CN108585592A - A kind of Concrete synergist and preparation method thereof - Google Patents

A kind of Concrete synergist and preparation method thereof Download PDF

Info

Publication number
CN108585592A
CN108585592A CN201810798649.0A CN201810798649A CN108585592A CN 108585592 A CN108585592 A CN 108585592A CN 201810798649 A CN201810798649 A CN 201810798649A CN 108585592 A CN108585592 A CN 108585592A
Authority
CN
China
Prior art keywords
concrete
triisopropanolamine
calgon
polyacrylamide
calcium formate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810798649.0A
Other languages
Chinese (zh)
Inventor
张再宏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Rz Innovation Industry And Trade Co Ltd
Original Assignee
Beijing Rz Innovation Industry And Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Rz Innovation Industry And Trade Co Ltd filed Critical Beijing Rz Innovation Industry And Trade Co Ltd
Priority to CN201810798649.0A priority Critical patent/CN108585592A/en
Publication of CN108585592A publication Critical patent/CN108585592A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

It is by polyacrylamide this application provides a kind of Concrete synergist and preparation method thereof;Sodium sulfite;Polyalcohol;Triisopropanolamine and calcium formate;Diethylenetriamine pentacarboxylic acid sodium;Calgon;Remaining is formed for water.The Concrete synergist of the present invention promotes hydrated cementitious speed, keeps hydrated cementitious more abundant by the dispersion degree of efficient excited cement particle.The phenomenon that cement component is filled with powder is reduced, the dosage of cement component can be effectively reduced while ensureing that the comprehensive performance of concrete is constant, Cost of Concrete is made to substantially reduce;And each component in Concrete synergist cooperates through the invention, can not only improve the early anaphase intensity of concrete, can also substantially improve the whole synthesis performance of concrete.Production process is simple, pollution-free discharge, environmental protection.

Description

A kind of Concrete synergist and preparation method thereof
Technical field
The invention belongs to technical field of concrete additives, and in particular to a kind of Concrete synergist and preparation method thereof.
Background technology
Concrete refers to by cementitious material by the general designation of the cementing integral engineered composite material of aggregate.The coagulation usually said A native word refers to making cementitious material, sand, masonry aggregate with cement;Match by a certain percentage with water (additive and admixture can be contained) Close, it is agitated obtained by cement concrete, also referred to as normal concrete, it is widely used in civil engineering.Concrete is as building Material is widely used, and up to the present there are no the applications that the material for foresight occur can substitute concrete.
Produce the cost highest of cement in each component of concrete.Cement, that is, powdery hydraulicity inorganic coagulation material.Add water At slurry after stirring, can harden in air or in water preferably hardening, and can the materials such as sand, stone securely it is cementing Together.The mixture of early stage lime and volcanic ash and modern lime pozzolanic cement are much like, made of its cementing rubble Concrete, not only intensity is higher after hardening, and can also resist the erosion of fresh water or brackish water.For a long time, it is as a kind of Important cementitious material is widely used in the engineerings such as civil construction, water conservancy, national defence.It is required according to strength grade of concrete, mixed Part of cement can also be replaced as cementitious material with other activity or nonactive powdered substance in solidifying soil, such as miberal powder or fine coal Ash etc..Ordinary circumstance in every side's concrete cement consumption between 150-500 kilograms, it is seen that the dosage of cement is still very big , the shared cost ratio highest in concrete.But since the degree of hydration of cement is unable to reach 100%, so mixed Some cement is intended only as powder filler material in solidifying soil, and booster action is not had to concrete.And Concrete synergist Addition, can make the cement granules for not carrying out hydration reaction fully fully react or accelerate the aquation of coarse granule cement, so as to To realize cement consumption is reduced while ensureing the groundwork performance and intensity requirement of concrete.Although current cement synergy The use of agent is not much, but it can produce identical quality concrete time province cement consumption, reduce concrete production cost, together When, indirectly because less with cement to the discharge for reducing the nitrogen oxides in manufacture of cement and energy-efficient effect, coagulation Native synergist will gradually will be used in the preparation of concrete in large quantities by more and more concrete production unit recipients. This is consistent with building a resource-conserving and environment-friendly society.
Invention content
In order to overcome the shortcomings of described in background technology, the present invention provides a kind of Concrete synergist and preparation method thereof, The synergist can effectively improve concrete crushing strength, improve workability of concrete, effectively reduce the dosage of cement, reduce The production cost of concrete.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of Concrete synergist, in parts by weight, the cement grinding aid are grouped as by following group:A kind of high property Energy Concrete synergist, is made of the raw material of following mass percent:
Polyacrylamide 7%-12%;
Sodium sulfite 4%-18%;
Polyalcohol 5%-7%;
Triisopropanolamine and calcium formate 10%-15%;
Diethylenetriamine pentacarboxylic acid sodium 3%-5%;
Calgon 2%-4%;
Surplus is water.
Further, polyalcohol is one or more in ethylene glycol, propylene glycol, three isopropanol of diethanol.
Further, triisopropanolamine:Calcium formate is 3:2.
Further, polyacrylamide 9%-10%;Sodium sulfite 8%-12%;Three isopropanol of ethylene glycol or diethanol 5%-7%;Triisopropanolamine 6-9%;Calcium formate 4%-6%;Diethylenetriamine pentacarboxylic acid sodium 3%-5%;Calgon 2%-4%.
Further, polyacrylamide 9.5%;Sodium sulfite 10%;Three isopropanol 6% of ethylene glycol and diethanol;Three is different Propanolamine 6%;Calcium formate 4%;Diethylenetriamine pentacarboxylic acid sodium 4%;Calgon 3%.
Further, polyacrylamide 9.5%;Sodium sulfite 10%;Ethylene glycol 4%;Three isopropanol 2% of diethanol;Three Isopropanolamine 6%;Calcium formate 4%;Diethylenetriamine pentacarboxylic acid sodium 4%;Calgon 3%.
The invention also discloses a kind of preparation methods of Concrete synergist, comprise the steps of:
1) each component is weighed by weight percentage:Polyacrylamide 7%-12%;Sodium sulfite 4%-18%;Polyalcohol 5%-7%;Triisopropanolamine and calcium formate 10%-15%;Diethylenetriamine pentacarboxylic acid sodium 3%-5%;Calgon 2%- 4%;Surplus is water.
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
The technique effect of the present invention:
The Concrete synergist of the present invention is reduced cement component and is filled out with powder by the dispersion degree of efficient excited cement particle The phenomenon that filling fully efficiently uses cement composition, while can accelerate hydrated cementitious speed, keeps hydrated cementitious more abundant.It is protecting The dosage that cement component can be effectively reduced while the comprehensive performance of card concrete is constant or improves, keeps Cost of Concrete big It is big to reduce;And cooperating between component in Concrete synergist through the invention, not only increase the morning of concrete Later strength, and substantially improve the whole synthesis performance of concrete.Production process is simple, pollution-free discharge, environmental protection.
Specific implementation mode
For the present invention by a kind of Concrete synergist of offer and preparation method thereof, solution existing concrete cement consumption is more, The higher problem of cost.
Technical solution general thought in the present invention is as follows:
A kind of Concrete synergist, in parts by weight, the cement grinding aid are grouped as by following group:A kind of high property Energy Concrete synergist, is made of the raw material of following mass percent:
Polyacrylamide 7%-12%;
Sodium sulfite 4%-18%;
Polyalcohol 5%-7%;
Triisopropanolamine and calcium formate 10%-15%;
Diethylenetriamine pentacarboxylic acid sodium 3%-5%;
Calgon 2%-4%;
Surplus is water.
Further, polyalcohol is one or more in ethylene glycol, propylene glycol, three isopropanol of diethanol.
Further, triisopropanolamine:Calcium formate is 3:2.
Further, polyacrylamide 9%-10%;Sodium sulfite 8%-12%;Three isopropanol of ethylene glycol or diethanol 5%-7%;Triisopropanolamine 6-9%;Calcium formate 4%-6%;Diethylenetriamine pentacarboxylic acid sodium 3%-5%;Calgon 2%-4%.
Further, polyacrylamide 9.5%;Sodium sulfite 10%;Three isopropanol 6% of ethylene glycol and diethanol;Three is different Propanolamine 6%;Calcium formate 4%;Diethylenetriamine pentacarboxylic acid sodium 4%;Calgon 3%.
Further, polyacrylamide 9.5%;Sodium sulfite 10%;Ethylene glycol 4%;Three isopropanol 2% of diethanol;Three Isopropanolamine 6%;Calcium formate 4%;Diethylenetriamine pentacarboxylic acid sodium 4%;Calgon 3%.
During concrete formation, various raw material mixing and water addings are molded, a large amount of cement, cement conduct are used in raw material Main powder binding material adds, and cement is combined with water occurs hydration reaction, in the hyrate bonded concrete of formation Each component, and with the process of aquation, the intensity of concrete is higher and higher.But in hydration process, since part of cement is thin Little particle, which is easily reunited, is easy for that moisture is hindered to enter, and hinders the aquation of internal cement granules, and in synergist in polyalcohol Hydroxyl has oleophylic and hydrophilicity, can be good at the finished ground cement for breaing up reunion, keeps the cement granules that reunion is wrapped up organic It can be contacted by the water.The wherein different polyalcohol of molecular size range, penetration is different, and cooperation is interactive, makes size cement group Poly- particle is dispersed more efficiently, and the cement granules of effective aquation is made to increase, so as to realize that reducing cement consumption also can Enough it is improved the intensity of concrete.In addition, cement consumption is reduced, you can accordingly to reduce the water consumption in concrete, increase The compactness for adding concrete, further increases concrete strength.
Isopropanolamine substance can significantly improve the activity of cement, promote cement further hydration.Here preferably three isopropanols Amine is mixed with calcium formate, and triisopropanolamine improves the activity of cement, and calcium formate introduces calcium ion, is increased concrete strength, is mutually assisted Same-action greatly enhances the intensity of cement and improves further hydration depth.Control the ratio of triisopropanolamine and calcium formate, control Hydration reaction is carried out towards positive direction, while ensureing that humidification maximizes.
Simultaneously diethylenetriamine pentacarboxylic acid sodium can effectively in excited cement nonactive mixing material activity, while can also Excite the activity of admixture flyash and slag micropowder in concrete.The introducing of calcium formate undoubtedly increases the concentration of calcium ion, But calgon can form complex compound with calcium ion, on the one hand reduce the concentration of calcium ion in hydrated product, accelerate water Mud hydration reaction is carried out to positive direction, and on the other hand, the calcium phosphate complex compound three-dimensional structure of formation can improve hydrated cementitious The compactness of structure, to improve the intensity of concrete.
Meanwhile after diethylenetriamine pentacarboxylic acid sodium, polyalcohol calcium formate meet water, a large amount of carboxyl and hydroxyl can be formed, by In intermolecular force, these polar groups are adsorbed onto cement particle surface, and it is smooth, fine and close can to destroy non-active material surface Si-O-Si keys and Si-O-Al keys and its network structure, so that crystal structure is generated defect, it accelerated to dissociate and aquation, so as to The enough intensity for improving concrete to greatest extent.These three-dimensional macromolecular structures are adsorbed on material surface from each orientation, mutually hand over Fork, increases the early anaphase intensity after concrete formation.
Sodium sulfite and the calcium ion of generation form the intensity of gypsum increasing concrete, and further promote aquation deep Degree.
Early period due to adding polyalcohol, triisopropanolamine and calcium formate etc. there is the component of dispersion effect, concrete to exist These dispersed components are preferentially combined abundant dissociation with water after water is added early period, by the thickening power of polyacrylamide, make coagulation Native other components are fully contacted with the dispersed component of dissociation, accelerate concrete formation, and improve concrete strength after molding.
So each component generates association in respective performance individual effect in the Concrete synergist of the present invention Same synergistic effect makes the efficiency of Concrete synergist reach optimum efficiency, can effectively improve the dispersion performance of concrete, make water The abundant aquation of mud powder, reduces the dosage of cement, while improving the intensity of concrete.
Embodiment 1:
1) each component is weighed by weight percentage:Polyacrylamide 7KG;Sodium sulfite 4KG;Polyalcohol 5KG;Three isopropanols Amine and calcium formate 10KG;Diethylenetriamine pentacarboxylic acid sodium 3KG;Calgon 2KG;Water 69KG.
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 2:
1) each component is weighed by weight percentage:Polyacrylamide 12KG;Sodium sulfite 18KG;Polyalcohol 7KG;Three isopropyls Hydramine and calcium formate 15KG;Diethylenetriamine pentacarboxylic acid sodium 5KG;Calgon 4KG;Water 39KG.
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment:3:
1) each component is weighed by weight percentage:Polyacrylamide 9KG;Sodium sulfite 8KG;Ethylene glycol 2KG, diethanol three Isopropanol 3KG;Triisopropanolamine 6KG;Calcium formate 4KG;Diethylenetriamine pentacarboxylic acid sodium 3KG;Calgon 2KG;Water 63KG.
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 4:
1) each component is weighed by weight percentage:Polyacrylamide 10KG;Sodium sulfite 12KG;Ethylene glycol 3KG, diethanol Three isopropanol 4KG;Triisopropanolamine 9KG;Calcium formate 6KG;Diethylenetriamine pentacarboxylic acid sodium 5KG;Calgon 4KG;Water 47KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 5:
1) each component is weighed by weight percentage:Polyacrylamide 9.5KG;Sodium sulfite 10KG;Ethylene glycol 3KG, diethyl Three isopropanol 2KG of alcohol;Triisopropanolamine 6KG;Calcium formate 4KG;Diethylenetriamine pentacarboxylic acid sodium 4KG;Calgon 3KG;Water 58.5KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 6:
1) each component is weighed by weight percentage:Polyacrylamide 9.5KG;Sodium sulfite 10KG;Ethylene glycol 4KG, diethyl Three isopropanol 2KG of alcohol;Triisopropanolamine 6KG;Calcium formate 4KG;Diethylenetriamine pentacarboxylic acid sodium 4KG;Calgon 3KG;Water 57.5KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 7:
1) each component is weighed by weight percentage:Polyacrylamide 9.5KG;Sodium sulfite 10KG;Ethylene glycol 1KG, diethyl Three isopropanol 4KG of alcohol;Triisopropanolamine 6KG;Calcium formate 4KG;Diethylenetriamine pentacarboxylic acid sodium 4KG;Calgon 3KG;Water 58.5KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 8:
1) each component is weighed by weight percentage:Polyacrylamide 9.5KG;Sodium sulfite 10KG;Ethylene glycol 6KG, diethyl Three isopropanol 1KG of alcohol;Triisopropanolamine 6KG;Calcium formate 4KG;Diethylenetriamine pentacarboxylic acid sodium 4KG;Calgon 3KG;Water 57.5KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 9:
1) each component is weighed by weight percentage:Polyacrylamide 9.5KG;Sodium sulfite 10KG;Ethylene glycol 6KG, diethyl Three isopropanol 1KG of alcohol;Triisopropanolamine 1KG;Calcium formate 9KG;Diethylenetriamine pentacarboxylic acid sodium 4KG;Calgon 3KG;Water 57.5KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Embodiment 10:
1) each component is weighed by weight percentage:Polyacrylamide 9.5KG;Sodium sulfite 10KG;Ethylene glycol 6KG, diethyl Three isopropanol 1KG of alcohol;Triisopropanolamine 14KG;Calcium formate 1KG;Diethylenetriamine pentacarboxylic acid sodium 4KG;Calgon 3KG;Water 51.5KG。
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, stirring is equal It is even, you can high performance concrete synergist is made.
Illustrate, the mixture any component therein in the present invention is not less than 1KG, that is, is more than or equal to 1GK.
High-performance cement synergist of the present invention is as follows to the contrast experiment of concrete crushing strength and slump:
This experiment uses mechanical agitation mixing concrete, additive and Concrete synergist to use with method addition is mixed, stir Time is 5-10 minutes, and compares sample with the blank for being not added with Concrete synergist and compared.Concrete strength is according to GB/ T50081-2016《Standard for test methods of mechanical properties of ordinary concrete》It tests, slump performance is according to GB/ T50080-2016《Normal concrete mixture performance methodology testing standard》It tests.
Concrete mix (C30) is as shown in table 1 below when control experiment.
1 concrete control experiment match ratio (kg/m3) of table
Cement Flyash It is classified stone Coarse sand Fine sand Water Additive
280 60 923 100 860 162 2.05%
In embodiment 1/3/5/7/9, all compositions and ratio are all identical as blank control experiment, only add in each embodiment 6 ‰ each cement synergist is entered, each performance is as shown in the following table 2 and table 3.
2 mechanical property experimental results of table
Group 7 days compression strength (MPa) 28 days compression strength (MPa)
Blank control experiment 27.3 46.7
Embodiment 1 33.4 50.2
Embodiment 3 33.1 50.4
Embodiment 5 32.8 49.7
Embodiment 7 32.5 51.2
Embodiment 9 33.4 51.6
3 slump of table and workability experimental result
It can be seen that from the experimental result of table 2 and table 3 after the synergist of the present invention is added in concrete, concrete 7 days intensity of mechanical property averagely increases 21%, and 28 days intensity increases 8.6%, and the intensity of concrete is obtained for Greatly improve;The first of concrete makes slump and loss of slump have a degree of improvement, at the same concrete and it is easy Property all performances it is good, and slightly have and a little improve.
Finally it should be noted that:Obviously, the above embodiment is merely an example for clearly illustrating the present invention, and simultaneously The non-restriction to embodiment.For those of ordinary skill in the art, it can also do on the basis of the above description Go out other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.And thus drawn The obvious changes or variations that Shen goes out are still in the protection scope of this invention.

Claims (7)

1. a kind of Concrete synergist, which is characterized in that in parts by weight, be made of the raw material of following mass percent 's:
Polyacrylamide 7%-12%;
Sodium sulfite 4%-18%;
Polyalcohol 5%-7%;
Triisopropanolamine and formic acid calcium compound 10%-15%;
Diethylenetriamine pentacarboxylic acid sodium 3%-5%;
Calgon 2%-4%;
Surplus is water.
2. a kind of Concrete synergist according to claim 1, which is characterized in that the polyalcohol is ethylene glycol, the third two It is one or more in alcohol, three isopropanol of diethanol.
3. a kind of Concrete synergist according to claim 2, which is characterized in that the triisopropanolamine:Calcium formate is 3:2。
4. a kind of Concrete synergist according to claim 2, which is characterized in that the polyacrylamide 9%-10%; Sodium sulfite 8%-12%;Three isopropanol mixture 5%-7% of ethylene glycol and diethanol;Triisopropanolamine 6%-9%;Calcium formate 4%-6%;Diethylenetriamine pentacarboxylic acid sodium 3%-5%;Calgon 2%-4%.
5. a kind of Concrete synergist according to claim 3, which is characterized in that the polyacrylamide 9.5%;Sulfurous Sour sodium 10%;Three isopropanol mixture 6% of ethylene glycol and diethanol;Triisopropanolamine 6%;Calcium formate 4%;Diethylenetriamine five Carboxylic acid sodium 4%;Calgon 3%.
6. a kind of Concrete synergist according to claim 4, which is characterized in that the polyacrylamide 9.5%;Sulfurous Sour sodium 10%;Ethylene glycol 4%;Three isopropanol 2% of diethanol;Triisopropanolamine 6%;Calcium formate 4%;Diethylenetriamine pentacarboxylic acid Sodium 4%;Calgon 3%.
7. preparing a kind of preparation method of Concrete synergist described in claim 1, which is characterized in that comprise the steps of:
1) each component is weighed by weight percentage:Polyacrylamide 7%-12%;Sodium sulfite 4%-18%;Polyalcohol 5%- 7%;Triisopropanolamine and calcium formate 10%-15%;Diethylenetriamine pentacarboxylic acid sodium 3%-5%;Calgon 2%-4%; Surplus is water.
2) polyalcohol and triisopropanolamine and calcium formate are mixed evenly, obtain initial mixing liquid;
3) initial mixing liquid and calgon are mixed, stirs evenly, obtains intermediate mixed solution;
4) diethylenetriamine pentacarboxylic acid sodium, polyacrylamide and sodium sulfite are added in intermediate mixed solution, is stirred evenly, i.e., High performance concrete synergist can be made.
CN201810798649.0A 2018-07-19 2018-07-19 A kind of Concrete synergist and preparation method thereof Pending CN108585592A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810798649.0A CN108585592A (en) 2018-07-19 2018-07-19 A kind of Concrete synergist and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810798649.0A CN108585592A (en) 2018-07-19 2018-07-19 A kind of Concrete synergist and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108585592A true CN108585592A (en) 2018-09-28

Family

ID=63618735

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810798649.0A Pending CN108585592A (en) 2018-07-19 2018-07-19 A kind of Concrete synergist and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108585592A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109095810A (en) * 2018-11-07 2018-12-28 青海民族大学 A kind of Concrete synergist and preparation method thereof
CN109626937A (en) * 2019-01-30 2019-04-16 郑州铁路职业技术学院 A kind of preparation method of water proof building plasterboard
CN109694230A (en) * 2019-02-15 2019-04-30 青海民族大学 A kind of magnesia oxychloride cement regenerated aggregate concrete
CN112279550A (en) * 2020-10-14 2021-01-29 武汉塔牌华轩新材料科技有限公司 Concrete synergist and preparation method thereof
CN112411299A (en) * 2020-11-21 2021-02-26 韶关市中群建设有限公司 Energy-saving and environment-friendly construction method for highway
CN112624677A (en) * 2021-01-05 2021-04-09 成都翔盛商品混凝土有限公司 High-strength concrete and preparation method thereof
CN114315208A (en) * 2021-12-23 2022-04-12 广州基业长青新材料有限公司 Concrete glue reducing agent and preparation method and application thereof
CN117228982A (en) * 2023-09-20 2023-12-15 中流砥柱(广州)新材料有限公司 Shield synchronous grouting agent synergist, preparation method thereof and shield synchronous grouting agent

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036587A (en) * 2015-09-06 2015-11-11 山东宏艺科技股份有限公司 High-performance concrete synergist and preparing method thereof
CN107935431A (en) * 2017-11-27 2018-04-20 固岩科技发展有限公司 A kind of Concrete synergist and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036587A (en) * 2015-09-06 2015-11-11 山东宏艺科技股份有限公司 High-performance concrete synergist and preparing method thereof
CN107935431A (en) * 2017-11-27 2018-04-20 固岩科技发展有限公司 A kind of Concrete synergist and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109095810A (en) * 2018-11-07 2018-12-28 青海民族大学 A kind of Concrete synergist and preparation method thereof
CN109626937A (en) * 2019-01-30 2019-04-16 郑州铁路职业技术学院 A kind of preparation method of water proof building plasterboard
CN109694230A (en) * 2019-02-15 2019-04-30 青海民族大学 A kind of magnesia oxychloride cement regenerated aggregate concrete
CN112279550A (en) * 2020-10-14 2021-01-29 武汉塔牌华轩新材料科技有限公司 Concrete synergist and preparation method thereof
CN112411299A (en) * 2020-11-21 2021-02-26 韶关市中群建设有限公司 Energy-saving and environment-friendly construction method for highway
CN112624677A (en) * 2021-01-05 2021-04-09 成都翔盛商品混凝土有限公司 High-strength concrete and preparation method thereof
CN114315208A (en) * 2021-12-23 2022-04-12 广州基业长青新材料有限公司 Concrete glue reducing agent and preparation method and application thereof
CN114315208B (en) * 2021-12-23 2022-09-02 广州基业长青新材料有限公司 Concrete glue reducing agent and preparation method and application thereof
CN117228982A (en) * 2023-09-20 2023-12-15 中流砥柱(广州)新材料有限公司 Shield synchronous grouting agent synergist, preparation method thereof and shield synchronous grouting agent
CN117228982B (en) * 2023-09-20 2024-05-24 中流砥柱(广州)新材料有限公司 Shield synchronous grouting agent synergist, preparation method thereof and shield synchronous grouting agent

Similar Documents

Publication Publication Date Title
CN108585592A (en) A kind of Concrete synergist and preparation method thereof
CN113307591B (en) Multi-source solid waste composite high-flow-state backfill material and preparation method and application thereof
CN108203281B (en) Micro-expansion grouting material and preparation method thereof
CN111072366B (en) Inorganic grouting material capable of stopping open water and reinforcing structure and preparation method and application thereof
CN109455992A (en) A kind of machine-made sand concrete and preparation method thereof
CN108545975A (en) A kind of modified SILICA FUME of gunite concrete
CN107382216B (en) High-strength concrete doped with iron tailings and construction waste and preparation method thereof
CN105622023B (en) A kind of sludge curing agent using clinker
CN1657473A (en) High titanium blast furnace slag concrete adulterant and its production method
CN103771776A (en) Recycled micropowder concrete and preparation method thereof
CN107417153B (en) Concrete synergist and preparation method thereof
CN108821689A (en) A kind of modified concrete and preparation method thereof
EP4082984A1 (en) Binder composition comprising pozzolanic material and fine filler
CN114671644B (en) High-early-strength low-resilience high-performance sprayed concrete and preparation method thereof
CN106630725B (en) Liquid accelerator for sprayed concrete and preparation method thereof
CN115073093A (en) Low-shrinkage high-strength self-compacting recycled concrete and preparation method thereof
CN106630882A (en) Medium/high-strength concrete prepared from modified phosphogypsum based binding material and manufacturing method of concrete
CN114605121A (en) Tungsten tailing autoclaved aerated concrete and preparation method thereof
CN112266211B (en) Early-strength low-shrinkage concrete containing waste stone powder and preparation method thereof
CN113105149A (en) Concrete glue reducing agent and preparation method and application method thereof
CN110759681A (en) Self-compacting lightweight aggregate concrete and preparation method and application thereof
CN114349405B (en) Composition for preparing filling material, preparation method of filling material and method for filling mine
CN115286348A (en) Coal mine/coal chemical industry solid waste synthetic concrete material and preparation method thereof
CN113603408A (en) Full-solid waste filling material for green filling mining of mine and proportioning method thereof
CN104291726A (en) Ultralow-content post-tensioned pre-stressed pipeline grouting agent, and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180928