CN113621414A - Environment-friendly energy-saving diesel alcohol-based biofuel additive - Google Patents
Environment-friendly energy-saving diesel alcohol-based biofuel additive Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
- C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
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Abstract
The invention relates to an environment-friendly energy-saving diesel alcohol-based biofuel additive which is prepared from the following raw materials in percentage by weight: 1-3% of n-butyl alcohol, 2-4% of n-octyl alcohol, 5-15% of multi-carbon alcohol, 1-3% of isopropanol, 2-4% of tert-butyl alcohol, 15-25% of fatty acid methyl ester, 4-6% of composite cetane number improver, 5-15% of composite universal cosolvent and 15-25% of composite biological assistant, wherein the composite cetane number improver is composed of isoamyl nitrate and isooctyl nitrate in a ratio of 2:3, the diesel oil alcohol-based biofuel additive can improve the cold start property and the acceleration performance of gasoline by mixing various raw materials, is beneficial to combustion supporting and full combustion of diesel oil, can reduce the oil consumption of the diesel oil, reduce the content of harmful substances in exhaust gas discharged by the diesel oil additive, further protect the environment, and through the addition of related biological fuels such as fatty acid methyl ester, biological trichosporium bacteria active agent and the like, the energy is saved and the environment is protected.
Description
Technical Field
The invention relates to the technical field of diesel fuel additives, in particular to an environment-friendly and energy-saving diesel alcohol-based biofuel additive.
Background
The diesel oil is a light petroleum product, and a complex hydrocarbon (with the carbon number of about 10-22) mixture. Is a diesel fuel. Is mainly prepared by blending diesel fractions produced in the processes of crude oil distillation, catalytic cracking, thermal cracking, hydrocracking, petroleum coking and the like; or from shale oil processing and coal liquefaction. The diesel oil is divided into light diesel oil (the boiling point range is about 180-370 ℃) and heavy diesel oil (the boiling point range is about 350-410 ℃). It is widely used for large vehicles, railway locomotives and ships. The most important use of diesel is in diesel engines for vehicles and ships. Compared with gasoline, diesel oil has high energy density and low fuel consumption. Diesel fuel has low energy consumption, so some small cars and even high performance cars are changed into diesel fuel.
The fuel additive belongs to fuel additives, the diesel additive is one of the fuel additives, the fuel additive generally comprises a gasoline additive and a diesel additive, and is used for making up the quality problems of fuel and the defects of the mechanical manufacturing limit of a motor vehicle, so that the cold shock effect and the gap effect of a gasoline engine can be overcome, carbon deposition of an air inlet valve and an electric nozzle can be eliminated, and the problems that an oil nozzle is difficult to atomize more finely and residual oil is generated and then drops can be overcome for the diesel engine.
However, when the existing fuel additive is used, the energy-saving and environment-friendly performance needs to be further improved. Therefore, the technical personnel in the field provide an environment-friendly and energy-saving diesel alcohol-based biofuel additive to solve the problems in the background technology.
Disclosure of Invention
In order to solve the problems in the background technology, the invention provides an environment-friendly and energy-saving diesel alcohol-based biofuel additive.
The invention provides an environment-friendly energy-saving diesel alcohol-based biofuel additive, which adopts the following technical scheme:
an environment-friendly energy-saving diesel alcohol-based biofuel additive is prepared from the following raw materials in percentage by weight: 1-3% of n-butyl alcohol, 2-4% of n-octyl alcohol, 5-15% of polyhydric alcohol, 1-3% of isopropanol, 2-4% of tert-butyl alcohol, 15-25% of fatty acid methyl ester, 4-6% of composite cetane number improver, 5-15% of composite universal cosolvent and 15-25% of composite biological additive.
Preferably, the composite cetane number improver consists of isoamyl nitrate and isooctyl nitrate in a ratio of 2: 3.
Preferably, the composite biological additive is prepared from 12: 3: 5 proportion of biological trichosporium bacteria activator, corrosion inhibitor and cleaning synergist.
Preferably, the multi-carbon alcohol is prepared from methanol, ethanol, propanol, butanol and the like in a uniform ratio.
Preferably, the composite universal cosolvent can be methyl tert-butyl ether.
The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive comprises the following steps:
s1, placing n-butanol, n-octanol, multi-carbon alcohol, isopropanol and tert-butanol in a container A, and fully stirring;
s2, taking fatty acid methyl ester, placing the fatty acid methyl ester in a container B, adding a composite cetane number improver, and fully stirring the mixture;
s3, when the solution in the container B is cooled to room temperature, adding the biological tricholoma matsutake activator into the container B for fully stirring;
and S4, pouring the solution in the container B into the solution in the container A, adding the corrosion inhibitor and the cleaning synergist, and fully stirring to complete the preparation.
Preferably, in the S2, before adding the composite cetane improver, the fatty acid methyl ester in the B tank is heated to 50 degrees until the fatty acid methyl ester is completely in a liquid state.
Preferably, in the S1, S2, S3 and S4, the stirring time is 10min, 15min, 10min and 20min respectively.
In summary, the invention has the following beneficial technical effects:
the diesel oil stabilizer has the advantages that the diesel oil stabilizer can play a role in stabilizing the diesel oil by adding the n-butyl alcohol, the n-octyl alcohol, the multi-carbon alcohol, the isopropanol and the tert-butyl alcohol, prevent a carburetor from freezing and has excellent antiknock property; the addition of isoamyl nitrate and multi-carbon alcohol can play a role in assisting dissolution, thereby being beneficial to the mutual fusion of various preparation raw materials; by adding the composite universal cosolvent, isooctyl nitrate, the cleaning synergist and the fuel oil cleaning synergist, the cold start characteristic and the acceleration performance of the gasoline can be improved, the air resistance is not adversely affected, the fuel consumption is reduced, the content of lead, carbon monoxide, polycyclic aromatic hydrocarbon and other harmful substances in the waste gas is reduced, a certain combustion supporting effect is realized on the diesel oil, and the full combustion of the diesel oil is facilitated; the fatty acid methyl ester and the biological trichosporium bacteria active agent belong to biological fuels, belong to biodiesel, can directly replace diesel oil to be used as fuel of a diesel engine, and are more energy-saving and environment-friendly.
Drawings
FIG. 1 is a schematic flow chart of an embodiment of the present invention.
Detailed Description
Referring to fig. 1, all other embodiments obtained by those of ordinary skill in the art without any inventive work are within the scope of the present invention based on the embodiments of the present invention.
Example one
The invention provides a technical scheme that:
an environment-friendly energy-saving diesel alcohol-based biofuel additive is prepared from the following raw materials in percentage by weight: 1% of n-butanol, 2% of n-octanol, 5% of higher alcohols, 1% of isopropanol, 2% of tert-butanol, 15% of fatty acid methyl ester, 4% of composite cetane number improver, 5% of composite universal cosolvent and 15% of composite biological additive; the composite cetane number improver consists of isoamyl nitrate and isooctyl nitrate in the ratio of 2: 3; the composite biological additive consists of 12: 3: 5, biological trichosporium, corrosion inhibitor and cleaning synergist; the multi-carbon alcohol is prepared from methanol, ethanol, propanol, butanol and the like in equal proportion; the composite universal cosolvent may be methyl tert-butyl ether.
The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive comprises the following steps:
s1, placing n-butanol, n-octanol, polyhydric alcohol, isopropanol and tert-butanol in a container A according to corresponding percentages, and fully stirring the n-butanol, the n-octanol, the polyhydric alcohol, the isopropanol and the tert-butanol for 10min respectively;
s2, placing fatty acid methyl ester with a corresponding percentage in a container B, then adding a composite cetane number improver with a corresponding percentage, fully stirring, and before adding the composite cetane number improver, heating the fatty acid methyl ester with the corresponding percentage in the container B to 50 ℃ until the fatty acid methyl ester is completely in a liquid state, wherein the stirring time is 15 min;
s3, when the solution in the container B is cooled to room temperature, adding the biological tricholoma matsutake activator with corresponding percentage into the container B for fully stirring, wherein the stirring time is 10min respectively;
and S4, pouring the solution in the container B into the solution in the container A, adding the corrosion inhibitor and the cleaning synergist in corresponding percentage, and fully stirring the mixture for 20min respectively to finish the preparation.
EXAMPLE III
The invention provides a technical scheme that:
an environment-friendly energy-saving diesel alcohol-based biofuel additive is prepared from the following raw materials in percentage by weight: 2% of n-butyl alcohol, 3% of n-octyl alcohol, 10% of polyhydric alcohol, 2% of isopropanol, 3% of tertiary butyl alcohol, 20% of fatty acid methyl ester, 5% of composite cetane number improver, 10% of composite universal cosolvent and 20% of composite biological additive; the composite cetane number improver consists of isoamyl nitrate and isooctyl nitrate in the ratio of 2: 3; the composite biological additive consists of 12: 3: 5, biological trichosporium, corrosion inhibitor and cleaning synergist; the multi-carbon alcohol is prepared from methanol, ethanol, propanol, butanol and the like in equal proportion; the composite universal cosolvent may be methyl tert-butyl ether.
The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive comprises the following steps:
s1, placing n-butanol, n-octanol, polyhydric alcohol, isopropanol and tert-butanol in a container A according to corresponding percentages, and fully stirring the n-butanol, the n-octanol, the polyhydric alcohol, the isopropanol and the tert-butanol for 10min respectively;
s2, placing fatty acid methyl ester with a corresponding percentage in a container B, then adding a composite cetane number improver with a corresponding percentage, fully stirring, and before adding the composite cetane number improver, heating the fatty acid methyl ester with the corresponding percentage in the container B to 50 ℃ until the fatty acid methyl ester is completely in a liquid state, wherein the stirring time is 15 min;
s3, when the solution in the container B is cooled to room temperature, adding the biological tricholoma matsutake activator with corresponding percentage into the container B for fully stirring, wherein the stirring time is 10min respectively;
and S4, pouring the solution in the container B into the solution in the container A, adding the corrosion inhibitor and the cleaning synergist in corresponding percentage, and fully stirring the mixture for 20min respectively to finish the preparation.
EXAMPLE III
The invention provides a technical scheme that:
an environment-friendly energy-saving diesel alcohol-based biofuel additive is prepared from the following raw materials in percentage by weight: 3% of n-butanol, 4% of n-octanol, 15% of higher alcohols, 3% of isopropanol, 4% of tert-butanol, 25% of fatty acid methyl ester, 6% of composite cetane number improver, 15% of composite universal cosolvent and 25% of composite biological additive; the composite cetane number improver consists of isoamyl nitrate and isooctyl nitrate in the ratio of 2: 3; the composite biological additive consists of 12: 3: 5, biological trichosporium, corrosion inhibitor and cleaning synergist; the multi-carbon alcohol is prepared from methanol, ethanol, propanol, butanol and the like in equal proportion; the composite universal cosolvent may be methyl tert-butyl ether.
The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive comprises the following steps:
s1, placing n-butanol, n-octanol, polyhydric alcohol, isopropanol and tert-butanol in a container A according to corresponding percentages, and fully stirring the n-butanol, the n-octanol, the polyhydric alcohol, the isopropanol and the tert-butanol for 10min respectively;
s2, placing fatty acid methyl ester with a corresponding percentage in a container B, then adding a composite cetane number improver with a corresponding percentage, fully stirring, and before adding the composite cetane number improver, heating the fatty acid methyl ester with the corresponding percentage in the container B to 50 ℃ until the fatty acid methyl ester is completely in a liquid state, wherein the stirring time is 15 min;
s3, when the solution in the container B is cooled to room temperature, adding the biological tricholoma matsutake activator with corresponding percentage into the container B for fully stirring, wherein the stirring time is 10min respectively;
and S4, pouring the solution in the container B into the solution in the container A, adding the corrosion inhibitor and the cleaning synergist in corresponding percentage, and fully stirring the mixture for 20min respectively to finish the preparation.
The principle of the environment-friendly energy-saving diesel alcohol-based biofuel additive is as follows: the addition of n-butyl alcohol, n-octyl alcohol, multi-carbon alcohol, isopropanol and tertiary butanol can play a role in stabilizing diesel oil, prevent the carburetor from freezing and have excellent antiknock property; the isoamyl nitrate is an organic solvent, which is beneficial to the mutual fusion of various preparation raw materials; the composite universal cosolvent can be methyl tert-butyl ether, can improve the cold start characteristic and the acceleration performance of gasoline, has no adverse effect on air resistance, reduces the fuel consumption, reduces the content of lead, carbon monoxide and polycyclic aromatic hydrocarbon in waste gas, plays a certain role in supporting combustion for diesel oil, and is beneficial to the full combustion of the diesel oil; the higher alcohols improve the problems of corrosion, swelling and cold start difficulty, hot air resistance, water separation, power reduction, fluidity, emulsification and the like of the diesel oil in use; the fatty acid methyl ester and the biological trichosporium bacteria active agent belong to biological fuels, belong to biodiesel, can directly replace diesel oil to be used as fuel of a diesel engine, and are more energy-saving and environment-friendly; the isooctyl nitrate can improve the cetane number of the diesel oil, improve the combustion performance of the diesel oil, shorten the ignition time, reduce the ignition point, improve the thermal condition and the dynamic property of the locomotive and save the oil consumption; the clean synergist and the fuel clean synergist can reduce the oil consumption of diesel oil, reduce the content of harmful substances in the exhaust gas discharged by the diesel oil, and protect the environment.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation. The use of the phrase "comprising one of the elements does not exclude the presence of other like elements in the process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. An environment-friendly energy-saving diesel alcohol-based biofuel additive is characterized by being prepared from the following raw materials in percentage by weight: 1-3% of n-butyl alcohol, 2-4% of n-octyl alcohol, 5-15% of polyhydric alcohol, 1-3% of isopropanol, 2-4% of tert-butyl alcohol, 15-25% of fatty acid methyl ester, 4-6% of composite cetane number improver, 5-15% of composite universal cosolvent and 15-25% of composite biological additive.
2. The environment-friendly energy-saving diesel alcohol-based biofuel additive as defined in claim 1, wherein: the composite cetane number improver consists of isoamyl nitrate and isooctyl nitrate in the ratio of 2: 3.
3. The environment-friendly energy-saving diesel alcohol-based biofuel additive as defined in claim 1, wherein: the composite biological additive is prepared from 12: 3: 5 proportion of biological trichosporium bacteria activator, corrosion inhibitor and cleaning synergist.
4. The environment-friendly energy-saving diesel alcohol-based biofuel additive as defined in claim 1, wherein: the said multi-carbon alcohol is composed of methanol, ethanol, propanol and butanol.
5. The environment-friendly energy-saving diesel alcohol-based biofuel additive as defined in claim 1, wherein: the composite universal cosolvent can be methyl tert-butyl ether.
6. The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive as claimed in any one of claims 1 to 5, characterized by comprising the following steps:
s1, placing n-butanol, n-octanol, multi-carbon alcohol, isopropanol and tert-butanol in a container A, and fully stirring;
s2, taking fatty acid methyl ester, placing the fatty acid methyl ester in a container B, adding a composite cetane number improver, and fully stirring the mixture;
s3, when the solution in the container B is cooled to room temperature, adding the biological tricholoma matsutake activator into the container B for fully stirring;
and S4, pouring the solution in the container B into the solution in the container A, adding the corrosion inhibitor and the cleaning synergist, and fully stirring to complete the preparation.
7. The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive as claimed in claim 5, characterized in that: in said S2, the fatty acid methyl ester in the B tank was heated to 50 degrees before adding the composite cetane improver until the fatty acid methyl ester was completely in a liquid state.
8. The preparation method of the environment-friendly energy-saving diesel alcohol-based biofuel additive as claimed in claim 5, characterized in that: in the S1, S2, S3 and S4, the stirring time is 10min, 15min, 10min and 20min respectively.
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CN114574254A (en) * | 2022-03-28 | 2022-06-03 | 湖南创欧新能源科技有限公司 | Biomass power fuel and preparation method thereof |
CN114958449A (en) * | 2021-11-26 | 2022-08-30 | 昆明理工大学 | Novel alcohol-based solid fuel and preparation method thereof |
CN116478744A (en) * | 2022-01-14 | 2023-07-25 | 中国石油天然气股份有限公司 | Multi-effect complexing agent suitable for ethanol diesel |
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CN101245267A (en) * | 2008-03-26 | 2008-08-20 | 刘振和 | Method for manufacturing methanol diesel fuel additive |
CN101935560A (en) * | 2010-09-09 | 2011-01-05 | 上海化工研究院 | Methanol diesel oil microemulsion and preparation method thereof |
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CN114958449A (en) * | 2021-11-26 | 2022-08-30 | 昆明理工大学 | Novel alcohol-based solid fuel and preparation method thereof |
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CN116478744A (en) * | 2022-01-14 | 2023-07-25 | 中国石油天然气股份有限公司 | Multi-effect complexing agent suitable for ethanol diesel |
CN114574254A (en) * | 2022-03-28 | 2022-06-03 | 湖南创欧新能源科技有限公司 | Biomass power fuel and preparation method thereof |
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