CN112358187A - Production process and product of marble-imitated super-wear-resistant soft-light brick - Google Patents

Production process and product of marble-imitated super-wear-resistant soft-light brick Download PDF

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Publication number
CN112358187A
CN112358187A CN202011358093.7A CN202011358093A CN112358187A CN 112358187 A CN112358187 A CN 112358187A CN 202011358093 A CN202011358093 A CN 202011358093A CN 112358187 A CN112358187 A CN 112358187A
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parts
layer
glaze
ink
texture
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Pending
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CN202011358093.7A
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Inventor
黄春林
谢怡伟
徐雪英
仝松贞
朱光耀
陈育昆
宁毓胜
傅建涛
韦前
叶德林
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Newpearl Ceramics Group Co ltd
Foshan Sanshui Newpearl Building Ceramic Industry Co Ltd
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Newpearl Ceramics Group Co ltd
Foshan Sanshui Newpearl Building Ceramic Industry Co Ltd
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Priority to CN202011358093.7A priority Critical patent/CN112358187A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Structural Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a production process of a marble-imitated super-wear-resistant soft-light brick and a product, and relates to the field of building materials, wherein the product prepared by the production process sequentially comprises a brick blank layer and a cover glaze layer from bottom to top, the cover glaze layer is arranged on the brick blank layer, the cover glaze layer consists of a basic glaze layer, an ink-jet pattern printing layer, a transition glaze printing layer, a micro-engraved ink printing layer and a super-wear-resistant protective glaze layer, the ink-jet pattern printing layer forms a line texture trend, the micro-engraved ink printing layer forms a concave-convex texture line, the width of the texture line is 0.01-0.1 mm, and the texture line texture trend is arranged along the line texture trend. The method has the advantages that the hyperfine concave-convex texture which is infinitely close to natural marble is obtained, the width of the hyperfine concave-convex texture lines is 0.02-0.1 mm, the alignment accuracy of the hyperfine concave-convex texture lines and the corresponding textures is high, and the wear resistance and the glossiness of a tile product are effectively improved.

Description

Production process and product of marble-imitated super-wear-resistant soft-light brick
Technical Field
The invention relates to the field of building materials, in particular to a production process and a product of a marble-imitated super wear-resistant soft light brick.
Background
Soft-light marble tiles have been introduced for many years, and soft-light tiles are marble tiles with a tile surface reflection between strong light and weak light, and have both high brightness and luster of bright-light tiles and low convergence of matte tiles.
As a new product category, the soft marble tile achieves the comfort of human visual perception and the decorative effect of no light pollution most particularly by reducing the light reflection rate.
The glossiness of the sheen brick produced by pu-yi is different from 15 degrees to 60 degrees, most of the surface shapes are planar, smooth and fine, the simulation degree of the concave-convex texture effect of a plurality of natural marbles is not enough, the silk screen printing effect is also achieved, the lines are rough and not vivid, after the technology is developed, the effect of a plurality of marble-imitated tiles is slightly rough due to the adoption of fine engraving ink or deep engraving ink, the fineness is not high, dirt and dirt are easily absorbed, the wear resistance is low (generally 900 revolutions and 1500 revolutions are 2-3 levels), and the use scene is limited.
Disclosure of Invention
In order to solve the above technical problems, a first object of the present invention is to provide a process for producing a marble-imitated super wear-resistant soft light brick, wherein a micro-engraved ink printing layer is formed on an ink-jet pattern printing layer by blending micro-engraved ink, and a concave-convex texture is formed by interaction between the micro-engraved ink and a super wear-resistant protective glaze, so as to obtain a mechanical texture of natural marble.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a production process of a marble-imitated super wear-resistant soft light brick comprises the following steps:
step (1): punching green bricks by a brick press and drying;
step (2): pouring glaze on the green brick formed in the step (1) through a bell jar type glaze pouring device to form a basic glaze layer on the green brick;
and (3): printing the imitated marble texture by using an ink-jet printer to form an ink-jet pattern layer, a transition glaze printing layer and a micro-carving ink printing layer;
step (3) comprises a step of preparing micro-carving ink and a step of extracting marble texture micro-carving patterns;
in the preparation step of the micro-carving ink, the proportion by weight is as follows: 25-45 parts of deep engraving ink and 40-55 parts of fine engraving ink;
and (4): spraying super wear-resistant protective glaze through a high-pressure spray gun to form a super wear-resistant protective glaze layer;
and (5): calcining for 1 hour in a roller kiln with the firing temperature of 1200 ℃;
and (6): and polishing by a polishing machine.
Through the arrangement, the micro-carving ink is oily ink, the super wear-resistant protective glaze is water-based, the water-based super wear-resistant protective glaze is applied to the oil-based micro-carving ink, the oil-based micro-carving ink repels the water-based super wear-resistant protective glaze along the existing line direction, and meanwhile, as the melting temperature of the micro-carving ink is far lower than that of the sprayed glaze and the super wear-resistant protective glaze, the micro-carving ink is melted into the sprayed glaze along the existing line direction, so that the ultra-fine concave-convex texture line is obtained.
Preferably, the super wear-resistant protective glaze comprises the following 9 raw materials in parts by weight: 10-20 parts of calcined kaolin, 20-30 parts of potassium feldspar, 10-18 parts of albite, 5-10 parts of quartz, 7-12 parts of calcined talc, 10-18 parts of barium carbonate, 6-15 parts of aluminum oxide, 1-5 parts of zinc oxide and 5-12 parts of clinker powder.
Through the arrangement, the content of the silicon dioxide, the aluminum oxide and the barium carbonate is far higher than that of the common protective glaze, the mechanical strength (such as wear resistance and hardness) of the glaze is obviously improved by the silicon dioxide, the wear resistance, hardness and elasticity of the glaze are also improved by the aluminum oxide, the mechanical strength (such as wear resistance and hardness) of the glaze surface is also improved by the barium oxide in the barium carbonate, and the high-silicon high-aluminum high-barium super-wear-resistant protective glaze is mainly characterized in that the super-wear-resistant protective glaze is different from the common protective glaze.
Preferably, the super wear-resistant protective glaze comprises the following 9 raw materials in parts by weight: 12 parts of calcined kaolin, 25 parts of potassium feldspar, 11 parts of albite, 6 parts of quartz, 8 parts of calcined talc, 16 parts of barium carbonate, 10 parts of alumina, 3 parts of zinc oxide and 8 parts of clinker powder.
Based on the same invention concept, the second purpose of the invention is to provide a marble-imitated super wear-resistant soft-light brick product prepared by the production process, which comprises a brick blank layer and a surface glaze layer, wherein the surface glaze layer consists of a base glaze layer, an ink-jet pattern printing layer, a transition glaze printing layer, a micro-carving ink printing layer and a super wear-resistant protective glaze layer.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the utility model provides an imitative super wear-resisting soft light brick goods of marble, includes and has adobe layer and cover glaze layer from bottom to top in proper order, and this cover glaze layer is arranged in on the adobe layer, the cover glaze layer comprises basic glaze layer, inkjet pattern printing layer, transition glaze printing layer, micro-carving ink printing layer, super wear-resisting protection glaze layer, basic glaze layer, inkjet pattern printing layer, transition glaze printing layer, micro-carving ink printing layer, super wear-resisting protection glaze layer set gradually by supreme down, inkjet pattern printing layer forms line texture trend, micro-carving ink printing layer forms the feel lines of unsmooth feel, the width of feel lines is 0.01 ~ 0.1mm, just the trend of feel lines is followed line texture trend sets up.
Through the arrangement, the transition glaze printing layer and the micro-carving ink printing layer are arranged on the ink-jet pattern layer, after texture lines are obtained, fine texture lines with concave-convex texture are formed, in addition, the texture lines are arranged along the trend of the texture lines, namely the trend of the texture lines is aligned with the trend of the line textures, the mechanism texture of natural marble is highly restored, the super-wear-resistant protective glaze layer is arranged above the glaze layer, the wear resistance of the ceramic tile is improved, and the service life of the ceramic tile is prolonged.
Preferably, the abrasion resistance coefficient of the super abrasion-resistant protective glaze layer reaches 4 grades.
Through setting up like this, effectively improve the wearability of ceramic tile product, the suitability is strong.
Preferably, the surface gloss of the overglaze layer is 25-35 degrees, and the Mohs hardness is 6 grades.
Through setting up like this, the glossiness of ceramic tile product is better, and intensity is high, and convenient the washing to reduce the broken possibility of collision.
Compared with the prior art, the invention has the beneficial technical effects that:
the production process comprises a blank rotating layer and a surface glaze layer, the structure of the surface glaze layer is improved through formula and process improvement, a transition glaze printing layer, a micro-carving ink printing layer and a super wear-resistant protective glaze layer are sequentially formed on an ink-jet pattern printing layer, the ultra-fine concave-convex texture infinitely close to natural marble is obtained, the width of the ultra-fine concave-convex texture line is 0.02-0.1 mm, the alignment accuracy of the ultra-fine concave-convex texture line and the corresponding texture is high, the texture of the natural marble is highly reduced, meanwhile, the protective glaze layer with super-strong wear resistance is applied, the wear resistance coefficient of the glaze surface reaches 2100-turn-4 level, the wear resistance of a ceramic tile product is effectively improved, the surface gloss is 25-35 degrees, and the Mohs hardness is 6 level.
Drawings
FIG. 1 is a schematic structural diagram of a marble-like super wear-resistant soft light brick of the first embodiment produced by the second embodiment of the present invention;
fig. 2 is a schematic view of the surface structure of the finished product of the marble-like super wear-resistant soft light brick in the first embodiment, which is manufactured by the manufacturing process in the second embodiment of the invention.
Wherein, the technical characteristics that each reference numeral refers to are as follows:
1. a layer of green bricks; 2. a cover glaze layer; 3. a base glaze layer; 4. an ink-jet pattern printing layer; 5. a transition glaze printing layer; 6. printing the micro-carving ink layer; 7. and the super wear-resistant protective glaze layer.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments, but the scope of the present invention is not limited to the following embodiments.
Example one
Referring to fig. 1-2, the embodiment discloses an imitation marble super wear-resistant soft-light brick product, which comprises a brick blank layer 1 and a surface glaze layer 2 from bottom to top, wherein the surface glaze layer 2 is arranged on the brick blank layer 1, the surface glaze layer 2 is composed of a base glaze layer 3, an inkjet pattern printing layer 4, a transition glaze printing layer 5, a micro-engraved ink printing layer 6 and a super wear-resistant protective glaze layer 7, the base glaze layer 3, the inkjet pattern printing layer 4, the transition glaze printing layer 5, the micro-engraved ink printing layer 6 and the super wear-resistant protective glaze layer 7 are arranged from bottom to top in sequence, the inkjet pattern printing layer 4 forms a line texture trend (such as x in fig. 2), the micro-engraved ink printing layer 6 forms a concave-convex texture line (such as Y in fig. 2), the width of the texture line is 0.01-0.1 mm, and the texture is aligned with the line texture trend.
The wear-resistant coefficient of the super wear-resistant protective glaze layer 7 reaches 4 grades.
The surface glossiness of the overglaze layer 2 is 25-35 degrees, and the Mohs hardness is 6 grades.
The brick blank layer 1, the basic glaze layer 3 and the transition glaze printing layer 5 can all adopt the existing manufacturing formula and raw materials.
The material of the micro-carving ink printing layer 6 is prepared by mineral raw materials and inorganic chemical raw materials through proportioning and ball milling fine processing (the granularity is less than 5 mu m) before sintering, and the micro-carving ink printing layer is prepared by combining deep carving ink and fine carving ink in parts by weight: 25-45 parts of deep engraving ink and 40-55 parts of finishing impression ink, wherein the combined ink, the sprayed glaze and the super wear-resistant protective glaze generate a series of physical and chemical reactions to obtain ultra-fine concave-convex texture lines, the size of each line reaches 0.02-0.1 mm, the ultra-fine concave-convex texture lines and the corresponding textures are accurately aligned to reach 100%, and the texture of the natural marble is highly restored.
Specifically, the formation principle of the texture lines is as follows: the micro-carving ink is oily ink, the super wear-resistant protective glaze is aqueous, the aqueous super wear-resistant protective glaze is applied to the oily micro-carving ink, the oily micro-carving ink repels the aqueous super wear-resistant protective glaze along the existing line direction, and meanwhile, as the melting temperature of the micro-carving ink is far lower than that of the sprayed glaze and the super wear-resistant protective glaze, the micro-carving ink is melted into the sprayed glaze along the existing line direction, so that the ultra-fine concave-convex texture line is obtained.
The material of the super wear-resistant protective glaze layer 7 is prepared by mixing inorganic mineral raw materials and inorganic chemical raw materials and performing ball milling fine processing (the granularity is less than 0.3mm) before sintering, and comprises the following 9 raw materials in parts by weight: 10-20 parts of calcined kaolin, 20-30 parts of potassium feldspar, 10-18 parts of albite, 5-10 parts of quartz, 7-12 parts of calcined talc, 10-18 parts of barium carbonate, 6-15 parts of aluminum oxide, 1-5 parts of zinc oxide and 5-12 parts of clinker powder.
Specifically, the super wear-resistant protective glaze comprises the following 9 raw materials in parts by weight: 12 parts of calcined kaolin, 25 parts of potassium feldspar, 11 parts of albite, 6 parts of quartz, 8 parts of calcined talc, 16 parts of barium carbonate, 10 parts of alumina, 3 parts of zinc oxide and 8 parts of clinker powder.
The contents of silicon dioxide, aluminum oxide and barium carbonate are far higher than those of common protective glaze, the mechanical strength (such as wear resistance and hardness) of the glaze is obviously improved by the silicon dioxide, the wear resistance, hardness and elasticity of the glaze are also improved by the aluminum oxide, the mechanical strength (such as wear resistance and hardness) of the glaze surface is also improved by the barium oxide in the barium carbonate, and the high-silicon high-aluminum high-barium super-wear-resistant protective glaze is mainly characterized by being different from the common protective glaze.
Example two
The invention discloses a production process for preparing ceramic tiles, which is used for preparing a marble-imitated super wear-resistant soft light brick product in the embodiment of the invention, adopts process equipment in the prior art, and comprises the following specific production process flows:
step (1): punching the adobes by a sago PH3590 brick press, and drying to form adobe layers;
step (2): pouring glaze through a bell jar type glaze pouring device, controlling the flow rate of the glaze to be 25-40 seconds and controlling the specific gravity to be 1.88g/cm3(ii) a Forming a base glaze layer 3;
and (3): the imitated marble texture is printed by using Sistem ink-jet, and an ink-jet pattern printing layer 4, a transition glaze printing layer 5 and a micro-carving ink printing layer 6 are sequentially formed;
the step (3) comprises a step of preparing micro-carving ink and a step of extracting marble texture micro-carving patterns, and further, in the step of extracting the marble texture micro-carving patterns, the gray value of the micro-carving ink of two groups of starlight 1024M 16 nozzles is 80-100% by using line pixels of 2-4 px;
in the preparation step of the micro-carving ink, the proportion by weight is as follows: 25-45 parts of deep engraving ink and 40-55 parts of fine engraving ink;
and (4): spraying super wear-resistant protective glaze with the specific gravity of 1.40-1.45 g/cm by an AirPower high-pressure spray gun3And the spraying weight is as follows: spraying 200-300 g of 800 mm-800 mm bricks to form a super wear-resistant protective glaze layer 7;
and (5): calcining for 1 hour in a roller kiln with the firing temperature of 1200 ℃;
and (6): polishing by a polishing machine, wherein the fine polishing requirement is as follows: adopting 400-mesh 2 group, 600-mesh 5 group and 800-mesh 5 group of elastic modules; the matte fiber brushes are 11 groups with 180 meshes and 5 groups with 240 meshes, and the surface glossiness of the soft-light brick is 25-35 degrees.
After the processes from (1) to (6), the marble-imitated super wear-resistant soft light brick with concave-convex texture infinitely close to the fine texture of the natural marble is obtained, as shown in fig. 2, the lines with fine concave-convex texture and the corresponding texture are precisely aligned to be high, the best condition can reach 100%, the texture of the marble is realistically restored, the super wear-resistant protective glaze layer 7 greatly enhances the wear resistance of the glaze, the wear-resistant coefficient reaches 2100-4 level, the surface glossiness is 25-35 degrees, and the Mohs hardness is 6 level.
Variations and modifications to the above-described embodiments may occur to those skilled in the art, which fall within the scope and spirit of the above description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.

Claims (6)

1. A production process of a marble-imitated super wear-resistant soft light brick is characterized by comprising the following steps:
step (1): punching green bricks by a brick press and drying;
step (2): pouring glaze on the green brick formed in the step (1) through a bell jar type glaze pouring device to form a basic glaze layer (3) on the green brick;
and (3): printing the imitated marble texture by using an ink-jet printer to form an ink-jet pattern layer (4), a transition glaze printing layer (5) and a micro-carving ink printing layer (6);
step (3) comprises a step of preparing micro-carving ink and a step of extracting marble texture micro-carving patterns;
in the preparation step of the micro-carving ink, the proportion by weight is as follows: 25-45 parts of deep engraving ink and 40-55 parts of fine engraving ink;
and (4): spraying super wear-resistant protective glaze through a high-pressure spray gun to form a super wear-resistant protective glaze layer (7);
and (5): calcining for 1 hour in a roller kiln with the firing temperature of 1200 ℃;
and (6): and polishing by a polishing machine.
2. The process for producing the marble-imitated super wear-resistant soft light brick according to claim 1, wherein the super wear-resistant protective glaze comprises the following 9 raw materials in parts by weight: 10-20 parts of calcined kaolin, 20-30 parts of potassium feldspar, 10-18 parts of albite, 5-10 parts of quartz, 7-12 parts of calcined talc, 10-18 parts of barium carbonate, 6-15 parts of aluminum oxide, 1-5 parts of zinc oxide and 5-12 parts of clinker powder.
3. The process for producing the marble-imitated super wear-resistant soft light brick according to claim 2, wherein the super wear-resistant protective glaze comprises the following 9 raw materials in parts by weight: 12 parts of calcined kaolin, 25 parts of potassium feldspar, 11 parts of albite, 6 parts of quartz, 8 parts of calcined talc, 16 parts of barium carbonate, 10 parts of alumina, 3 parts of zinc oxide and 8 parts of clinker powder.
4. A marble-imitated super wear-resistant soft-light brick product is characterized by being prepared by the production process of any one of claims 1 to 3, and comprising a brick blank layer (1) and a surface glaze layer (2) which are sequentially arranged from bottom to top, wherein the surface glaze layer (2) is arranged on the brick blank layer (1), the surface glaze layer (2) is composed of a basic glaze layer (3), an ink-jet pattern printing layer (4), a transition glaze printing layer (5), a micro-carving ink printing layer (6) and a super wear-resistant protective glaze layer (7), the basic glaze layer (3), the ink-jet pattern printing layer (4), the transition glaze printing layer (5), the micro-carving ink printing layer (6) and the super wear-resistant protective glaze layer (7) are sequentially arranged from bottom to top, the ink-jet pattern printing layer (4) forms a line texture trend, the micro-carving ink printing layer (6) forms concave-convex texture lines, and the width of the texture lines is 0.01-0.1 mm, and the texture lines are arranged along the line texture direction.
5. The marble-imitated super abrasion-resistant soft-light brick product according to claim 4, wherein the super abrasion-resistant protective glaze layer (7) has an abrasion resistance coefficient of 4 grade.
6. The marble-imitated super wear-resistant soft-light brick product according to claim 5, wherein the surface gloss of the overglaze layer (2) is 25-35 degrees, and the Mohs hardness is 6 grade.
CN202011358093.7A 2020-11-27 2020-11-27 Production process and product of marble-imitated super-wear-resistant soft-light brick Pending CN112358187A (en)

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CN113233921A (en) * 2021-05-18 2021-08-10 广东宏海陶瓷实业发展有限公司 Preparation method of mold texture ceramic tile and ceramic tile
CN113248150A (en) * 2021-06-22 2021-08-13 佛山市东鹏陶瓷发展有限公司 Engraving protection glaze and ceramic tile capable of improving engraving depth and preparation method thereof
CN113321536A (en) * 2021-07-07 2021-08-31 肇庆市将军陶瓷有限公司 Preparation process for imitating effect of engraving and milling mold of rock plate
CN113526869A (en) * 2021-09-13 2021-10-22 佛山市东鹏陶瓷有限公司 Pattern mold texture brick with clear mold texture and preparation process thereof
CN113998993A (en) * 2021-10-12 2022-02-01 广东清远蒙娜丽莎建陶有限公司 Carved stone-like ceramic polished tile and preparation method thereof
CN116178050A (en) * 2022-09-07 2023-05-30 佛山市东鹏陶瓷有限公司 Preparation method of glaze with flash dry grain effect, brick and application thereof

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CN113248150A (en) * 2021-06-22 2021-08-13 佛山市东鹏陶瓷发展有限公司 Engraving protection glaze and ceramic tile capable of improving engraving depth and preparation method thereof
CN113321536A (en) * 2021-07-07 2021-08-31 肇庆市将军陶瓷有限公司 Preparation process for imitating effect of engraving and milling mold of rock plate
CN113526869A (en) * 2021-09-13 2021-10-22 佛山市东鹏陶瓷有限公司 Pattern mold texture brick with clear mold texture and preparation process thereof
CN113526869B (en) * 2021-09-13 2021-12-28 佛山市东鹏陶瓷有限公司 Pattern mold texture brick with clear mold texture and preparation process thereof
CN113998993A (en) * 2021-10-12 2022-02-01 广东清远蒙娜丽莎建陶有限公司 Carved stone-like ceramic polished tile and preparation method thereof
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