CN112646655A - High-quality low-oil-mist plant base oil micro-emulsified cutting fluid and preparation method thereof - Google Patents
High-quality low-oil-mist plant base oil micro-emulsified cutting fluid and preparation method thereof Download PDFInfo
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- CN112646655A CN112646655A CN202011543054.4A CN202011543054A CN112646655A CN 112646655 A CN112646655 A CN 112646655A CN 202011543054 A CN202011543054 A CN 202011543054A CN 112646655 A CN112646655 A CN 112646655A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/20—Rosin acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/102—Polyesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a preparation method of a high-quality low-oil-mist plant base oil microemulsion cutting fluid, which comprises the following steps: s1: adding 4-7% of isopropanolamine, 4-8% of tricarboxylic acid, 0.7-1.2% of benzotriazole, 0.4-0.7% of potassium hydroxide and the balance of water into a beaker according to the weight percentage; s2: stirring the liquid until the liquid becomes uniform and transparent liquid A; s3: adding 1.5-3 wt% of anticorrosive agent, 5-8 wt% of lubricant, 3-6 wt% of tall oil, 2-4 wt% of isomeric tridecanol polyoxyethylene ether, 48-56 wt% of vegetable base oil, 2-4 wt% of Guerbet alcohol, 2-4 wt% of ether carboxylic acid compound agent, 4-6 wt% of Sasol polyether 1740 and 3-5 wt% of emulsifier into the liquid A; s4: the liquid was stirred until the liquid became a uniform transparent finished product. The cutting fluid prepared by the method has the advantages of small oil mist, low cost, good stability and strong applicability.
Description
Technical Field
The invention belongs to the technical field of cutting fluid, and particularly relates to high-quality low-oil-mist plant base oil micro-emulsified cutting fluid and a preparation method thereof.
Background
The cutting fluid (coolant) is an industrial liquid used for cooling and lubricating cutters and workpieces in the metal cutting and grinding process, is formed by scientifically compounding and matching various super-strong functional additives, and has the characteristics of good cooling performance, lubricating performance, antirust performance, oil removal and cleaning functions, anticorrosion function and easiness in dilution. The defects that the traditional soap-based emulsion is easy to smell in summer, difficult to dilute in winter and poor in antirust effect are overcome, the lathe paint is not affected, and the soap-based emulsion is suitable for cutting and grinding ferrous metal and belongs to the most advanced grinding product at present.
Along with the increasing sound of the environment-friendly clarion in China, the environment protection supervision and management is more and more strict, and the punishment force is also more and more big, so the requirement on the environment-friendly performance of the cutting fluid is higher and higher, but the cutting fluid in the current market can not meet the requirements of current people, and the specific reasons are as follows:
(1) under the process with higher requirements, cutting fluid with higher concentration must be used to meet the production requirements, the consumption is high, and the cost is high;
(2) in the using process of the cutting fluid, oil mist is large, which is toxic to operators and seriously pollutes workshops;
(3) contains a large amount of harmful substances, such as formaldehyde, dicyclohexylamine, nitrite, phenol and phenol bactericides and VOC volatile substances;
(4) poor lubricity and applicability;
(5) the stability is poor, and the soap is easy to separate out under the water quality processing condition with high hardness.
Disclosure of Invention
The invention aims to: the high-quality low-oil-mist plant base oil micro-emulsified cutting fluid and the preparation method thereof are provided for solving the problems of high cutting fluid consumption, high cost, large oil mist, serious pollution, poor applicability and poor stability in the existing market.
In order to achieve the purpose, the invention adopts the following technical scheme: a high-quality low-oil-mist plant base oil micro-emulsified cutting fluid is characterized by comprising the following components in percentage by weight:
further, the high-quality low-oil-mist plant base oil micro-emulsified cutting fluid comprises the following components: 5% of isopropanolamine; 2% of corrosion inhibitor; 5% of tricarboxylic acid; 1% of benzotriazole; 6% of a lubricant; 4% of tall oil; 2% of isomeric tridecanol polyoxyethylene ether; 50% of vegetable base oil; 3% of Guerbet alcohol; 2% of ether carboxylic acid compound agent; 17405% of sapropolyether; 0.5% of hydroxide compound in alkalinity; 4% of hydrophobic emulsifier; the balance being water.
As a further description of the above technical solution:
the alkaline hydroxide is potassium hydroxide.
As a further description of the above technical solution:
the water is soft water or deionized water.
As a further description of the above technical solution:
the water in the S1 is soft water or deionized water.
As a further description of the above technical solution:
the corrosion inhibitor is Rhodafac ASI 80.
As a further description of the above technical solution:
the lubricant is polyester GY-25.
As a further description of the above technical solution:
the hydrophobic emulsifier is MARLOX RT 42.
On the other hand, the invention provides a preparation method of a high-quality low-oil-mist plant base oil micro-emulsified cutting fluid, which comprises the following steps:
s1: according to the proportion of any one of claims 1 to 2, isopropanolamine, tricarboxylic acid, benzotriazole, alkaline hydroxide compound and the balance of water are added into a 250ml beaker;
s2: stirring the liquid in the beaker for the first time until the liquid becomes uniform and transparent liquid A;
s3: adding an anticorrosive agent, a lubricant, tall oil, isotridecanol polyoxyethylene ether, vegetable base oil, Guerbet alcohol, ether carboxylic acid built agent, Saxol polyether 1740 and a hydrophobic emulsifier to the liquid A according to the formulation of any one of claims 1-2;
s4: and stirring the liquid in the beaker for the second time until the liquid becomes uniform and transparent to form a finished product.
As a further description of the above technical solution:
the first stirring in S2 is stirring at normal temperature.
As a further description of the above technical solution:
the second stirring in the S4 is carried out at 35-45 ℃.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
1. in the invention, the Rhodafac ASI8 is used as an anticorrosive agent for preparing the cutting fluid, the Rhodafac ASI8 has very good lubricating and extreme pressure properties, a concentrate can be directly added without adding a coupling agent, and the Rhodafac ASI80 is most effective in surface treatment of metal aluminum, particularly in treatment of sensitive aviation aluminum alloy, the Rhodafac ASI80 is also very effective in metal zinc at a concentration of 1%, and can also play a role in corrosion inhibition on magnesium, so that the application range is wide.
2. In the invention, soft water or deionized water is adopted as water, so that the Rhodafac ASI of Rhodia and oxide or calcium and magnesium ions in the processing liquid are prevented from complexing and generating obvious precipitates.
3. In the invention, the polyester GY-25 is used as the lubricant, the lubricant has good hydrolytic stability and thermal and oxidation properties, is suitable for high-temperature annealing, inhibits bacteria from breeding, replaces a chlorine-and sulfur-containing extreme pressure additive, and avoids generation of toxic substances and oil mist.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a technical scheme that: a high-quality low-oil-mist plant base oil micro-emulsified cutting fluid is characterized by comprising the following components in percentage by weight:
further, the high-quality low-oil-mist plant base oil micro-emulsified cutting fluid comprises the following components: 5% of isopropanolamine; 2% of corrosion inhibitor; 5% of tricarboxylic acid; 1% of benzotriazole; 6% of a lubricant; 4% of tall oil; 2% of isomeric tridecanol polyoxyethylene ether; 50% of vegetable base oil; 3% of Guerbet alcohol; 2% of ether carboxylic acid compound agent; 17405% of sapropolyether; 0.5% of hydroxide compound in alkalinity; 4% of hydrophobic emulsifier; the balance being water.
The alkaline hydroxide is potassium hydroxide. Because most of cutting fluid is organic acid-base reaction, the reaction activity is weaker, catalysis and activation are needed, and the potassium hydroxide is added, so that the reaction activity of fatty acid and alcohol amine in the cutting fluid can be improved, and the efficiency can be improved. Can improve the base number and reduce the dosage of alkali. Hard water is activated, and hydroxide radical is combined with calcium and magnesium in water to form fine particle sediment, so that fatty acid is prevented from being combined with calcium and magnesium to form flocculent sediment.
The water is soft water or deionized water; avoid Rhodafac ASI from complexing with oxide or calcium and magnesium ions in the processing liquid and generating obvious precipitation.
The corrosion inhibitor is Rhodafac ASI 80; the Rhodafac ASI8 has very good lubricating and extreme pressure properties, can be directly added into a concentrate without adding a coupling agent, and simultaneously, the Rhodafac ASI80 is most effective in treating the surface of metal aluminum, particularly in the treatment of sensitive aviation aluminum alloy, the Rhodafac ASI80 is also very effective in metal zinc at the concentration of 1 percent and has a corrosion inhibition effect on magnesium, so that the application range is wide.
The lubricant is polyester GY-25; the lubricant has good hydrolytic stability and thermal and oxidation properties, is suitable for high-temperature annealing, inhibits bacteria from breeding, replaces chlorine-containing and sulfur-containing extreme pressure additives, and avoids the generation of toxic gases.
The hydrophobic emulsifier is MARLOX RT 42; has excellent low foam, excellent calcium soap dispersing capacity, easy biodegradation and good environmental protection.
On the other hand, the preparation method of the high-quality low-oil-mist plant base oil micro-emulsified cutting fluid provided by the invention comprises the following steps:
s1: according to the proportion of any one of claims 1 to 2, isopropanolamine, tricarboxylic acid, benzotriazole, alkaline hydroxide compound and the balance of water are added into a 250ml beaker;
s2: stirring the liquid in the beaker for the first time until the liquid becomes uniform and transparent liquid A;
s3: adding an anticorrosive agent, a lubricant, tall oil, isotridecanol polyoxyethylene ether, vegetable base oil, Guerbet alcohol, ether carboxylic acid built agent, Saxol polyether 1740 and a hydrophobic emulsifier to the liquid A according to the formulation of any one of claims 1-2;
s4: and stirring the liquid in the beaker for the second time until the liquid becomes uniform and transparent to form a finished product.
The first stirring in S2 is stirring at normal temperature;
the second stirring in the S4 is carried out at the temperature of 35-45 ℃; the reaction speed of chemical substances in the solution is accelerated, and the generation efficiency of the cutting fluid is improved.
The working principle is as follows: adding 4-7% of isopropanolamine, 4-8% of tricarboxylic acid, 0.7-1.2% of benzotriazole, 0.4-0.7% of potassium hydroxide and the balance of water into a 250ml beaker according to the weight percentage, stirring at normal temperature until the liquid becomes uniform and transparent liquid A, then adding 1.5-3% of Rhodafac ASI80 of Rodia, 5-8% of polyester GY-25, 3-6% of tall oil, 2-4% of isotridecanol polyoxyethylene ether, 48-56% of vegetable base oil, 2-4% of Guerbet alcohol, 2-4% of ether carboxylic acid compound agent, 4-6% of Saxol polyether 1740 and 3-5% of MARLOX RT42 according to the weight percentage, stirring at 40 ℃ until the liquid becomes uniform and transparent to form a finished product, wherein the cutting fluid adopts polyester GY-25 as a lubricant, the cutting fluid has the advantages of good stability, environmental protection and strong applicability, the Rhodamac ASI8 is used as an anticorrosive agent for preparing the cutting fluid, the corrosion inhibition effect on various metal surfaces can be realized by low concentration, the cost is low, and the effect is good.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (10)
1. A high-quality low-oil-mist plant base oil micro-emulsified cutting fluid is characterized by comprising the following components in percentage by weight:
2. the high-quality low-oil-mist plant base oil microemulsion cutting fluid comprises the following components in percentage by weight: 5% of isopropanolamine; 2% of corrosion inhibitor; 5% of tricarboxylic acid; 1% of benzotriazole; 6% of a lubricant; 4% of tall oil; 2% of isomeric tridecanol polyoxyethylene ether; 50% of vegetable base oil; 3% of Guerbet alcohol; 2% of ether carboxylic acid compound agent; 17405% of sapropolyether; 0.5% of hydroxide compound in alkalinity; 4% of hydrophobic emulsifier; the balance being water.
3. The high-quality low-oil-mist plant base oil microemulsion cutting fluid is characterized in that the alkaline hydroxide compound is potassium hydroxide.
4. The high-quality low-oil mist plant base oil microemulsion cutting fluid is characterized in that the water is soft water or deionized water.
5. The high-quality low-oil-mist plant base oil microemulsion cutting fluid is characterized in that the anti-corrosion agent is Rhodafac ASI 80.
6. The high-quality low-oil-mist plant base oil microemulsion cutting fluid is characterized in that the lubricant is polyester GY-25.
7. The high-quality low-oil-mist plant base oil microemulsion cutting fluid is characterized in that the hydrophobic emulsifier is MARLOX RT 42.
8. A preparation method of a high-quality low-oil-mist plant base oil micro-emulsified cutting fluid comprises the following steps:
s1: according to the proportion of any one of claims 1 to 2, isopropanolamine, tricarboxylic acid, benzotriazole, alkaline hydroxide compound and the balance of water are added into a 250ml beaker;
s2: stirring the liquid in the beaker for the first time until the liquid becomes uniform and transparent liquid A;
s3: adding an anticorrosive agent, a lubricant, tall oil, isotridecanol polyoxyethylene ether, vegetable base oil, Guerbet alcohol, ether carboxylic acid built agent, Saxol polyether 1740 and a hydrophobic emulsifier to the liquid A according to the formulation of any one of claims 1-2;
s4: and stirring the liquid in the beaker for the second time until the liquid becomes uniform and transparent to form a finished product.
9. The method for preparing a high-quality low-oil-mist plant base oil microemulsion cutting fluid according to claim 8, wherein the first stirring in the step S2 is stirring at normal temperature.
10. The method for preparing a high-quality and low-oil-mist plant base oil microemulsion cutting fluid according to claim 8, wherein the second stirring in the step S4 is performed at 35-45 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011543054.4A CN112646655A (en) | 2020-12-23 | 2020-12-23 | High-quality low-oil-mist plant base oil micro-emulsified cutting fluid and preparation method thereof |
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| CN202011543054.4A CN112646655A (en) | 2020-12-23 | 2020-12-23 | High-quality low-oil-mist plant base oil micro-emulsified cutting fluid and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115678657A (en) * | 2022-11-01 | 2023-02-03 | 富兰克润滑科技（太仓）有限公司 | Universal high-lubrication fully-synthetic cutting fluid and preparation method thereof |
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| US5780399A (en) * | 1995-02-10 | 1998-07-14 | Nippon Zeon Co., Ltd. | Oil-soluble polyester, additive for lubricating oil, and lubricating oil composition |
| CN102618358A (en) * | 2012-03-06 | 2012-08-01 | 上海应用技术学院 | Green micro-emulsification metal machining liquid and preparation method thereof |
| CN105296131A (en) * | 2015-11-19 | 2016-02-03 | 诺泰生物科技(合肥)有限公司 | Chlorine-sulfur-phosphor-less high-extreme pressure fully synthetic cutting fluid and preparation method thereof |
| CN109294714A (en) * | 2018-09-21 | 2019-02-01 | 江苏富兰克化学有限公司 | A kind of novel environment friendly cutting fluid free of cleaning |
| CN111040861A (en) * | 2019-12-11 | 2020-04-21 | 富兰克润滑科技（太仓）有限公司 | Magnesium alloy highlight liquid and preparation method thereof |
| CN111876224A (en) * | 2020-08-13 | 2020-11-03 | 华阳-恩赛有限公司 | Micro-emulsified cutting fluid for Al-7050, preparation method and application thereof |
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2020
- 2020-12-23 CN CN202011543054.4A patent/CN112646655A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5780399A (en) * | 1995-02-10 | 1998-07-14 | Nippon Zeon Co., Ltd. | Oil-soluble polyester, additive for lubricating oil, and lubricating oil composition |
| CN102618358A (en) * | 2012-03-06 | 2012-08-01 | 上海应用技术学院 | Green micro-emulsification metal machining liquid and preparation method thereof |
| CN105296131A (en) * | 2015-11-19 | 2016-02-03 | 诺泰生物科技(合肥)有限公司 | Chlorine-sulfur-phosphor-less high-extreme pressure fully synthetic cutting fluid and preparation method thereof |
| CN109294714A (en) * | 2018-09-21 | 2019-02-01 | 江苏富兰克化学有限公司 | A kind of novel environment friendly cutting fluid free of cleaning |
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| CN111876224A (en) * | 2020-08-13 | 2020-11-03 | 华阳-恩赛有限公司 | Micro-emulsified cutting fluid for Al-7050, preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115678657A (en) * | 2022-11-01 | 2023-02-03 | 富兰克润滑科技（太仓）有限公司 | Universal high-lubrication fully-synthetic cutting fluid and preparation method thereof |
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