CN113459244B - Intelligent preparation process of TZO semiconductor material for glass - Google Patents
Intelligent preparation process of TZO semiconductor material for glass Download PDFInfo
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- CN113459244B CN113459244B CN202110787045.8A CN202110787045A CN113459244B CN 113459244 B CN113459244 B CN 113459244B CN 202110787045 A CN202110787045 A CN 202110787045A CN 113459244 B CN113459244 B CN 113459244B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/24—Producing shaped prefabricated articles from the material by injection moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C17/00—Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
- B02C17/10—Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls with one or a few disintegrating members arranged in the container
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28C—PREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28C3/00—Apparatus or methods for mixing clay with other substances
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Mixers Of The Rotary Stirring Type (AREA)
Abstract
The invention provides an intelligent preparation process of a TZO semiconductor material for glass, which uses an intelligent preparation device of the TZO semiconductor material for glass, and comprises the following steps: 1) preparing a mixed solution of water and polyvinyl alcohol; 2) placing the mixed solution into an intelligent preparation device of the TZO semiconductor material for glass, and mixing with ZnO and SnO2Preparing the powder mixture into slurry; 3) ball milling, adding a polymerization catalyst and a polymerization initiator, and stirring and mixing; 4) placing the stirred material in a mold for sintering, and obtaining a TZO semiconductor material after the temperature is reduced to room temperature; the intelligent preparation device of the TZO semiconductor material for glass can ensure ZnO and SnO2The powder mixture and the mixed solution are fully reacted, the quality of the produced slurry is ensured, the structure is simple, and the practicability is high.
Description
Technical Field
The invention relates to the technical field of TZO semiconductor material preparation, in particular to an intelligent preparation process of a TZO semiconductor material for glass.
Background
The use of energy-saving glass is an important aspect of building energy saving, and as modern buildings increasingly use larger windows or glass curtain walls, it becomes more and more important how to reduce the heat loss of buildings through doors and windows. At present, the utilization rate of energy-saving glass in China has a great gap with developed countries, but China is also a main energy consuming country, and how to realize the purpose of achieving energy saving of newly-added buildings according to plan requirements in China faces a great challenge2In the prior art, the slurry is added at one time and then stirred and mixed, so that the condition of insufficient stirring is easy to occur, and the quality of the slurry prepared by stirring is influenced.
Therefore, it is necessary to provide a new intelligent manufacturing process of the TZO semiconductor material for glass to solve the above technical problems.
Disclosure of Invention
In order to solve the technical problems, the invention provides an intelligent preparation process of the TZO semiconductor material for glass.
The intelligent preparation process of the TZO semiconductor material for glass provided by the invention comprises the following steps: an intelligent preparation process of a TZO semiconductor material for glass, which uses an intelligent preparation device of the TZO semiconductor material for glass, and comprises the following steps:
1) mixing a mixed solution of water and polyvinyl alcohol and a polymerization monomer in a stirring container, and adding a dispersing agent while mixing to obtain a mixed solution;
2) placing the mixed solution into an intelligent preparation device of the TZO semiconductor material for glass, and gradually adding ZnO and SnO into the mixed solution2The powder mixture is stirred while adding to ensure that ZnO and SnO2The powder mixture can fully react with the mixed solution for 40 minutes to prepare slurry;
3) the prepared slurry is fed from an intelligent preparation device of the TZO semiconductor material for glass, enters a ball milling mechanism for ball milling, is placed in a vacuum stirrer after ball milling, is added with a polymerization catalyst and a polymerization initiator, is stirred and mixed for 65 minutes and is at the temperature of 40 ℃;
4) placing the stirred material in a mold, performing injection molding to prepare a biscuit, drying the biscuit in air at 100 ℃, sintering the biscuit in an environment of 1400 ℃ for 4 hours, cooling the biscuit to room temperature, and reprocessing to obtain a TZO semiconductor material;
wherein the intelligent preparation facilities of TZO semiconductor material for glass in step 2) includes the box, the case lid is installed in the top cooperation of box, feed inlet and discharge gate have been seted up on the surface of box, the upper surface center department fixedly connected with rabbling mechanism of case lid, the inner wall fixedly connected with adjusting device of box, adjusting device and rabbling mechanism fixed connection, the inside of box is equipped with transmission, transmission and adjusting device fixed connection, the lower fixed surface of case lid is connected with the storage case, the storage case rotates the installation with adjusting device, the storage case rotates the installation with transmission, the fixed surface of storage case is connected with the connecting pipe, the connecting pipe is linked together with the inner chamber of storage case, the feed opening has been seted up to the bottom of storage case.
In some embodiments of the invention, the polymerized monomer is a methacrylamide monomer and N-N' -dimethyl bisacrylamide in a weight ratio of 10: 1, the weight ratio of the ZnO to the SnO2 is 10: 6, the polymerization catalyst is tetramethylethylenediamine, the polymerization initiator is ammonium persulfate, and the dispersant is sodium tripolyphosphate
Preferably, the composition comprises the following components in parts by weight: 100 parts of deionized water, 10 parts of polyvinyl alcohol, 10 parts of methacrylamide monomer, 1 part of N-N' -dimethyl bisacrylamide, 0.1 part of polymerization catalyst, 0.02 part of polymerization initiator and 0.5 part of dispersant.
Preferably, rabbling mechanism includes motor case, servo motor, upstand, first gear, second gear, stirring post, puddler and cross, the fixedly connected with motor case is located at the upper surface center of case lid, the internally mounted of motor case has servo motor, servo motor's output fixedly connected with upstand, the first gear of servo motor's one end fixedly connected with is kept away from to the upstand, the outside symmetry meshing of first gear is connected with the second gear, box inner wall fixedly connected with cross, first gear rotates the installation with the cross, two the second gear rotates the installation with the cross, the fixed surface of second gear is connected with the stirring post, the equidistance fixedly connected with puddler in the outside of stirring post.
Preferably, the surface of the cross plate is fixedly connected with an arc plate, the first gear is rotatably mounted with the arc plate, the second gears are rotatably mounted with the arc plate, and the stirring columns are rotatably connected with the arc plate.
Preferably, the lower surface of the box cover is symmetrically and fixedly connected with L-shaped plates, and the two L-shaped plates are fixedly connected with the storage box.
Preferably, the adjusting device comprises a rotary disc, a first rack, a connecting column, a third gear, a fourth gear, a semicircular plate, a first arc-shaped groove, a second rack, a spring, a limiting block, a first arc-shaped column and a second arc-shaped column, wherein the semicircular plate is fixedly connected to the inner wall of the box body below the box cover, the first arc-shaped groove is formed in the surface of the semicircular plate, the first arc-shaped column is fixedly connected to the surface of the first arc-shaped groove, the limiting block is fixedly connected to one end of the surface of the arc-shaped column, the spring is fixedly connected to the surface of the limiting block, the second arc-shaped column is slidably mounted at one end of the surface of the first arc-shaped groove, the second arc-shaped groove is formed in the end face of the second arc-shaped column, one end of the spring, which is far away from the limiting block, is fixedly connected to the bottom of the second arc-shaped groove, the surface of the second arc-shaped column is fixedly connected to the first rack, the one end meshing on first rack surface is connected with the third gear, the last one end fixedly connected with fourth gear that is kept away from the third gear through one-way bearing rotation is connected with the spliced pole on the third gear, the outside meshing of fourth gear is connected with the second rack, the top of storage case is rotated and is installed the carousel, carousel and second rack fixed connection, carousel and upstand fixed connection, the carousel rotates the installation with the case lid.
Preferably, the surface of the semicircular plate is fixedly connected with a square plate, and the third gear and the square plate are rotatably mounted.
Preferably, the transmission device comprises a first rotating column, a mounting block, a first bevel gear, a second rotating column, a convex block, a transverse column, a spiral groove, a fixing block, a connecting rod, a fixing rod and a cover plate, wherein the square plate is rotatably connected with the first rotating column, one end of the first rotating column, which is close to the semicircular plate, is fixedly connected with a third gear, one end of the first rotating column, which is far away from the third gear, is fixedly connected with the first bevel gear, the outer side of the first bevel gear is connected with the second bevel gear in a meshing manner, the surface of the second bevel gear is fixedly connected with the second rotating column, one end of the second rotating column, which is far away from the second bevel gear, is fixedly connected with the convex block, the surface of the second rotating column is rotatably connected with the transverse column, the spiral groove is formed in the surface of the transverse column, the convex block is installed in a matching manner with the spiral groove, and the end surface of the transverse column, which is far away from the second bevel gear, is symmetrically and fixedly connected with the fixing block, the below of storage case is provided with the connecting rod, and the connecting rod has two, the one end and the fixed block of connecting rod rotate the installation, the surface symmetry of feed opening rotates installs the apron, the fixed surface of apron connects the dead lever, the dead lever is kept away from the one end rotation of fixed block with the connecting rod and is connected, the inner wall of box is located the below fixedly connected with installation piece of semicircle board, first bevel gear and second bevel gear all rotate the installation with the installation piece.
Preferably, the internally mounted of feed inlet has first feed valve, the internally mounted of discharge gate has the bleeder valve, the internally mounted of connecting pipe has the second feed valve.
Compared with the related technology, the intelligent preparation process of the TZO semiconductor material for glass provided by the invention has the following beneficial effects:
the invention provides a box cover, wherein a controller can be arranged on the upper surface of the box cover, a servo motor, a first feeding valve, a second feeding valve and a discharging valve are all connected with the controller through leads, the controller is precisely controlled by a computer program and is controlled by the controller, the servo motor drives a vertical post to rotate, the vertical post is fixedly connected with a rotary table, the rotary table rotates along with the rotation of the vertical post, further a second rack is driven to rotate, further a fourth gear is driven to rotate, the third gear is driven to rotate by the connecting post, further a first rotating post is driven to rotate, the second rotating post is driven to rotate by the first bevel gear and a second bevel gear, further the second rotating post is driven to rotate, further a transverse post is driven to approach towards a discharging port, two cover plates are driven to move towards opposite directions by the transmission of two connecting rods, the discharging port is opened, and ZnO and SnO are added while the discharging port is opened2While stirring, the third gear rotates and drives the first rack and the second arc-shaped column to slide along the first arc-shaped groove, the spring is compressed, when the second rack and the fourth gear are not meshed any more, the second arc-shaped column and the first rack recover to the initial position under the action of the spring force, the third gear rotates by the same angle towards the opposite direction, namely, the transverse column can reset, the two cover plates are in a closed state, one-time feeding is completed, and the feeding is performed while feedingThe line stirring, compare in prior art, can guarantee to react fully in the same time, and then guarantee the quality of the thick liquids of making.
Drawings
FIG. 1 is a flow chart of the preparation of the TZO semiconductor material for glass provided by the invention;
FIG. 2 is a schematic view of the overall structure provided by the present invention;
FIG. 3 is a schematic view of an internal structure of the case according to the present invention;
FIG. 4 is a schematic structural diagram of a stirring mechanism provided in the present invention;
FIG. 5 is a schematic view of a structure of the second rack and the fourth gear according to the present invention;
FIG. 6 is a second schematic view of the internal structure of the case according to the present invention;
FIG. 7 is a schematic view of a transmission configuration provided by the present invention;
fig. 8 is a schematic structural diagram of an adjusting device provided by the present invention.
Reference numbers in the figures: 1. a box body; 2. a box cover; 3. a feed inlet; 4. a discharge port; 5. an adjustment device; 6. a stirring mechanism; 7. a transmission device; 8. a material storage box; 9. a connecting pipe; 10. a feeding port; 11. a motor case; 12. a servo motor; 13. a vertical post; 14. a first gear; 15. a second gear; 16. a stirring column; 17. a stirring rod; 18. a cross plate; 19. an arc-shaped plate; 20. an L-shaped plate; 21. a turntable; 22. a first rack; 23. connecting columns; 24. a third gear; 25. a fourth gear; 26. a semicircular plate; 27. a first arc-shaped slot; 28. a second arc-shaped slot; 29. a second rack; 30. a spring; 31. a limiting block; 32. a first arc-shaped column; 33. a square plate; 34. a first rotating column; 35. mounting blocks; 36. a first bevel gear; 37. a second bevel gear; 38. a second rotating cylinder; 39. a bump; 40. a cross post; 41. a helical groove; 42. a fixed block; 43. a connecting rod; 44. fixing the rod; 45. a cover plate; 46. a first feed valve; 47. a discharge valve; 48. a second feed valve; 49. a second arc-shaped column.
Detailed Description
The invention is further described with reference to the following figures and embodiments.
Referring to fig. 1, fig. 2, fig. 3, fig. 4, fig. 5, fig. 6, fig. 7 and fig. 8 in combination, wherein fig. 1 is a flow chart of a process for preparing a TZO semiconductor material for glass according to the present invention; FIG. 2 is a schematic view of the overall structure provided by the present invention; FIG. 3 is a schematic view of an internal structure of the case according to the present invention; FIG. 4 is a schematic structural diagram of a stirring mechanism provided in the present invention; FIG. 5 is a schematic view of a structure of the second rack and the fourth gear according to the present invention; FIG. 6 is a second schematic view of the internal structure of the case according to the present invention; FIG. 7 is a schematic view of a transmission configuration provided by the present invention; fig. 8 is a schematic structural diagram of an adjusting device provided by the present invention.
In specific implementation, as shown in fig. 2, 3 and 4, the intelligent preparation process of the TZO semiconductor material for glass uses an intelligent preparation device of the TZO semiconductor material for glass, and comprises the following steps:
1) mixing a mixed solution of water and polyvinyl alcohol and a polymerization monomer in a stirring container, and adding a dispersing agent while mixing to obtain a mixed solution;
2) placing the mixed solution into an intelligent preparation device of the TZO semiconductor material for glass, and gradually adding ZnO and SnO into the mixed solution2The powder mixture is stirred while adding to ensure that ZnO and SnO2The powder mixture can fully react with the mixed solution for 40 minutes to prepare slurry;
3) the prepared slurry is fed from an intelligent preparation device of the TZO semiconductor material for glass, enters a ball milling mechanism for ball milling, is placed in a vacuum stirrer, is added with a polymerization catalyst and a polymerization initiator, is stirred and mixed for 65 minutes and is at the temperature of 40 ℃; after ball milling, the size D50 reaches 0.1-0.4 mu m;
4) placing the stirred material in a mold, performing injection molding to prepare a biscuit, drying the biscuit in air at 100 ℃, sintering the biscuit in an environment of 1400 ℃ for 4 hours, cooling the biscuit to room temperature, and reprocessing to obtain a TZO semiconductor material;
in some embodiments of the invention, the polymerized monomer is a methacrylamide monomer and N-N' -dimethyl bisacrylamide in a weight ratio of 10: 1, the weight ratio of the ZnO to the SnO2 is 10: 6, the polymerization catalyst is tetramethylethylenediamine, the polymerization initiator is ammonium persulfate, and the dispersant is sodium tripolyphosphate, wherein the components are calculated according to parts by weight and comprise the following components: 100 parts of deionized water, 10 parts of polyvinyl alcohol, 10 parts of methacrylamide monomer, 1 part of N-N' -dimethyl bisacrylamide, 0.1 part of polymerization catalyst, 0.02 part of polymerization initiator and 0.5 part of dispersant.
Wherein the intelligent preparation device of the TZO semiconductor material for glass in the step 2) comprises a box body 1, the top of the box body 1 is provided with a box cover 2 in a matching way, the surface of the box body 1 is provided with a feed inlet 3 and a discharge outlet 4, the center of the upper surface of the box cover 2 is fixedly connected with a stirring mechanism 6, the inner wall of the box body 1 is fixedly connected with an adjusting device 5, the adjusting device 5 is fixedly connected with the stirring mechanism 6, a transmission device 7 is arranged in the box body 1, the transmission device 7 is fixedly connected with the adjusting device 5, the lower surface of the box cover 2 is fixedly connected with a material storage box 8, the material storage box 8 is rotatably arranged with the adjusting device 5, the material storage box 8 is rotatably arranged with the transmission device 7, the fixed surface of storage case 8 is connected with connecting pipe 9, connecting pipe 9 is linked together with the inner chamber of storage case 8, feed opening 10 has been seted up to the bottom of storage case 8.
As shown in fig. 3 and 4, the stirring mechanism 6 includes a motor box 11, a servo motor 12, a vertical column 13, a first gear 14, a second gear 15, a stirring column 16, a stirring rod 17 and a cross plate 18, the motor box 11 is fixedly connected to the center of the upper surface of the box cover 2, the servo motor 12 is installed inside the motor box 11, the vertical column 13 is fixedly connected to the output end of the servo motor 12, the first gear 14 is fixedly connected to one end of the vertical column 13 away from the servo motor 12, the second gear 15 is symmetrically engaged and connected to the outer side of the first gear 14, the cross plate 18 is fixedly connected to the inner wall of the box 1, the first gear 14 and the cross plate 18 are rotatably installed, two second gears 15 and the cross plate 18 are rotatably installed, the stirring column 16 is fixedly connected to the surface of the second gear 15, the stirring rod 17 is fixedly connected to the outer side of the stirring column 16 at equal intervals, servo motor 12 starts, drives upstand 13 and rotates, carousel 21 and upstand 13 fixed connection, and carousel 21 rotates along with upstand 13, and upstand 13 rotates and drives first gear 14 and rotate, and then drives two and first gear 14 meshing and be connected with second gear 15 and rotate, and two second gear 15 rotation directions are the same, and second gear 15 rotates and drives stirring column 16 and rotate, and a plurality of puddlers 17 rotate along with stirring column 16 rotates and stir.
As shown in fig. 3, the surface of the cross plate 18 is fixedly connected with an arc plate 19, the first gear 14 is rotatably mounted with the arc plate 19, the second gear 15 is rotatably mounted with the arc plate 19, and the stirring posts 16 are rotatably connected with the arc plate 19, so that the first gear 14 and the second gear 15 are prevented from contacting with a mixed solution or slurry, the mounting stability of the first gear 14 and the second gear 15 is ensured, and the supported slurry can be prevented from being accumulated on the surface of the arc plate 19.
As shown in fig. 3, the lower surface of the box cover 2 is symmetrically and fixedly connected with L-shaped plates 20, and the two L-shaped plates 20 are both fixedly connected with the storage box 8 to play a role in connection and ensure stable installation of the storage box 8.
As shown in fig. 5, 6 and 8, the adjusting device 5 includes a rotary table 21, a first rack 22, a connecting column 23, a third gear 24, a fourth gear 25, a semicircular plate 26, a first arc-shaped groove 27, a second arc-shaped groove 28, a second rack 29, a spring 30, a limiting block 31, a first arc-shaped column 32 and a second arc-shaped column 49, the inner wall of the box body 1 is located below the box cover 2 and is fixedly connected with the semicircular plate 26, the surface of the semicircular plate 26 is provided with the first arc-shaped groove 27, the surface of the first arc-shaped groove 27 is fixedly connected with the first arc-shaped column 32, one end of the surface of the arc-shaped column is fixedly connected with the limiting block 31, the surface of the limiting block 31 is fixedly connected with the spring 30, one end of the surface of the first arc-shaped groove 27 far away from the arc-shaped column is slidably provided with the second arc-shaped column, the end surface of the second arc-shaped column close to the first arc-shaped column 32 is provided with the second arc-shaped groove 28, one end of the spring 30 far from the limiting block 31 is fixedly connected with the bottom of the second arc-shaped groove 28, and the surface of the second arc-shaped column is fixedly connectedThere is first rack 22, the meshing of the one end on first rack 22 surface is connected with third gear 24, go up through one-way bearing rotation on third gear 24 and be connected with spliced pole 23, the one end fixedly connected with fourth gear 25 that third gear 24 was kept away from to spliced pole 23, the outside meshing of fourth gear 25 is connected with second rack 29, the top of storage tank 8 rotates and installs carousel 21, carousel 21 and second rack 29 fixed connection, carousel 21 and upstand 13 fixed connection, carousel 21 and case lid 2 rotate the installation, third gear 24 and first rack 22 meshing, third gear 24 rotates and drives second arc post 49 and slides on the surface of first arc wall 27, and spring 30 is compressed, and the reaction force that produces acts on the surface of stopper 31, stopper 31 and first arc wall 32 get into second arc wall 28, until second rack 29 and fourth gear 25 separate, under the action of the elastic force of the spring 30, the second arc-shaped column 49 is restored to the initial position, the first rack 22 is matched with the third gear 24 to drive the third gear 24 to reversely rotate by the same angle, and further drive the first rotating column 34 to reversely rotate, the first bevel gear 36 and the second bevel gear 37 drive the second rotating column 38 to rotate, the convex block 39 is matched with the spiral groove 41 to drive the cross column 40 to be restored to the initial position, the two cover plates 45 are restored to the initial position, and the ZnO and SnO are stopped from being performed2Blanking the powder mixture.
As shown in fig. 5, a square plate 33 is fixedly connected to the surface of the semicircular plate 26, and the third gear 24 and the square plate 33 are rotatably mounted to ensure the stability of the mounting of the third gear 24.
As shown in fig. 3, 4, 6 and 7, the transmission device 7 includes a first rotating column 34, a mounting block 35, a first bevel gear 36, a second bevel gear 37, a second rotating column 38, a protrusion 39, a transverse column 40, a spiral groove 41, a fixing block 42, a connecting rod 43, a fixing rod 44 and a cover plate 45, the first rotating column 34 is rotatably connected inside the square plate 33, one end of the first rotating column 34 close to the semicircular plate 26 is fixedly connected with the third gear 24, one end of the first rotating column 34 far from the third gear 24 is fixedly connected with the first bevel gear 36, the outer side of the first bevel gear 36 is engaged with the second bevel gear 37, and the surface of the second bevel gear 37 is fixedly connected with the second bevel gear 37The second rotating column 38 is connected, a convex block 39 is fixedly connected to one end of the surface of the second rotating column 38, which is far away from the second bevel gear 37, a cross column 40 is rotatably connected to the surface of the second rotating column 38, a spiral groove 41 is formed in the surface of the cross column 40, the convex block 39 and the spiral groove 41 are installed in a matched mode, fixed blocks 42 are symmetrically and fixedly connected to the end surface of the cross column 40, which is far away from the second bevel gear 37, connecting rods 43 are arranged below the material storage box 8, two connecting rods 43 are arranged, one end of each connecting rod 43 is rotatably installed with the corresponding fixed block 42, a cover plate 45 is symmetrically and rotatably installed on the surface of the blanking port 10, a fixed rod 44 is fixedly connected to the surface of the cover plate 45, the fixed rod 44 is rotatably connected to one end of each connecting rod 43, which is far away from the corresponding fixed block 42, the mounting block 35 is fixedly connected to the inner wall of the box body 1, which is located below the semicircular plate 26, and the first bevel gear 36 and the second bevel gear 37 are rotatably installed with the mounting block 35, play the transmission effect, third gear 24 rotates and drives first rotating column 34 to rotate, and then drive first bevel gear 36 to rotate, and then drive second bevel gear 37 to rotate, and then drive second rotating column 38 to rotate, lug 39 and helicla flute 41 cooperate, it is close to drive spreader 40 towards the direction of feed opening 10, apron 45 is installed in the rotation of surface symmetry of feed opening 10, the end symmetry fixedly connected with fixed block 42 of installation piece 35 is kept away from to spreader 40, spreader 40 is when removing, by the transmission of two connecting rods 43, drive two apron 45 to rotate, feed opening 10 is opened, ZnO and SnO are rotated2The powder mixture of (a) falls into the mixed solution.
As shown in fig. 2, a first feeding valve 46 is installed inside the feeding port 3, a discharging valve 47 is installed inside the discharging port 4, and a second feeding valve 48 is installed inside the connecting pipe 9, so that feeding and discharging are facilitated.
In fact, the specific preparation method can refer to the chinese patent with publication number CN108516819A, and the main innovation point of the present invention is that the apparatus of the present invention is adopted, so that the whole process is more intelligent and automatic, and the following provides the working principle of the apparatus of the present invention to help the skilled in the art to have more deep understanding and full working principle of the preparation process of the present invention: on the upper surface of the case cover 2The surface mountable controller, servo motor 12, first feed valve 46, second feed valve 48 and bleeder valve 47 all pass through the wire with the controller and are connected, and the controller is by accurate control of computer program, opens first feed valve 46, adds the mixed solution, opens second feed valve 48, adds ZnO and SnO2The powder mixture is controlled by a controller, a servo motor 12 is started to drive a vertical column 13 to rotate, a rotary table 21 is fixedly connected with the vertical column 13, the rotary table 21 rotates along with the vertical column 13, the vertical column 13 rotates to drive a first gear 14 to rotate, and then two second gears 15 meshed with the first gear 14 are driven to rotate, the rotation directions of the two second gears 15 are the same, the second gear 15 rotates to drive a stirring column 16 to rotate, a plurality of stirring rods 17 rotate along with the stirring column 16 to stir, a second rack 29 rotates along with the rotation of the rotary table 21, the second rack 29 is meshed with a fourth gear 25 in the rotating process to drive a fourth gear 25 to rotate, and then a connecting column 23 is driven to rotate, the connecting column 23 is connected with a third gear 24 through a one-way bearing in a rotating manner, and then the third gear 24 is driven to rotate, the third gear 24 rotates to drive a first rotating column 34 to rotate, and then drive first bevel gear 36 and rotate, and then drive second bevel gear 37 and rotate, and then drive second rotation post 38 and rotate, lug 39 and helicla flute 41 cooperation, it is close to drive spreader 40 towards the direction of feed opening 10, the surface symmetry of feed opening 10 is rotated and is installed apron 45, the symmetrical fixedly connected with fixed block 42 of terminal surface that installation piece 35 was kept away from to spreader 40, spreader 40 is when removing, by two connecting rod 43 transmissions, drive two apron 45 and rotate, feed opening 10 is opened, ZnO and SnO2The powder mixture falls into the mixed solution, the two stirring columns 16 have the same rotation direction, and can simultaneously drive the plurality of stirring rods 17 to drop ZnO and SnO in the mixed solution2The third gear 24 is meshed with the first rack 22, the third gear 24 rotates to drive the second arc-shaped column 49 to slide on the surface of the first arc-shaped groove 27, the spring 30 is compressed, the generated reaction force acts on the surface of the limiting block 31, the limiting block 31 and the first arc-shaped column 32 enter the second arc-shaped groove 28 until the second rack 29 is separated from the fourth gear 25, the second arc-shaped column 49 returns to the initial position under the elastic force of the spring 30, and the first rack 22 and the third rack 22 are separatedThe wheels 24 are matched to drive the third gear 24 to rotate reversely by the same angle, and further drive the first rotating column 34 to rotate reversely, the first bevel gear 36 and the second bevel gear 37 drive the second rotating column 38 to rotate, the convex block 39 is matched with the spiral groove 41 to drive the cross column 40 to return to the initial position, the two cover plates 45 return to the initial position, and the ZnO and SnO stop2The servo motor 12 drives the vertical column 13 to rotate, the process is repeated, and after a certain time, the controller controls the discharge valve 47 to open for discharging.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by using the contents of the present specification and the accompanying drawings, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (7)
1. The intelligent preparation process of the TZO semiconductor material for the glass uses an intelligent preparation device of the TZO semiconductor material for the glass, and is characterized by comprising the following steps of:
1) mixing a mixed solution of water and polyvinyl alcohol and a polymerization monomer in a stirring container, and adding a dispersing agent while mixing to obtain a mixed solution;
2) placing the mixed solution into an intelligent preparation device of the TZO semiconductor material for glass, and gradually adding ZnO and SnO into the mixed solution2The powder mixture is stirred while adding to ensure that ZnO and SnO2The powder mixture can fully react with the mixed solution for 40 minutes to prepare slurry;
3) the prepared slurry is fed from an intelligent preparation device of the TZO semiconductor material for glass, enters a ball milling mechanism for ball milling, is placed in a vacuum stirrer, is added with a polymerization catalyst and a polymerization initiator, is stirred and mixed for 65 minutes and is at the temperature of 40 ℃;
4) placing the stirred material in a mold, performing injection molding to prepare a biscuit, drying the biscuit in air at 100 ℃, sintering the biscuit in an environment of 1400 ℃ for 4 hours, cooling the biscuit to room temperature, and reprocessing to obtain a TZO semiconductor material;
wherein the intelligent preparation device of the TZO semiconductor material for glass in the step 2) comprises a box body (1), a box cover (2) is installed at the top of the box body (1) in a matched mode, a feeding hole (3) and a discharging hole (4) are formed in the surface of the box body (1), a stirring mechanism (6) is fixedly connected to the center of the upper surface of the box cover (2), an adjusting device (5) is fixedly connected to the inner wall of the box body (1), the adjusting device (5) is fixedly connected with the stirring mechanism (6), a transmission device (7) is arranged inside the box body (1), the transmission device (7) is fixedly connected with the adjusting device (5), a storage box (8) is fixedly connected to the lower surface of the box cover (2), the storage box (8) is rotatably installed with the adjusting device (5), and the storage box (8) is rotatably installed with the transmission device (7), the surface of the storage box (8) is fixedly connected with a connecting pipe (9), the connecting pipe (9) is communicated with an inner cavity of the storage box (8), a feed opening (10) is formed in the bottom of the storage box (8), the adjusting device (5) comprises a turntable (21), a first rack (22), a connecting column (23), a third gear (24), a fourth gear (25), a semicircular plate (26), a first arc-shaped groove (27), a second arc-shaped groove (28), a second rack (29), a spring (30), a limiting block (31), a first arc-shaped column (32) and a second arc-shaped column (49), the inner wall of the box body (1) is positioned below the box cover (2) and is fixedly connected with the semicircular plate (26), the surface of the semicircular plate (26) is provided with the first arc-shaped groove (27), the surface of the first arc-shaped groove (27) is fixedly connected with the first arc-shaped column (32), one end of the surface of the first arc-shaped column (32) is fixedly connected with a limiting block (31), the surface of the limiting block (31) is fixedly connected with a spring (30), one end of the surface of the first arc-shaped groove (27), far away from the first arc-shaped column (32), is slidably mounted with a second arc-shaped column (49), the end surface of the second arc-shaped column (49), close to the first arc-shaped column (32), is provided with a second arc-shaped groove (28), one end of the spring (30), far away from the limiting block (31), is fixedly connected with the bottom of the second arc-shaped groove (28), the surface of the second arc-shaped column (49) is fixedly connected with a first rack (22), one end of the surface of the first rack (22) is meshed with a third gear (24), the upper part of the third gear (24) is rotatably connected with a connecting column (23) through an one-way bearing, one end of the connecting column (23), far away from the third gear (24), is fixedly connected with a fourth gear (25), the outer side of the fourth gear (25) is meshed with a second rack (29), a rotary table (21) is rotatably mounted above the storage box (8), the rotary table (21) is fixedly connected with the second rack (29), the rotary table (21) is fixedly connected with a vertical column (13), the rotary table (21) is rotatably mounted with a box cover (2), a square plate (33) is fixedly connected to the surface of the semicircular plate (26), the third gear (24) is rotatably mounted with the square plate (33), the transmission device (7) comprises a first rotary column (34), a mounting block (35), a first bevel gear (36), a second bevel gear (37), a second rotary column (38), a convex block (39), a transverse column (40), a spiral groove (41), a fixed block (42), a connecting rod (43), a fixing rod (44) and a cover plate (45), and the inner part of the square plate (33) is rotatably connected with the first rotary column (34), one end, close to the semicircular plate (26), of the first rotating column (34) is fixedly connected with the third gear (24), one end, far away from the third gear (24), of the first rotating column (34) is fixedly connected with a first bevel gear (36), the outer side of the first bevel gear (36) is in meshed connection with a second bevel gear (37), the surface of the second bevel gear (37) is fixedly connected with a second rotating column (38), one end, far away from the second bevel gear (37), of the surface of the second rotating column (38) is fixedly connected with a convex block (39), the surface of the second rotating column (38) is rotatably connected with a transverse column (40), the surface of the transverse column (40) is provided with a spiral groove (41), the convex block (39) and the spiral groove (41) are installed in a matched mode, and the end face, far away from the second bevel gear (37), of the transverse column (40) is symmetrically and fixedly connected with a fixing block (42), the connecting rods (43) are arranged below the material storage box (8), the number of the connecting rods (43) is two, one end of each connecting rod (43) is rotatably mounted with one fixing block (42), the cover plates (45) are symmetrically and rotatably mounted on the surface of the feed opening (10), the surface of each cover plate (45) is fixedly connected with one fixing rod (44), each fixing rod (44) is rotatably connected with one end, far away from the corresponding fixing block (42), of each connecting rod (43), the mounting block (35) is fixedly connected to the inner wall of the box body (1) below the semicircular plate (26), and the first bevel gear (36) and the second bevel gear (37) are rotatably mounted with the mounting block (35); the internally mounted of feed inlet (3) has first feed valve (46), the internally mounted of discharge gate (4) has bleeder valve (47), the internally mounted of connecting pipe (9) has second feed valve (48).
2. The intelligent preparation process of TZO semiconductor material for glass as claimed in claim 1, wherein the polymerization monomer is methacrylamide monomer and N-N' -dimethyl bisacrylamide in a weight ratio of 10: 1 of the resulting mixture.
3. The intelligent preparation process of TZO semiconductor material for glass as claimed in claim 2, wherein the ZnO and SnO are2The weight ratio of (A) to (B) is 10: 6.
4. the intelligent preparation process of TZO semiconductor material for glass as claimed in claim 3, wherein the polymerization catalyst is tetramethylethylenediamine, the polymerization initiator is ammonium persulfate, and the dispersant is sodium tripolyphosphate.
5. The intelligent preparation process of the TZO semiconductor material for glass as claimed in claim 4, wherein the TZO semiconductor material for glass comprises the following components in parts by weight: 100 parts of deionized water, 10 parts of polyvinyl alcohol, 10 parts of methacrylamide monomer, 1 part of N-N' -dimethyl bisacrylamide, 0.1 part of polymerization catalyst, 0.02 part of polymerization initiator and 0.5 part of dispersant.
6. The intelligent preparation process of the TZO semiconductor material for glass as claimed in claim 1, wherein the stirring mechanism (6) comprises a motor box (11), a servo motor (12), a vertical column (13), a first gear (14), a second gear (15), a stirring column (16), a stirring rod (17) and a cross plate (18), the motor box (11) is fixedly connected to the center of the upper surface of the box cover (2), the servo motor (12) is installed inside the motor box (11), the vertical column (13) is fixedly connected to the output end of the servo motor (12), the first gear (14) is fixedly connected to one end, away from the servo motor (12), of the vertical column (13), the second gear (15) is symmetrically engaged and connected to the outer side of the first gear (14), the cross plate (18) is fixedly connected to the inner wall of the box body (1), and the first gear (14) and the cross plate (18) are rotatably installed, two second gear (15) and cross (18) rotate the installation, the fixed surface of second gear (15) is connected with stirring post (16), the outside equidistance fixedly connected with puddler (17) of stirring post (16).
7. The intelligent preparation process of the TZO semiconductor material for glass as claimed in claim 6, wherein an arc-shaped plate (19) is fixedly connected to the surface of the cross plate (18), the first gear (14) is rotatably mounted with the arc-shaped plate (19), the two second gears (15) are rotatably mounted with the arc-shaped plate (19), and the two stirring columns (16) are rotatably connected with the arc-shaped plate (19); the lower surface of the box cover (2) is symmetrically and fixedly connected with L-shaped plates (20), and the two L-shaped plates (20) are fixedly connected with the material storage box (8).
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