods 0.000 abstract description 8
- 238000005261 decarburization Methods 0.000 abstract description 4
- 238000010583 slow cooling Methods 0.000 abstract 2
- 239000000047 product Substances 0.000 description 7
- 239000012535 impurity Substances 0.000 description 4
- 238000005554 pickling Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000012858 packaging process Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/561—Continuous furnaces for strip or wire with a controlled atmosphere or vacuum
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D11/00—Process control or regulation for heat treatments
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The invention relates to an annealing process of a drywall nail steel semi-finished steel wire, which uses a roller bottom type continuous annealing furnace to carry out full continuous annealing production on the drywall nail steel semi-finished steel wire, the inlet end and the outlet end of the roller bottom type continuous annealing furnace are both provided with a vacuum air lock chamber, RX and nitrogen are used as protective gases of the semi-finished steel wire, the decarburization quality of the surface of a product can be ensured, so the process idea of high heating temperature and fast roller speed can be adopted. The invention reasonably designs the roller speed according to the length parameters of each process section of the roller-hearth continuous annealing furnace, balances the heating temperature and the heating time, and balances the slow cooling temperature and the slow cooling time, thereby not only meeting the product quality requirement, but also improving the yield and reducing the comprehensive production cost.
Description
Technical Field
The invention relates to the technical field of annealing processes, in particular to an annealing process of a semi-finished steel wire for drywall nail steel.
Background
Drywall nail series is one of the most important major groups of the overall fastener product, primarily for the installation of various gypsum board, light weight partition, and suspended ceiling series. The steel grade of the steel for the dry wall nail is SWRCH22A, a hot rolled wire rod with the production process flow of phi 6.5mm is subjected to husking and continuous drawing on a straight wire drawing machine to form a semi-finished steel wire with the phi 2.3mm to 5.25mm, and the semi-finished steel wire is wound, so that annealing treatment is carried out to reduce the hardness of the steel wire due to processing hardening, and the annealing treatment is carried out to ensure that the hardness, decarburization and spheroidization grade of the steel wire meet corresponding technical requirements; and (4) carrying out acid pickling and drawing (the drawing amount is not more than 10%) after the annealing is finished, and delivering to a fastener factory to produce the drywall nail.
At present, the semi-finished steel wire of the drywall nail steel SWRCH22A is generally annealed by a well annealing furnace, but the loading amount of the well annealing furnace is small, and the yield is low; during production, nitrogen is used as protective gas, and the depth of the surface decarburized layer is higher; the hardness fluctuation is large, so the annealing treatment is carried out on the semi-finished steel wire of the drywall nail steel SWRCH22A by using a well type annealing furnace, and the comprehensive production cost is high.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: in order to overcome the defects in the prior art, the invention provides the annealing process of the drywall nail steel semi-finished steel wire with low product decarburization, high heating temperature, long heat preservation section and low product hardness, and the production cost is reduced.
The technical scheme adopted by the invention for solving the technical problems is as follows: an annealing process of a drywall nail steel semi-finished steel wire comprises the following steps:
(1) A roller hearth type continuous annealing furnace is adopted to divide a furnace zone into 11 zones, wherein the lengths of 1-3 zones are respectively 4 meters, 4.8 meters and 6.3 meters, the lengths of 4-7 zones are respectively 5.2 meters, the length of 8 zone is 3.4 meters, and the lengths of 9-11 zones are respectively 4 meters, 4.8 meters and 6.3 meters;
(2) The 1-3 area of the annealing furnace is a process preparation area, the set temperature of the 4 area is 650 ℃, the set temperature of the 5 area is 680 ℃, the set temperature of the 6 area is 720 ℃, the set temperature of the 7 area is 720 ℃, the set temperature of the 8 area is 680 ℃, the set temperature of the 9 area is 660 ℃, the set temperature of the 10 area is 620 ℃ and the set temperature of the 11 area is 550 ℃;
(3) The vacuum degree of the vacuum chamber before and after the annealing furnace is not more than 0.1mbar;
(4) 1080 oxygen potential in the annealing furnace is set, the protective atmosphere is RX gas and nitrogen, the dosage of the RX gas is 25m3/h, and the composition of the RX gas is CO:19 to 21 percent; h 2 ：38-42％；CO 2 :0.25 to 0.45 percent of N and the balance of N 2 (ii) a The nitrogen dosage is 60m 3 H, the purity is more than or equal to 99.995 percent;
(5) And loading the steel wire coil by adopting a chassis bracket to sequentially pass through each process area in the annealing furnace, wherein the roller speed is 1.85 m/h, and finishing annealing.
The annealed hardness of the semi-finished steel wire is not more than 65HRB, and the fluctuation range of the annealed hardness of the semi-finished steel wire in the same batch is within 5 HRB; the semi-decarburized layer on the surface of the steel wire finished product after annealing is less than or equal to 0.10mm, and no full decarburized layer exists.
The beneficial effects of the invention are: the invention uses the roller-hearth continuous annealing furnace to carry out annealing production on the dry wall nail steel semi-finished product steel wire, realizes full continuous production, and has high roller speed, high yield and low cost; the inlet end and the outlet end are both provided with vacuum air lock chambers, RX and nitrogen are used as protective gas of semi-finished steel wires, and the decarburization of the product is low; high heating temperature, long heat preservation section and low product hardness.
Detailed Description
The technical solution of the present invention is further illustrated by the following specific examples.
Example 1, a semi-finished steel wire, i.e., 2.78mm drawn from SWRCH22A of 6.5mm is illustrated.
An annealing process of a drywall nail steel semi-finished steel wire comprises the following steps:
(1) The steel wire comprises the following components in percentage by weight: c0.19 wt.%, si 0.03wt.%, mn 0.82wt.%, S0.08 wt.%, P0.13 wt.%, cr 0.02wt.%, ni 0.01wt.%, cu 0.02wt.%, al 0.042wt.%, N0.0028 wt.%, balance Fe and impurities;
(2) A roller-hearth continuous annealing furnace is adopted, the furnace zone is divided into 11 zones, the lengths of the 1-3 zones are respectively 4 meters, 4.8 meters and 6.3 meters, the lengths of the 4-7 zones are respectively 5.2 meters, the length of the 8 th zone is 3.4 meters, the lengths of the 9-11 zones are respectively 4 meters, 4.8 meters and 6.3 meters, and the roller speed is 1.85 meters per hour;
(3) The 1-3 zones of the annealing furnace are preparation zones, the set temperature of the 4 zones is 650 ℃, the set temperature of the 5 zones is 680 ℃, the set temperature of the 6 zones is 720 ℃, the set temperature of the 7 zones is 720 ℃, the set temperature of the 8 zones is 680 ℃, the set temperature of the 9 zones is 660 ℃, the set temperature of the 10 zones is 620 ℃ and the set temperature of the 11 zones is 550 ℃;
(4) The vacuum degree of the vacuum chamber before and after the annealing furnace is not more than 0.1mbar;
(5) Oxygen potential 1080 in the annealing furnace, RX gas for protective atmosphere, dosage 25m 3 The composition of RX gas is CO:19 to 21 percent; h 2 ：38-42％；CO 2 :0.35% and the balance N 2 (ii) a The nitrogen dosage is 60m 3 H, the purity is more than or equal to 99.995 percent;
(6) And loading the steel wire coil by adopting a chassis bracket to sequentially pass through each process area in the annealing furnace, wherein the roller speed is 1.85 m/h, and finishing annealing.
And the steel wire comes out from the 11 th area of the roller-hearth continuous annealing furnace, the annealing process is finished, and the steel wire sequentially enters the subsequent pickling process, the fine drawing process and the packaging process and then is put in storage.
Example 2.phi 6.5mm SWRCH22A drawn to phi 3.7mm semi-finished steel wire.
An annealing process of a drywall nail steel semi-finished steel wire comprises the following steps:
(1) The steel wire comprises the following components in percentage by weight: c0.20 wt.%, si 0.04wt.%, mn 0.79wt.%, S0.09 wt.%, P0.11 wt.%, cr 0.02wt.%, ni 0.01wt.%, cu 0.02wt.%, al 0.039wt.%, N0.0025 wt.%, the balance being Fe and impurities;
(2) A roller hearth type continuous annealing furnace is adopted, the furnace zone is divided into 11 zones, the lengths of the 1-3 zones are respectively 4 meters, 4.8 meters and 6.3 meters, the lengths of the 4-7 zones are respectively 5.2 meters, the length of the 8 th zone is 3.4 meters, the lengths of the 9-11 zones are respectively 4 meters, 4.8 meters and 6.3 meters, and the roller speed is 1.85 meters per hour;
(3) The 1-3 zones of the annealing furnace are preparation zones, the set temperature of the 4 zones is 650 ℃, the set temperature of the 5 zones is 680 ℃, the set temperature of the 6 zones is 720 ℃, the set temperature of the 7 zones is 720 ℃, the set temperature of the 8 zones is 680 ℃, the set temperature of the 9 zones is 660 ℃, the set temperature of the 10 zones is 620 ℃ and the set temperature of the 11 zones is 550 ℃;
(4) The vacuum degree of the vacuum chamber before and after the annealing furnace is not more than 0.1mbar;
(5) Oxygen potential 1080 in the annealing furnace, RX gas for protective atmosphere, dosage 25m 3 The composition of RX gas is CO:19 to 21 percent; h 2 ：38-42％；CO 2 ：0.35％，The rest is N 2 (ii) a The nitrogen dosage is 60m 3 H, the purity is more than or equal to 99.995 percent;
(6) And loading the steel wire coil by adopting a chassis bracket to sequentially pass through each process area in the annealing furnace, wherein the roller speed is 1.85 m/h, and finishing annealing.
And the steel wire comes out from the 11 th area of the roller-hearth continuous annealing furnace, the annealing process is finished, and the steel wire sequentially enters the subsequent pickling process, the fine drawing process and the packaging process and then is put in storage.
Example 3, a semi-finished steel wire, i.e., SWRCH22A of phi 6.5mm, drawn to phi 4.6mm, is described.
An annealing process of a drywall nail steel semi-finished steel wire comprises the following steps:
(1) The steel wire comprises the following components in percentage by weight: c0.19 wt.%, si 0.04wt.%, mn 0.83wt.%, S0.09 wt.%, P0.12 wt.%, cr 0.02wt.%, ni 0.01wt.%, cu 0.02wt.%, al 0.04wt.%, N0.0030 wt.%, the balance being Fe and impurities;
(2) A roller hearth type continuous annealing furnace is adopted, the furnace zone is divided into 11 zones, the lengths of the 1-3 zones are respectively 4 meters, 4.8 meters and 6.3 meters, the lengths of the 4-7 zones are respectively 5.2 meters, the length of the 8 th zone is 3.4 meters, the lengths of the 9-11 zones are respectively 4 meters, 4.8 meters and 6.3 meters, and the roller speed is 1.85 meters per hour;
(3) The 1-3 zones of the annealing furnace are preparation zones, the set temperature of the 4 zones is 650 ℃, the set temperature of the 5 zones is 680 ℃, the set temperature of the 6 zones is 720 ℃, the set temperature of the 7 zones is 720 ℃, the set temperature of the 8 zones is 680 ℃, the set temperature of the 9 zones is 660 ℃, the set temperature of the 10 zones is 620 ℃ and the set temperature of the 11 zones is 550 ℃;
(4) The vacuum degree of the vacuum chamber before and after the annealing furnace is not more than 0.1mbar;
(5) Oxygen potential 1080 in the annealing furnace, RX gas for protective atmosphere, dosage 25m 3 The composition of RX gas is CO:19 to 21 percent; h 2 ：38-42％；CO 2 :0.35% and the balance N 2 (ii) a The nitrogen dosage is 60m 3 The purity is more than or equal to 99.995 percent.
(6) And loading the steel wire coil by adopting a chassis bracket to sequentially pass through each process area in the annealing furnace, wherein the roller speed is 1.85 m/h, and finishing annealing.
And (3) the steel wire comes out from the 11 th area of the roller-hearth continuous annealing furnace, the annealing process is finished, the subsequent acid pickling process, the fine pumping process and the packaging process are sequentially carried out, and then the steel wire is put in storage.
Comparative example 1
Taking the example of the production of phi 3.7mm semi-finished steel wire drawn by SWRCH22A with phi 6.5mm and annealed by using a shaft furnace, the annealing process comprises the following steps:
(1) The steel wire comprises the following components in percentage by weight: c0.19 wt.%, si 0.04wt.%, mn 0.83wt.%, S0.09 wt.%, P0.12 wt.%, cr 0.02wt.%, ni 0.01wt.%, cu 0.02wt.%, al 0.04wt.%, N0.0030 wt.%, the balance being Fe and impurities;
(2) Annealing by using a phi 3800mm pit furnace, wherein the charging amount is 30 tons, and the annealing process comprises the following steps: heating to 580 ℃, keeping the temperature for 60 minutes, then heating to 660 ℃, keeping the temperature for 60 minutes, then heating to 700 ℃, keeping the temperature for 300 minutes, and then starting to cool; the annealing period is 22 hours;
(3) The protective gas used for annealing is nitrogen, and the dosage is 60m 3 The purity is more than or equal to 99.995 percent.
The quality test data of the above examples 1, 2 and 3 and comparative example 1 are shown in Table 1.
TABLE 1
As can be seen from Table 1, the quality of the semi-finished steel wire produced by annealing in the roller hearth type continuous annealing furnace is significantly superior to that produced by annealing in the pit furnace.
In the embodiment 1, the embodiment 2 and the embodiment 3 of the invention, a roller-hearth continuous annealing furnace is adopted, the roller speed is 1.85 m/h, and one chassis bracket enters and exits every 110 minutes. Each chassis carrier is loaded with 8 wire coils with a diameter of 850mm and a weight of 2.2 tons, according to which the daily yield is 2.2 tons/column × 8 × 24 × 60/110=230.4 tons; the annealing period of the pit furnace is 22 hours, and the annealing period plus the auxiliary time needs 24 hours, namely only 30 tons of products are produced every day.
The production costs of examples 1, 2 and 3 according to the present invention are compared with those of comparative example 1 in the following table 2:
TABLE 2
In light of the foregoing description of the preferred embodiment of the present invention, many modifications and variations will be apparent to those skilled in the art without departing from the spirit and scope of the invention. The technical scope of the present invention is not limited to the content of the specification, and must be determined according to the scope of the claims.
Claims (1)
1. An annealing process of a drywall nail steel semi-finished steel wire is characterized in that: comprises the following steps:
(1) A roller hearth type continuous annealing furnace is adopted to divide a furnace zone into 11 zones, wherein the lengths of 1-3 zones are respectively 4 meters, 4.8 meters and 6.3 meters, the lengths of 4-7 zones are respectively 5.2 meters, the length of 8 zone is 3.4 meters, and the lengths of 9-11 zones are respectively 4 meters, 4.8 meters and 6.3 meters;
(2) The 1-3 area of the annealing furnace is a process preparation area, the set temperature of the 4 area is 650 ℃, the set temperature of the 5 area is 680 ℃, the set temperature of the 6 area is 720 ℃, the set temperature of the 7 area is 720 ℃, the set temperature of the 8 area is 680 ℃, the set temperature of the 9 area is 660 ℃, the set temperature of the 10 area is 620 ℃ and the set temperature of the 11 area is 550 ℃;
(3) The vacuum degree of the vacuum chamber before and after the annealing furnace is not more than 0.1mbar;
(4) The oxygen potential in the annealing furnace is set to 1080, the inlet and outlet ends of the furnace body are provided with vacuum air lock chambers, the protective atmosphere is RX gas and nitrogen, the dosage of the RX gas is 25m 3 H, composition of RX gas CO:19 to 21 percent; h 2 ：38-42%；CO 2 :0.25 to 0.45 percent, and the balance ofN 2 (ii) a The nitrogen dosage is 60m 3 H, the purity is more than or equal to 99.995 percent;
(5) Loading a steel wire coil by adopting a chassis bracket to sequentially pass through each process area in the annealing furnace, wherein the roller speed is 1.85 m/h, and finishing annealing;
the semi-finished steel wire has the annealing hardness of not more than 65HRB, the fluctuation range of the annealing hardness of the semi-finished steel wire in the same batch is within 5HRB, the semi-decarburized layer on the surface of the semi-finished steel wire after annealing is not more than 0.10mm, and no full decarburized layer exists.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000309826A (en) * | 1999-04-22 | 2000-11-07 | Nippon Steel Weld Prod & Eng Co Ltd | Continuous annealing of steel wire for welding |
| CN104313281A (en) * | 2014-09-30 | 2015-01-28 | 东莞市科力钢铁线材有限公司 | Process for producing high-nodularity fastener wire rod |
| CN104878166A (en) * | 2015-05-26 | 2015-09-02 | 邢台钢铁有限责任公司 | Spheroidized annealing process for shortening annealing cycle of hot rolled wire rods |
| CN107881423A (en) * | 2017-12-27 | 2018-04-06 | 南京宝日钢丝制品有限公司 | The method of cold-forging steel and preparation method with preparing steel wire using the cold-forging steel |
| CN109609738A (en) * | 2018-12-27 | 2019-04-12 | 东莞科力线材技术有限公司 | Mobile phone big homalocephalus precision screw wire rod and preparation method thereof |
| CN111560499A (en) * | 2020-05-18 | 2020-08-21 | 南京钢铁股份有限公司 | Annealing process of steel for high-strength-grade mining chain |
| CN112359362A (en) * | 2020-10-27 | 2021-02-12 | 中天钢铁集团有限公司 | Acid-washing, phosphorizing and saponifying method for bearing steel |
-
2021
- 2021-08-18 CN CN202110947856.XA patent/CN113667816B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000309826A (en) * | 1999-04-22 | 2000-11-07 | Nippon Steel Weld Prod & Eng Co Ltd | Continuous annealing of steel wire for welding |
| CN104313281A (en) * | 2014-09-30 | 2015-01-28 | 东莞市科力钢铁线材有限公司 | Process for producing high-nodularity fastener wire rod |
| CN104878166A (en) * | 2015-05-26 | 2015-09-02 | 邢台钢铁有限责任公司 | Spheroidized annealing process for shortening annealing cycle of hot rolled wire rods |
| CN107881423A (en) * | 2017-12-27 | 2018-04-06 | 南京宝日钢丝制品有限公司 | The method of cold-forging steel and preparation method with preparing steel wire using the cold-forging steel |
| CN109609738A (en) * | 2018-12-27 | 2019-04-12 | 东莞科力线材技术有限公司 | Mobile phone big homalocephalus precision screw wire rod and preparation method thereof |
| CN111560499A (en) * | 2020-05-18 | 2020-08-21 | 南京钢铁股份有限公司 | Annealing process of steel for high-strength-grade mining chain |
| CN112359362A (en) * | 2020-10-27 | 2021-02-12 | 中天钢铁集团有限公司 | Acid-washing, phosphorizing and saponifying method for bearing steel |
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