CN1128163C - 薄膜用聚丙烯及薄膜的制造方法 - Google Patents
薄膜用聚丙烯及薄膜的制造方法 Download PDFInfo
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- CN1128163C CN1128163C CN99107556A CN99107556A CN1128163C CN 1128163 C CN1128163 C CN 1128163C CN 99107556 A CN99107556 A CN 99107556A CN 99107556 A CN99107556 A CN 99107556A CN 1128163 C CN1128163 C CN 1128163C
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- JVUVKQDVTIIMOD-UHFFFAOYSA-N dimethoxy(dipropyl)silane Chemical compound CCC[Si](OC)(OC)CCC JVUVKQDVTIIMOD-UHFFFAOYSA-N 0.000 description 1
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 1
- WERMRYHPOOABQT-UHFFFAOYSA-N dimethoxy-bis(prop-2-enyl)silane Chemical compound C=CC[Si](OC)(CC=C)OC WERMRYHPOOABQT-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- SRSBRBJUZOPZGQ-UHFFFAOYSA-N dodecanoic acid;2-[dodecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCC(O)=O.CCCCCCCCCCCCN(CCO)CCO SRSBRBJUZOPZGQ-UHFFFAOYSA-N 0.000 description 1
- YGUFXEJWPRRAEK-UHFFFAOYSA-N dodecyl(triethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OCC)(OCC)OCC YGUFXEJWPRRAEK-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- HTSRFYSEWIPFNI-UHFFFAOYSA-N ethyl-dimethoxy-methylsilane Chemical group CC[Si](C)(OC)OC HTSRFYSEWIPFNI-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 229920006379 extruded polypropylene Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- NHJGUALUPXMDGR-UHFFFAOYSA-N hexadecanoic acid;2-[2-hydroxyethyl(tetradecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCN(CCO)CCO NHJGUALUPXMDGR-UHFFFAOYSA-N 0.000 description 1
- MUJKVUYFJGYWRX-UHFFFAOYSA-N hexadecanoic acid;2-[hexadecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCN(CCO)CCO MUJKVUYFJGYWRX-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- 239000005001 laminate film Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229960002337 magnesium chloride Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229940073589 magnesium chloride anhydrous Drugs 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005673 polypropylene based resin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- CDZULFMEYKOAEF-UHFFFAOYSA-N triethoxy(ethynyl)silane Chemical compound CCO[Si](OCC)(OCC)C#C CDZULFMEYKOAEF-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- FHVAUDREWWXPRW-UHFFFAOYSA-N triethoxy(pentyl)silane Chemical compound CCCCC[Si](OCC)(OCC)OCC FHVAUDREWWXPRW-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- MJINPUKGRATQAC-UHFFFAOYSA-N triethoxy(prop-1-enyl)silane Chemical compound CCO[Si](OCC)(OCC)C=CC MJINPUKGRATQAC-UHFFFAOYSA-N 0.000 description 1
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 238000012725 vapour phase polymerization Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Images
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
Description
MFRg/10分 | 共聚单体含量摩尔% | TREF测定值 | 膨胀比 | 总灰分量含量ppm | Iso | ||||
20℃以下溶出量重量% | 20-70℃成分溶出量重量% | Tp℃ | σ℃ | ||||||
实施例1实施例2实施例3实施例4实施例5实施例6实施例7实施例8比较例1比较例2比较例3比较例4比较例5比较例6比较例7比较例8 | 2.83.12.62.83.02.82.82.82.82.82.82.63.82.82.82.8 | 0.0(均聚物)0.0(均聚物)0.0(均聚物)0.0(均聚物)0.28(乙烯)0.0(均聚物)0.0(均聚物)0.0(均聚物)0.0(均聚物)0.0(均聚物)0.0(均聚物)0.24(乙烯)0.23(乙烯)0.0(均聚物)0.0(均聚物)0.0(均聚物) | 2.52.52.62.83.02.52.52.52.55.10.50.45.15.65.12.5 | 3.12.43.13.13.53.13.13.13.14.70.81.54.64.44.33.1 | 121.1121.5120.6119.6118.5121.1121.1121.1121.1110.1127.0120.1119.2120.5120.6121.1 | 10.49.810.910.511.610.410.410.410.420.04.46.68.612.112.110.4 | 1.391.321.431.501.531.391.391.391.391.811.011.211.401.461.401.39 | 2001702802002402002002004007001003007506001001000 | 0.9300.9400.9260.9100.9300.9300.9300.9300.9300.8700.9800.9700.8900.9250.9100.930 |
薄膜厚度μm | 制膜速度m/分 | 纵向拉伸倍率倍 | 片材端部的卷曲 | 膜厚精度 | 透明性(雾度)% | MD热收缩率% | 压粘性值g | 抗静电性表面电阻率值Ω | 薄膜破裂次数次数/12小时 | |
实施例1实施例2实施例3实施例4实施例5实施例6实施例7实施例8比较例1比较例2比较例3比较例4比较例5比较例6比较例7比较例8 | 20202020204020202020202020202020 | 25025025025025013025025025025025025025090250250 | 4.54.54.54.54.54.58.03.84.54.54.54.54.54.54.54.5 | ◎○◎◎◎○○◎◎◎××◎△○△ | ◎○◎○◎○○○◎◎××◎△×△ | 1.21.21.11.21.11.61.31.51.52.31.01.21.31.41.33.5 | 0.62.22.72.32.92.32.92.02.54.72.02.63.53.02.42.6 | 200100300<100100200300100200700150200650550250<100 | 2.0×10123.0×10121.0×10125.0×10122.0×10120.8×10124.0×10122.0×10122.0×10120.5×10121.0×10121.0×10120.7×10120.7×10121.0×10121.0×1012 | 0100003010211561310638 |
薄膜厚度μm | 制膜速度m/分 | 防粘连剂添加量/(种类)重量% | 防静电剂总添加量重量% | 压粘性值g | 抗静电性表面电阻率 | 薄膜破断次数次数/12小时 | 透明性(雾度)% | |
实施例9实施例10实施例11实施例12 | 20202020 | 250250250250 | 0.5/(二氧化硅)0.05/(蜜胺)0.1/(碳酸钙)0.1/(二氧化硅) | 0.60.60.60.61) | <100100<100200 | 8.4×10125.5×10125.5×10126.5×1012 | 2010 | 2.91.11.31.2 |
热合树脂熔点℃ | 薄膜厚度μm | 热合树脂厚度μm | 热合树脂层合面 | 热合树脂开始温度℃ | 透明性(雾度)% | MD热收缩率% | 薄膜破裂次数次数/12小时 | |
实施例13实施例14实施例15实施例16实施例17 | 90601459090 | 2020202020 | 22224 | 一面一面一面两面一面 | 85601258583 | 0.32.91.21.82.4 | 1.93.22.73.22.1 | 00000 |
Claims (4)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP96361/98 | 1998-04-08 | ||
JP96361/1998 | 1998-04-08 | ||
JP9636198 | 1998-04-08 |
Publications (2)
Publication Number | Publication Date |
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CN1238343A CN1238343A (zh) | 1999-12-15 |
CN1128163C true CN1128163C (zh) | 2003-11-19 |
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CN99107556A Expired - Fee Related CN1128163C (zh) | 1998-04-08 | 1999-04-08 | 薄膜用聚丙烯及薄膜的制造方法 |
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CN (1) | CN1128163C (zh) |
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US20030039826A1 (en) * | 2000-03-20 | 2003-02-27 | Sun Edward I. | Conformable and die-cuttable biaxially oriented films and labelstocks |
CN104070757A (zh) * | 2014-06-19 | 2014-10-01 | 晋江市新合发塑胶印刷有限公司 | 一种消光cpp膜及其制作方法 |
CN111100225B (zh) * | 2018-10-29 | 2022-08-19 | 中国石油化工股份有限公司 | 一种丙烯聚合方法及装置 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4916498A (en) * | 1985-09-15 | 1990-04-10 | Trw Inc. | High electron mobility power transistor |
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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US4916498A (en) * | 1985-09-15 | 1990-04-10 | Trw Inc. | High electron mobility power transistor |
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