CN112273710B - Cigarette with porous material for improving cigarette combustion performance and preparation method thereof - Google Patents

Cigarette with porous material for improving cigarette combustion performance and preparation method thereof Download PDF

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Publication number
CN112273710B
CN112273710B CN202011145276.0A CN202011145276A CN112273710B CN 112273710 B CN112273710 B CN 112273710B CN 202011145276 A CN202011145276 A CN 202011145276A CN 112273710 B CN112273710 B CN 112273710B
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cigarette
porous
stage filter
rod
filter stick
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CN112273710A (en
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朱龙杰
张华�
曹毅
孙海平
朱怀远
陈晶波
吴洋
廖惠云
沈晓晨
王瑞
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China Tobacco Jiangsu Industrial Co Ltd
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China Tobacco Jiangsu Industrial Co Ltd
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes

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  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The invention provides a cigarette with a porous material for improving the combustion performance of the cigarette and a preparation method thereof, belonging to the technical field of tobacco preparation. The invention relates to a cigarette for increasing the combustion performance of the cigarette by utilizing a porous material, which comprises a rear-stage filter stick, a front-stage filter stick and a primary cigarette section, wherein the front-stage filter stick and the primary cigarette are wrapped and connected through tipping paper 1 to obtain a second cigarette, the rear-stage filter stick and the second cigarette are wrapped and connected through tipping paper 2, the cigarette further comprises a porous cylindrical rod wrapped in the second cigarette, and the porous cylindrical rod is formed by connecting a plurality of cylindrical rods of which the two ends are in one of a conical shape and a wedge shape in series. The invention rolls and packs the porous material cylinder rod which is full of pores and has high surface area into the cigarette, the porous material cylinder rod penetrates the whole tobacco section and the preceding stage filter rod section, and the cigarette product has small suction resistance, high oxygen content and full combustion of tobacco when being smoked.

Description

Cigarette with porous material for improving cigarette combustion performance and preparation method thereof
Technical Field
The invention belongs to the technical field of tobacco preparation, and particularly relates to a cigarette with a porous material for improving the combustion performance of the cigarette and a preparation method thereof.
Background
At present, two conventional methods for improving the combustion performance of cigarettes are mainly used, wherein the first method is to improve the combustion performance of tobacco shreds by adding feed liquid containing a combustion improver into tobacco leaves, and the second method is to improve the combustion performance of cigarettes by using cigarette paper with high air permeability.
Tobacco leaves with poor combustion performance can increase the number of cigarette suction openings, increase the release amount of tar, and often extinguish cigarettes in static combustion. The combustion improver is used in the cigarette to change the combustion condition of the cigarette to promote the combustion of tobacco shreds, so that the cigarette is fully combusted, the ashing is complete, and the number of suction openings of each cigarette is reduced, thereby reducing the generation amount of smoke particle phase substances (tar) when the cigarette is smoked every time. Meanwhile, the combustion improver can also improve the combustion rate of the cigarettes during static combustion and smoking combustion and reduce the number of smoking openings of the cigarettes. Most of the combustion improvers commonly used in tobacco are alkali metal salts of organic acids, such as potassium tartrate, potassium citrate, sodium citrate, potassium carbonate, etc. However, almost all combustion improvers have various degrees of influence on the smoking taste of cigarettes, and thus the amount thereof to be used needs to be effectively limited.
The static combustion rate of the cigarette can be improved by using the high natural air permeability, the static combustion rate of the cigarette is accelerated along with the increase of the natural air permeability of the cigarette paper, so that the number of suction openings of the cigarette is reduced, the tar content in the smoke is reduced, and when the natural air permeability is increased to 80-100 CU, the static combustion rate of the cigarette is stable and does not influence the static combustion rate of the cigarette any more. When the natural air permeability of the cigarette paper reaches a certain degree, the smoking speed of the cigarettes is reduced, the number of the smoking openings of the cigarettes is increased reversely, and therefore the tar content is increased.
After the cigarette is ignited, carbon is generated at the first end, and the burning solid matter forms a cone, namely a burning cone. During suction, the combustion temperature is highest around the bottom of the combustion cone, most of the air flow passes through the bottom, and a dense and airtight carbonized body is formed in the middle of the combustion cone, and the air flow cannot easily pass through the carbonized body, so that the blockage effect is realized. In this case, combustion mainly occurs around the combustion cone, and combustion is performed under oxygen-rich conditions. And the interior of the combustion cone is effectively an oxygen-free zone throughout the pumping cycle, resulting in a significant increase in the concentration of carbon monoxide in the combustion cone. Meanwhile, insufficient oxygen supply in the combustion cone can cause insufficient combustion, so that a plurality of cracking reactions can occur, a plurality of complex particle-phase substances can be generated, and aromatic hydrocarbons and polycyclic aromatic hydrocarbons can be easily generated.
Disclosure of Invention
In view of the above, the invention provides a cigarette using porous material to increase the combustion performance of the cigarette and a preparation method thereof, wherein a porous material cylindrical rod filled with pores and having a high surface area is rolled and packaged inside the cigarette, the porous material cylindrical rod penetrates through the whole tobacco shred section and the preceding stage filter rod section, and the cigarette has the characteristics of small suction resistance, high oxygen content, sufficient tobacco shred combustion, less generated tar and the like during smoking, thereby effectively solving the defects of large suction resistance, no air circulation, less oxygen content, insufficient tobacco shred combustion, higher tar and harmful component release and the like caused by compact combustion cone of the traditional cigarette during burning and smoking.
The invention relates to a cigarette for increasing the combustion performance of the cigarette by utilizing a porous material, which comprises a rear-stage filter stick, a front-stage filter stick and a primary cigarette section, wherein the front-stage filter stick and the primary cigarette are wrapped and connected through tipping paper 1 to obtain a second cigarette, the rear-stage filter stick and the second cigarette are wrapped and connected through tipping paper 2, the cigarette further comprises a porous cylindrical rod wrapped in the second cigarette, and the porous cylindrical rod is formed by connecting a plurality of cylindrical rods of which the two ends are in one of a conical shape and a wedge shape in series.
Preferably, the material of the porous cylindrical rod is one of a silicon-based porous material and a non-silicon-based porous material.
Preferably, the porous cylindrical rod is one or two of a silicon oxide porous cylindrical rod and an aluminum silicate porous cylindrical rod.
Preferably, the material of the porous cylindrical rod is one or more of metal oxide, phosphate and metal sulfide.
Preferably, the length of the porous cylindrical rod is less than or equal to the sum of the lengths of the preceding stage filter stick and the primary cigarette segment.
Preferably, the post-stage filter stick is one of an acetate fiber filter stick, a polypropylene fiber filter stick and a paper filter stick.
Preferably, the former-stage filter stick is one of an acetate fiber filter stick and a polypropylene fiber filter stick.
Based on the above, the preparation method of the cigarette for improving the combustion performance of the cigarette by using the porous material comprises the following steps:
(1) the tobacco shreds are rolled into a filter-rod-free primary cigarette section by using the cigarette paper, so that fine bamboo sticks, metal wires and other articles can be pre-buried in the tobacco shreds in the process of rolling the tobacco shreds into the filter-rod-free primary cigarette, and after the primary cigarette is made, the pre-buried articles are drawn out to form the primary cigarette with a certain fine cavity;
(2) cutting the cylindrical rod into cylindrical rods with the same length and different widths, and connecting a plurality of cylindrical rods in series to form a plurality of cylindrical rods
The two ends of the porous cylindrical rod can be cut into conical and wedge shapes so as to be connected in series, so that the porous cylindrical rod can be formed by cylindrical rods made of different materials and having different porous properties, thus, the porous cylindrical rods at different positions can have different air-guiding capacities, because the air circulation of the tobacco is poorer at the position closer to the cigarette holder in the smoking process, the air circulation of the internal space of the part close to the cigarette holder is improved, the uniform distribution of the oxygen content can be facilitated, the generation of harmful substances caused by insufficient combustion is avoided, and in addition, the mode of serial splicing is adopted, when the cigarette is burnt, the porous cylindrical rod can fall off one section by one section along with the burning of the cigarette, and a long central rod with temperature cannot be left after the cigarette is completely burnt so as to avoid scalding consumers;
(3) inserting a porous cylindrical rod into the front-stage filter stick and the primary cigarette section, and rolling and connecting through tipping paper 1 to obtain a secondary cigarette, wherein the widths of the porous cylindrical rod from the front-stage filter stick to the primary cigarette section are sequentially reduced;
(4) and (4) using the tipping paper 2 to splice the post-stage filter stick and the secondary cigarette again to finally obtain the cigarette containing the porous cylindrical stick.
The porous cylindrical rod uses the solid porous material which is full of pores and has high surface area to increase and improve the air flow exchange between the inside and the outside of the combustion cone, so that the oxygen content in the combustion cone can be increased, the completeness and the uniformity of the cigarette combustion can be obviously improved, and the release of tar and harmful substances is reduced. In the aspect of improving the combustion performance of cigarette, change the local structure of burning awl (because porous cylinder stick can not burn when cigarette tobacco burns, can rely on porous cylinder stick when the tobacco burns, and the porosity of porous cylinder stick can improve richer oxygen simultaneously, does benefit to the homogeneous combustion, and most air current passes through from the bottom, and burning awl middle part sets up many empty materials, can not form a compact airtight carbide, and the air current can pass through from here), make inside and outside intercommunication, increase inside specific surface area, increase circulation of air and oxygen exchange.
The porous material is a material with a network structure formed by interconnected or closed pores. Compared with continuous medium materials, porous materials generally have the advantages of low relative density, high specific strength, high specific surface area, light weight, sound insulation, heat insulation, good permeability and the like. The porous material has large specific surface area, adsorption capacity and many special properties, and is widely applied to the fields of adsorption, separation, catalysis and the like. The porous material is wrapped in the tobacco shreds, the internal structure of the combustion cone is changed during combustion, the air circulation and the oxygen supply are increased, and the combustion performance of the cigarette is improved.
The cigarette product concept designed by the invention is greatly different from the production mode of the existing commercialized traditional cigarette. Compared with the traditional cigarette, the cigarette product of the invention rolls and packs the porous material cylindrical rod which is filled with pores and has high surface area into the cigarette through a specific procedure, and the porous material cylindrical rod penetrates through the whole cut tobacco section and the preceding stage filter rod section. The cigarette has the characteristics of small resistance to draw, high oxygen content, sufficient combustion of the tobacco shreds, less generated tar and the like when being smoked, and effectively solves the defects of large resistance to draw, no air circulation, low oxygen content, insufficient combustion of the tobacco shreds and higher tar and harmful component release caused by compact combustion cone of the traditional cigarette when being smoked. Meanwhile, many porous materials, such as solid high-temperature resistant materials such as silicon oxide, aluminum silicate, aluminum oxide, titanium dioxide and the like, have the characteristic of not releasing any volatile substances during combustion, and have the characteristics of environmental friendliness, safety, friendliness and the like.
Drawings
Fig. 1 is a schematic structural diagram of a cigarette using a porous material to increase the combustion performance of the cigarette according to an embodiment of the present invention.
Detailed Description
The present invention will be described in detail with reference to specific embodiments.
Example 1
Referring to fig. 1, a cigarette using a porous material to increase the combustion performance of the cigarette comprises a rear-stage filter rod, a front-stage filter rod, a primary cigarette segment, and a second cigarette obtained by wrapping and connecting the front-stage filter rod and the primary cigarette with tipping paper 1, wherein the rear-stage filter rod and the second cigarette are wrapped and connected with tipping paper 2, and the cigarette further comprises a porous cylindrical rod wrapped inside the second cigarette, and the porous cylindrical rod is formed by connecting a plurality of cylindrical rods with two conical ends in series.
The porous cylindrical rod is made of one of a silicon-based porous material and a non-silicon-based porous material, in the embodiment, the porous cylindrical rod can be a silicon oxide porous cylindrical rod, and the length of the porous cylindrical rod is less than or equal to the sum of the lengths of the preceding-stage filter stick and the primary cigarette segment.
The rear-stage filter stick is an acetate fiber filter stick, and the front-stage filter stick is an acetate fiber filter stick.
Based on the above, the preparation method of the cigarette for improving the combustion performance of the cigarette by using the porous material comprises the following steps:
(1) the tobacco shreds are rolled into a filter-rod-free primary cigarette section by using the cigarette paper, so that fine bamboo sticks, metal wires and other articles can be pre-buried in the tobacco shreds in the process of rolling the tobacco shreds into the filter-rod-free primary cigarette, and after the primary cigarette is made, the pre-buried articles are drawn out to form the primary cigarette with a certain fine cavity;
(2) cutting the cylindrical rod into cylindrical rods with the same length and different widths, and connecting a plurality of cylindrical rods in series to form a plurality of cylindrical rods
The porous cylindrical rods can be made of different materials and have different porous properties, so that the porous cylindrical rods at different parts can have different air-guiding capacities, and because the air circulation and the oxygen of the tobacco are poor at the positions closer to the cigarette holder in the smoking process, the air circulation performance of the inner space of the position close to the cigarette holder is improved, the uniform distribution of the oxygen content can be facilitated, and the generation of harmful substances caused by insufficient combustion is avoided;
(3) inserting a porous cylindrical rod into the front-stage filter stick and the primary cigarette section, and rolling and connecting through tipping paper 1 to obtain a secondary cigarette, wherein the widths of the porous cylindrical rod from the front-stage filter stick to the primary cigarette section are sequentially reduced;
(4) and (4) using the tipping paper 2 to splice the post-stage filter stick and the secondary cigarette again to finally obtain the cigarette containing the porous cylindrical stick.
Example 2
Referring to fig. 1, a cigarette using a porous material to increase the combustion performance of the cigarette comprises a rear-stage filter rod, a front-stage filter rod, a primary cigarette segment, and a second cigarette obtained by wrapping and connecting the front-stage filter rod and the primary cigarette with tipping paper 1, wherein the rear-stage filter rod and the second cigarette are wrapped and connected with tipping paper 2, and the cigarette further comprises a porous cylindrical rod wrapped inside the second cigarette, and the porous cylindrical rod is formed by connecting a plurality of cylindrical rods with two wedge-shaped ends in series.
The porous cylindrical rod is made of one of a silicon-based porous material and a non-silicon-based porous material, in the embodiment, the porous cylindrical rod is an aluminum silicate porous cylindrical rod, and the length of the porous cylindrical rod is less than or equal to the sum of the lengths of the preceding-stage filter stick and the primary cigarette segment.
The rear-stage filter rod is a polypropylene filter rod, and the front-stage filter rod is a polypropylene filter rod.
Based on the above, the preparation method of the cigarette for improving the combustion performance of the cigarette by using the porous material comprises the following steps:
(1) the tobacco shreds are rolled into a filter-rod-free primary cigarette section by using the cigarette paper, so that fine bamboo sticks, metal wires and other articles can be pre-buried in the tobacco shreds in the process of rolling the tobacco shreds into the filter-rod-free primary cigarette, and after the primary cigarette is made, the pre-buried articles are drawn out to form the primary cigarette with a certain fine cavity;
(2) the method comprises the following steps of cutting a cylindrical rod into cylindrical rods with the same length and different widths, connecting a plurality of cylindrical rods in series to form a porous cylindrical rod, wherein two ends of the cylindrical rod can be cut into wedges so as to be connected in series, so that one porous cylindrical rod can be composed of cylindrical rods made of different materials and having different porous properties, and the porous cylindrical rods at different positions can have different air drainage capabilities, because the air circulation and the oxygen circulation of tobacco at positions closer to a cigarette holder are poor in the smoking process, the air circulation of the inner space at the positions closer to the cigarette holder can be improved, the uniform distribution of oxygen content can be facilitated, and the generation of harmful substances caused by insufficient combustion can be avoided;
(3) inserting a porous cylindrical rod into the front-stage filter stick and the primary cigarette section, and rolling and connecting through tipping paper 1 to obtain a secondary cigarette, wherein the widths of the porous cylindrical rod from the front-stage filter stick to the primary cigarette section are sequentially reduced;
(4) and (4) using the tipping paper 2 to splice the post-stage filter stick and the secondary cigarette again to finally obtain the cigarette containing the porous cylindrical stick.
Example 3
Referring to fig. 1, a cigarette using a porous material to increase the combustion performance of the cigarette comprises a rear-stage filter rod, a front-stage filter rod, a primary cigarette segment, and a second cigarette obtained by wrapping and connecting the front-stage filter rod and the primary cigarette with tipping paper 1, wherein the rear-stage filter rod and the second cigarette are wrapped and connected with tipping paper 2, and the cigarette further comprises a porous cylindrical rod wrapped inside the second cigarette, and the porous cylindrical rod is formed by connecting a plurality of cylindrical rods with two conical ends in series.
The porous cylindrical rod can be made of a combination of metal oxide and metal sulfide. The length of the porous cylindrical rod is less than or equal to the sum of the lengths of the preceding stage filter stick and the primary cigarette segment.
The post-stage filter stick is a paper filter stick. The front-stage filter stick is an acetate fiber filter stick.
Based on the above, the preparation method of the cigarette for improving the combustion performance of the cigarette by using the porous material comprises the following steps:
(1) the tobacco shreds are rolled into a filter-rod-free primary cigarette section by using the cigarette paper, so that fine bamboo sticks, metal wires and other articles can be pre-buried in the tobacco shreds in the process of rolling the tobacco shreds into the filter-rod-free primary cigarette, and after the primary cigarette is made, the pre-buried articles are drawn out to form the primary cigarette with a certain fine cavity;
(2) the method comprises the following steps of cutting a cylindrical rod into cylindrical rods with the same length and different widths, connecting a plurality of cylindrical rods in series to form a porous cylindrical rod, wherein two ends of the cylindrical rod can be cut into cones so as to be connected in series, so that one porous cylindrical rod can be composed of cylindrical rods with different porous properties and made of different materials, and the porous cylindrical rods at different positions can have different air drainage capacities, because the air circulation of tobacco at a position closer to a cigarette holder in the smoking process is poor and the oxygen is poor, the air circulation of the internal space at a position close to the cigarette holder is improved, so that the uniform distribution of the oxygen content can be facilitated, and the generation of harmful substances caused by insufficient combustion is avoided;
(3) inserting a porous cylindrical rod into the front-stage filter stick and the primary cigarette section, and rolling and connecting through tipping paper 1 to obtain a secondary cigarette, wherein the widths of the porous cylindrical rod from the front-stage filter stick to the primary cigarette section are sequentially reduced;
(4) and (4) using the tipping paper 2 to splice the post-stage filter stick and the secondary cigarette again to finally obtain the cigarette containing the porous cylindrical stick.
Example 4
A cigarette utilizing a porous material to increase cigarette combustion performance comprises a rear-stage filter rod, a front-stage filter rod and a primary cigarette section, wherein the front-stage filter rod and the primary cigarette are wrapped and connected through tipping paper 1 to obtain a second cigarette, the rear-stage filter rod and the second cigarette are wrapped and connected through tipping paper 2, the cigarette further comprises a porous cylindrical rod wrapped inside the second cigarette, and the porous cylindrical rod is formed by serially connecting a plurality of cylindrical rods of which two ends are conical.
The porous cylindrical rod is made of phosphate.
The length of the porous cylindrical rod is less than or equal to the sum of the lengths of the preceding stage filter stick and the primary cigarette segment.
The rear-stage filter stick is an acetate fiber filter stick, and the front-stage filter stick is an acetate fiber filter stick.
Based on the above, the preparation method of the cigarette for improving the combustion performance of the cigarette by using the porous material comprises the following steps:
(1) the tobacco shreds are rolled into a filter-rod-free primary cigarette section by using the cigarette paper, so that fine bamboo sticks, metal wires and other articles can be pre-buried in the tobacco shreds in the process of rolling the tobacco shreds into the filter-rod-free primary cigarette, and after the primary cigarette is made, the pre-buried articles are drawn out to form the primary cigarette with a certain fine cavity;
(2) cutting the cylindrical rod into cylindrical rods with the same length and different widths, and connecting a plurality of cylindrical rods in series to form a plurality of cylindrical rods
The porous cylindrical rods can be made of different materials and have different porous properties, so that the porous cylindrical rods at different parts can have different air-guiding capacities, and because the air circulation and the oxygen of the tobacco are poor at the positions closer to the cigarette holder in the smoking process, the air circulation performance of the inner space of the position close to the cigarette holder is improved, the uniform distribution of the oxygen content can be facilitated, and the generation of harmful substances caused by insufficient combustion is avoided;
(3) inserting a porous cylindrical rod into the front-stage filter stick and the primary cigarette section, and rolling and connecting through tipping paper 1 to obtain a secondary cigarette, wherein the widths of the porous cylindrical rod from the front-stage filter stick to the primary cigarette section are sequentially reduced;
(4) and (4) using the tipping paper 2 to splice the post-stage filter stick and the secondary cigarette again to finally obtain the cigarette containing the porous cylindrical stick.
The present invention is not limited to the above-described specific embodiments, and various modifications and variations are possible. Any modifications, equivalents, improvements and the like made to the above embodiments in accordance with the technical spirit of the present invention should be included in the scope of the present invention.

Claims (7)

1. A cigarette utilizing a porous material to increase the combustion performance of the cigarette is characterized by comprising a rear-stage filter rod, a front-stage filter rod and a primary cigarette section, wherein the front-stage filter rod and the primary cigarette section are wrapped and connected through tipping paper 1 to obtain a second cigarette, the rear-stage filter rod and the second cigarette are wrapped and connected through tipping paper 2, the cigarette further comprises a porous cylindrical rod wrapped inside the second cigarette, the porous cylindrical rod is formed by connecting a plurality of cylindrical rods of which two ends are in one of conical shapes and wedge shapes in series, and the preparation method of the cigarette comprises the following steps:
(1) rolling tobacco shreds into a primary cigarette section without a filter stick by using cigarette paper;
(2) cutting the cylindrical rod into cylindrical rods with the same length and different widths, and connecting a plurality of cylindrical rods in series to form a porous cylindrical rod;
(3) inserting a porous cylindrical rod into the front-stage filter stick and the primary cigarette section, and rolling and connecting through tipping paper 1 to obtain a secondary cigarette, wherein the widths of the porous cylindrical rod from the front-stage filter stick to the primary cigarette section are sequentially reduced;
(4) and (4) using the tipping paper 2 to splice the post-stage filter stick and the secondary cigarette again to finally obtain the cigarette containing the porous cylindrical stick.
2. The cigarette utilizing the porous material to increase the cigarette combustion performance according to claim 1, wherein the porous cylindrical rod is made of one of a silicon-based porous material and a non-silicon-based porous material.
3. The cigarette utilizing the porous material to increase the cigarette combustion performance according to claim 2, wherein the porous cylindrical rod is one or two of a silica porous cylindrical rod and an aluminum silicate porous cylindrical rod.
4. The cigarette utilizing the porous material to increase the cigarette combustion performance according to claim 3, wherein the porous cylindrical rod is made of one or more of metal oxides, phosphates and metal sulfides.
5. The cigarette utilizing the porous material to increase the cigarette combustion performance according to claim 1, wherein the length of the porous cylindrical rod is less than or equal to the sum of the lengths of the preceding stage filter rod and the primary cigarette segment.
6. The cigarette using porous material to increase the cigarette combustion performance according to claim 1, wherein the post-stage filter stick is one of an acetate fiber filter stick, a polypropylene fiber filter stick and a paper filter stick.
7. The cigarette utilizing the porous material to increase the cigarette combustion performance according to claim 6, wherein the pre-stage filter stick is one of an acetate fiber filter stick and a polypropylene fiber filter stick.
CN202011145276.0A 2020-10-23 2020-10-23 Cigarette with porous material for improving cigarette combustion performance and preparation method thereof Active CN112273710B (en)

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CN210017847U (en) * 2019-01-02 2020-02-07 深圳市紫莹新材料科技有限公司 Cigarette filter stick with irritation reducing function

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Publication number Priority date Publication date Assignee Title
US5105835A (en) * 1989-01-25 1992-04-21 Imperial Tobacco, Ltd. Smoking articles
CN1233158A (en) * 1996-10-15 1999-10-27 乐富门·本森及赫奇斯有限公司 Cigarette sidestream smoke and free-burn rate control device
US20050066986A1 (en) * 2003-09-30 2005-03-31 Nestor Timothy Brian Smokable rod for a cigarette
CN106418679A (en) * 2016-10-26 2017-02-22 中国烟草总公司郑州烟草研究院 Cigarette with porous material
CN107048473A (en) * 2017-06-06 2017-08-18 陈绍明 high fuel efficiency cigarette
CN208462945U (en) * 2018-05-03 2019-02-05 韩力 A kind of smoking product with microexplosion micro-capsule
CN210017847U (en) * 2019-01-02 2020-02-07 深圳市紫莹新材料科技有限公司 Cigarette filter stick with irritation reducing function

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