CN113184995A - High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor - Google Patents

High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor Download PDF

Info

Publication number
CN113184995A
CN113184995A CN202110544067.1A CN202110544067A CN113184995A CN 113184995 A CN113184995 A CN 113184995A CN 202110544067 A CN202110544067 A CN 202110544067A CN 113184995 A CN113184995 A CN 113184995A
Authority
CN
China
Prior art keywords
autotrophic denitrification
reactor
synchronous nitrification
nitrification
nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202110544067.1A
Other languages
Chinese (zh)
Other versions
CN113184995B (en
Inventor
薛罡
徐磊
陈钰婷
陈红
王铮
曾琳
贾林春
张羽
王晓暖
何月玲
宋宾学
张承基
于鑫
孙苏阳
陆晓峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Donghua University
Original Assignee
Donghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Donghua University filed Critical Donghua University
Priority to CN202110544067.1A priority Critical patent/CN113184995B/en
Publication of CN113184995A publication Critical patent/CN113184995A/en
Application granted granted Critical
Publication of CN113184995B publication Critical patent/CN113184995B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses a synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on a multi-source electron donor and a reactor. The denitrification method comprises the following steps: adding sodium thiosulfate into the high-nitrogen wastewater, then sequentially entering a three-stage synchronous nitrification-autotrophic denitrification reactor, and suspending siderite (FeCO) in the reactor3) Pyrite (FeS)2) And iron shavings (Fe)0) The composite filler is subjected to synchronous nitrification-autotrophic denitrification under the aeration and oxygenation conditions, so that the total nitrogen in the wastewater is efficiently removed, and the treated water enters a sedimentation tank for sedimentation and then is discharged. Compared with the traditional nitrification and denitrification (AO) denitrification, the high-nitrogen wastewater synchronous nitrification-autotrophic denitrification method and the reactor based on the multi-source electron donor do not need additional organic carbon source,The return flow of the nitrifying liquid is not needed, and the operation cost is greatly reduced.

Description

High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor
Technical Field
The invention relates to a high-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on a multi-source electron donor and a reactor, belonging to the technical field of sewage and wastewater nitrogen removal.
Background
High-nitrogen wastewater is generated in industrial and agricultural production such as printing, breeding and the like in the processes of refuse landfill, fermentation and printing and dyeing. The treatment method of the high-nitrogen wastewater is generally nitrification and denitrification combined (AO). However, because the C/N of the wastewater is low, a large amount of carbon sources need to be added in the denitrification process. Meanwhile, in order to obtain higher total nitrogen removal rate, the denitrification efficiency is improved by adopting multi-stage AO and setting a high reflux ratio of the nitrifying liquid in the actual engineering, and the treatment cost is higher.
Carbon source for denitrification of high-nitrogen wastewaterThe problems of large demand and high treatment cost, and research on autotrophic denitrification technology using inorganic substances as electron donors has been carried out in recent years. The low-valent sulfur replaces an additional organic carbon source to form autotrophic denitrification and polyculture denitrification, and the enhanced denitrification and carbon source saving effects are obvious; for example: the magnetic pyrite with the nano structure is prepared by calcining natural pyrite, and is applied to the autotrophic denitrification biological filter for treating actual secondary biochemical effluent, so that the high removal rate of the total nitrogen can be obtained under the condition of low C/N ratio. The low-valent iron may also serve as an autotrophic or a mixotrophic denitrification electron donor, for example: fe-based inoculation of activated sludge2+The oxidation autotrophic denitrification reactor can obtain stable NO in a running period of 3 months3-N removal rate, successful Fe enrichment in the system2+Oxidizing bacteria and nitrate reducing bacteria. As sulfur autotrophic denitrification produces acid and iron autotrophic denitrification produces alkali, the sulfur and iron are coordinated with autotrophic denitrification or mixotrophic denitrification to balance and buffer the pH of a denitrification system and carry out nitrogen treatment on N2And the emission reduction of the greenhouse gas O is obviously contributed.
In order to solve the problems of high carbon source consumption and high reflux ratio of the high-nitrogen wastewater, the invention provides a high-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method and a high-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal reactor based on a principle of sulfur-iron synergistic autotrophic denitrification and synchronous nitrification denitrification, which are based on a multi-source electron donor.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the denitrification of the high-nitrogen wastewater has the problems of high carbon source consumption, high reflux ratio and the like.
In order to solve the technical problems, the invention provides a synchronous nitrification-autotrophic denitrification method for high-nitrogen wastewater based on a multi-source electron donor, which comprises the following steps:
step 1): adding sodium thiosulfate into high-nitrogen wastewater with TN not less than 1000mg/L, introducing into a primary synchronous nitrification-autotrophic denitrification reactor, and suspending siderite FeCO in the reactor3FeS, pyrite2And iron shavings Fe0The composite filler forms a multi-source electron donor which performs synchronous nitrification-autotrophic denitrification under the aeration and oxygenation conditionsSo that the total nitrogen in the wastewater can be partially removed;
step 2): the wastewater treated by the step 1) enters a secondary synchronous nitrification-autotrophic denitrification reactor, and siderite FeCO is also hung in the reactor3FeS, pyrite2And iron shavings Fe0The filling amount of the formed composite filler is lower than that of the composite filler in the primary synchronous nitrification-autotrophic denitrification reactor, and synchronous nitrification-autotrophic denitrification is performed under the condition of aeration and oxygenation, so that the total nitrogen in the wastewater is further reduced;
step 3): the wastewater treated in the step 2) enters a three-stage synchronous nitrification-autotrophic denitrification reactor, and siderite (FeCO) is hung in the reactor3) And iron shavings (Fe)0) The composite filler is subjected to synchronous nitrification-autotrophic denitrification in a three-stage reactor under the condition of aeration and oxygenation, so that the total nitrogen in the wastewater is reduced to a lower level;
step 4): and (3) performing solid-liquid separation on the wastewater subjected to the denitrification treatment in the step 3), returning partial residual sludge to the primary synchronous nitrification-autotrophic denitrification reactor, wherein the reflux ratio is 50-100%, mixing the residual sludge with the inlet water of the primary synchronous nitrification-autotrophic denitrification reactor, and then feeding the mixture into the primary synchronous nitrification-autotrophic denitrification reactor to supplement the sludge lost in the reactor, and discharging partial residual sludge for further treatment.
Preferably, the dosage of the sodium thiosulfate in the step 1) is controlled to be 0.6 to 0.8 in S/N molar ratio; the reaction residence time is controlled to be 20-24 h, and the gas-water ratio in the aeration oxygenation condition is controlled to be 8-10: 1. .
Preferably, the composite filler in the step 1) comprises the following components in parts by weight: pyrite: iron shavings-1: 2: 3, the composite filler is wrapped by a polyethylene mesh bag and then hung in the reactor, the weight of the wrapped single-package filler is 10-12 kg, and the filling amount of the composite filler in the primary synchronous nitrification-autotrophic denitrification reactor is 30-40 kg/m3
Preferably, the reaction residence time of the step 2) is controlled to be 16-20 h; and the air-water ratio in the aeration oxygenation condition is controlled to be 6-8: 1.
preferably, the weight proportion, the weight of the single-package filler, the packaging and the installation mode of the composite filler in the step 2) are the same as those of the primary synchronous nitrification-autotrophic denitrification reactor, but the filling amount of the composite filler is 2/3 of the primary synchronous nitrification-autotrophic denitrification reactor.
Preferably, the reaction residence time of the step 3) is controlled to be 12-14 h; and the air-water ratio in the aeration oxygenation condition is controlled to be 4-6: 1.
preferably, the composite filler in the step 3) comprises the following components in parts by weight: iron shavings-1: 2, the composite filler material is wrapped by polyethylene mesh bags and then made into string packages to be hung in the reactor, the weight of the wrapped single-package filler is 10-12 kg, and the filling amount of the composite filler in the three-stage synchronous nitrification-autotrophic denitrification reactor is 40-50 kg/m3
Preferably, the sludge reflux ratio in the step 4) is controlled to be 50-100%.
The invention also provides a high-nitrogen wastewater synchronous nitrification-autotrophic denitrification reactor based on the multi-source electron donor, which is applied to the denitrification method of the high-nitrogen wastewater synchronous nitrification-autotrophic denitrification based on the multi-source electron donor, and comprises the following steps:
the device comprises a primary synchronous nitrification-autotrophic denitrification reactor (5) provided with a composite filler I (4), wherein a water inlet pipe (1) connected with a sulfur source electron donor feeding pipe (2) is arranged on the water inlet side of the primary synchronous nitrification-autotrophic denitrification reactor (5), a first water outlet pipe (8) is arranged on the water outlet side, and a first aeration pipe (7) is arranged at the bottom of the primary synchronous nitrification-autotrophic denitrification reactor;
a second-stage synchronous nitrification-autotrophic denitrification reactor (11) provided with a second composite filler (10), wherein the water inlet side of the second-stage synchronous nitrification-autotrophic denitrification reactor (11) is connected with a first water outlet pipe (8), the water outlet side is provided with a second water outlet pipe (14), and the bottom of the second-stage synchronous nitrification-autotrophic denitrification reactor is provided with a second aeration pipe (13);
a three-stage synchronous nitrification-autotrophic denitrification reactor (17) provided with a composite filler III (16), wherein the water inlet side of the three-stage synchronous nitrification-autotrophic denitrification reactor (17) is connected with a second water outlet pipe (14), the water outlet side is provided with a third water outlet pipe (20), and the bottom of the three-stage synchronous nitrification-autotrophic denitrification reactor is provided with a third aeration pipe (19);
the bottom of the sedimentation tank is provided with a sludge discharge pipe (23) and a sedimentation tank (21) of a sludge return pipe (24), the water inlet side of the sedimentation tank (21) is connected with a third water outlet pipe (20), and the water outlet side is provided with a fourth water outlet pipe (22).
Preferably, the water inlet side of the first, second and third-stage synchronous nitrification-autotrophic denitrification reactors is respectively provided with a first water distribution channel 3, a second water distribution channel 9 and a third water distribution channel 15, and the water outlet side is respectively provided with a first water collecting channel 6, a second water collecting channel 12 and a third water collecting channel 18.
The principle of the invention is as follows: aiming at the problems that a large amount of carbon sources are required to be added for denitrification and denitrification, the operation cost is high and the denitrification efficiency is low due to low C/N of high-nitrogen wastewater, synchronous nitrification-autotrophic denitrification is realized in a three-stage aerobic process by adopting a sulfur-iron multi-source electron donor, and the problems that a large amount of carbon sources are added for conventional nitrification and denitrification and the reflux ratio of nitrifying liquid is high can be solved.
The application range of the invention is as follows: high-nitrogen wastewater (TN, NH) generated in industrial and agricultural production such as printing and breeding in the processes of refuse landfill, fermentation and printing and dyeing4 +-N is more than or equal to 1000 mg/L). By the synchronous nitrification-autotrophic denitrification nitrogen removal method and the reactor for the high-nitrogen wastewater based on the multi-source electron donor, the TN of the effluent can be stably lower than 100 mg/L.
Compared with the prior art, the invention has the beneficial effects that:
1. compared with the traditional nitrification and denitrification (AO) denitrification, the high-nitrogen wastewater synchronous nitrification-autotrophic denitrification method and the reactor based on the multi-source electron donor do not need additional organic carbon source and nitrification liquid reflux, have high denitrification efficiency and low operation cost;
2. by the multi-source electron donor synchronous nitrification-autotrophic denitrification nitrogen removal method and the reactor for the high-nitrogen wastewater based on the multi-source electron donor, the TN of the high-nitrogen wastewater effluent can be stably lower than 100 mg/L.
Drawings
FIG. 1 is a schematic diagram of a synchronous nitrification-autotrophic denitrification reactor for high-nitrogen wastewater based on multi-source electron donors, provided by the invention;
reference numerals: 1. a water inlet pipe; 2. a sulfur source electron donor feeding pipe; 3. a first water distribution channel; 4. a first composite filler; 5. a primary synchronous nitrification-autotrophic denitrification reactor; 6. a first catchment channel; 7. a first aeration pipe; 8. a first water outlet pipe; 9. a second water distribution channel; 10. a second composite filler; 11. a secondary synchronous nitrification-autotrophic denitrification reactor; 12. a second catchment channel; 13. a second aeration pipe; 14. a second water outlet pipe; 15. a third water distribution channel; 16. a third composite filler; 17. a three-stage synchronous nitrification-autotrophic denitrification reactor; 18. a third water collection channel; 19. a third aeration pipe; 20. a third water outlet pipe; 21. a sedimentation tank; 22. a fourth water outlet pipe; 23. a sludge discharge pipe; 24. a sludge return pipe.
Detailed Description
In order to make the invention more comprehensible, preferred embodiments are described in detail below with reference to the accompanying drawings.
Example 1
The embodiment provides a synchronous nitrification-autotrophic denitrification nitrogen removal method and a reactor for high-nitrogen wastewater based on a multi-source electron donor, wherein raw wastewater water in the embodiment is from aged leachate of a certain refuse landfill, and the water quality indexes are as follows: COD 4000-5000 mg/L, TN 3000-4000 mg/L, NH4 +-N is 2800-4000 mg/L, and nitrogen is mainly NH4 +-N is present. In order to solve the problem of denitrification of high-nitrogen and low-C/N old landfill leachate, a synchronous nitrification-autotrophic denitrification method for high-nitrogen wastewater based on a multi-source electron donor is adopted, and the method comprises the following steps:
step 1): adding sodium thiosulfate into the aged percolate, introducing the aged percolate into a primary synchronous nitrification-autotrophic denitrification reactor, and suspending siderite (FeCO) in the reactor3) Pyrite (FeS)2) And iron shavings (Fe)0) The composite filler is subjected to synchronous nitrification-autotrophic denitrification under the aeration and oxygenation conditions, so that the total nitrogen in the wastewater is partially removed.
Step 2): the aged percolate treated by the step 1) enters a secondary synchronous nitrification-autotrophic denitrification reactor, and siderite (FeCO) is hung in the reactor3) Pyrite (FeS)2) And iron shavings (Fe)0) The filling amount of the composite filler is lower than that of a first-stage reactor,the synchronous nitrification-autotrophic denitrification effect is generated in the secondary reactor under the condition of aeration and oxygenation, so that the total nitrogen in the wastewater is further reduced.
Step 3): the aged percolate treated by the step 2) enters a three-stage synchronous nitrification-denitrification reactor, and siderite (FeCO) is hung in the reactor3) And iron shavings (Fe)0) The composite filler is subjected to synchronous nitrification-autotrophic denitrification in a three-stage reactor under the condition of aeration and oxygenation, so that the total nitrogen in the wastewater is reduced to a lower level.
Step 4): and (3) performing solid-liquid separation on the aged leachate after denitrification treatment in the step 3) in a sedimentation tank, refluxing partial residual sludge to a primary reactor, mixing the residual sludge with the primary reactor inlet water, and then feeding the mixture into a primary reaction tank to supplement the sludge lost in the reaction tank, wherein partial residual sludge is discharged and then further treated.
Wherein the dosage of the sodium thiosulfate in the step 1) is controlled to be 0.6-0.8 of S/N molar ratio. The reaction residence time is controlled to be 20-24 h; the composite filler comprises siderite (FeCO)3): pyrite (FeS)2): iron shavings (Fe)0) 1: 2: 3, the weight of the single-package filler is 10-12 kg, and the single-package filler is wrapped by a polyethylene mesh bag. The packing bags are made into serial packs and hung in the reaction tank, and the packing amount of the packing is 30-40 kg/m3(ii) a The gas-water ratio in aeration oxygenation is 8-10: 1.
wherein the reaction residence time of the step 2) is controlled to be 16-20 h; the weight proportion of the composite filler, the weight of the single-package filler, the packaging and installation modes are the same as those of the first-stage reactor, but the filling amount of the filler is 2/3 of the first-stage reactor; the gas-water ratio in aeration oxygenation is 6-8: 1.
wherein, the reaction residence time in the step 3) is controlled to be 12-14 h; the composite filler comprises siderite (FeCO)3): iron shavings (Fe)0) 1: 2, the weight of the single-package filler is 10-12 kg, the single-package filler is wrapped by a polyethylene mesh bag, the filler bags are made into serial packages and hung in the reaction tank, and the filling amount of the filler is 40-50 kg/m3(ii) a The gas-water ratio in aeration oxygenation is 4-6: 1.
wherein the sludge reflux ratio in the step 4) is controlled to be 50-100%.
The denitrification method adopts a high-nitrogen wastewater synchronous nitrification-autotrophic denitrification reactor based on a multi-source electron donor as shown in figure 1, and comprises the following steps:
the primary synchronous nitrification-autotrophic denitrification reactor 5 is provided with a composite filler I4, the water inlet side of the primary synchronous nitrification-autotrophic denitrification reactor 5 is provided with a water inlet pipe 1 connected with a sulfur source electron donor adding pipe 2, the water outlet side is provided with a first water outlet pipe 8, and the bottom is provided with a first aeration pipe 7;
the two-stage synchronous nitrification-autotrophic denitrification reactor 11 is provided with a composite filler II 10, the water inlet side of the two-stage synchronous nitrification-autotrophic denitrification reactor 11 is connected with the first water outlet pipe 8, the water outlet side is provided with a second water outlet pipe 14, and the bottom of the two-stage synchronous nitrification-autotrophic denitrification reactor is provided with a second aeration pipe 13;
a third-stage synchronous nitrification-autotrophic denitrification reactor 17 provided with a composite filler III 16, wherein the water inlet side of the third-stage synchronous nitrification-autotrophic denitrification reactor 17 is connected with a second water outlet pipe 14, the water outlet side is provided with a third water outlet pipe 20, and the bottom of the third-stage synchronous nitrification-autotrophic denitrification reactor is provided with a third aeration pipe 19;
the bottom of the sedimentation tank 21 is provided with a sludge discharge pipe 23 and a sludge return pipe 24, the water inlet side of the sedimentation tank 21 is connected with a third water outlet pipe 20, and the water outlet side is provided with a fourth water outlet pipe 22;
the water inlet side of the first, second and third-stage synchronous nitrification-autotrophic denitrification reactor is respectively provided with a first water distribution channel 3, a second water distribution channel 9 and a third water distribution channel 15, and the water outlet side is respectively provided with a first water collecting channel 6, a second water collecting channel 12 and a third water collecting channel 18.
TN of the aged percolate treated by the denitrification method and the denitrification reactor is lower than 100 mg/L.
The above-described embodiments are only preferred embodiments of the present invention, and are not intended to limit the present invention in any way and substantially, it should be noted that those skilled in the art may make several modifications and additions without departing from the scope of the present invention, which should also be construed as a protection scope of the present invention.

Claims (10)

1. A high-nitrogen wastewater synchronous nitrification-autotrophic denitrification denitrogenation method based on a multi-source electron donor is characterized by comprising the following steps:
step 1): adding sodium thiosulfate into high-nitrogen wastewater with TN not less than 1000mg/L, introducing into a primary synchronous nitrification-autotrophic denitrification reactor, and suspending siderite FeCO in the reactor3FeS, pyrite2And iron shavings Fe0The composite filler forms a multi-source electron donor, and the synchronous nitrification-autotrophic denitrification effect is generated under the aeration and oxygenation conditions, so that the total nitrogen in the wastewater is partially removed;
step 2): the wastewater treated by the step 1) enters a secondary synchronous nitrification-autotrophic denitrification reactor, and siderite FeCO is also hung in the reactor3FeS, pyrite2And iron shavings Fe0The filling amount of the formed composite filler is lower than that of the composite filler in the primary synchronous nitrification-autotrophic denitrification reactor, and synchronous nitrification-autotrophic denitrification is performed under the condition of aeration and oxygenation, so that the total nitrogen in the wastewater is further reduced;
step 3): the wastewater treated in the step 2) enters a three-stage synchronous nitrification-autotrophic denitrification reactor, and siderite FeCO is hung in the reactor3And iron shavings Fe0The composite filler is subjected to synchronous nitrification-autotrophic denitrification in a three-stage reactor under the condition of aeration and oxygenation, so that the total nitrogen in the wastewater is reduced to a lower level;
step 4): and 3) performing solid-liquid separation on the wastewater subjected to the denitrification treatment in the step 3) in a sedimentation tank, refluxing partial residual sludge to the primary synchronous nitrification-autotrophic denitrification reactor, mixing the residual sludge with the inlet water of the primary synchronous nitrification-autotrophic denitrification reactor, and then feeding the mixed residual sludge into the primary synchronous nitrification-autotrophic denitrification reactor to supplement the sludge lost in the reactor, wherein partial residual sludge is discharged and then is further treated.
2. The synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the dosage of sodium thiosulfate in the step 1) is controlled to be 0.6-0.8 of S/N molar ratio; the reaction residence time is controlled to be 20-24 h; and the air-water ratio in the aeration oxygenation condition is controlled to be 8-10: 1.
3. the synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the composite filler in the step 1) comprises the following components in parts by weight: pyrite: iron shavings-1: 2: 3, the composite filler is wrapped by a polyethylene mesh bag and then hung in the reactor, the weight of the wrapped single-package filler is 10-12 kg, and the filling amount of the composite filler in the primary synchronous nitrification-autotrophic denitrification reactor is 30-40 kg/m3
4. The synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the reaction residence time of the step 2) is controlled within 16-20 h; and the air-water ratio in the aeration oxygenation condition is controlled to be 6-8: 1.
5. the method for simultaneous nitrification-autotrophic denitrification of nitrogen removal from high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the composite filler of step 2) has the same composition weight ratio, weight of single-package filler, packaging and installation manner as the primary simultaneous nitrification-autotrophic denitrification reactor, but the filling amount of the composite filler is 2/3 of the primary simultaneous nitrification-autotrophic denitrification reactor.
6. The synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the reaction residence time of the step 3) is controlled within 12-14 h; and the air-water ratio in the aeration oxygenation condition is controlled to be 4-6: 1.
7. the synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the composite filler of the step 3) comprises the following components in parts by weight: iron shavings-1: 2, Polymer for composite Filler MaterialThe ethylene mesh bags are wrapped and made into string packages to be hung in the reactor, the weight of the wrapped single-package filler is 10-12 kg, and the filling amount of the composite filler in the three-stage synchronous nitrification-autotrophic denitrification reactor is 40-50 kg/m3
8. The synchronous nitrification-autotrophic denitrification nitrogen removal method for high-nitrogen wastewater based on multi-source electron donors according to claim 1, wherein the sludge reflux ratio in the step 4) is controlled to be 50% -100%.
9. A synchronous nitrification-autotrophic denitrification reactor for high-nitrogen wastewater based on multi-source electron donors is applied to the denitrification method for synchronous nitrification-autotrophic denitrification of high-nitrogen wastewater based on multi-source electron donors in any one of claims 1-8, and comprises the following steps:
the device comprises a primary synchronous nitrification-autotrophic denitrification reactor (5) provided with a composite filler I (4), wherein a water inlet pipe (1) connected with a sulfur source electron donor feeding pipe (2) is arranged on the water inlet side of the primary synchronous nitrification-autotrophic denitrification reactor (5), a first water outlet pipe (8) is arranged on the water outlet side, and a first aeration pipe (7) is arranged at the bottom of the primary synchronous nitrification-autotrophic denitrification reactor;
a second-stage synchronous nitrification-autotrophic denitrification reactor (11) provided with a second composite filler (10), wherein the water inlet side of the second-stage synchronous nitrification-autotrophic denitrification reactor (11) is connected with a first water outlet pipe (8), the water outlet side is provided with a second water outlet pipe (14), and the bottom of the second-stage synchronous nitrification-autotrophic denitrification reactor is provided with a second aeration pipe (13);
a three-stage synchronous nitrification-autotrophic denitrification reactor (17) provided with a composite filler III (16), wherein the water inlet side of the three-stage synchronous nitrification-autotrophic denitrification reactor (17) is connected with a second water outlet pipe (14), the water outlet side is provided with a third water outlet pipe (20), and the bottom of the three-stage synchronous nitrification-autotrophic denitrification reactor is provided with a third aeration pipe (19);
the bottom of the sedimentation tank is provided with a sludge discharge pipe (23) and a sedimentation tank (21) of a sludge return pipe (24), the water inlet side of the sedimentation tank (21) is connected with a third water outlet pipe (20), and the water outlet side is provided with a fourth water outlet pipe (22).
10. The multi-source electron donor-based synchronous nitrification-autotrophic denitrification and denitrification reactor for high-nitrogen wastewater according to claim 9, wherein the first, second and third stages of synchronous nitrification-autotrophic denitrification reactors are respectively provided with a first water distribution channel 3, a second water distribution channel 9 and a third water distribution channel 15 on water inlet sides thereof, and respectively provided with a first water collection channel 6, a second water collection channel 12 and a third water collection channel 18 on water outlet sides thereof.
CN202110544067.1A 2021-05-19 2021-05-19 High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor Active CN113184995B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110544067.1A CN113184995B (en) 2021-05-19 2021-05-19 High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110544067.1A CN113184995B (en) 2021-05-19 2021-05-19 High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor

Publications (2)

Publication Number Publication Date
CN113184995A true CN113184995A (en) 2021-07-30
CN113184995B CN113184995B (en) 2022-11-04

Family

ID=76982347

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110544067.1A Active CN113184995B (en) 2021-05-19 2021-05-19 High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor

Country Status (1)

Country Link
CN (1) CN113184995B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114409082A (en) * 2022-02-08 2022-04-29 东华大学 High-ammonia-nitrogen and low-carbon-nitrogen-ratio sewage wastewater OAO coupling zero-valent iron nitrogen and phosphorus removal method
WO2024022192A1 (en) * 2022-07-26 2024-02-01 苏州科技大学 Method and system for treating aged landfill leachate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101973629A (en) * 2010-10-29 2011-02-16 南京大学 Nitrogen and phosphorus removal method by using pyrite as biochemical filling
CN108046540A (en) * 2018-01-22 2018-05-18 云南合续环境科技有限公司 A kind of synchronous nitration and denitrification sewage water treatment method and its device
WO2018107740A1 (en) * 2016-12-14 2018-06-21 江南大学 Wastewater nitrogen and phosphorus removal device and application thereof
CN112047565A (en) * 2020-08-11 2020-12-08 青岛清泽环保有限公司 PHBV-pyrite substance mixotrophic denitrification biofilm reactor and application thereof
CN212713159U (en) * 2020-07-03 2021-03-16 南京华创环境技术研究院有限公司 Reactor capable of realizing efficient nitrogen and phosphorus removal treatment of sewage with low carbon-nitrogen ratio

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101973629A (en) * 2010-10-29 2011-02-16 南京大学 Nitrogen and phosphorus removal method by using pyrite as biochemical filling
WO2018107740A1 (en) * 2016-12-14 2018-06-21 江南大学 Wastewater nitrogen and phosphorus removal device and application thereof
CN108046540A (en) * 2018-01-22 2018-05-18 云南合续环境科技有限公司 A kind of synchronous nitration and denitrification sewage water treatment method and its device
CN212713159U (en) * 2020-07-03 2021-03-16 南京华创环境技术研究院有限公司 Reactor capable of realizing efficient nitrogen and phosphorus removal treatment of sewage with low carbon-nitrogen ratio
CN112047565A (en) * 2020-08-11 2020-12-08 青岛清泽环保有限公司 PHBV-pyrite substance mixotrophic denitrification biofilm reactor and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114409082A (en) * 2022-02-08 2022-04-29 东华大学 High-ammonia-nitrogen and low-carbon-nitrogen-ratio sewage wastewater OAO coupling zero-valent iron nitrogen and phosphorus removal method
CN114409082B (en) * 2022-02-08 2024-03-01 东华大学 OAO coupling zero-valent iron denitrification and dephosphorization method for high ammonia nitrogen and low carbon nitrogen ratio sewage and wastewater
WO2024022192A1 (en) * 2022-07-26 2024-02-01 苏州科技大学 Method and system for treating aged landfill leachate

Also Published As

Publication number Publication date
CN113184995B (en) 2022-11-04

Similar Documents

Publication Publication Date Title
CN104961306B (en) A kind of processing method of vaccary breeding wastewater
CN112456646B (en) Device and method for coupling A0A-SBR of anaerobic ammonia oxidation through heterotrophic denitrification and autotrophic denitrification enhanced partial denitrification
US10160680B2 (en) Process for biological removal of nitrogen from wastewater
US20230331609A1 (en) System and method for realizing partial anammox advanced nitrogen and phosphorus removal through mainstream and sidestream biofilm cyclic alternating for municipal wastewater treatment plant
CN113184995B (en) High-nitrogen wastewater synchronous nitrification-autotrophic denitrification nitrogen removal method based on multi-source electron donor and reactor
CN112978925A (en) Sulfur-iron synergistic polyculture denitrification enhanced low C/N sewage denitrification method and reactor
CN216890310U (en) Sludge fermentation reinforced low C/N sewage nitrogen and phosphorus removal and resource recovery device
CN114409082B (en) OAO coupling zero-valent iron denitrification and dephosphorization method for high ammonia nitrogen and low carbon nitrogen ratio sewage and wastewater
CN105776751A (en) Process for efficient separation of organic carbon source in sewage and energy development and utilization
CN113912184A (en) Method for improving sewage treatment effect of low CN ratio
CN107055963B (en) Efficient and low-consumption advanced treatment device and treatment method for landfill leachate
CN110627320B (en) Wastewater treatment combined device and process based on physical-chemical-biological method
KR100274534B1 (en) Nitrogen and phosphorus removal methods with using fermented organic wastes
CN116715345A (en) Autotrophic denitrification bioreactor based on pyrite coupling filler and application
CN116143352A (en) Full-quantification combined treatment system and method for landfill leachate
CN215102271U (en) Secondary biochemical effluent ferro-sulphur synergistic polyculture denitrification deep denitrification reactor
CN114149080A (en) Device and method for enhancing deep nitrogen and phosphorus removal and resource recovery of low C/N sewage by anaerobic fermentation of sludge
CN110790378B (en) Method for treating high-solid-content organic wastewater by anaerobic-aerobic deep coupling
JP2003024982A (en) Biological denitrification method and biological denitrification apparatus
CN108793614B (en) Continuous sewage treatment method and device
KR100300820B1 (en) Advanced Treatment Method for Sewage or Industrial Waste Water
KR100360561B1 (en) A treatment methods for organic sewage
CN102515440B (en) Device and method for conducting depth denitrification treatment on landfill leachate
CN111217495A (en) Advanced treatment device and treatment method for organic wastewater
CN205346941U (en) Device of sewage and bed mud among combination treatment black and odorous watercourse

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant