CN112569166B - 一种温和的洗发水 - Google Patents
一种温和的洗发水 Download PDFInfo
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- CN112569166B CN112569166B CN202011490284.9A CN202011490284A CN112569166B CN 112569166 B CN112569166 B CN 112569166B CN 202011490284 A CN202011490284 A CN 202011490284A CN 112569166 B CN112569166 B CN 112569166B
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- lauroyl
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- 241000209140 Triticum Species 0.000 claims abstract description 28
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- 102000004169 proteins and genes Human genes 0.000 claims abstract description 25
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 25
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- 108010035532 Collagen Proteins 0.000 claims abstract description 13
- 229920001436 collagen Polymers 0.000 claims abstract description 13
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 11
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 11
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
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- 239000001331 rosmarinus officinalis leaf Substances 0.000 claims description 4
- 150000001413 amino acids Chemical class 0.000 claims description 2
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 claims 1
- OCZLHFXYCIDGNN-RJXKWAGSSA-N N[C@@H](CCC(O)=O)C(O)=O.CCCCCCCCCCCC([Na])=O Chemical compound N[C@@H](CCC(O)=O)C(O)=O.CCCCCCCCCCCC([Na])=O OCZLHFXYCIDGNN-RJXKWAGSSA-N 0.000 claims 1
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- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 4
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- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 2
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- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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Abstract
本发明公开了一种温和的洗发水,属于日用化学品技术领域。本发明以刺激性很低的椰油酰水解小麦蛋白的盐类物质作为主要的发泡清洁剂,以月桂酰谷氨酸钠、甲基椰油酰基牛磺酸钠、月桂酰水解胶原TEA盐以及椰油酰胺丙基PG‑二甲基氯化铵磷酸酯作为辅助发泡清洁剂,并以刺激性低的麦芽糖和水解小麦蛋白作为柔顺剂,令使用后不容易头痒,同时,椰油酰水解小麦蛋白、麦芽糖和水解小麦蛋白在柔顺头发以及清洁方面产生具有协同增效的作用。
Description
技术领域
本发明属于日用化学品技术领域,涉及一种温和的洗发水。
背景技术
人们常使用洗发水清洁头发以除去灰尘和油垢。随着人们生活水平的提高,人们也希望洗发水无刺激,洗发过程中不刺激眼睛,同时洗发后头发柔顺有光泽。但是目前市售的洗发水中的发泡剂多采用硫酸盐等化学合成原料,清洁去脂能力强,起泡性好,泡沫丰富,但刺激性较强,使用后会对头皮及头发产生一定的刺激,由于清洁过度而加重头油、头屑、头痒和脱发等。
因此,有必要开发一种洗发水,刺激性低,具有良好清洁效果和柔顺效果。
发明内容
为解决上述现有技术中存在的缺点和不足,本发明的目的在于提供一种温和的洗发水,以弥补市场上同类产品的不足。
本发明提供了一种温和的洗发水,包括以下重量百分含量的组分:椰油酰水解小麦蛋白的盐类物质2.4-7.5%,水解小麦蛋白0.1-0.6%,麦芽糖0.2%-1.2%,月桂酰肌氨酸钠0-3%,月桂酰谷氨酸钠0.5-1.5%,甲基椰油酰基牛磺酸钠0.6-1.2%,月桂酰水解胶原TEA盐0.3-0.9%,椰油酰胺丙基PG-二甲基氯化铵磷酸酯0.18-0.3%。
椰油酰水解小麦蛋白的盐类物质对皮肤及头发有很低的刺激性,用于洗发剂中具有优良的乳化、分散、去污、抗静电能力;麦芽糖和水解小麦蛋白均具有良好的保湿和调理作用,能够柔软顺滑头发。上述洗发水以椰油酰水解小麦蛋白的盐类物质作为主要的发泡清洁剂,对皮肤刺激性比常规硫酸盐表面活性剂更低,比仲链烷胺或叔链烷胺等易形成亚硝胺的表面活性剂更安全;以麦芽糖和水解小麦蛋白作为柔顺剂,在使头发达到柔软顺滑的前提下,刺激性比聚季铵盐、阳离子瓜尔胶更低,不容易头痒,同时,麦芽糖和水解小麦蛋白能与椰油酰水解小麦蛋白的盐类物质在柔顺头发以及清洁方面产生协同增效的作用。另外,上述洗发水还添加了月桂酰谷氨酸钠、甲基椰油酰基牛磺酸钠、月桂酰水解胶原TEA盐、椰油酰胺丙基PG-二甲基氯化铵磷酸酯等发泡清洁剂,以进一步提高发泡清洁效果和冲洗效果。
优选地,所述洗发水包括以下重量百分含量的组分:椰油酰水解小麦蛋白的盐类物质6%,水解小麦蛋白0.2%,麦芽糖0.4%,月桂酰肌氨酸钠1.5%,月桂酰谷氨酸钠0.9%,甲基椰油酰基牛磺酸钠0.9%,月桂酰水解胶原TEA盐0.9%,椰油酰胺丙基PG-二甲基氯化铵磷酸酯0.3%。当椰油酰水解小麦蛋白的盐类物质、麦芽糖、水解小麦蛋白、月桂酰谷氨酸钠、甲基椰油酰基牛磺酸钠、月桂酰水解胶原TEA盐以及椰油酰胺丙基PG-二甲基氯化铵磷酸酯为该特定含量时,所述洗发水的清洁力以及柔顺性都更好,也更易冲水洗净。
优选地,所述洗发水的pH值为6.0-6.3。所述洗发水不需要额外添加防腐剂,只需将其pH值调节至6.0-6.3,即能获得很好的防腐效果,而且pH适中,刺激性小。
优选地,所述洗发水的pH值采用柠檬酸进行调节。
优选地,所述洗发水还包括抗刺激性剂、头发光泽剂、赋脂剂、螯合剂以及香料。
优选地,所述抗刺激性剂包括燕麦仁提取物,所述头发光泽剂包括泛醇,所述赋脂剂包括辛酸/癸酸甘油酯类聚甘油-10酯类、PPG-3辛基醚中的至少一种,所述螯合剂包括EDTA二钠,所述香料包括迷迭香叶提取物。
优选地,述洗发水包括以下重量百分含量的组分:燕麦仁提取物0.25-1%,泛醇0.2-1%,辛酸/癸酸甘油酯类聚甘油-10酯类0.1-1%,PPG-3辛基醚0.1-0.5%,EDTA二钠0.01-0.1%,迷迭香叶提取物0.5-2%。
进一步优选地,所述洗发水包括以下重量百分含量的组分:燕麦仁提取物0.5%,泛醇0.5%,辛酸/癸酸甘油酯类聚甘油-10酯类0.5%,PPG-3辛基醚0.2%,EDTA二钠0.05%,迷迭香叶提取物1%。
优选地,所述洗发水还包含余量的水。
与现有技术相比,本发明具有如下优点:本发明温和的洗发水以椰油酰水解小麦蛋白的盐类物质作为主要的发泡清洁剂,比月桂醇聚醚硫酸酯钠(铵)、月桂醇硫酸酯钠(铵)等硫酸盐表面活性剂对皮肤的刺激性更低;以麦芽糖和水解小麦蛋白作为柔顺剂,在使头发达到柔软顺滑的前提下,刺激性比聚季铵盐、阳离子瓜尔胶更低,不容易头痒,同时,椰油酰水解小麦蛋白、麦芽糖和水解小麦蛋白在柔顺头发以及清洁方面产生具有协同增效的作用。本发明温和的洗发水还添加了月桂酰谷氨酸钠、甲基椰油酰基牛磺酸钠、月桂酰水解胶原TEA盐、椰油酰胺丙基PG-二甲基氯化铵磷酸酯等发泡清洁剂以进一步提高发泡清洁效果和冲洗效果。
具体实施方式
为更好的说明本发明的目的、技术方案和优点,本发明通过下列实施例进一步说明。显然,下列实施例仅是本发明的一部分实施例,而不是全部的实施例。应理解,本发明实施例仅用于说明本发明的技术效果,而非用于限制本发明的保护范围。
实施例1-5
实施例1-3均为本发明温和的洗发水的一种实施方式,这些洗发水的原料组成如表1所示。
表1实施例1-3以及对比例1-4洗发水的原料组成/wt%
实施例1-3洗发水的制备方法包括以下步骤:
(1)将A相原料混合,搅拌至完全溶解,其中A相原料为水、椰油酰水解小麦蛋白钠(30wt%)、月桂酰肌氨酸钠(30wt%)、月桂酰谷氨酸钠、泛醇、燕麦(Avena Sativa)仁提取物以及月桂酰水解胶原TEA盐(30wt%);
(2)将B相原料预先混合后,加入步骤(1)所得A相中,其中B相为油酰胺丙基PG-二甲基氯化铵磷酸酯、丙二醇和水的混合物、甲基椰油酰基牛磺酸钠(30wt%)、辛酸/癸酸甘油酯类聚甘油-10酯类、柔顺剂以及PPG-3辛基醚;
(3)然后加入C相原料,搅拌均匀,其中C相原料为EDTA二钠以及迷迭香(ROSMARINUS OFFICINALIS)叶提取物;
(4)用柠檬酸调整pH值至6.0-6.3,真空脱气10分钟;
(5)出料,静置,检验合格后,灌装、包装、喷码;
(6)检验合格后,入库,即得洗发水。
对比例1-3
对比例1-3均提供了一种洗发水,这些洗发水的原料组成如表1所示,制备方法同实施例。
上述实施例和对比例所用椰油酰水解小麦蛋白钠(30wt%)、月桂酰肌氨酸钠(30wt%)以及甲基椰油酰基牛磺酸钠(30wt%)指的是由相应的表面活性剂和水组成,相应的表面活性剂和水的质量比为相应的表面活性剂:水=30:70;所用月桂酰水解胶原TEA盐(30wt%)中含30wt%月桂酰水解胶原TEA盐、0.45%胶原氨基酸类表面活性剂和余量水,所用油酰胺丙基PG-二甲基氯化铵磷酸酯、丙二醇和水的混合物中油酰胺丙基PG-二甲基氯化铵磷酸酯、丙二醇和水的质量比为30:25:45,甲基椰油酰基牛磺酸钠(30wt%)中钠含量为5wt%。
效果例1
将各实施例和对比例中的洗发水以及市售普通洗发露分别进行清洁性能和柔顺性能测试,具体为将这些洗发产品分发给100名志愿者,在其每种产品试用后对清洁效果以及柔顺效果进行评分,对相应的效果满意即得一分,不满意则得零分,最后计算各产品各项得分之和,具体结果见表2。
表2
另外,将实施例3洗发水与洗发水(不含月桂酰肌氨酸钠、月桂酰谷氨酸钠、甲基椰油酰基牛磺酸钠、月桂酰水解胶原TEA盐以及椰油酰胺丙基PG-二甲基氯化铵磷酸酯,其他成分及含量与实施例3相同)进行对比,发现后者发泡性更差,也更难冲洗干净。
效果例3
将实施例1-3和对比例1的洗发水以及市售普通洗发露分别进行防腐挑战测试,菌株分别为大肠杆菌(初始浓度7.7×104cfu/mL)、绿脓杆菌(初始浓度6.6×104cfu/mL)、金黄葡萄球菌(初始浓度7.0×104cfu/mL)、白色念珠菌(初始浓度1.0×104cfu/mL)、黑曲霉(初始浓度1.3×104cfu/mL)以及这五种菌的混合菌(初始浓度5.9×104cfu/mL),洗发水样品用量相同。防腐试验进行到第7天,混合菌菌种浓度如表3所示。
表3
样品 | CTFA(cfu/mL) |
实施例1 | <500 |
实施例2 | <300 |
实施例3 | <200 |
对比例1 | >1000 |
市售普通洗发露 | 600-800 |
效果例4
将实施例1-3的洗发水以及上述市售普通洗发露分别进行刺激性测试,结果如表4所示。
表4
样品 | ES |
实施例1 | 8 |
实施例2 | 7 |
实施例3 | 5 |
市售普通洗发露 | 15 |
ES≤12的为无刺激或低刺激产品,ES>12为中刺激产品,本发明的ES值均小于12。
最后应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。
Claims (1)
1.一种温和的洗发水,其特征在于,由以下重量百分含量的组分组成:椰油酰水解小麦蛋白钠6%,水解小麦蛋白0.2%,麦芽糖0.4%,月桂酰肌氨酸钠1.5%,月桂酰谷氨酸钠0.9%,甲基椰油酰基牛磺酸钠0.9%,月桂酰水解胶原TEA盐0.9%,胶原氨基酸类表面活性剂0.0135%,椰油酰胺丙基PG-二甲基氯化铵磷酸酯0.3%,丙二醇0.25%,燕麦仁提取物0.5%,泛醇0.5%,辛酸/癸酸甘油酯类聚甘油-10酯类0.5%,PPG-3辛基醚0.2%,EDTA二钠0.05%,迷迭香叶提取物1%,水余量;
用柠檬酸调整所述洗发水的pH为6.0-6.3。
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