CN113651617A - Preparation method of vanadium carbide and chromium carbide composite material - Google Patents
Preparation method of vanadium carbide and chromium carbide composite material Download PDFInfo
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- CN113651617A CN113651617A CN202110765191.0A CN202110765191A CN113651617A CN 113651617 A CN113651617 A CN 113651617A CN 202110765191 A CN202110765191 A CN 202110765191A CN 113651617 A CN113651617 A CN 113651617A
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- vanadium
- chromium
- pellets
- composite material
- carbide
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- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 title claims abstract description 52
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910003470 tongbaite Inorganic materials 0.000 title claims abstract description 52
- 239000002131 composite material Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000008188 pellet Substances 0.000 claims abstract description 53
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000001035 drying Methods 0.000 claims abstract description 17
- WFISYBKOIKMYLZ-UHFFFAOYSA-N [V].[Cr] Chemical compound [V].[Cr] WFISYBKOIKMYLZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 238000007599 discharging Methods 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000011261 inert gas Substances 0.000 claims abstract description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 20
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 20
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 19
- 229910052804 chromium Inorganic materials 0.000 claims description 19
- 239000011651 chromium Substances 0.000 claims description 19
- 239000000571 coke Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000001307 helium Substances 0.000 claims description 7
- 229910052734 helium Inorganic materials 0.000 claims description 7
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 13
- 239000002245 particle Substances 0.000 abstract description 8
- 229910045601 alloy Inorganic materials 0.000 abstract description 7
- 239000000956 alloy Substances 0.000 abstract description 7
- 239000000919 ceramic Substances 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 239000012535 impurity Substances 0.000 abstract description 4
- 238000005272 metallurgy Methods 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 description 9
- 238000001514 detection method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000003966 growth inhibitor Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/5607—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/95—Products characterised by their size, e.g. microceramics
Abstract
The invention relates to the technical field of metallurgy, in particular to a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps: step one, uniformly mixing a vanadium-chromium-containing material and a carbon raw material, adding a binder, and uniformly mixing to prepare pellets; drying the pellets, then putting the pellets into a vacuum furnace, uniformly heating the pellets to 900-1200 ℃ at a heating speed of 350-450 ℃/h, and keeping the temperature for 2-4 h; and step three, cooling the pellets under the protection of inert gas, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material. The preparation method of the vanadium carbide and chromium carbide composite material provided by the invention is simple to operate, and the prepared vanadium carbide and chromium carbide composite material is fine in granularity, uniform in particle size, single in composition and low in impurity content, can meet the requirements of the fields of superfine hard alloy, metal ceramic and the like, and has very important significance for improving the quality of the vanadium carbide and chromium carbide composite material.
Description
Technical Field
The invention relates to the technical field of metallurgy, in particular to a preparation method of a vanadium carbide and chromium carbide composite material.
Background
The vanadium carbide and the chromium carbide have higher melting point, hardness and strength, and good electrical conductivity and thermal conductivity under a high-temperature environment. The vanadium carbide and chromium carbide composite material has important function as a grain inhibitor in the fields of superfine hard alloy and metal ceramic.
What is needed in industrial applications is a vanadium carbide and chromium carbide composite material with a single fine grain size and phase composition, such as in the preparation of ultra-fine cemented carbides, that can better inhibit the grain growth of tungsten carbide if a vanadium carbide and chromium carbide composite material with a single fine grain size and phase composition is used as a grain growth inhibitor. If the composite material of vanadium carbide and chromium carbide with coarse particles is used as the grain growth inhibitor, the grain growth of tungsten carbide is difficult to inhibit due to the small specific surface, low surface activation energy and low atom transfer speed of the composite material of vanadium carbide and chromium carbide with coarse particles, so that the performance of the superfine hard alloy is difficult to further improve. Therefore, vanadium carbide and chromium carbide composite materials with fine particle size and single phase composition are urgently needed in the fields of high-performance superfine hard alloys and the like.
Disclosure of Invention
Based on the problems in the prior art, the invention provides a preparation method of a vanadium carbide and chromium carbide composite material, the vanadium carbide and chromium carbide composite material prepared by the preparation method has the advantages of fine particle size, uniform particle size, single phase composition and low impurity content, can meet the requirements of the fields of superfine hard alloy, metal ceramic and the like, and overcomes the defects in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
the embodiment of the invention provides a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps: step one, uniformly mixing a vanadium-chromium-containing material and a carbon raw material, adding a binder, and uniformly mixing to prepare pellets;
drying the pellets, then putting the pellets into a vacuum furnace, uniformly heating the pellets to 900-1200 ℃ at a heating speed of 350-450 ℃/h, and keeping the temperature for 2-4 h;
and step three, cooling the pellets under the protection of inert gas, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material.
According to the preparation method of the vanadium carbide and chromium carbide composite material, the vanadium and chromium containing material and the carbon raw material are uniformly mixed and then added with the binder to prepare the pellet, so that the vanadium and chromium containing material and the carbon raw material can be fully mixed and tightly contacted, and the phenomenon of unstable product quality caused by incomplete reaction is reduced. The preparation method of the vanadium carbide and chromium carbide composite material provided by the invention is favorable for controlling the reaction temperature by controlling the temperature rise speed, and can avoid the phenomena of incomplete carbonization or over-carbonization of vanadium-chromium-containing materials due to large temperature fluctuation in the process of preparing the vanadium carbide and chromium carbide composite material, thereby reducing the generation of impurities and greatly improving the quality of the vanadium carbide and chromium carbide composite material. In addition, the combination of the first step, the second step and the third step in the preparation method of the vanadium carbide and chromium carbide composite material provided by the invention can ensure that the prepared vanadium carbide and chromium carbide composite material has fine granularity, uniform grain size and single phase composition, and can meet the requirements of the fields of superfine hard alloy, metal ceramic and the like.
The material containing vanadium and chromium can adopt vanadium and chromium-containing waste recovered from vanadium precipitation wastewater vanadium and chromium, so that the cost can be reduced, and the resource utilization of the vanadium and chromium-containing waste can be realized.
Preferably, in the step one, the mass percent of vanadium in the vanadium-chromium-containing material is 1-5%, and the mass percent of chromium is 10-15%.
Preferably, in the step one, the carbon raw material is one or more of semi coke, graphite, carbon black, activated carbon, coke and organic carbon.
Preferably, in the first step, the binder is one of polyacrylamide, polyethylene glycol, polyvinyl alcohol or starch glue.
Preferably, in the first step, the weight ratio of the vanadium-chromium-containing material to the carbon raw material to the binder is 1: 0.2-0.4: 0.03 to 0.05.
Preferably, in the second step, the drying temperature is 80-150 ℃, and the drying time is 1-2 hours.
Preferably, in step three, the inert gas is argon or helium.
Preferably, in the third step, the mixture is cooled to 130-150 ℃ and discharged.
The preparation method of the vanadium carbide and chromium carbide composite material provided by the invention is simple to operate, and the prepared vanadium carbide and chromium carbide composite material is fine in granularity, uniform in particle size, single in composition and low in impurity content, can meet the requirements of the fields of superfine hard alloy, metal ceramic and the like, and has very important significance for improving the quality of the vanadium carbide and chromium carbide composite material. The method can select the vanadium-chromium-containing waste recovered from vanadium-precipitation wastewater vanadium and chromium as the raw material, not only can reduce the cost, but also can realize the resource utilization of the vanadium-chromium-containing waste.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
The embodiment provides a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps:
(1) 100g of vanadium-chromium-containing waste (the content of vanadium is 5 percent, and the content of chromium is 10 percent) and 20g of semi-coke are mixed uniformly, 3g of polyacrylamide is added, and the mixture is put into a mixer, added with a certain amount of water and mixed uniformly to prepare pellets.
(2) Drying the pellets, then putting the pellets into a vacuum furnace, drying at 80 ℃ for 2h, uniformly heating from 200 ℃ to 900 ℃, heating at a speed of 400 ℃/h, and keeping the temperature for 2 h.
(3) And cooling the pellets to 150 ℃ under the protection of helium, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material. The particle size of the obtained vanadium carbide and chromium carbide composite material is 200-500 nm, and through detection, the content of chromium in the product is 82.64%, the content of vanadium is 5.67%, and the content of carbon is 11.59%.
Example 2
The embodiment provides a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps:
(1) 100g of vanadium-chromium-containing waste (the vanadium content is 4 percent, and the chromium content is 11 percent) and 30g of semi-coke are mixed uniformly, 5g of polyacrylamide is added, and the mixture is put into a mixer, added with a certain amount of water and mixed uniformly to prepare pellets.
(2) Drying the pellets, then putting the pellets into a vacuum furnace, drying at 90 ℃ for 1h, uniformly heating the pellets from 150 ℃ to 950 ℃, heating at the speed of 350 ℃/h, and keeping the temperature for 3 h.
(3) And cooling the pellets to 140 ℃ under the protection of helium, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material. The particle size of the obtained vanadium carbide and chromium carbide composite material is 200-500 nm, and through detection, the chromium content in the product is 83.12%, the vanadium content is 4.82%, and the carbon content is 11.93%.
Example 3
The embodiment provides a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps:
(1) 100g of vanadium-chromium-containing waste (the content of vanadium is 3 percent, and the content of chromium is 12 percent) and 40g of semi-coke are mixed uniformly, then 3g of polyacrylamide is added, and the mixture is put into a mixer, added with a certain amount of water and mixed uniformly to prepare pellets.
(2) Drying the pellets, then putting the pellets into a vacuum furnace, drying at 100 ℃ for 1h, uniformly heating from 250 ℃ to 1200 ℃, heating at a speed of 450 ℃/h, and keeping the temperature for 4 h.
(3) And cooling the pellets to 130 ℃ under the protection of helium, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material. The particle size of the obtained vanadium carbide and chromium carbide composite material is 200-500 nm, and through detection, the chromium content in the product is 84.06%, the vanadium content is 3.99%, and the carbon content is 11.83%.
Example 4
The embodiment provides a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps:
(1) 100g of vanadium-chromium-containing waste (the vanadium content is 2 percent, and the chromium content is 13 percent) and 25g of semi-coke are uniformly mixed, 4g of polyacrylamide is added, and the mixture is put into a mixer, added with a certain amount of water and uniformly mixed to prepare pellets.
(2) Drying the pellets, then putting the pellets into a vacuum furnace, drying at 130 ℃ for 2h, uniformly heating from 180 ℃ to 1000 ℃, heating at a speed of 380 ℃/h, and keeping the temperature for 3 h.
(3) And cooling the pellets to 140 ℃ under the protection of helium, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material. The particle size of the obtained vanadium carbide and chromium carbide composite material is 200-500 nm, and through detection, the content of chromium in the product is 84.36%, the content of vanadium is 3.04%, and the content of carbon is 12.45%.
Example 5
The embodiment provides a preparation method of a vanadium carbide and chromium carbide composite material, which comprises the following steps:
(1) 100g of vanadium-chromium-containing waste (the vanadium content is 1 percent, and the chromium content is 15 percent) and 35g of semi-coke are uniformly mixed, 5g of polyacrylamide is added, and the mixture is put into a mixer, added with a certain amount of water and uniformly mixed to prepare pellets.
(2) Drying the pellets, then putting the pellets into a vacuum furnace, drying at 150 ℃ for 1h, uniformly heating from 230 ℃ to 1100 ℃, heating at a speed of 420 ℃/h, and keeping the temperature for 4 h.
(3) And cooling the pellets to 150 ℃ under the protection of helium, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material. The particle size of the obtained vanadium carbide and chromium carbide composite material is 200-500 nm, and through detection, the content of chromium in the product is 84.75%, the content of vanadium is 2.58%, and the content of carbon is 12.51%.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents or improvements made within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (8)
1. A preparation method of a vanadium carbide and chromium carbide composite material is characterized by comprising the following steps:
step one, uniformly mixing a vanadium-chromium-containing material and a carbon raw material, adding a binder, and uniformly mixing to prepare pellets;
drying the pellets, then putting the pellets into a vacuum furnace, uniformly heating the pellets to 900-1200 ℃ at a heating speed of 350-450 ℃/h, and keeping the temperature for 2-4 h;
and step three, cooling the pellets under the protection of inert gas, discharging the pellets out of the furnace, and crushing the pellets to obtain the vanadium carbide and chromium carbide composite material.
2. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: in the first step, the vanadium content of the vanadium-chromium-containing material is 1-5% by mass, and the chromium content of the vanadium-chromium-containing material is 10-15% by mass.
3. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: in the first step, the carbon raw material is one or more of semi-coke, graphite, carbon black, activated carbon, coke and organic carbon.
4. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: in the first step, the binder is one of polyacrylamide, polyethylene glycol, polyvinyl alcohol or starch glue.
5. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: in the first step, the weight ratio of the vanadium-chromium-containing material to the carbon raw material to the binder is 1: 0.2-0.4: 0.03 to 0.05.
6. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: in the second step, the drying temperature is 80-150 ℃, and the drying time is 1-2 hours.
7. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: in the third step, the inert gas is argon or helium.
8. The method of preparing a vanadium carbide and chromium carbide composite material according to claim 1, wherein: and in the third step, cooling to 130-150 ℃ and discharging.
Priority Applications (1)
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|---|---|---|---|
| CN202110765191.0A CN113651617A (en) | 2021-07-06 | 2021-07-06 | Preparation method of vanadium carbide and chromium carbide composite material |
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| CN202110765191.0A CN113651617A (en) | 2021-07-06 | 2021-07-06 | Preparation method of vanadium carbide and chromium carbide composite material |
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| CN202110765191.0A Pending CN113651617A (en) | 2021-07-06 | 2021-07-06 | Preparation method of vanadium carbide and chromium carbide composite material |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003300778A (en) * | 2002-04-03 | 2003-10-21 | Toshiba Tungaloy Co Ltd | Tungsten carbide based sintered compact |
| CN101857196A (en) * | 2010-05-31 | 2010-10-13 | 河南工业大学 | Method for preparing nano chrome/vanadium carbide composite powder |
| CN102674844A (en) * | 2012-06-04 | 2012-09-19 | 河南工业大学 | Method for preparing nanometer vanadium/chromium carbide composite powder by reduction with microwave method |
| CN103274407A (en) * | 2013-05-29 | 2013-09-04 | 北京工业大学 | Preparation method of composite crystalline grain growth inhibitor with adjustable ratio |
| CN108117392A (en) * | 2017-12-04 | 2018-06-05 | 株洲夏普高新材料有限公司 | Corrosion resistant non-bond cemented carbide and preparation method thereof |
-
2021
- 2021-07-06 CN CN202110765191.0A patent/CN113651617A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003300778A (en) * | 2002-04-03 | 2003-10-21 | Toshiba Tungaloy Co Ltd | Tungsten carbide based sintered compact |
| CN101857196A (en) * | 2010-05-31 | 2010-10-13 | 河南工业大学 | Method for preparing nano chrome/vanadium carbide composite powder |
| CN102674844A (en) * | 2012-06-04 | 2012-09-19 | 河南工业大学 | Method for preparing nanometer vanadium/chromium carbide composite powder by reduction with microwave method |
| CN103274407A (en) * | 2013-05-29 | 2013-09-04 | 北京工业大学 | Preparation method of composite crystalline grain growth inhibitor with adjustable ratio |
| CN108117392A (en) * | 2017-12-04 | 2018-06-05 | 株洲夏普高新材料有限公司 | Corrosion resistant non-bond cemented carbide and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 储满生等: "《特色冶金资源非焦冶炼技术》", 31 March 2014, 冶金工业出版社 * |
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Application publication date: 20211116 |