CN112624693A - Method for preparing concrete by using waste bricks and tiles - Google Patents

Method for preparing concrete by using waste bricks and tiles Download PDF

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Publication number
CN112624693A
CN112624693A CN202011516434.9A CN202011516434A CN112624693A CN 112624693 A CN112624693 A CN 112624693A CN 202011516434 A CN202011516434 A CN 202011516434A CN 112624693 A CN112624693 A CN 112624693A
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waste
concrete
tiles
mixing
preparing
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CN202011516434.9A
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Chinese (zh)
Inventor
汪恭胜
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Beijing Union Green Technology Group Co ltd
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Beijing Union Green Technology Group Co ltd
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Priority to CN202011516434.9A priority Critical patent/CN112624693A/en
Publication of CN112624693A publication Critical patent/CN112624693A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a method for preparing concrete by using waste bricks and tiles, which belongs to the field of building materials and comprises the steps of crushing the waste bricks and tiles, mixing raw materials and preparing a composite reinforcer, wherein the composite reinforcer is prepared by mixing aluminum sulfate, aluminum ferric silicate, ammonium phosphate, magnesium sulfate and redispersed latex powder, and the mixed raw materials and the composite reinforcer are mixed and then mixed with sand, stone and water for concrete casting. The invention not only effectively utilizes the waste brick tiles, but also has the characteristics of high strength, high hardening speed, no cracking and firm bonding with the basic building after the concrete is cast.

Description

Method for preparing concrete by using waste bricks and tiles
Technical Field
The invention belongs to the field of building materials, and particularly relates to a method for preparing concrete by using waste bricks and tiles.
Background
The waste bricks and tiles are common building wastes, have low economic value of recycling, and are commonly used for roadbed filling at present. The waste bricks and tiles contain a large amount of silicate, alkali metal and other components, and can be used for preparing cement with higher economic value.
The waste brick and tile contains a large amount of silicate and can be used for concrete casting, but the components in the waste brick and tile are complex, so the waste brick and tile are easy to crack, low in strength and poor in bonding effect with a substrate when used for preparing concrete.
Disclosure of Invention
In order to overcome the problems in the background art, the invention provides a method for preparing concrete by using waste bricks and tiles, which not only effectively utilizes the waste bricks and tiles, but also has the characteristics of high strength, high hardening speed, no cracking and firm bonding with a basic building when being used for casting the concrete.
In order to realize the purpose, the invention is realized by the following technical scheme:
the method for preparing the concrete by using the waste tiles comprises the following steps:
(1) crushing the waste bricks and tiles to 170-200 meshes to obtain waste brick and tile powder;
(2) adding portland cement and a water reducing agent into the waste brick and tile powder, and fully mixing to obtain a mixed raw material;
(3) mixing aluminum sulfate, aluminum ferric silicate, ammonium phosphate, magnesium sulfate and redispersed rubber powder to obtain a composite reinforcer;
(4) mixing the mixed raw materials and the composite reinforcer, adding sand, stone and water, and then using for concrete casting.
Further, the mixed raw materials in the step (2) comprise the following components in percentage by mass: 32-40% of waste brick and tile powder, 3-5% of water reducing agent and the balance of portland cement.
Further, the mass ratio of the composite reinforcer in the step (1) is 20-30% of aluminum sulfate, 15-25% of aluminum ferric silicate, 10-18% of ammonium phosphate, 8-16% of magnesium sulfate and the balance of re-dispersed latex powder.
Furthermore, the mass ratio of the mixed raw materials to the composite enhancer is 9.95-9.99: 1.
Further, the water reducing agent is a polyhydroxy high-performance water reducing agent.
The casting temperature of the concrete is more than 20 ℃.
The invention has the beneficial effects that:
the composite reinforcer is used, so that the composite reinforcer and the mixed raw materials are combined during concrete casting, the cast concrete has high strength and is not cracked, and the concrete is firmly bonded with a matrix such as a reinforcing steel bar.
The invention takes the waste bricks and tiles as one of the raw materials, not only effectively utilizes the waste bricks and tiles, but also has the characteristics of high strength, no cracking and high hardening speed after concrete casting, and is firmly bonded with the matrix.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, preferred embodiments of the present invention will be described in detail below to facilitate understanding of the skilled person.
The method for preparing concrete by using waste bricks and tiles comprises the following steps:
(1) crushing the waste bricks and tiles to 170-200 meshes to obtain waste brick and tile powder; the waste tile can be effectively mixed with other materials after being crushed, and is easily crosslinked and cured together with other raw materials under the action of a composite reinforcer, so that a structure which is stable in structure, high in strength and not easy to crack is obtained.
(2) Adding Portland cement and a polyhydroxy high-performance water reducing agent into the waste brick and tile powder, and fully mixing to obtain a mixed raw material, wherein the waste brick and tile powder is 32-40%, the water reducing agent is 3-5%, and the balance is Portland cement.
(3) Mixing 20-30% of aluminum sulfate, 15-25% of aluminum ferric silicate, 10-18% of ammonium phosphate, 8-16% of magnesium sulfate and the balance of re-dispersed emulsion powder to obtain the composite enhancer. After the aluminum sulfate and the ferric aluminum silicate are added with water for construction, an acid environment and positive charges can be provided, so that the redispersed rubber powder and the water reducing agent are effectively dissolved and dispersed and are firmly adsorbed with other raw materials, and the structure after solidification is more stable. The addition of magnesium sulfate and ammonium sulfate can react with trace phosphorus plasma in the waste tiles to form trace fine crystals, the generated crystals have strong induction effect, the hardening of cement can be accelerated, the hardened cement generates mutual crosslinking effect, the structure is more stable, the strength is high, and the cement is not cracked.
(4) Mixing the mixed raw materials and the composite reinforcer according to a mass ratio of 9.95-9.99:1, adding sand, stone and water, and then using the mixture for casting concrete, wherein the casting temperature is higher than 20 ℃. When the temperature is higher than 20 ℃, the ammonium phosphate and the magnesium sulfate can be quickly dissolved and react to generate fine crystals, and the fine crystals interact with the ferric aluminum silicate and the aluminum sulfate to increase the stability of the whole concrete structure.
Example 1
Method for preparing concrete by using waste bricks and tiles
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 5% of polyhydroxy high-performance water reducing agent, 40% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) Mixing 25% of aluminum sulfate, 20% of aluminum ferric silicate, 10% of ammonium phosphate, 10% of magnesium sulfate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(4) Mixing the mixed raw materials and the composite enhancer according to the mass ratio of 9.97: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
Table 1 example 1 test results after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 42.54 5.82 Without cracking or spalling
Comparative example 1
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 5% of polyhydroxy high-performance water reducing agent, 40% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) 31.25 percent of aluminum sulfate, 25 percent of ferric aluminum silicate and the balance of ethylene-vinyl acetate copolymer are mixed to obtain the composite reinforcer.
(4) Mixing the mixed raw materials and the composite enhancer according to the mass ratio of 9.97: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
Table 2 test results of comparative example 1 after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 23.54 1.82 With obvious cracks and spalling
Comparative example 2
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 5% of polyhydroxy high-performance water reducing agent, 40% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) And mixing 18.2% of ammonium phosphate, 18.2% of magnesium sulfate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(4) Mixing the mixed raw materials and the composite enhancer according to the mass ratio of 9.97: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
TABLE 3 test results of comparative example 2 after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 32.54 3.82 Having cracks and not peeling off
Example 2
Method for preparing concrete by using waste bricks and tiles
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 4% of polyhydroxy high-performance water reducing agent, 35% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) Mixing 15% of aluminum sulfate, 20% of aluminum ferric silicate, 18% of ammonium phosphate, 16% of magnesium sulfate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(4) Mixing the mixed raw materials and the composite enhancer according to the mass ratio of 9.97: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
Table 4 example 2 test results after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 46.84 4.25 Without cracking or spalling
Comparative example 3
Method for preparing concrete by using waste bricks and tiles
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 4% of polyhydroxy high-performance water reducing agent, 35% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) Mixing 22.7% of aluminum sulfate, 30.3% of ferric aluminum silicate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(4) Mixing the mixed raw materials and the composite enhancer according to the mass ratio of 9.97: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
TABLE 5 test results of comparative example 3 after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 28.26 2.82 With obvious cracks and spalling
Comparative example 4
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 4% of polyhydroxy high-performance water reducing agent, 35% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) And mixing 27.7% of ammonium phosphate, 24.6% of magnesium sulfate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(4) Mixing the mixed raw materials and the composite enhancer according to the mass ratio of 9.97: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
TABLE 6 test results of comparative example 4 after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 28.56 3.75 Has cracks
Example 3
Method for preparing concrete by using waste bricks and tiles
(1) And crushing the waste bricks and tiles to 170 meshes to obtain the waste brick and tile powder.
(2) Fully mixing 4% of polyhydroxy high-performance water reducing agent, 32% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) Mixing 20% of aluminum sulfate, 20% of aluminum ferric silicate, 12% of ammonium phosphate, 14% of magnesium sulfate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(4) Mixing the mixed raw materials and the composite enhancer in a mass ratio of 9.99: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
Table 7 example 3 test results after concrete casting
Detecting items Compressive strength/MPa Tensile Strength/MPa Cracking after 90d curing
Index (I) 42.28 5.29 Without cracking or spalling
Comparative example 5
Method for preparing concrete by using waste bricks and tiles
(1) The waste tiles are crushed to 100-230 meshes to obtain the waste tile powder.
(2) Fully mixing 4% of polyhydroxy high-performance water reducing agent, 32% of waste brick and tile powder and the balance of portland cement to obtain a mixed raw material.
(3) Mixing 20% of aluminum sulfate, 20% of aluminum ferric silicate, 12% of ammonium phosphate, 14% of magnesium sulfate and the balance of ethylene-vinyl acetate copolymer to obtain the composite enhancer.
(5) Mixing the mixed raw materials and the composite enhancer in a mass ratio of 9.99: 1.
(5) And (3) adding the materials in the step (4) into sand, stone and water, mixing the materials in a mass ratio of 150:350:280:35, and casting the mixture for plain concrete at a casting temperature of 25 ℃ to ensure that the temperature of the concrete before initial setting is not lower than 20 ℃.
TABLE 8 detection results of fineness of waste tiles on concrete after construction
Number of meshes of waste bricks and tiles Cracking after 90d curing Compressive strength/MPa Tensile Strength/MPa
120 Obvious cracks 22.56 1.22
140 Obvious cracks 22.87 1.56
170 Without cracks and spalling 37.35 3.99
230 Without cracks and spalling 44.82 5.76
The self-leveling cement prepared can be effectively combined with other raw materials only after the brick and tile are crushed to 170 meshes in fineness, probably because the components in the waste brick and tile are complex, and the pore structure and the activity can be effectively combined with a composite reinforcer to form a stable structure only when the granularity is small enough.
Finally, it is noted that the above-mentioned preferred embodiments illustrate rather than limit the invention, and that, although the invention has been described in detail with reference to the above-mentioned preferred embodiments, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the scope of the invention as defined by the appended claims.

Claims (6)

1. A method for preparing concrete by using waste bricks and tiles is characterized by comprising the following steps: the method for preparing the concrete by using the waste tiles comprises the following steps:
(1) crushing the waste bricks and tiles to 170-200 meshes to obtain waste brick and tile powder;
(2) adding portland cement and a water reducing agent into the waste brick and tile powder, and fully mixing to obtain a mixed raw material;
(3) mixing aluminum sulfate, aluminum ferric silicate, ammonium phosphate, magnesium sulfate and redispersed latex powder to obtain a composite enhancer;
(4) mixing the mixed raw materials and the composite reinforcer, adding sand, stone and water, and then using for concrete casting.
2. The method for preparing concrete from waste tiles according to claim 1, characterized in that: the mixed raw materials in the step (2) comprise the following components in percentage by mass: 32-40% of waste brick and tile powder, 3-5% of water reducing agent and the balance of portland cement.
3. The method for preparing concrete from waste tiles according to claim 1, characterized in that: the mass ratio of the composite reinforcer in the step (1) is 20-30% of aluminum sulfate, 15-25% of aluminum ferric silicate, 10-18% of ammonium phosphate, 8-16% of magnesium sulfate and the balance of re-dispersed emulsion powder.
4. A method for the preparation of concrete from waste tiles according to any one of claims 1 to 3, characterized in that: the mass ratio of the mixed raw materials to the composite enhancer is 9.95-9.99: 1.
5. The method for preparing concrete from waste tiles according to claim 1, characterized in that: the water reducing agent is a polyhydroxy high-performance water reducing agent.
6. The method for the preparation of concrete from waste tiles according to any one of claims 1 to 5, characterized in that: the casting temperature of the concrete is more than 20 ℃.
CN202011516434.9A 2020-12-21 2020-12-21 Method for preparing concrete by using waste bricks and tiles Pending CN112624693A (en)

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CN112830736A (en) * 2021-01-21 2021-05-25 北京惠地智能技术研究院有限公司 Method for manufacturing self-leveling cement by using waste bricks and tiles

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CN112830736A (en) * 2021-01-21 2021-05-25 北京惠地智能技术研究院有限公司 Method for manufacturing self-leveling cement by using waste bricks and tiles

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Application publication date: 20210409