CN112335672A - Pesticide composition for increasing soluble solid of citrus - Google Patents
Pesticide composition for increasing soluble solid of citrus Download PDFInfo
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- CN112335672A CN112335672A CN202011513340.6A CN202011513340A CN112335672A CN 112335672 A CN112335672 A CN 112335672A CN 202011513340 A CN202011513340 A CN 202011513340A CN 112335672 A CN112335672 A CN 112335672A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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Abstract
The invention relates to a pesticide composition for increasing soluble solid of citrus, which solves the problem that the soluble solid of fruits is difficult to improve in 1-3 months before the citrus is ripe and picked due to overcast and rainy days, little illumination and low-temperature weather, and comprises the following components in percentage by weight: 1-20% of a solvent, 0.5-30% of guanidinoacetic acid, 0.05-10% of strigolactone, and a surfactant: 0.5-10% of synergist, 0.5-10% of water and the balance of water, wherein the synergist is mixed powder of alginate oligosaccharides and rutin in a weight ratio of 1: 8-12. The soluble solid content of the citrus is improved by 1.7-2.4%.
Description
Technical Field
The invention relates to a pesticide composition for increasing soluble solids of citrus, belonging to the field of plant growth regulators.
Background
Citrus quality is a complex of multiple factors, including appearance quality, flavor quality, nutritional quality, processing quality, and storage quality. Among a plurality of quality factors, the appearance and the flavor quality are most important, the color and the taste of fruits are the most important, the taste of citrus varieties and soluble solid matters of the citrus are in a positive relationship, the content of the soluble solid matters is higher, the taste sweetness of the citrus is higher, and the solid-acid ratio is higher, so that before harvest in the field, growers generally adopt a handheld sugar meter to test the soluble solid matters of the citrus to judge whether the soluble solid matters meet the harvest standard, meanwhile, the level of the soluble solid matters of the citrus is directly related to the coloring degree of the fruits, only when the accumulation of the soluble solid matters of the fruits meets the specified requirements, the taste sweetness and the sugar-acid ratio are high, the highest economic benefit can be obtained, otherwise, only the cost can be reduced, the citrus varieties sold in autumn and winter in southwest areas, such as love, navel orange, blood orange and the like, are always rainy 1-3 months before mature, in low-illumination and low-temperature weather, sufficient illumination and temperature are not available, the soluble solid matters of the fruits are difficult to be rapidly improved by means of conventional application of potassium dihydrogen phosphate or potassium sulfate or benzylaminopurine for compounding kasugamycin, the time of marketing can be delayed, meanwhile, the color and luster of the fruits are also influenced due to the side effect that the fruits turn green caused by improper use of benzylaminopurine, the influence on the commodity value of the fruits is serious, and the influence on the economic benefit of growers is huge. The traditional pesticide for increasing the soluble solid of the citrus is diluted 1000 times by monopotassium phosphate or 1000 times by potassium sulfate or 1000 times by 2% benzylaminopurine and 7.5% kasugamycin, the pesticide application period is 1 month before harvest, and the mode of uniformly spraying the leaf surface is adopted.
Disclosure of Invention
The invention aims to provide the pesticide composition for increasing the soluble solid content of the citrus, which can quickly increase the soluble solid content of the citrus, increase the solid-acid ratio, improve the sweetness of the citrus in taste, is not influenced by weather, is safe and environment-friendly and has low cost.
The purpose of the invention is realized by the following steps:
the pesticide composition for increasing soluble solids of citrus comprises the following components in percentage by weight:
0.5 to 30 percent of guanidinoacetic acid,
0.05 to 10 percent of strigolactone,
1 to 20 percent of solvent
Surfactant (b): 0.5 to 10 percent of the total weight of the composition,
0.5 to 10 percent of synergist,
the balance of water.
The synergist is mixed powder of brown algae oligosaccharide and rutin in the weight ratio of 1: 8-12.
The pesticide composition for increasing the soluble solids of the citrus comprises the following components in percentage by weight:
1 to 20 percent of guanidinoacetic acid,
0.1 to 5 percent of strigolactone,
1 to 10 percent of solvent
Surfactant (b): 1 to 5 percent of the total weight of the steel,
0.5 to 3 percent of synergist,
the balance of water.
The solvent is at least one of ethylene glycol, dimethyl sulfoxide and N-methyl pyrrolidone.
The surfactant is at least one of sodium dodecyl benzene sulfonate, lauryl betaine and fatty alcohol-polyoxyethylene ether.
The pesticide composition for increasing the soluble solid content of the citrus is a liquid agent.
The pesticide composition for increasing the soluble solids of the citrus is prepared by the following steps: the strigolactone and the synergist are dissolved by a solvent, the guanidinoacetic acid is dissolved by water, then the mixture is mixed, the surfactant is added, and the mixture is stirred and mixed evenly, so that the pesticide composition for increasing the soluble solid of the citrus can be prepared.
The types of the oranges are as follows: pretty girl, navel orange and blood orange.
Guanidinoacetic acid is a functional promoter, and guanidinoacetic acid is a precursor of creatine. Creatine phosphate containing high phosphate group transfer potential is widely present in muscle and nerve tissues and is a main energy supply substance in animal muscle tissues. The glycocyamine is additionally added, so that the body generates a large amount of phosphate group transfer substances (phosphocreatine), thereby providing power for high-efficiency work of tissues such as muscles, brains, gonads and the like and promoting energy to be continuously distributed into the muscle tissues.
Strigolactone is a novel phytohormone, which inhibits the growth of branches and lateral buds of plants, and it controls the amount of branches or tillering of plants in cooperation with auxin and cytokinin. The strigolactone, a carotenoid derivative produced at the roots of plants, can promote the symbiotic action of plants and soil microorganisms and promote the branching of arbuscular mycorrhiza and fungal hyphae. The strigolactone induces parasitic plants such as striga asiatica of striga asiatica and broomrape seeds of broomrape to germinate, and in addition, the strigolactone has cross with an important signal substance ABA for stress resistance of plants on a pathway, and the strigolactone is probably an important node substance in a plant hormone regulation network and is known as 7 th major plant hormone.
Rutin is one of vitamin P, is glycoside of dehydroflavonone, can participate in vivo oxidoreductase, and can enhance vitamin C function and promote its accumulation in vivo.
The brown algae oligosaccharide is formed by connecting beta-D-mannuronic acid and alpha-L-guluronic acid through 1-4 glycosidic bonds, has wide biological activity, has the effects of promoting plant growth, relieving plant abiotic stress, resisting tumors, inhibiting bacteria and the like, and has wide prospects in the fields of green agriculture, medical care and the like.
During the mature period of the citrus, a large amount of accumulated nutrient substances are required to be transported to fruit parts to promote the accumulation of soluble solid matters of the fruits and promote sugar increasing and coloring, in the southwest area of China in autumn and winter, in rainy days and low-temperature days, the accumulation of photosynthesis is less, so that the accumulation speed of the soluble solid matters of the citrus is greatly reduced, guanidinoacetic acid is used as a functional nutrient promoter, the nutrient substances absorbed by plants can be rapidly transported to the required parts, and the use of strigolactone can inhibit the growth of branches and lateral buds of the plants. In autumn and winter, a large amount of new tips of citrus are extracted and sent out, in the process of nutrition transfer, a large amount of nutrient substances can be wasted by the new tips, the cumulant at fruit parts is reduced, the effect cannot be achieved, the germination of the new tips can be well controlled, the effect of glycocyamine is maximized, most of the nutrient substances are transferred to the fruit parts, the synergistic effect of rutin in rapidly increasing vitamin C accumulation and alginate oligosaccharide stress resistance and promoting plant absorption and growth is combined, the soluble solid matter of the citrus can be rapidly increased in the mature period, the mouthfeel and sweetness of the citrus are greatly increased, the conversion of titratable acid to reducing sugar is improved, the content of titratable acid is greatly reduced, the solid acid ratio is improved, the fruit quality is improved, and the economic benefit of farmers is increased.
The pesticide composition for increasing soluble solid content of citrus can rapidly increase the soluble solid content of citrus at the mature period of the citrus, improve the solid-acid ratio, improve the sweetness of the citrus taste, and is not influenced by climate.
Detailed description of the preferred embodiments
Example 1:
this example 1 provides a pesticide composition for increasing citrus soluble solids, comprising, by weight: 0.5% of guanidinoacetic acid, 0.05% of strigolactone, 0.5% of synergist, 1% of sodium dodecyl benzene sulfonate, 2% of dimethyl sulfoxide and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
Example 2:
this example 2 provides a pesticide composition for increasing citrus soluble solids, comprising, by weight: 5% of guanidinoacetic acid, 0.1% of strigolactone, 1% of synergist, 2% of lauryl betaine, 2% of dimethyl sulfoxide, 1% of glycol and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 11.
Example 3:
this example 3 provides a pesticide composition for increasing citrus soluble solids, comprising, by weight: 10% of guanidinoacetic acid, 0.2% of strigolactone, 1.5% of synergist, 2% of lauryl betaine, 1% of sodium dodecyl benzene sulfonate, 2% of dimethyl sulfoxide, 1% of glycol, 1% of N-methylpyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
Example 4:
this example 4 provides a pesticide composition for increasing citrus soluble solids, comprising, by weight: 15% of guanidinoacetic acid, 0.5% of strigolactone, 2% of synergist, 2% of lauryl betaine, 2% of fatty alcohol-polyoxyethylene ether, 5% of dimethyl sulfoxide, 1% of ethylene glycol, 1% of N-methyl pyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
Example 5:
this example 5 pesticide composition for increasing citrus soluble solids, comprising by weight: 20% of guanidinoacetic acid, 1% of strigolactone, 2.5% of a synergist, 2% of lauryl betaine, 2% of fatty alcohol-polyoxyethylene ether, 1% of sodium dodecyl benzene sulfonate, 5% of dimethyl sulfoxide, 2% of ethylene glycol, 1% of N-methyl pyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin in the weight ratio of 1: 12.
Example 6:
this example 6 provides a citrus soluble solids-enhanced pesticide composition, comprising, by weight: 22% of guanidinoacetic acid, 5% of strigolactone, 2.5% of a synergist, 2% of lauryl betaine, 2% of fatty alcohol-polyoxyethylene ether, 1% of sodium dodecyl benzene sulfonate, 10% of dimethyl sulfoxide, 2% of ethylene glycol, 1% of N-methyl pyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin in the weight ratio of 1: 9.
Example 7:
this example 7 pesticide composition for increasing citrus soluble solids, comprising by weight: 25% of guanidinoacetic acid, 7% of strigolactone, 5% of a synergist, 3% of lauryl betaine, 2% of fatty alcohol-polyoxyethylene ether, 1% of sodium dodecyl benzene sulfonate, 5% of dimethyl sulfoxide, 2% of ethylene glycol, 10% of N-methylpyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
Example 8:
this example 8 provides a pesticide composition for increasing citrus soluble solids, comprising, by weight: 26% of guanidinoacetic acid, 8% of strigolactone, 8% of synergist, 3% of lauryl betaine, 4% of fatty alcohol-polyoxyethylene ether, 1% of sodium dodecyl benzene sulfonate, 5% of dimethyl sulfoxide, 1% of ethylene glycol, 10% of N-methylpyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 8.
Example 9:
this example 9 shows a pesticide composition for increasing citrus soluble solids, comprising, by weight: 28% of guanidinoacetic acid, 9% of strigolactone, 9% of synergist, 3% of lauryl betaine, 5% of fatty alcohol-polyoxyethylene ether, 1% of sodium dodecyl benzene sulfonate, 6% of dimethyl sulfoxide, 2% of ethylene glycol, 10% of N-methylpyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
Example 10:
this example 10 provides a pesticide composition for increasing citrus soluble solids, comprising, by weight: 30% of guanidinoacetic acid, 10% of strigolactone, 10% of synergist, 3% of lauryl betaine, 5% of fatty alcohol-polyoxyethylene ether, 2% of sodium dodecyl benzene sulfonate, 6% of dimethyl sulfoxide, 4% of ethylene glycol, 10% of N-methylpyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
Test examples
Comparative example B is the citrus soluble solids enhanced pesticide composition of example 4 above, in weight percent: 15% of guanidinoacetic acid, 0.5% of strigolactone, 2% of synergist, 2% of lauryl betaine, 2% of fatty alcohol-polyoxyethylene ether, 5% of dimethyl sulfoxide, 1% of ethylene glycol, 1% of N-methyl pyrrolidone and the balance of water. The synergist is mixed powder of brown algae oligosaccharide and rutin with the weight percentage of 1: 10.
The 16 comparative examples A to S including the citrus soluble solids-increased pesticidal composition (B) obtained in example 4 were subjected to experimental comparison on two citrus varieties of pretty girl 38 and Citrus aurantium of Taruoke family.
The test is respectively carried out in the Qigong of Sichuan province and Qin of Yuan of city of Sichuan province and the Xueyang industry park of Sichuan province. 114 citrus trees with consistent growth conditions are respectively selected from each variety in an industrial park, 19 treatments are counted by A-S, the comparison test is repeated for three times, two trees with different varieties are treated each time, and nineteen comparison examples are as follows: a: clear water control; b: example 4 above was diluted 500 times (guanidinoacetic acid 300ppm + monolaurate 10ppm + synergist 40 ppm); c: 15% guanidinoacetic acid dilution 500-fold (guanidinoacetic acid 300 ppm); d: diluting 0.5% of strigolactone 500 times (strigolactone 10 ppm); e: 2% synergist is diluted 500 times (synergist 40 ppm); f: 15% guanidinoacetic acid +0.5% strigolactone (300 ppm guanidinoacetic acid + 10ppm strigolactone); g: diluting 500 times by 15% of guanidinoacetic acid and 2% of synergist (300 ppm of guanidinoacetic acid and 40ppm of synergist); h: diluting by 500 times (10 ppm of strigolactone and 40ppm of synergist) with 0.5% of strigolactone and 2% of synergist; i: 15% guanidinoacetic acid +0.5% monolaurate +0.18% alginate-derived oligosaccharide (300 ppm guanidinoacetic acid + 10ppm monolaurate + 3.6ppm alginate-derived oligosaccharide); j: diluting with 15% guanidinoacetic acid, 0.5% strigolactone and 1.82% rutin for 500 times (guanidinoacetic acid 300ppm, strigolactone 10ppm and rutin 36.4 ppm); k: 0.18% brown alginate oligosaccharide is diluted 500 times (brown alginate oligosaccharide 3.6 ppm); l: diluting 1.82% rutin 500 times (rutin 36.4 ppm); m: diluting with 15% guanidinoacetic acid +0.18% alginate-derived oligosaccharide 500 times (guanidinoacetic acid 300ppm + alginate-derived oligosaccharide 3.64 ppm); n: 15% guanidinoacetic acid +1.82% rutin (guanidinoacetic acid 300ppm + rutin 36.4 ppm); o: diluting 0.5% of strigolactone and 0.18% of alginate-derived oligosaccharide by 500 times (strigolactone 10ppm and alginate-derived oligosaccharide 3.64 ppm); p: 0.5% of strigolactone +1.82% of rutin (strigolactone 10ppm + rutin 36.4 ppm); q: diluting potassium dihydrogen phosphate 1000 times; r: diluting potassium sulfate 1000 times; s: 2% benzylaminopurine +7.5% kasugamycin diluted 1000-fold (benzylaminopurine 20ppm + kasugamycin 75 ppm).
The comparative test is repeated for three times, the application period is 1 month before the harvest, the uniform spraying mode of the leaf surface is adopted, the application time of pretty girl 38 is about 9 months 25, the application time of the taro blood orange is about 12 months 5, and the test is carried out for two consecutive years. And selecting fruits with consistent quantity according to the orientation in each comparative example, testing the soluble solids of the fresh citrus fruits according to GB/T8210-2011, and then averaging.
And (3) test results:
1. the effect of different agents on the different kinds of soluble solid in Sichuan province, different kinds of city, different kinds of girls 38 (see Table 1)
TABLE 1 Effect of different agent treatments on pretty quality 38 soluble solids
2.
3. The effect of two consecutive years of different drug treatments on the soluble solid content of blood orange of Tarocco, Zhongzhong, Sichuan province (see Table 2)
TABLE 2 Effect of different drug treatments on the soluble solids of blood oranges of Taruoke
As can be seen from tables 1 and 2, the pesticide composition B for increasing soluble solids of citrus is diluted 1000 times more than potassium dihydrogen phosphate or potassium sulfate or 2% benzylaminopurine +7.5% kasugamycin of the background art, and increases the soluble solids of citrus by 1.7-2.4%, and in terms of soluble solids of fruits, the difference of 1 percentage point is significant difference, and the pesticide composition for increasing soluble solids of citrus has significant difference in taste compared with the control example. Through two years of continuous comparative tests, the pesticide composition for increasing the soluble solid content of the citrus is very stable in effect, has a remarkable effect on improving the quality of citrus fruits, and can remarkably increase the economic benefit of farmers.
The above embodiments are further illustrative of the present invention, but it should not be construed that the scope of the above subject matter is limited to the above embodiments. All the technologies realized based on the above contents belong to the scope of the present invention.
Claims (7)
1. The pesticide composition for increasing the soluble solids of the citrus is characterized by comprising the following components in percentage by weight:
1 to 20 percent of solvent
0.5 to 30 percent of guanidinoacetic acid,
0.05 to 10 percent of strigolactone,
surfactant (b): 0.5 to 10 percent of the total weight of the composition,
0.5 to 10 percent of synergist,
the balance of water is water,
the synergist is mixed powder of brown algae oligosaccharide and rutin in the weight percentage of 1 (8-12).
2. The citrus soluble solids increasing pesticide composition as set forth in claim 1, comprising in weight percent:
1 to 20 percent of guanidinoacetic acid,
0.1 to 5 percent of strigolactone,
1 to 10 percent of solvent
Surfactant (b): 1 to 5 percent of the total weight of the steel,
0.5 to 3 percent of synergist,
the balance of water.
3. A citrus soluble solids increasing pesticide composition as set forth in claim 1 or claim 2 wherein said solvent is at least one of ethylene glycol, dimethyl sulfoxide, and N-methyl pyrrolidone.
4. A citrus soluble solids increasing pesticidal composition according to claim 1 or claim 2 wherein said surfactant is at least one of sodium dodecyl benzene sulfonate, lauryl betaine and fatty alcohol polyoxyethylene ether.
5. A citrus soluble solids increasing pesticidal composition according to claim 1 or claim 2 wherein the citrus soluble solids increasing pesticidal composition is a liquid formulation.
6. A citrus soluble solids increasing pesticide composition as claimed in claim 1 or claim 2, prepared by a process comprising: the strigolactone and the synergist are dissolved by a solvent, the guanidinoacetic acid is dissolved by water, then the mixture is mixed, the surfactant is added, and the mixture is stirred and mixed evenly, so that the pesticide composition for increasing the soluble solid of the citrus can be prepared.
7. A citrus soluble solids increasing pesticide composition as claimed in claim 1 or claim 2 wherein the citrus species is: pretty girl, navel orange and blood orange.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114605192A (en) * | 2022-03-18 | 2022-06-10 | 新洋丰农业科技股份有限公司 | Fertilizer biological synergistic additive for promoting color change and preparation method thereof |
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| CN111990546A (en) * | 2020-08-17 | 2020-11-27 | 固安君德同创生物工程有限公司 | Composition of guanidinoacetic acid and synergist thereof, preparation method and application |
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2020
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| CN106818751A (en) * | 2015-12-04 | 2017-06-13 | 中国科学院大连化学物理研究所 | A kind of plant flower and fruit protector of wide spectrum and its application |
| CN110352977A (en) * | 2019-08-27 | 2019-10-22 | 四川省兰月科技有限公司 | Composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid |
| CN111990546A (en) * | 2020-08-17 | 2020-11-27 | 固安君德同创生物工程有限公司 | Composition of guanidinoacetic acid and synergist thereof, preparation method and application |
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| 袁飞荣等: "枳橙CPMAX2基因的克隆、载体构建及其表达研究 ", 《武汉生物工程学院学报》 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114605192A (en) * | 2022-03-18 | 2022-06-10 | 新洋丰农业科技股份有限公司 | Fertilizer biological synergistic additive for promoting color change and preparation method thereof |
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