CN113265565A - Iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction and preparation method thereof - Google Patents

Iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction and preparation method thereof Download PDF

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CN113265565A
CN113265565A CN202110528553.4A CN202110528553A CN113265565A CN 113265565 A CN113265565 A CN 113265565A CN 202110528553 A CN202110528553 A CN 202110528553A CN 113265565 A CN113265565 A CN 113265565A
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high magnetic
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nickel
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CN113265565B (en
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杨帆
徐明舟
李重阳
安杨
张�荣
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Beijing Beiye Functional Materials Corp
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/057Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being less 10%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/023Alloys based on nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/02Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/147Alloys characterised by their composition
    • H01F1/14708Fe-Ni based alloys
    • H01F1/14716Fe-Ni based alloys in the form of sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties

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  • Soft Magnetic Materials (AREA)

Abstract

The invention discloses an iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction and a preparation method thereof. The alloy comprises the following components in percentage by mass: 70.00 to 75.00 percent of nickel; 0.20 to 1.00 percent of manganese; 0.15 to 0.50 percent of silicon; 0.50 to 2.50 percent of molybdenum; 0.10 to 0.40 percent of chromium; 0 to 2.00 percent of copper; carbon is less than 0.01 percent; the balance of iron and inevitable impurities. The method comprises the steps of smelting, forging, hot rolling and cold rolling to finally prepare the iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction. The high-permeability high-magnetic-induction iron-nickel soft magnetic alloy cold-rolled strip prepared by the invention has higher mu0、μmAnd Bs, and low Hc,. mu.0>180mH/m,μmMore than 600mH/m, Bs more than 1.20T, Br less than 0.3T and Hc less than 0.8A/m, and the electromagnetic device manufactured by the material can meet the use requirements under certain specific conditions, thereby being beneficial to improving the response speed of the electromagnetic device and realizing the miniaturization of the electromagnetic device. The iron-nickel soft magnetic alloy cold-rolled strip with high magnetic conductivity and high magnetic induction prepared by the invention has good processing performance, simple processing technology and heat treatment technology and low cost, and is suitable for industrial production.

Description

Iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction and preparation method thereof
Technical Field
The invention relates to the field of alloys, in particular to an iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction and a preparation method thereof.
Background
With the rapid development of the current electronics and informatization fields, the soft magnetic alloy used for manufacturing the traditional electrical equipment can not meet the performance requirement which is increasing day by day, and a novel soft magnetic alloy needs to be developed to meet the new use requirement. Fe-Ni soft magnetic alloy with high initial permeability mu0High maximum magnetic permeability mumAnd low coercive force Hc, as well as good processability, have been widely used in many electromagnetic device applications. The Fe-Ni soft magnetic alloy generally refers to an alloy series with 35-90% of Ni, and is classified by medium-Ni soft magnetic alloy and high-Ni soft magnetic alloy, wherein the medium-Ni soft magnetic alloy generally has 40-60% of Ni, common alloys such as national standard 1J46 and 1J50 alloy, foreign 45H and PB series alloys and the like, and the alloys have higher magnetic induction Bs (Bs is more than or equal to 1.50T), but mu m is0And mumIs generally low (mu)0≤20mH/m,μmLess than or equal to 200mH/m), and Hc is higher (Hc is more than or equal to 3A/m), which easily causes overlarge loss, leads to the reduction of the reaction sensitivity of the electromagnetic device and the performance reduction. The high nickel soft magnetic alloy usually has a nickel content of 70-90%, and common alloys such as national standard 1J79 and 1J85 alloy, and foreign 78H and PC series alloy, etc., although have lower Hc (Hc < 2.0A/m) and higher mu0And mum0≥30mH/m,μm200mH/m) but has low Bs (Bs < 1.10T), and the alloy is easy to reach saturation under a specific use environment, so that the application of the alloy is limited.
The prior scholars have applied for patents relating to soft magnetic alloys of high magnetic permeability and high nickel series, such as the publication numberCN 102723158B and EP 1283275A1, the two patents further improve the mu on the basis of the performance of the existing high-nickel soft magnetic alloy by optimizing and mixing gold components0And mumAnd Hc is reduced, but Bs is generally between 0.6T and 0.9T, compared with the existing high-nickel soft magnetic alloy, the alloy is not obviously improved, the alloy is easy to reach a saturation state during application, the miniaturization design requirement of an electromagnetic device is not facilitated, and the application limit of the current high-nickel soft magnetic alloy in a specific field cannot be broken through. The publication No. CN 112176222A comprises the following components in percentage by mass: 13-50% of iron, 0-6% of molybdenum, 0.1-0.6% of silicon, 0.2-0.8% of manganese, 2.0-8.2% of copper, 0.001-0.1% of cerium, and the balance of nickel and inevitable impurities.
As described above, the conventional high nickel-based soft magnetic alloy cannot simultaneously have high magnetic permeability and high magnetic induction properties. Therefore, in order to solve the existing problems, a mu needs to be developed0>180mH/m,μmMore than 600mH/m, Bs more than 1.20T, Br less than 0.3T and Hc less than 0.8A/m, can meet the use requirements of high-performance iron-nickel soft magnetic alloys under specific conditions, and simultaneously enriches the series of the existing high-nickel soft magnetic alloys.
Disclosure of Invention
Therefore, the invention provides the iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction and the preparation method thereof, and aims to solve the problem that the existing high-nickel soft magnetic alloy cannot have the characteristics of high magnetic conductivity and high magnetic induction at the same time.
In order to achieve the above purpose, the invention provides the following technical scheme:
according to the first aspect of the invention, the iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction provided by the invention comprises the following components in percentage by mass: 70.00 to 75.00 percent of nickel; 0.20 to 1.00 percent of manganese; 0.15 to 0.50 percent of silicon; 0.50 to 2.50 percent of molybdenum; 0.10 to 0.40 percent of chromium; 0 to 2.00 percent of copper; carbon is less than 0.01 percent; the balance of iron and inevitable impurities.
Further, the inevitable impurities are impurities carried in the raw materials of nickel, manganese, silicon, molybdenum, chromium, copper, carbon and iron by themselves; the total amount of the inevitable impurities is less than 0.10%.
Further, the magnetic property of the alloy is as follows: mu.s0>180mH/m,μm>600mH/m,Bs>1.20T,Br<0.3T,Hc<0.8A/m。
According to a second aspect of the present invention, there is provided a method for preparing the above-mentioned iron-nickel soft magnetic alloy with high permeability and high magnetic induction, the method comprising:
step one, smelting
Under the vacuum condition, raw materials of nickel, molybdenum, chromium, copper, iron and carbon are mixed and smelted according to chemical composition proportion, silicon and manganese are added 10min to 1.5h before tapping, tapping can be carried out after complete melting, and steel ingots are cast; after the steel ingot is cooled to room temperature by air cooling, removing oxide skin on the surface of the steel ingot to obtain an oxide skin-removed steel ingot;
step two, forging and hot rolling
After heating and heat preservation, the descaled steel ingot is forged and pressed into a flat blank at the heat preservation temperature; cooling the flat blank to room temperature, and removing oxide skin on the surface of the flat blank to obtain a descaled flat blank; heating and insulating the descaling flat blank, and then hot-rolling the descaling flat blank into a hot-rolled strip; after the hot rolled strip is cooled to room temperature, removing oxide skin on the surface of the hot rolled strip to obtain a descaled hot rolled strip;
step three, cold rolling
Performing cold rolling processing on the hot rolled strip with the scale removed at room temperature; if intermediate continuous furnace annealing is needed, annealing the cold strip blank semi-finished product by adopting an intermediate continuous annealing furnace; cooling the annealed semi-finished cold strip blank to room temperature, and then continuously cold rolling to obtain a finished cold strip; the finished product of the cold zone is subjected to 1100-1200 ℃ H2And annealing in a furnace to obtain the iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction.
Further, in the first step, the smelting temperature is 1400-1600 ℃, and the tapping temperature is 1400-1600 ℃.
Further, in the second step, the heat preservation temperature is 900-.
Further, in the third step, the intermediate continuous furnace annealing adopts H at 900-1150 DEG C2The atmosphere is carried out at a speed of 0.5-2.0 m/min.
Further, in the third step, the cooling speed of the semi-finished product cooled to the room temperature is more than 500 ℃/h.
Further, in the third step, the rolling deformation of the cold-processed finished product of the cold-rolled finished product of the cold strip is 80-95%.
Further, in the third step, the thickness of the finished product of the cold belt is 0.05-1.00 mm.
The influence of the chemical components of the raw materials adopted by the invention on the alloy of the invention is as follows:
nickel: increase the mu of the alloy0And mumLowering Hc, too low nickel content tends to increase Hc and lower μ0And mumToo high nickel content tends to result in a decrease in Bs. To make the alloy have high mu0、μmAnd Bs, and Hc is reduced, so that the nickel content is preferably (in mass%) 70.00-75.00%;
manganese: adjusting the magnetocrystalline anisotropy constant and the magnetostriction coefficient of the alloy to enable the magnetocrystalline anisotropy constant and the hysteresis expansion coefficient of the alloy to approach zero, thereby being beneficial to reducing the Hc of the alloy;
silicon: the resistivity of the alloy is improved, and the eddy current loss of the alloy is reduced;
molybdenum: the magnetocrystalline anisotropy constant and the magnetostriction coefficient of the alloy are adjusted to lead the magnetocrystalline anisotropy constant and the hysteresis expansion coefficient of the alloy to approach zero, inhibit the generation of long-range order in the heat treatment process of the alloy, contribute to reducing Hc of the alloy and improve mu0And mumMeanwhile, the requirement of the alloy on the cooling speed in the heat treatment process of the finished product is reduced, and the method is suitable for industrial production;
copper: adjusting the magnetocrystalline anisotropy constant and the magnetostriction coefficient of the alloy, and improving the cold processing performance of the alloy;
chromium: the resistivity is improved, the eddy current loss is reduced, and the corrosion resistance of the alloy is improved;
carbon: the content is controlled below 0.01 percent (mass percentage). Carbon is an element that forms interstitial solid solutions, and interstitial atoms will cause domain wall displacement resistance, adversely affecting the magnetic properties of the alloy.
The invention has the following advantages:
the iron-nickel soft magnetic alloy cold-rolled strip with high magnetic conductivity and high magnetic induction prepared by the invention has higher mu0、μmAnd Bs, and low Hc,. mu.0>180mH/m,μmMore than 600mH/m, Bs more than 1.20T, Br less than 0.3T, Hc less than 0.8A/m, thus the prepared Fe-Ni soft magnetic alloy has higher magnetic conductivity and magnetic induction; the electromagnetic device manufactured by the method can meet the use requirements under certain specific conditions, is favorable for improving the response speed of the electromagnetic device, and realizes the miniaturization of the electromagnetic device.
The iron-nickel soft magnetic alloy cold-rolled strip with high magnetic conductivity and high magnetic induction prepared by the invention has good processing performance, simple processing technology and heat treatment technology and low cost, and is suitable for industrial production.
Detailed Description
The present invention is described in terms of particular embodiments, other advantages and features of the invention will become apparent to those skilled in the art from the following disclosure, and it is to be understood that the described embodiments are merely exemplary of the invention and that it is not intended to limit the invention to the particular embodiments disclosed. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention aims to provide a novel iron-nickel soft magnetic alloy aiming at the defects of the existing alloy, and the alloy has higher mu compared with the traditional high-nickel soft magnetic alloy0、μmAnd Bs and low Hc, and the electromagnetic device manufactured by the alloy meets the use requirements under certain specific conditions and perfects the existing high-nickel soft magnetic alloy series.
Design guiding idea of the invention: taking iron and nickel as basic chemical components, obtaining higher Bs of the alloy by optimizing the proportion of the iron and nickel, properly adding molybdenum, copper, chromium and manganese elements, adjusting the magnetostriction coefficient and magnetocrystalline anisotropy constant of the alloy, and obtaining higher mu of the alloy after heat treatment0And mumAnd low Hc, and simultaneously improves the resistivity of the alloy, reduces the eddy current loss and improves the corrosion resistance of the alloy.
Embodiment 1 iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction and preparation method thereof
The iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction comprises the following components in percentage by mass: 70.50 percent of nickel; 0.20 percent of manganese; 0.20% of silicon; 0.60 percent of molybdenum; 0.15 percent of chromium; carbon is less than 0.01 percent; the balance of iron and inevitable impurities (the inevitable impurities are impurities carried by the raw materials of nickel, manganese, silicon, molybdenum, chromium, carbon and iron per se, and the total amount of the inevitable impurities is less than 0.1%).
The preparation method of the alloy comprises the following steps:
step one, smelting
Under the vacuum condition, raw materials of nickel, molybdenum, chromium, iron and carbon are mixed according to chemical composition proportion, are mixed and loaded at 1400-1600 ℃ for smelting, silicon and manganese are added 10min-1.5h before tapping, tapping can be carried out after complete melting, the tapping temperature is 1400-1600 ℃, and steel ingots are cast; removing oxide skin on the surface of the steel ingot after the steel ingot is cooled to room temperature to obtain an oxide skin-removed steel ingot;
step two, forging and hot rolling
The heating and heat preservation temperature of the forging and the hot rolling is 900-1150 ℃, the heat preservation time of the forging and the hot rolling is 1-5h, the cooling rate of the forging and the hot rolling is not higher than 200 ℃/h, and the cooling rate of the forging and the hot rolling after being cooled to the room temperature is not lower than 500 ℃/h. And after forging and hot rolling, surface oxide skin needs to be polished, and the thickness of a hot rolled strip is 4.0 mm.
Step three, cold rolling
And (3) carrying out 95% of cold-processing on the hot-rolled strip with the scale removed at room temperature to obtain a finished cold strip with the thickness of 0.2 mm.
H of finished product strip passing through 1100-1200 DEG C2Thermal treatmentAfter treatment, the magnetic property of the obtained alloy is as follows: mu.s0=180mH/m,μm=625mH/m,Bs=1.30T,Br=0.28T,Hc=0.7A/m。
Embodiment 2 iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction and preparation method thereof
The iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction comprises the following components in percentage by mass: 72.00 percent of nickel; 0.40 percent of manganese; 0.30% of silicon; 1.50% of molybdenum; 0.15 percent of chromium; 0.50% of copper; carbon is less than 0.01 percent; the balance of iron and inevitable impurities (the inevitable impurities are impurities carried by the raw materials of nickel, manganese, silicon, molybdenum, chromium, copper, carbon and iron per se, and the total amount of the inevitable impurities is less than 0.1%).
The preparation method of the alloy comprises the following steps:
step one, smelting
Under the vacuum condition, raw materials of nickel, molybdenum, chromium, iron and carbon are mixed according to chemical composition proportion, are mixed and loaded at 1400-1600 ℃ for smelting, silicon and manganese are added 10min-1.5h before tapping, tapping can be carried out after complete melting, the tapping temperature is 1400-1600 ℃, and steel ingots are cast; removing oxide skin on the surface of the steel ingot after the steel ingot is cooled to room temperature to obtain an oxide skin-removed steel ingot;
step two, forging and hot rolling
The heating and heat preservation temperature of the forging and the hot rolling is 900-1150 ℃, the heat preservation time of the forging and the hot rolling is 1-5h, the cooling rate of the forging and the hot rolling is not higher than 200 ℃/h, and the cooling rate of the forging and the hot rolling after being cooled to the room temperature is not lower than 500 ℃/h. And after forging and hot rolling, surface oxide skin needs to be polished, and the thickness of a hot rolled strip is 6.0 mm.
Step three, cold rolling
Cold rolling the hot rolled strip with the scale removed to a cold strip semi-finished product with the thickness of 5.0mm at room temperature; then the semi-finished product cold belt adopts H within the temperature range of 900-1150 DEG C2Annealing in a continuous annealing furnace at a speed of 0.5-2 m/min, and cooling to room temperature at a cooling rate of more than 500 ℃/h; and rolling and deforming by 93% of the cold-processed finished product to obtain a cold strip finished product with the thickness of 0.35 mm.
The finished product strip passes through 1100-1200 DEG CH of (A) to (B)2After heat treatment, the magnetic property of the obtained alloy is as follows: mu.s0=250mH/m,μm=670mH/m,Bs=1.28T,Br=0.27T,Hc=0.6A/m。
Embodiment 3 iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction and preparation method thereof
The iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction comprises the following components in percentage by mass: 73.50% of nickel; 0.60 percent of manganese; 0.30% of silicon; 1.80 percent of molybdenum; 0.20 percent of chromium; 0.80% of copper; carbon is less than 0.01 percent; the balance of iron and inevitable impurities (the inevitable impurities are impurities carried by the raw materials of nickel, manganese, silicon, molybdenum, chromium, copper, carbon and iron per se, and the total amount of the inevitable impurities is less than 0.1%).
The preparation method of the alloy comprises the following steps:
step one, smelting
Under the vacuum condition, raw materials of nickel, molybdenum, chromium, iron and carbon are mixed according to chemical composition proportion, are mixed and loaded at 1400-1600 ℃ for smelting, silicon and manganese are added 10min-1.5h before tapping, tapping can be carried out after complete melting, the tapping temperature is 1400-1600 ℃, and steel ingots are cast; removing oxide skin on the surface of the steel ingot after the steel ingot is cooled to room temperature to obtain an oxide skin-removed steel ingot;
step two, forging and hot rolling
The heating and heat preservation temperature of the forging and the hot rolling is 900-1150 ℃, the heat preservation time of the forging and the hot rolling is 1-5h, the cooling rate of the forging and the hot rolling is not higher than 200 ℃/h, and the cooling rate of the forging and the hot rolling after being cooled to the room temperature is not lower than 500 ℃/h. And after forging and hot rolling, surface oxide skin needs to be polished, and the thickness of a hot rolled strip is 4.0 mm.
Step three, cold rolling
Cold rolling the hot rolled strip with the scale removed to a cold strip semi-finished product with the thickness of 1.3mm at room temperature; then the semi-finished product cold belt adopts H within the temperature range of 900-1150 DEG C2Annealing in a continuous annealing furnace at a speed of 0.5-2 m/min, and cooling to room temperature at a cooling rate of more than 500 ℃/h; after rolling deformation of the cold-processed finished product of 85 percent, a cold strip finished product with the thickness of 0.2mm is prepared.
Finished product beltH of material warp at 1100-1200 DEG C2After heat treatment, the magnetic property of the obtained alloy is as follows: mu.s0=270mH/m,μm=685mH/m,Bs=1.25T,Br=0.25T,Hc=0.55A/m。
Embodiment 4 iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction and preparation method thereof
The iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction comprises the following components in percentage by mass: 74.50% of nickel; 0.50 percent of manganese; 0.40% of silicon; 2.00 percent of molybdenum; 0.20 percent of chromium; 1.20 percent of copper; carbon is less than 0.01 percent; the balance of iron and inevitable impurities (the inevitable impurities are impurities carried by the raw materials of nickel, manganese, silicon, molybdenum, chromium, copper, carbon and iron per se, and the total amount of the inevitable impurities is less than 0.1%).
The preparation method of the alloy comprises the following steps:
step one, smelting
Under the vacuum condition, raw materials of nickel, molybdenum, chromium, iron and carbon are mixed according to chemical composition proportion, are mixed and loaded at 1400-1600 ℃ for smelting, silicon and manganese are added 10min-1.5h before tapping, tapping can be carried out after complete melting, the tapping temperature is 1400-1600 ℃, and steel ingots are cast; removing oxide skin on the surface of the steel ingot after the steel ingot is cooled to room temperature to obtain an oxide skin-removed steel ingot;
step two, forging and hot rolling
The heating and heat preservation temperature of the forging and the hot rolling is 900-1150 ℃, the heat preservation time of the forging and the hot rolling is 1-5h, the cooling rate of the forging and the hot rolling is not higher than 200 ℃/h, and the cooling rate of the forging and the hot rolling after being cooled to the room temperature is not lower than 500 ℃/h. And after forging and hot rolling, surface oxide skin needs to be polished, and the thickness of a hot rolled strip is 4.5 mm.
Step three, cold rolling
Cold rolling the hot rolled strip with the scale removed to obtain a cold strip semi-finished product with the thickness of 4.0mm at room temperature; then the semi-finished product cold belt adopts H within the temperature range of 900-1150 DEG C2Annealing in a continuous annealing furnace at a speed of 0.5-2 m/min, and cooling to room temperature at a cooling rate of more than 500 ℃/h; after the rolling deformation of the cold-processed finished product of 95 percent, a cold belt finished product with the thickness of 0.2mm is prepared.
H of finished product strip passing through 1100-1200 DEG C2After heat treatment, the magnetic property of the obtained alloy is as follows: mu.s0=285mH/m,μm=700mH/m,Bs=1.23T,Br=0.23T,Hc=0.4A/m。
As can be seen from examples 1 to 4, the iron-nickel soft magnetic alloy cold-rolled strip with high magnetic permeability and high magnetic induction prepared by the invention has higher mu0、μmAnd Bs, and low Hc,. mu.0>180mH/m,μmMore than 600mH/m, Bs more than 1.20T, Br less than 0.3T and Hc less than 0.8A/m, and the electromagnetic device manufactured by the material can meet the use requirements under certain specific conditions, thereby being beneficial to improving the response speed of the electromagnetic device and realizing the miniaturization of the electromagnetic device.
Although the invention has been described in detail above with reference to a general description and specific examples, it will be apparent to one skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. The iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction is characterized by comprising the following components in percentage by mass: 70.00 to 75.00 percent of nickel; 0.20 to 1.00 percent of manganese; 0.15 to 0.50 percent of silicon; 0.50 to 2.50 percent of molybdenum; 0.10 to 0.40 percent of chromium; 0 to 2.00 percent of copper; carbon is less than 0.01 percent; the balance of iron and inevitable impurities.
2. The Fe-Ni soft magnetic alloy of high magnetic permeability and high magnetic induction as claimed in claim 1, wherein the inevitable impurities are impurities introduced by the raw materials of Ni, Mn, Si, Mo, Cr, Cu, C and Fe themselves; the total amount of the inevitable impurities is less than 0.10%.
3. The high permeability high magnetic induction iron-nickel soft magnetic alloy of claim 1, wherein the magnetic properties of the alloy are: mu.s0>180mH/m,μm>600mH/m,Bs>1.20T,Br<0.3T,Hc<0.8A/m。
4. A method for preparing a high permeability, high magnetic induction iron-nickel soft magnetic alloy according to any one of claims 1 to 3, the method comprising:
step one, smelting
Under the vacuum condition, raw materials of nickel, molybdenum, chromium, copper, iron and carbon are mixed and smelted according to chemical composition proportion, silicon and manganese are added 10min to 1.5h before tapping, tapping can be carried out after complete melting, and steel ingots are cast; after the steel ingot is cooled to room temperature by air cooling, removing oxide skin on the surface of the steel ingot to obtain an oxide skin-removed steel ingot;
step two, forging and hot rolling
After heating and heat preservation, the descaled steel ingot is forged and pressed into a flat blank at the heat preservation temperature; cooling the flat blank to room temperature, and removing oxide skin on the surface of the flat blank to obtain a descaled flat blank; heating and insulating the descaling flat blank, and then hot-rolling the descaling flat blank into a hot-rolled strip; after the hot rolled strip is cooled to room temperature, removing oxide skin on the surface of the hot rolled strip to obtain a descaled hot rolled strip;
step three, cold rolling
Performing cold rolling processing on the hot rolled strip with the scale removed at room temperature; if intermediate continuous furnace annealing is needed, annealing the cold strip blank semi-finished product by adopting an intermediate continuous annealing furnace; cooling the annealed semi-finished cold strip blank to room temperature, and then continuously cold rolling to obtain a finished cold strip; the finished product of the cold zone is subjected to 1100-1200 ℃ H2And annealing in a furnace to obtain the iron-nickel soft magnetic alloy with high magnetic conductivity and high magnetic induction.
5. The method for preparing the Fe-Ni soft magnetic alloy with high magnetic permeability and high magnetic induction as claimed in claim 4, wherein in the step one, the smelting temperature is 1400-1600 ℃, and the tapping temperature is 1400-1600 ℃.
6. The method for preparing the iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction according to claim 4, wherein in the second step, the heat preservation temperature is 900-1150 ℃, the heat preservation time is 1-5h, the cooling speed in the forging and hot rolling processing process is not higher than 200 ℃/h, the cooling speed after the forging and hot rolling processing is cooled to room temperature is more than 500 ℃/h, and the thickness of the hot rolled strip is 4.0-6.0 mm.
7. The method for preparing the Fe-Ni soft magnetic alloy with high magnetic permeability and high magnetic induction as claimed in claim 4, wherein in the third step, the intermediate continuous furnace annealing is performed by using H at 900-1150 ℃2The atmosphere is carried out at a speed of 0.5-2.0 m/min.
8. The method for preparing the iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction according to claim 4, wherein in the third step, the cooling speed of the semi-finished product to room temperature is more than 500 ℃/h.
9. The method for preparing the iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction according to claim 4, wherein in the third step, the cold rolled finished product of the cold rolled cold strip has a rolling deformation of 80-95%.
10. The method for preparing the iron-nickel soft magnetic alloy with high magnetic permeability and high magnetic induction according to the claim 4, wherein in the third step, the thickness of the cold strip finished product is 0.05-1.00 mm.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113539653A (en) * 2021-09-16 2021-10-22 西安钢研功能材料股份有限公司 Preparation method of high-strength soft magnetic alloy bar
CN115074579A (en) * 2022-07-25 2022-09-20 西安钢研功能材料股份有限公司 Cryogenic low-temperature permalloy and preparation method of strip thereof
CN116162868A (en) * 2023-01-17 2023-05-26 北京北冶功能材料有限公司 Medium nickel soft magnetic alloy and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050161123A1 (en) * 2002-02-15 2005-07-28 Imphy Alloys Soft magnetic alloy for clock-making
CN101892440A (en) * 2009-05-22 2010-11-24 宝山钢铁股份有限公司 High-resistance, easy-cutting and corrosion-resistant soft magnetic alloy for electromagnetic valve
WO2014150323A1 (en) * 2013-03-15 2014-09-25 Kennametal Inc. Cladded articles and methods of making the same
CN104575912A (en) * 2014-12-31 2015-04-29 北京北冶功能材料有限公司 High-saturation magnetic intensity, low-consumption, stress-resistant and high-rigidity magnetically soft alloy
CN109524191A (en) * 2019-01-11 2019-03-26 北京北冶功能材料有限公司 A kind of high-performance iron nickel magnetically soft alloy
CN111101057A (en) * 2019-12-25 2020-05-05 北京北冶功能材料有限公司 Soft magnetic alloy strip for ultralow-temperature magnetic shielding and preparation method thereof
CN112746176A (en) * 2020-12-29 2021-05-04 常州中钢精密锻材有限公司 Method for controlling distribution of trace elements in ESR (equivalent series resistance) ingot

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050161123A1 (en) * 2002-02-15 2005-07-28 Imphy Alloys Soft magnetic alloy for clock-making
CN101892440A (en) * 2009-05-22 2010-11-24 宝山钢铁股份有限公司 High-resistance, easy-cutting and corrosion-resistant soft magnetic alloy for electromagnetic valve
WO2014150323A1 (en) * 2013-03-15 2014-09-25 Kennametal Inc. Cladded articles and methods of making the same
US20160193660A1 (en) * 2013-03-15 2016-07-07 Kennametal Inc. Cladded articles and methods of making the same
CN104575912A (en) * 2014-12-31 2015-04-29 北京北冶功能材料有限公司 High-saturation magnetic intensity, low-consumption, stress-resistant and high-rigidity magnetically soft alloy
CN109524191A (en) * 2019-01-11 2019-03-26 北京北冶功能材料有限公司 A kind of high-performance iron nickel magnetically soft alloy
CN111101057A (en) * 2019-12-25 2020-05-05 北京北冶功能材料有限公司 Soft magnetic alloy strip for ultralow-temperature magnetic shielding and preparation method thereof
CN112746176A (en) * 2020-12-29 2021-05-04 常州中钢精密锻材有限公司 Method for controlling distribution of trace elements in ESR (equivalent series resistance) ingot

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
强文江等: "《金属材料学》", 30 September 2016, 冶金工业出版 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113539653A (en) * 2021-09-16 2021-10-22 西安钢研功能材料股份有限公司 Preparation method of high-strength soft magnetic alloy bar
CN115074579A (en) * 2022-07-25 2022-09-20 西安钢研功能材料股份有限公司 Cryogenic low-temperature permalloy and preparation method of strip thereof
CN115074579B (en) * 2022-07-25 2023-11-14 西安钢研功能材料股份有限公司 Preparation method of cryogenic low Wen Pomo soft magnetic alloy and strip thereof
CN116162868A (en) * 2023-01-17 2023-05-26 北京北冶功能材料有限公司 Medium nickel soft magnetic alloy and preparation method thereof

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