CN110352977A - Composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid - Google Patents
Composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid Download PDFInfo
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- CN110352977A CN110352977A CN201910793358.7A CN201910793358A CN110352977A CN 110352977 A CN110352977 A CN 110352977A CN 201910793358 A CN201910793358 A CN 201910793358A CN 110352977 A CN110352977 A CN 110352977A
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- China
- Prior art keywords
- chloropyuril
- aminobutyric acid
- angle gold
- gold lactone
- composition pesticide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Composition pesticide of the present invention containing chloropyuril, only angle gold lactone and γ-aminobutyric acid, includes: chloropyuril 0.05%~10% by weight percentage, only angle gold lactone 0.001~1%, γ-aminobutyric acid 0.05%~5%, auxiliary agent 0.5%~10%, solvent 10%~40%, water surplus.The present invention can significantly improve Kiwi berry mean fruit weight, dramatically increase per mu yield economic value, significantly improve normal temperature storage stability, can spray.
Description
Technical field
The invention belongs to plant growth regulator field, in particular to a kind of pyrrole containing chlorine significantly increased production for Kiwi berry
The composition pesticide of urea, only angle gold lactone and γ-aminobutyric acid.
Background technique
Kiwi berry just can enter normal Fruit Development Process after normal Pollination Fertilization.The development of kiwifruit fruit
Generally need 140~180 days, there are three the apparent stage, May early and middle ten days bear fruit after to mid-June be fast growing period, this phase fruit
Real volume and fresh weight can increase to the 70%~80% of the maturity period；It hereafter is slow growth period, from mid or late June to August early and middle ten days,
The speed of growth of this phase fruit slows down, even stops growing, and late August to harvesting is faint growth period, this phase fruit growth amount
Very little, but the concentration of nutriment improves quickly.Kiwi berry can promote fruit using growth regulator in fast growing period
Development, expands fruit, and conventional use of regulator is 0.1% chloropyuril soluble liquid.The recommended by routine usage of chloropyuril is leaching
Fruit, although the weight of fruit can be improved largely, the duration of whole drug effect only maintains fast growing period,
Crop in slow growth period is little, and heart Kiwi berry green for Hayward, Xu Xiang, Qin Mei etc. etc. is by output increased commodity value
For Kiwi berry, mean fruit weight is not promoted significantly, and per mu yield economic value will decline.If using ultrahigh concentration
Processing young fruit increases the way of yield with this, and the normal temperature storage stability of Kiwi berry can be made to decline, influence commodity value.
Summary of the invention
In order to overcome the above shortcomings, it is an object of the present invention to provide one kind can significantly improve Kiwi berry mean fruit weight,
Dramatically increase per mu yield economic value, it is significantly improving normal temperature storage stability, can spray containing chloropyuril, only angle gold lactone and
The composition pesticide of γ-aminobutyric acid.
The object of the present invention is achieved like this:
Composition pesticide of the present invention containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes with the following group by weight percentage
Point:
Chloropyuril 0.05%~10%,
Only angle gold lactone 0.001~1%,
γ-aminobutyric acid 0.05%~5%,
Auxiliary agent 0.5%~10%,
Solvent 10%~40%,
Water surplus.
The above-mentioned composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid include by weight percentage with
Lower component:
Chloropyuril 0.1%~1%,
Only angle gold lactone 0.05~0.5%,
γ-aminobutyric acid 0.05%~2%,
Auxiliary agent 5%~8%,
Solvent 10%~30%,
Water surplus.
Above-mentioned auxiliary agent is lauryl sodium sulfate, fatty alcohol polyoxyethylene ether, Aceonon 300 MO, polyoxyethylene
At least one of sorbitan mono-laurate.
Above-mentioned solvent is ethyl alcohol, dimethyl sulfoxide, cyclohexanone, dimethylformamide, ethylene glycol, at least one in glycerine
Kind.
The above-mentioned composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid is liquid preparation.
The preparation method of composition pesticide of the present invention containing chloropyuril, only angle gold lactone and γ-aminobutyric acid: first by chlorine pyrrole
Urea and only angle gold lactone are individually dissolved with solvent, and γ-aminobutyric acid is first dissolved with a small amount of water, are then mixed the two, are added
Auxiliary agent, water, which is supplied, to be mixed evenly.
Chloropyuril is the plant growth regulator that a kind of substituted urea class has kinetin effect, can via root, stem, leaf, flower,
Fruit absorbs, and then transports to the position worked.Major physiological effect is to promote cell division, increases cell quantity, increases fruit
It is real, improve pollen can pregnant property, be allowed to be easy pollination, it is mesh that inducing moiety fruit tree parthenocarpy promotion, which bears fruit, improves fruit quality,
Before deposit into a kind of highest artificial synthesized hormone of cell division activity.Only angle gold lactone is a Plant Hormone of discovered in recent years
Or its precursor, it is able to suppress the growth of the branch and lateral bud of plant, it and auxin and basic element of cell division Collaborative Control plant
Branch (Tiller) quantity.As a kind of carotenoid derivatives for resulting from plant root, only angle gold lactone can promote plant
With the synbiosis of edaphon.γ-aminobutyric acid is widely present in animal and plant body, is critically important in central nervous system
Inhibitory neurotransmitter, it is a kind of naturally occurring non-protein composition amino acid, has extremely important physiological function, its energy
The reactivity for promoting brain, delays brain aging function.It can by reduce animal unintentional motion, to reduce energy consumption, from
And reach somatotrophic purpose.Gabanergic promotes the secretion of animal gastric juice and growth hormone, to improve the speed of growth
And feed intake；The feeding maincenter of the excited animal of energy, to increase feed intake.
In the growth course of the green heart Kiwi berry such as Hayward, Xu Xiang, Qin Mei, chloropyuril product routine average fruit is not used
Weight is in 80~90g or so, using average fruit weight conventional after chloropyuril product in 120~130g or so, for economy
It is worth for relatively low green heart Kiwi berry, perfect condition is much not achieved in per mu yield value.It is studied by the practical exploration of many years,
In the application process of chloropyuril, by introducing γ-aminobutyric acid, activity of the activation chloropyuril in Kiwi berry is played, is prolonged
It is grown in the function and effect of Kiwi berry fast growing period, it is made still to maintain relatively high activity, while energy in slow growth period
Promote plant to generate more growth hormone both to increase in conjunction with the synergistic effect of only angle gold lactone and auxin and the basic element of cell division
The strong bioactivity of the basic element of cell division, and stimulate and generate more growth hormone inside crop, thus swollen in kiwifruit fruit
Broad aspect plays very good effect, and also plays good effect to the normal temperature storage of Kiwi berry.
Composition pesticide of the present invention containing chloropyuril, only angle gold lactone and γ-aminobutyric acid, can be with by effectively arranging in pairs or groups
Realization sprays use, and the usage of chloropyuril product routine is leaching fruit, according to the speed of conventional leaching fruit, can only soak fruit for each person every day
1.5 mu of ground, and after composition pesticide of the present invention containing chloropyuril, only angle gold lactone and γ-aminobutyric acid is by effectively cooperateing with, it adopts
It is average to spray 10 mu of ground or more for each person every day with spraying mode, the cost of labor during medication is effectively reduced, together
When by the synergy between three, Kiwi berry mean fruit weight can be significantly improved, dramatically increase per mu yield economic value, it is aobvious
Writing improves normal temperature storage stability.
Specific embodiment
Embodiment 1:
Composition pesticide of the present embodiment 1 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid include by weight percentage
0.05% chloropyuril, 0.001% only angle gold lactone, 0.05% γ-aminobutyric acid, 0.5% lauryl sodium sulfate, 10% ethyl alcohol, more than water
Amount.
Embodiment 2:
Composition pesticide of the present embodiment 2 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid include by weight percentage
0.1% chloropyuril, 0.5% only angle gold lactone, 1% γ-aminobutyric acid, 8% polyoxyethylene 20 sorbitan monolaurate, 20% second
Alcohol, water surplus.
Embodiment 3:
Composition pesticide of the present embodiment 3 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 1% by weight percentage
Chloropyuril, 0.7% only angle gold lactone, 2% γ-aminobutyric acid, 2% polyoxyethylene 20 sorbitan monolaurate, 4% poly alkyl alcohol
Ethylene oxide ether, 10% ethyl alcohol, 15% cyclohexanone, water surplus.
Embodiment 4:
Composition pesticide of the present embodiment 4 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 2% by weight percentage
Chloropyuril, 0.8% only angle gold lactone, 4% γ-aminobutyric acid, 2% polyoxyethylene 20 sorbitan monolaurate, 4% poly alkyl alcohol
Ethylene oxide ether, 3% Aceonon 300 MO, 10% dimethyl sulfoxide, 15% cyclohexanone, 5% ethylene glycol, water surplus.
Embodiment 5:
Composition pesticide of the present embodiment 5 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 5% by weight percentage
Chloropyuril, 0.5% only angle gold lactone, 3% γ-aminobutyric acid, 2% polyoxyethylene 20 sorbitan monolaurate, 5% poly alkyl alcohol
Ethylene oxide ether, 2% Aceonon 300 MO, 15% dimethyl sulfoxide, 15% cyclohexanone, 5% ethylene glycol, water surplus.
Embodiment 6:
Composition pesticide of the present embodiment 6 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 6% by weight percentage
Chloropyuril, 0.8% only angle gold lactone, 4% γ-aminobutyric acid, 10% fatty alcohol polyoxyethylene ether, 10% dimethyl sulfoxide, 15% hexamethylene
Ketone, 10% ethyl alcohol, water surplus are supplied.
Embodiment 7:
Composition pesticide of the present embodiment 7 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 7% by weight percentage
Chloropyuril, 1% only angle gold lactone, 5% γ-aminobutyric acid, 10% polyoxyethylene 20 sorbitan monolaurate, 10% diformazan are sub-
Sulfone, 30% ethylene glycol, water surplus.
Embodiment 8:
Composition pesticide of the present embodiment 8 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 10% by weight percentage
Chloropyuril, 0.8% only angle gold lactone, 3% γ-aminobutyric acid, 10% polyoxyethylene 20 sorbitan monolaurate, 10% dimethyl
Formamide, 15% cyclohexanone, 15% ethylene glycol, water surplus.
Embodiment 9:
Composition pesticide of the present embodiment 9 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid include by weight percentage
0.5% chloropyuril, 0.005% only angle gold lactone, 2% γ-aminobutyric acid, 1% polyoxyethylene 20 sorbitan monolaurate, 4% rouge
Fat alcohol polyoxyethylene ether, 3% Aceonon 300 MO, 10% dimethyl sulfoxide, 15% cyclohexanone, 6% ethylene glycol, water surplus.
Embodiment 10:
Composition pesticide of the present embodiment 10 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid include by weight percentage
0.8% chloropyuril, 0.01% only angle gold lactone, 1% γ-aminobutyric acid, 10% fatty alcohol polyoxyethylene ether, 25% glycerine, more than water
Amount.
Embodiment 11:
Composition pesticide of the present embodiment 11 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes 1% by weight percentage
Chloropyuril, 1% only angle gold lactone, 0.5% γ-aminobutyric acid, 8% Aceonon 300 MO, 10% dimethyl sulfoxide, 15% cyclohexanone,
5% glycerine, water surplus.
Embodiment 12:
Composition pesticide of the present embodiment 12 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid include by weight percentage
0.5% chloropyuril, 0.05% only angle gold lactone, 0.08% γ-aminobutyric acid, 3% polyoxyethylene 20 sorbitan monolaurate, 4%
Fatty alcohol polyoxyethylene ether, 3% Aceonon 300 MO, 10% dimethyl sulfoxide, 15% cyclohexanone, 15% ethyl alcohol, water surplus.
Application example:
By obtained in above-described embodiment 2 containing composition pesticide (0.1% chlorine of chloropyuril, only angle gold lactone and γ-aminobutyric acid
Only+1% γ-aminobutyric acid of angle gold lactone of pyrrole urea+0.5%) it can with commercially available 0.1% chloropyuril soluble concentrate, 0.5% only angle gold lactone
Solution, 1% γ-aminobutyric acid aqua carry out comparative test in tri- Qin Mei, extra large water, Xu Xiang kinds respectively.Test difference
It is carried out in Kiwi berry industrial zone in Shaanxi week to, Mei County.Each kind chooses growing state always respectively in industrial zone
60 plants of actinidia tree, 10 processing, in triplicate, two plants of every replicated plot tree, ten processing random alignments.Processing setting
Are as follows: A: clear water control；B: above-described embodiment 2 dilutes 100 times and sprays (the only angle gold lactone 50ppm+ gamma-amino of chloropyuril 10ppm+
Butyric acid 100ppm)；C: commercially available 0.1% chloropyuril dilutes 100 times of leaching fruits (chloropyuril 10ppm)；D: commercially available 0.1% chloropyuril dilution
100 times spray (chloropyuril 10ppm)；The only angle gold lactone of E:0.5% dilutes 100 times and sprays (only angle gold lactone 50ppm)；F:1% γ-
Aminobutyric acid dilutes 100 times and sprays (γ-aminobutyric acid 100ppm)；G: commercially available 0.1% chloropyuril and 0.5% only angle gold lactone bucket are mixed
100 times of dilution sprays (the only angle gold lactone 50ppm of chloropyuril 10ppm+)；H: commercially available 0.1% chloropyuril and 1% γ-aminobutyric acid bucket
Mixed 100 times of dilution sprays (chloropyuril 10ppm+ γ-aminobutyric acid 100ppm)；The only angle gold lactone of I:0.5% and 1% gamma-amino fourth
Mixed 100 times of the dilution of sour bucket sprays (only angle gold lactone 50ppm+ γ-aminobutyric acid 100ppm)；J: commercially available 0.5% chloropyuril can solution
100 times of leaching fruits (chloropyuril 50ppm) of dilution agent.
In triplicate, insecticide spraying time is and thanks to spend the 22nd day afterwards, is tested within continuous 2 years.Number is chosen in each reprocessing
The Kiwi berry fruit for measuring consistent (100 or more) measures mean fruit weight, and normal temperature storage stablizes number of days.
Test result:
1. different agents, which are handled continuous 2 years, stablizes number of days to Shaanxi Zhouzhi County Actinidia deliciosacv.Qinmei mean fruit weight, normal temperature storage
Influence (see Table 1):
2. different agents handle the continuous 2 years shadows for stablizing number of days to Shaanxi Mei County Xu Xiang Kiwi berry mean fruit weight, normal temperature storage
Ring (see Table 2):
.
3. different agents, which are handled continuous 2 years, stablizes number of days to Shaanxi Mei County sea water Kiwi berry mean fruit weight, normal temperature storage
Influence (see Table 3):
As can be seen that the composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid can be with from table 1, table 2, table 3
The average fruit weight of Kiwi berry is significantly improved, and there is apparent growth in the time being stored at room temperature.Pass through continuous comparison in 2 years
Test, compared with 0.1% traditional chloropyuril soluble concentrate, first in usage by the way of spraying, significantly reduces
Secondly the recruitment cost in field has a big promotion in terms of mean fruit weight, increases per mu yield economic value, while right
Room temperature, which stores the stable time also, after harvesting apparent extension.
Above-described embodiment is to be further described to above content of the invention, but this should not be interpreted as in the present invention
The range for stating theme is only limitted to above-described embodiment.It is all to be all belonged to the scope of the present invention based on the technology that above content is realized.
Claims (4)
1. the composition pesticide containing chloropyuril, only angle gold lactone and γ-aminobutyric acid includes following components by weight percentage:
Chloropyuril 0.05%~10%,
Only angle gold lactone 0.001~1%,
γ-aminobutyric acid 0.05%~5%,
Auxiliary agent 0.5%~10%,
Solvent 10%~40%,
Water surplus.
2. the composition pesticide according to claim 1 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid, by weight
Percentage includes following components:
Chloropyuril 0.1%~1%,
Only angle gold lactone 0.05~0.5%,
γ-aminobutyric acid 0.05%~2%,
Auxiliary agent 5%~8%,
Solvent 10%~30%,
Water surplus.
3. the composition pesticide according to claim 1 or 2 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid, special
Sign is that auxiliary agent is lauryl sodium sulfate, fatty alcohol polyoxyethylene ether, Aceonon 300 MO, polyoxyethylene sorbitan
At least one of alcohol monolaurate.
4. the composition pesticide according to claim 1 or 2 containing chloropyuril, only angle gold lactone and γ-aminobutyric acid, special
Sign is that solvent is at least one of ethyl alcohol, dimethyl sulfoxide, cyclohexanone, dimethylformamide, ethylene glycol, glycerine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910793358.7A CN110352977B (en) | 2019-08-27 | 2019-08-27 | Pesticide composition containing forchlorfenuron, strigolactone and gamma-aminobutyric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910793358.7A CN110352977B (en) | 2019-08-27 | 2019-08-27 | Pesticide composition containing forchlorfenuron, strigolactone and gamma-aminobutyric acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110352977A true CN110352977A (en) | 2019-10-22 |
| CN110352977B CN110352977B (en) | 2021-03-16 |
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| CN201910793358.7A Active CN110352977B (en) | 2019-08-27 | 2019-08-27 | Pesticide composition containing forchlorfenuron, strigolactone and gamma-aminobutyric acid |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112335672A (en) * | 2020-12-21 | 2021-02-09 | 四川省新兰月生物科技有限公司 | Pesticide composition for increasing soluble solid of citrus |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1907028A (en) * | 2006-08-16 | 2007-02-07 | 牛俊武 | Conditioning agent for improvement of Kiwi berry shape and its preparation process |
| CN107371939A (en) * | 2017-06-13 | 2017-11-24 | 罗忠华 | Planting method for improving yield of kiwi fruits |
-
2019
- 2019-08-27 CN CN201910793358.7A patent/CN110352977B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1907028A (en) * | 2006-08-16 | 2007-02-07 | 牛俊武 | Conditioning agent for improvement of Kiwi berry shape and its preparation process |
| CN107371939A (en) * | 2017-06-13 | 2017-11-24 | 罗忠华 | Planting method for improving yield of kiwi fruits |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112335672A (en) * | 2020-12-21 | 2021-02-09 | 四川省新兰月生物科技有限公司 | Pesticide composition for increasing soluble solid of citrus |
| CN112335672B (en) * | 2020-12-21 | 2021-11-09 | 四川省新兰月生物科技有限公司 | Pesticide composition for increasing soluble solid of citrus |
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| CN110352977B (en) | 2021-03-16 |
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