CN113046188A - Alkaline metal cleaning solution - Google Patents

Alkaline metal cleaning solution Download PDF

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Publication number
CN113046188A
CN113046188A CN202110315161.XA CN202110315161A CN113046188A CN 113046188 A CN113046188 A CN 113046188A CN 202110315161 A CN202110315161 A CN 202110315161A CN 113046188 A CN113046188 A CN 113046188A
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Prior art keywords
cleaning solution
sodium
alkaline metal
metal cleaning
imidazolidinone
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Pending
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CN202110315161.XA
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Chinese (zh)
Inventor
刘宁
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Individual
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Individual
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Priority to CN202110315161.XA priority Critical patent/CN113046188A/en
Publication of CN113046188A publication Critical patent/CN113046188A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/37Mixtures of compounds all of which are anionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/16Metals

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to the technical field of cleaning fluid, in particular to an alkaline metal cleaning fluid which comprises the following substances in percentage by weight: 1-5% of sodium fatty alcohol polyoxyethylene ether sulfate, 3-8% of sodium dodecyl sulfate, 2-8% of fatty acid methyl ester ethoxylate sodium sulfonate FMES, 1-5% of dimethyl-2-imidazolidinone, 1-6% of penetrant JFC and 2-8% of strong alkali-resistant penetrant, wherein the alkali metal cleaning liquid is enhanced in strong alkali resistance and super-degreasing and washing dispersion capacity through added sodium dodecyl sulfate, the fatty acid methyl ester ethoxylate sodium sulfonate FMES is used for washing dispersion and oil removal, wax removal and deinking functions, the dimethyl-2-imidazolidinone can dissolve dirt strongly and rapidly, the components are added reasonably, the preparation cost is low, and the practicability is high.

Description

Alkaline metal cleaning solution
Technical Field
The invention relates to the technical field of cleaning liquid, in particular to alkaline metal cleaning liquid.
Background
The alkaline cleaning agent is a cleaning agent with the pH value larger than 7, and is mainly compounded by a surfactant and other raw materials; the cleaning agent is widely applied due to the characteristics of environmental protection, no toxicity, safety, low economic cost and good cleaning effect.
Most of the existing electroplating plants and spraying plants adopt acid cleaning solution, and the cleaning solution causes great harm to human bodies and the environment, so the practicability is not strong.
Disclosure of Invention
The invention aims to solve the defects that an acidic cleaning solution in the prior art causes great harm to human bodies and the environment and the like, and provides an alkaline metal cleaning solution.
In order to achieve the purpose, the invention adopts the following technical scheme:
designing an alkaline metal cleaning solution, which consists of the following substances in percentage by weight, calculated by per liter: 1-5% of sodium alcohol ether sulphate, 3-8% of sodium dodecyl sulfate, 2-8% of sodium fatty acid methyl ester ethoxylate sulfonate FMES, 1-5% of dimethyl-2-imidazolidinone, 1-6% of penetrant JFC I, 2-8% of strong alkali resistant penetrant, 0.6-1.2% of diethylene glycol monobutyl ether, 1-6% of crawling agent TTM, 5-12% of glass deinking agent, 1-7% of potassium pyrophosphate, 3-10% of sodium gluconate, 2-8% of sodium metasilicate pentahydrate, 4NA 2-8% of HEDP I, 1-6% of EDTA I, 0.5-1% of citric acid, 3-10% of sodium hydroxide, 0.5-1.2% of potassium hydroxide, 0.5-1.2% of kathon and the balance of deionized water.
Preferably, the essence also comprises 3 to 8 percent of the rhizoma kaempferiae essence.
A preparation method of an alkaline metal cleaning solution comprises the following steps:
s1, processing raw materials, namely adding the raw materials into a reaction kettle according to the weight ratio, and stirring and mixing;
s2, filtering and detecting, measuring the pH value and the conductivity of the solution in the S1, and filtering after the solution is qualified to obtain a finished cleaning solution;
and S3, packaging the finished product, and canning, packaging and warehousing the finished product cleaning solution of S2.
Preferably, the stirring time is 8-10h, and the temperature during stirring is 40 ℃.
The alkaline metal cleaning solution provided by the invention has the beneficial effects that: according to the invention, the strong alkali resistance, the super grease removal and cleaning dispersion capability are enhanced by adding the sodium dodecyl sulfate, the sodium fatty acid methyl ester ethoxylate sulfonate FMES is used for cleaning dispersion and oil removal, wax removal and deinking functions, the dimethyl-2-imidazolidinone can strongly and rapidly dissolve dirt, the components are reasonably added, the preparation cost is low, and the practicability is strong.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Example one
An alkaline metal cleaning solution comprises the following substances in percentage by weight, calculated by per liter: 1% of sodium fatty alcohol polyoxyethylene ether sulfate, 3% of sodium dodecyl sulfate, 2% of sodium fatty acid methyl ester ethoxylate sulfonate FMES, 1% of dimethyl-2-imidazolidinone, 1% of penetrating agent JFC, 2% of strong alkali resistant penetrating agent, 0.6% of diethylene glycol butyl ether, 1% of crawling agent TTM, 5% of glass deinking agent, 1% of potassium pyrophosphate, 3% of sodium gluconate, 2% of sodium metasilicate pentahydrate, 4% of HEDP 2%, 4% of EDTA (ethylene diamine tetraacetic acid), 0.5% of citric acid, 3% of sodium hydroxide, 0.5% of potassium hydroxide, 0.5% of kathon and the balance of deionized water.
The essence also comprises 3 percent of the rhizoma kaempferiae essence.
A preparation method of an alkaline metal cleaning solution comprises the following steps:
s1, processing raw materials, namely adding the raw materials into a reaction kettle according to the weight ratio, and stirring and mixing;
s2, filtering and detecting, measuring the pH value and the conductivity of the solution in the S1, and filtering after the solution is qualified to obtain a finished cleaning solution;
and S3, packaging the finished product, and canning, packaging and warehousing the finished product cleaning solution of S2.
The stirring time is 8h, and the temperature during stirring is 40 ℃.
Example two
An alkaline metal cleaning solution comprises the following substances in percentage by weight, calculated by per liter: 3% of sodium fatty alcohol polyoxyethylene ether sulfate, 5.5% of sodium dodecyl sulfate, 5% of sodium fatty acid methyl ester ethoxylate sulfonate FMES, 3% of dimethyl-2-imidazolidinone, 3.5% of penetrating agent JFC-G, 5% of strong alkali resistant penetrating agent, 0.9% of diethylene glycol monobutyl ether, 3.5% of crawling agent TTM, 8.5% of glass deinking agent, 4% of potassium pyrophosphate, 6.5% of sodium gluconate, 5% of sodium metasilicate pentahydrate, 5% of HEDP-4 NA, 3.5% of EDTA-4 NA, 0.75% of citric acid, 6.5% of sodium hydroxide, 0.85% of potassium hydroxide, 0.85% of kathon and the balance of deionized water.
The essence also comprises 5.5 percent of rhizoma kaempferiae essence.
A preparation method of an alkaline metal cleaning solution comprises the following steps:
s1, processing raw materials, namely adding the raw materials into a reaction kettle according to the weight ratio, and stirring and mixing;
s2, filtering and detecting, measuring the pH value and the conductivity of the solution in the S1, and filtering after the solution is qualified to obtain a finished cleaning solution;
and S3, packaging the finished product, and canning, packaging and warehousing the finished product cleaning solution of S2.
The stirring time is 9h, and the temperature during stirring is 40 ℃.
EXAMPLE III
An alkaline metal cleaning solution comprises the following substances in percentage by weight, calculated by per liter: 5% of sodium fatty alcohol polyoxyethylene ether sulfate, 8% of sodium dodecyl sulfate, 8% of sodium fatty acid methyl ester ethoxylate sulfonate FMES, 5% of dimethyl-2-imidazolidinone, 6% of penetrating agent JFC, 8% of strong alkali resistant penetrating agent, 1.2% of diethylene glycol butyl ether, 6% of creeping agent TTM, 12% of glass deinking agent, 7% of potassium pyrophosphate, 10% of sodium gluconate, 8% of sodium metasilicate pentahydrate, 8% of HEDP-4 NA, 6% of EDTA-4 NA, 1% of citric acid, 10% of sodium hydroxide, 1.2% of potassium hydroxide, 1.2% of kathon and the balance of deionized water.
The essence also comprises 8 percent of the rhizoma kaempferiae essence.
A preparation method of an alkaline metal cleaning solution comprises the following steps:
s1, processing raw materials, namely adding the raw materials into a reaction kettle according to the weight ratio, and stirring and mixing;
s2, filtering and detecting, measuring the pH value and the conductivity of the solution in the S1, and filtering after the solution is qualified to obtain a finished cleaning solution;
and S3, packaging the finished product, and canning, packaging and warehousing the finished product cleaning solution of S2.
The stirring time is 10h, and the temperature during stirring is 40 ℃.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (4)

1. The alkaline metal cleaning solution is characterized by comprising the following substances in percentage by weight, calculated by per liter: 1-5% of sodium alcohol ether sulphate, 3-8% of sodium dodecyl sulfate, 2-8% of sodium fatty acid methyl ester ethoxylate sulfonate FMES, 1-5% of dimethyl-2-imidazolidinone, 1-6% of penetrant JFC I, 2-8% of strong alkali resistant penetrant, 0.6-1.2% of diethylene glycol monobutyl ether, 1-6% of crawling agent TTM, 5-12% of glass deinking agent, 1-7% of potassium pyrophosphate, 3-10% of sodium gluconate, 2-8% of sodium metasilicate pentahydrate, 4NA 2-8% of HEDP I, 1-6% of EDTA I, 0.5-1% of citric acid, 3-10% of sodium hydroxide, 0.5-1.2% of potassium hydroxide, 0.5-1.2% of kathon and the balance of deionized water.
2. The alkaline metal cleaning solution as claimed in claim 1, further comprising a flavor of kaempferiae, wherein the percentage of the flavor of kaempferiae is 3% -8%.
3. The method for preparing an alkaline metal cleaning solution according to claim 2, comprising the steps of:
s1, processing raw materials, namely adding the raw materials into a reaction kettle according to the weight ratio, and stirring and mixing;
s2, filtering and detecting, measuring the pH value and the conductivity of the solution in the S1, and filtering after the solution is qualified to obtain a finished cleaning solution;
and S3, packaging the finished product, and canning, packaging and warehousing the finished product cleaning solution of S2.
4. The method for preparing an alkaline metal cleaning solution according to claim 3, characterized in that: the stirring time is 8-10h, and the temperature during stirring is 40 ℃.
CN202110315161.XA 2021-03-24 2021-03-24 Alkaline metal cleaning solution Pending CN113046188A (en)

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CN202110315161.XA CN113046188A (en) 2021-03-24 2021-03-24 Alkaline metal cleaning solution

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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101538512A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Water-based cleaner
CN103668239A (en) * 2013-11-19 2014-03-26 青岛汇而通商贸有限公司 Detergent for metal equipment
CN105950309A (en) * 2016-05-13 2016-09-21 宁波市乾东网络科技有限公司 Cleaning agent for automotive body and preparation method of cleaning agent
CN107267998A (en) * 2017-06-15 2017-10-20 潍坊万方环保科技有限公司 A kind of metal detergent formula and preparation method thereof
CN109750305A (en) * 2018-12-28 2019-05-14 力信(江苏)能源科技有限责任公司 A kind of aluminum-shell battery shell decontamination rust remover and the preparation method and application thereof
CN112410132A (en) * 2020-12-22 2021-02-26 苏州柏越纳米科技有限公司 Low VOC semi-aqueous heavy oil stain cleaner

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101538512A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Water-based cleaner
CN103668239A (en) * 2013-11-19 2014-03-26 青岛汇而通商贸有限公司 Detergent for metal equipment
CN105950309A (en) * 2016-05-13 2016-09-21 宁波市乾东网络科技有限公司 Cleaning agent for automotive body and preparation method of cleaning agent
CN107267998A (en) * 2017-06-15 2017-10-20 潍坊万方环保科技有限公司 A kind of metal detergent formula and preparation method thereof
CN109750305A (en) * 2018-12-28 2019-05-14 力信(江苏)能源科技有限责任公司 A kind of aluminum-shell battery shell decontamination rust remover and the preparation method and application thereof
CN112410132A (en) * 2020-12-22 2021-02-26 苏州柏越纳米科技有限公司 Low VOC semi-aqueous heavy oil stain cleaner

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Application publication date: 20210629