CN112758983A - 一种七钼酸铵的制备方法 - Google Patents
一种七钼酸铵的制备方法 Download PDFInfo
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- CN112758983A CN112758983A CN202011585359.1A CN202011585359A CN112758983A CN 112758983 A CN112758983 A CN 112758983A CN 202011585359 A CN202011585359 A CN 202011585359A CN 112758983 A CN112758983 A CN 112758983A
- Authority
- CN
- China
- Prior art keywords
- ammonium
- ammonium heptamolybdate
- molybdate solution
- molybdenum
- heptamolybdate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 59
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 49
- 239000011733 molybdenum Substances 0.000 claims abstract description 49
- 238000002386 leaching Methods 0.000 claims abstract description 47
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 29
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 25
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 25
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims abstract description 12
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims abstract description 12
- 238000002425 crystallisation Methods 0.000 claims abstract description 11
- 230000008025 crystallization Effects 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 10
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- 238000001704 evaporation Methods 0.000 claims abstract description 8
- 238000000605 extraction Methods 0.000 claims description 51
- 238000006243 chemical reaction Methods 0.000 claims description 46
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 24
- 239000011684 sodium molybdate Substances 0.000 claims description 18
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 18
- 229910002651 NO3 Inorganic materials 0.000 claims description 17
- 239000000292 calcium oxide Substances 0.000 claims description 17
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 15
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 239000003350 kerosene Substances 0.000 claims description 6
- 235000015393 sodium molybdate Nutrition 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 abstract description 11
- 239000002351 wastewater Substances 0.000 abstract description 9
- 230000008020 evaporation Effects 0.000 abstract description 6
- 230000020477 pH reduction Effects 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229910004619 Na2MoO4 Inorganic materials 0.000 description 12
- 239000003513 alkali Substances 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 11
- 229910015667 MoO4 Inorganic materials 0.000 description 8
- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 239000002893 slag Substances 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 235000012501 ammonium carbonate Nutrition 0.000 description 6
- 229910017604 nitric acid Inorganic materials 0.000 description 6
- 238000005554 pickling Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 229910019934 (NH4)2MoO4 Inorganic materials 0.000 description 4
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 238000011085 pressure filtration Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- 238000003916 acid precipitation Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- XMYHHSMIUHHPEW-UHFFFAOYSA-N azane;molybdenum Chemical compound N.[Mo] XMYHHSMIUHHPEW-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000009615 deamination Effects 0.000 description 2
- 238000006481 deamination reaction Methods 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052961 molybdenite Inorganic materials 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (10)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113502403A (zh) * | 2021-06-02 | 2021-10-15 | 四川星明能源环保科技有限公司 | 一种从废催化剂碱性溶液中回收钼的方法 |
CN115403071A (zh) * | 2022-08-23 | 2022-11-29 | 安庆市月铜钼业有限公司 | 一种低钨二钼酸铵的生产方法及用其生产的二钼酸铵 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4079116A (en) * | 1976-12-27 | 1978-03-14 | Amax Inc. | Process for producing ammonium heptamolybdate and/or ammonium dimolybdate |
CN101792852A (zh) * | 2009-11-17 | 2010-08-04 | 灵宝市金源矿业有限责任公司 | 一种湿法回收低品位氧化钼精矿的工艺 |
CN109650447A (zh) * | 2019-01-31 | 2019-04-19 | 成都虹波钼业有限责任公司 | 一种环保高效的钼酸铵生产工艺 |
-
2020
- 2020-12-28 CN CN202011585359.1A patent/CN112758983A/zh active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4079116A (en) * | 1976-12-27 | 1978-03-14 | Amax Inc. | Process for producing ammonium heptamolybdate and/or ammonium dimolybdate |
CN101792852A (zh) * | 2009-11-17 | 2010-08-04 | 灵宝市金源矿业有限责任公司 | 一种湿法回收低品位氧化钼精矿的工艺 |
CN109650447A (zh) * | 2019-01-31 | 2019-04-19 | 成都虹波钼业有限责任公司 | 一种环保高效的钼酸铵生产工艺 |
Non-Patent Citations (3)
Title |
---|
党晓娥等: "《稀有金属冶金学-钨钼钒冶金》", 30 September 2018, 冶金工业出版社 * |
曹璇等: "七钼酸铵的制备及进展", 《铜业工程》 * |
陈敏华: "含铁废盐酸的萃取分离研究", 《中国优秀硕士学位论文全文数据库》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113502403A (zh) * | 2021-06-02 | 2021-10-15 | 四川星明能源环保科技有限公司 | 一种从废催化剂碱性溶液中回收钼的方法 |
CN115403071A (zh) * | 2022-08-23 | 2022-11-29 | 安庆市月铜钼业有限公司 | 一种低钨二钼酸铵的生产方法及用其生产的二钼酸铵 |
CN115403071B (zh) * | 2022-08-23 | 2024-05-28 | 安庆市月铜钼业有限公司 | 一种低钨二钼酸铵的生产方法及用其生产的二钼酸铵 |
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CB03 | Change of inventor or designer information | ||
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Inventor after: Zhang Guiqing Inventor after: Guan Wenjuan Inventor after: Li Qinggang Inventor after: Xu Hongfei Inventor after: Xu Zunping Inventor after: Jiang Laigao Inventor before: Xu Hongfei Inventor before: Xu Zunping Inventor before: Jiang Laigao |
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TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20230725 Address after: 410000 Mount Yuelu, Changsha, Hunan Province, left home Applicant after: CENTRAL SOUTH University Address before: 246000 No. 8 Dangui Road, Fenghuang Circular Economy Industrial Park, Daguan District, Anqing City, Anhui Province Applicant before: Anqing YueTong Molybdenum Industry Co.,Ltd. |
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Application publication date: 20210507 |