CN112694683B - 丙烯酸酯橡胶与三元乙丙橡胶共混复合橡胶的制备方法 - Google Patents
丙烯酸酯橡胶与三元乙丙橡胶共混复合橡胶的制备方法 Download PDFInfo
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- CN112694683B CN112694683B CN202011631147.2A CN202011631147A CN112694683B CN 112694683 B CN112694683 B CN 112694683B CN 202011631147 A CN202011631147 A CN 202011631147A CN 112694683 B CN112694683 B CN 112694683B
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- ethylene propylene
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 130
- 229920002943 EPDM rubber Polymers 0.000 title claims abstract description 47
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 46
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000006229 carbon black Substances 0.000 claims abstract description 21
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 19
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 17
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 17
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 17
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 17
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000008117 stearic acid Substances 0.000 claims abstract description 17
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
- 239000011593 sulfur Substances 0.000 claims abstract description 17
- 239000011787 zinc oxide Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000003825 pressing Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 17
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical group C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 16
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 16
- 238000004073 vulcanization Methods 0.000 claims description 16
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 10
- 239000004711 α-olefin Substances 0.000 claims description 10
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 238000011010 flushing procedure Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 3
- UEZWYKZHXASYJN-UHFFFAOYSA-N cyclohexylthiophthalimide Chemical group O=C1C2=CC=CC=C2C(=O)N1SC1CCCCC1 UEZWYKZHXASYJN-UHFFFAOYSA-N 0.000 claims description 3
- KPNYFXUDBVQRNK-UHFFFAOYSA-N 1-(4-anilinophenyl)pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1NC1=CC=CC=C1 KPNYFXUDBVQRNK-UHFFFAOYSA-N 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000007731 hot pressing Methods 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- OLNMJIHADFYHAK-UHFFFAOYSA-N n,n-diethyl-4-nitrosoaniline Chemical compound CCN(CC)C1=CC=C(N=O)C=C1 OLNMJIHADFYHAK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical group CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 2
- 238000005242 forging Methods 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 2
- 150000003254 radicals Chemical class 0.000 abstract description 2
- 238000010558 suspension polymerization method Methods 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 229920000800 acrylic rubber Polymers 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 230000006750 UV protection Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
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CN202011631147.2A CN112694683B (zh) | 2020-12-31 | 2020-12-31 | 丙烯酸酯橡胶与三元乙丙橡胶共混复合橡胶的制备方法 |
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CN202011631147.2A CN112694683B (zh) | 2020-12-31 | 2020-12-31 | 丙烯酸酯橡胶与三元乙丙橡胶共混复合橡胶的制备方法 |
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CN112694683A CN112694683A (zh) | 2021-04-23 |
CN112694683B true CN112694683B (zh) | 2024-01-16 |
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Citations (9)
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KR980009367A (ko) * | 1996-07-10 | 1998-04-30 | 권오상 | 미끄럼 방지용 신발 겉창용 조성물 및 이를 이용한 신발 겉창의 제조 방법 |
CN101173161A (zh) * | 2007-10-31 | 2008-05-07 | 天津市润达塑料包装有限公司 | 烯烃类热塑性弹性体防水材及其制造方法 |
CN101456934A (zh) * | 2009-01-04 | 2009-06-17 | 上海大学 | 一种反应型界面相容剂的制备方法 |
CN104403211A (zh) * | 2014-11-09 | 2015-03-11 | 衡水百金复合材料科技有限公司 | 一种具备低温硫化性能的三元乙丙橡胶和止水带及止水带的制造方法 |
CN104672624A (zh) * | 2014-10-11 | 2015-06-03 | 台州市百花胶带有限公司 | 橡胶组合物、采用该橡胶组合物的v带包布胶及制备方法 |
WO2017080513A1 (zh) * | 2015-11-13 | 2017-05-18 | 怡维怡橡胶研究院有限公司 | 湿法混炼母炼胶并用填料或母胶的橡胶组合物及制备方法 |
CN107880406A (zh) * | 2017-11-02 | 2018-04-06 | 衡水滨河工程橡塑有限公司 | 改性三元乙丙胶、止水带及其制备方法、应用和制造厂 |
CN110054844A (zh) * | 2019-05-22 | 2019-07-26 | 遂宁森帝汽配制造有限责任公司 | 高耐热低压变汽车输水软管胶料及其制备方法和应用 |
CN110922686A (zh) * | 2019-12-05 | 2020-03-27 | 青岛海力威新材料科技股份有限公司 | 一种新型止水带橡胶材料以及制备方法 |
-
2020
- 2020-12-31 CN CN202011631147.2A patent/CN112694683B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR980009367A (ko) * | 1996-07-10 | 1998-04-30 | 권오상 | 미끄럼 방지용 신발 겉창용 조성물 및 이를 이용한 신발 겉창의 제조 방법 |
CN101173161A (zh) * | 2007-10-31 | 2008-05-07 | 天津市润达塑料包装有限公司 | 烯烃类热塑性弹性体防水材及其制造方法 |
CN101456934A (zh) * | 2009-01-04 | 2009-06-17 | 上海大学 | 一种反应型界面相容剂的制备方法 |
CN104672624A (zh) * | 2014-10-11 | 2015-06-03 | 台州市百花胶带有限公司 | 橡胶组合物、采用该橡胶组合物的v带包布胶及制备方法 |
CN104403211A (zh) * | 2014-11-09 | 2015-03-11 | 衡水百金复合材料科技有限公司 | 一种具备低温硫化性能的三元乙丙橡胶和止水带及止水带的制造方法 |
WO2017080513A1 (zh) * | 2015-11-13 | 2017-05-18 | 怡维怡橡胶研究院有限公司 | 湿法混炼母炼胶并用填料或母胶的橡胶组合物及制备方法 |
CN107880406A (zh) * | 2017-11-02 | 2018-04-06 | 衡水滨河工程橡塑有限公司 | 改性三元乙丙胶、止水带及其制备方法、应用和制造厂 |
CN110054844A (zh) * | 2019-05-22 | 2019-07-26 | 遂宁森帝汽配制造有限责任公司 | 高耐热低压变汽车输水软管胶料及其制备方法和应用 |
CN110922686A (zh) * | 2019-12-05 | 2020-03-27 | 青岛海力威新材料科技股份有限公司 | 一种新型止水带橡胶材料以及制备方法 |
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Address after: 100089 rooms 501, 503-506, 510, 517-523, 601-605, East auxiliary building, No.10 Fuxing Road, Haidian District, Beijing Patentee after: CHINA RAILWAY ECONOMIC AND PLANNING RESEARCH INSTITUTE Co.,Ltd. Country or region after: China Patentee after: CHINA RAILWAY DESIGN Corp. Patentee after: CHINA RAILWAY ERYUAN ENGINEERING GROUP Co.,Ltd. Patentee after: Shangde Technology (Anhui) Co.,Ltd. Address before: 100089 rooms 501, 503-506, 510, 517-523, 601-605, East auxiliary building, No.10 Fuxing Road, Haidian District, Beijing Patentee before: CHINA RAILWAY ECONOMIC AND PLANNING RESEARCH INSTITUTE Co.,Ltd. Country or region before: China Patentee before: CHINA RAILWAY DESIGN Corp. Patentee before: CHINA RAILWAY ERYUAN ENGINEERING GROUP Co.,Ltd. Patentee before: ANHUI SHOULDER TECHNOLOGY Co.,Ltd. |
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