CN112210295A - Water-based ceramic wall cleaning finish paint capable of being drawn and wiped and preparation method thereof - Google Patents
Water-based ceramic wall cleaning finish paint capable of being drawn and wiped and preparation method thereof Download PDFInfo
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- CN112210295A CN112210295A CN202011098141.3A CN202011098141A CN112210295A CN 112210295 A CN112210295 A CN 112210295A CN 202011098141 A CN202011098141 A CN 202011098141A CN 112210295 A CN112210295 A CN 112210295A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
A water-based porcelain wall cleaning finish paint capable of being drawn and wiped mainly comprises the following components: high molecular polymer emulsion, dispersant, defoamer, preservative, antibacterial agent, water, mineral filler, thickener, anti-fouling agent, surface feeling agent and film forming additive. The preparation method comprises the following steps: (1) dispersing high molecular polymer emulsion, water, a dispersing agent, a defoaming agent, a preservative and an antibacterial agent at a low speed; (2) adding a mineral filler; (3) dispersing at high speed until the diameter of the dispersed particles is below 25 μm; (4) adding a thickening agent, an anti-fouling agent, a surface feeling agent and a film-forming assistant for low-speed dispersion; (5) and (5) detecting to be qualified, and filtering to obtain a finished product. The product of the invention has the characteristics that the painting can be drawn on the paint surface by using the water-based pen and can be cleaned by wiping with wet cloth, the paint surface is smooth like the surface of a ceramic tile, the hand feeling is fine and smooth, the highest glossiness can reach 60 degrees, and the antibacterial and pollution-resistant capabilities are strong.
Description
Technical Field
The invention relates to the technical field of water-based wall paint, in particular to water-based ceramic wall paint capable of being drawn and wiped and a preparation method thereof.
Background
At present, the water-based wall paint sold in the market has the advantages of unsmooth surface effect, rough hand feeling, low gloss, darkness and dull luster, no pollution resistance (such as pollution caused by red wine, ketchup, seniority, vinegar, soy sauce and the like), no alcohol and 84 disinfectant resistance, no antibacterial function, no writing or drawing by using a water-based pen on the surface of the water-based wall paint, and no capability of wiping clean handwriting in time.
Disclosure of Invention
Aiming at the defects of the prior art, the technical problem solved by the invention is to provide a water-based wall paint which can be drawn and wiped.
In order to solve the technical problems, the invention adopts the technical scheme that the water-based porcelain wall cleaning finish paint capable of being drawn and wiped mainly comprises the following components in parts by mass:
80-100 parts of high-molecular polymer emulsion,
1-5 parts of a dispersing agent,
0.2 to 3 portions of defoaming agent,
1-5 parts of a preservative agent,
1-5 parts of an antibacterial agent,
1-30 parts of water, namely,
20-40 parts of a mineral filler,
0.5 to 4 portions of thickening agent,
10-30 parts of an anti-fouling agent,
5-20 parts of a surface hand feeling agent,
10-40 parts of a film-forming assistant.
The high molecular polymer emulsion consists of structural units
Polymerizing to obtain the product;
the dispersing agent is modified copolymer amine salt or propenyl ester sodium salt;
the defoaming agent is one of hydrophobic silicon dioxide, hydrophobic polyhydroxy compound and organic ester polyhydroxy compound;
the preservative is 5-chloro-2-methyl-4-isothiazoline-3-ketone or 2-methyl-4-isothiazoline-3-ketone;
the mineral filler is one of kaolin, titanium dioxide, calcium carbonate powder and talcum powder;
the antibacterial agent is silver ions or organic bromine;
the thickening agent is acrylic acid or nonionic aqueous polyurethane;
the anti-fouling agent is organic fluorine modified polysiloxane;
the surface hand feeling agent is polyether modified organic silicon;
the film-forming aid is Oxfilm 351 in Oxea Ozoea Quetima, Germany.
The invention also provides a preparation method of the water-based porcelain wall-cleaning finish paint capable of being drawn and wiped.
Therefore, the technical scheme provided by the invention is a preparation method of the paintable and erasable water-based porcelain wall cleaning finish, which comprises the following steps:
(1) adding the high molecular polymer emulsion and water into a stirrer, stirring for low-speed dispersion, and then sequentially adding a dispersing agent, a defoaming agent, a preservative and an antibacterial agent while performing low-speed dispersion at the rotating speed of 400 revolutions per minute;
(2) after 5 to 10 minutes of low speed dispersion, adding mineral filler;
(3) the stirring speed is increased to 1500 revolutions per minute, high-speed dispersion is carried out for 25 to 30 minutes, and the diameter of dispersed particles is reduced to the fineness below 25 micrometers;
(4) reducing the rotating speed to 800 r/min, and sequentially adding a thickening agent, an anti-fouling agent, a surface feeling agent and a film-forming assistant for low-speed dispersion;
(5) dispersing at low speed for 10-15 min, detecting to be qualified, and filtering with a filter screen of 100-150 meshes to obtain the finished product.
The application method of the water-based porcelain wall cleaning finish paint capable of being drawn and wiped comprises the following steps: the paint is sprayed on a cement board, the thickness of a paint film is 100 microns, and after the paint film is dried for 7 days at normal temperature, painting and wiping can be carried out on the paint surface, and the wiping effect is clean.
The product of the invention comprises the following main components:
the high molecular polymer is a high molecular weight (usually 10-106) compound formed by repeatedly connecting a plurality of same and simple structural units through covalent bonds, and has flocculation, adhesion, resistance reduction and thickening properties.
The fluorocarbon modified polysiloxane has the main purpose of changing the physical properties of the polysiloxane, so that the polysiloxane has the characteristics of oil resistance, solvent resistance and chemicals resistance, and single organic silicon and organic fluorine materials have single defects in the use of a coating system, such as high temperature resistance, substrate wettability, oil resistance and the like. The organic fluorine modified polysiloxane belongs to a fluoro-organosilicon material with a novel structure, combines the advantages of the two aspects, has better high temperature resistance, oil resistance and wetting and leveling capability, is a special modified silicon and fluorine composition, has better high temperature resistance than common organosilicon, does not crack when the temperature reaches 360 ℃, does not affect recoatability, is suitable for baking paint for high-temperature film forming, can also be used for organosilicon non-stick pan coating, has high transparency, high gloss and fullness, prevents pigment and dye from flooding and layering, can eliminate oil stain and orange peel, has good intermiscibility, and does not affect recoatability.
The polyether modified organic silicon has good leveling property as a surface hand feeling agent, is suitable for being added into various resins (polyurethane resin, paint resin, plastic resin and the like), can well improve intermolecular stress of the resins, reduce surface tension, and has good effects of controlling surface flow capacity, increasing smoothness, resisting shrinkage cavity and resisting adhesion.
The German OXEA Oxfilm 351 as a film forming additive is a new generation film forming additive with low odor and almost zero content of VOC, and the proper formula combination can obtain low odor and very low VOC emission; the low-temperature film forming temperature (MFFT) is reduced by 10-20%, and the low-temperature film forming characteristics are excellent.
Compared with the prior art, the product of the invention has the characteristics that the painting surface can be painted by using the water-based pen and can be cleaned by using wet cloth, the painting surface is smooth like the surface of a ceramic tile, the hand feeling is fine and smooth, the highest glossiness can reach 60 degrees, and the antibacterial and pollution-resistant capabilities are strong.
Detailed Description
The following examples are given to further illustrate the embodiments of the present invention, but are not intended to limit the invention.
Example 1
A water-based porcelain wall cleaning finish paint capable of being drawn and wiped mainly comprises the following components in parts by mass:
80 parts of high-molecular polymer emulsion,
5 parts of a dispersing agent, namely,
0.2 part of defoaming agent, 0.2 part of,
5 parts of a preservative, namely 5 parts of,
1 part of an antibacterial agent, namely,
30 parts of water, namely, water,
20 parts of a mineral filler, namely,
4 parts of a thickening agent, namely 4 parts of,
10 parts of an anti-fouling agent,
20 parts of a surface hand feeling agent,
and 10 parts of a film-forming assistant.
The high molecular polymer emulsion consists of structural units
Polymerizing to obtain the product;
the dispersant is modified copolymer amine salt;
the defoaming agent is hydrophobic silicon dioxide;
the preservative is 5-chloro-2-methyl-4-isothiazolin-3-one;
the mineral filler is kaolin;
the antibacterial agent is silver ions;
the thickening agent is acrylic acid;
the anti-fouling agent is organic fluorine modified polysiloxane;
the surface hand feeling agent is polyether modified organic silicon;
the film-forming aid was OXEA Oxfilm 351, Germany.
Example 2
A water-based porcelain wall cleaning finish paint capable of being drawn and wiped mainly comprises the following components in parts by mass:
90 parts of high-molecular polymer emulsion,
3 parts of a dispersing agent, namely 3 parts of,
2 parts of a defoaming agent, namely 2 parts of,
2 parts of a preservative, namely 2 parts of,
2 parts of an antibacterial agent, namely 2 parts of a carrier,
20 parts of water, namely, water,
30 parts of a mineral filler,
2 parts of a thickening agent, namely 2 parts of,
15 parts of an anti-fouling agent, namely,
15 parts of a surface hand feeling agent, namely,
20 parts of a film-forming assistant.
The high molecular polymer emulsion consists of structural units
Polymerizing to obtain the product;
the dispersant is sodium acrylate;
the defoaming agent is a hydrophobic polyhydroxy compound;
the preservative is 2-methyl-4-isothiazoline-3-ketone;
the mineral filler is titanium dioxide;
the antibacterial agent is organic bromine;
the thickening agent is nonionic waterborne polyurethane;
the anti-fouling agent is organic fluorine modified polysiloxane;
the surface hand feeling agent is polyether modified organic silicon;
the film-forming aid was OXEA Oxfilm 351, Germany.
Example 3
A water-based porcelain wall cleaning finish paint capable of being drawn and wiped mainly comprises the following components in parts by mass:
100 parts of high-molecular polymer emulsion,
1 part of a dispersing agent, namely,
3 parts of a defoaming agent, namely 3 parts of,
1 part of a preservative, namely 1 part of,
5 parts of an antibacterial agent, namely a bactericide,
1 part of water, namely, water,
40 parts of a mineral filler,
0.5 part of a thickening agent, namely,
30 parts of an anti-fouling agent,
5 parts of a surface hand feeling agent,
40 parts of a film-forming assistant.
The high molecular polymer emulsion consists of structural units
Polymerizing to obtain the product;
the dispersant is modified copolymer amine salt;
the defoaming agent is an organic ester polyhydroxy compound;
the preservative is 5-chloro-2-methyl-4-isothiazolin-3-one;
the mineral filler is talcum powder;
the antibacterial agent is silver ions;
the thickening agent is acrylic acid;
the anti-fouling agent is organic fluorine modified polysiloxane;
the surface hand feeling agent is polyether modified organic silicon;
the film-forming aid was OXEA Oxfilm 351, Germany.
The preparation method of the above embodiments 1 to 3 comprises the following steps:
(1) adding the high molecular polymer emulsion and water into a stirrer, stirring for low-speed dispersion, and then sequentially adding a dispersing agent, a defoaming agent, a preservative and an antibacterial agent while performing low-speed dispersion at the rotating speed of 400 revolutions per minute;
(2) after 5 to 10 minutes of low speed dispersion, adding mineral filler;
(3) the stirring speed is increased to 1500 revolutions per minute, high-speed dispersion is carried out for 25 to 30 minutes, and the diameter of dispersed particles is reduced to the fineness below 25 micrometers;
(4) reducing the rotating speed to 800 r/min, and sequentially adding a thickening agent, an anti-fouling agent, a surface feeling agent and a film-forming assistant for low-speed dispersion;
(5) dispersing at low speed for 10-15 min, detecting to be qualified, and filtering with a filter screen of 100-150 meshes to obtain the finished product.
The application method of the water-based porcelain wall cleaning finish paint capable of being drawn and wiped comprises the following steps: the paint is sprayed on a cement board, the thickness of a paint film is 100 microns, and after the paint film is dried for 7 days at normal temperature, painting and wiping can be carried out on the paint surface, and the wiping effect is clean.
In order to better illustrate the beneficial effects of the invention, the following comparison of the product of the invention with the product of the same or similar type on the market is carried out.
The product of the invention is taken as an example and a commercial product is taken as a comparative example 1 and a comparative example 2 to be respectively sprayed on a cement board, the thickness of a paint film is 100 microns, after the paint film is dried for 7 days at normal temperature, main technical index tests are carried out for comparison, and the comparison result is shown in the following table 1:
table 1:
as can be seen from the above table 1, compared with the products sold in the market, the product of the invention has the characteristics that the painting surface can be painted by using the water-based pen and cleaned by wiping with wet cloth, the paint surface is smooth like the surface of a ceramic tile, the hand feeling is fine and smooth, the highest glossiness can reach 60 degrees, and the antibacterial and pollution-resistant capabilities are strong.
The embodiments of the present invention have been described in detail with reference to the examples, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention.
Claims (10)
1. A water-based porcelain wall cleaning finish paint capable of being drawn and wiped is characterized by mainly comprising the following components in parts by mass:
80-100 parts of high-molecular polymer emulsion,
1-5 parts of a dispersing agent,
0.2 to 3 portions of defoaming agent,
1-5 parts of a preservative agent,
1-5 parts of an antibacterial agent,
1-30 parts of water, namely,
20-40 parts of a mineral filler,
0.5 to 4 portions of thickening agent,
10-30 parts of an anti-fouling agent,
5-20 parts of a surface hand feeling agent,
10-40 parts of a film-forming assistant.
2. The paintable and erasable water-based porcelain wall paint according to claim 1, wherein the high molecular polymer emulsion is composed of structural units
And polymerizing to obtain the product.
3. The paintable and erasable water-based porcelain wall paint according to claim 1, wherein the dispersant is a modified copolymer amine salt or an acrylic ester sodium salt.
4. The paintable and erasable water-based porcelain wall paint according to claim 1, wherein the defoamer is one of hydrophobic silica, hydrophobic polyol, and organic ester polyol.
5. The paintable, erasable water-based porcelain wall finish according to claim 1, wherein the preservative is 5-chloro-2-methyl-4-isothiazolin-3-one or 2-methyl-4-isothiazolin-3-one.
6. The paintable and erasable water-based porcelain wall paint according to claim 1, wherein the mineral filler is one of kaolin, titanium dioxide, calcium carbonate powder and talcum powder.
7. The paintable and erasable water-based porcelain wall paint according to claim 1, wherein the antibacterial agent is silver ions or organic bromine.
8. The paintable and erasable aqueous porcelain wall finish according to claim 1, wherein the thickener is an acrylic or non-ionic aqueous polyurethane; the anti-fouling agent is organic fluorine modified polysiloxane; the surface hand feeling agent is polyether modified organic silicon.
9. The paintable and erasable water-based porcelain wall paint according to claim 1, wherein the film forming aid is OXEA Oxfilm 351 in Oxea, Germany.
10. A method of preparing the paintable and erasable water-based porcelain wall paint according to claim 1, comprising the steps of:
(1) adding the high molecular polymer emulsion and water into a stirrer, stirring for low-speed dispersion, and then sequentially adding a dispersing agent, a defoaming agent, a preservative and an antibacterial agent while performing low-speed dispersion at the rotating speed of 400 revolutions per minute;
(2) after 5 to 10 minutes of low speed dispersion, adding mineral filler;
(3) the stirring speed is increased to 1500 revolutions per minute, high-speed dispersion is carried out for 25 to 30 minutes, and the diameter of dispersed particles is reduced to the fineness below 25 micrometers;
(4) reducing the rotating speed to 800 r/min, and sequentially adding a thickening agent, an anti-fouling agent, a surface feeling agent and a film-forming assistant for low-speed dispersion;
(5) dispersing at low speed for 10-15 min, detecting to be qualified, and filtering with a filter screen of 100-150 meshes to obtain the finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011098141.3A CN112210295A (en) | 2020-10-14 | 2020-10-14 | Water-based ceramic wall cleaning finish paint capable of being drawn and wiped and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011098141.3A CN112210295A (en) | 2020-10-14 | 2020-10-14 | Water-based ceramic wall cleaning finish paint capable of being drawn and wiped and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5536582A (en) * | 1993-05-13 | 1996-07-16 | American Cyanamid Company | Aqueous silicone coating compositions, method of coating substrates with the same and coated surgical needles produced thereby |
| CN103694887A (en) * | 2013-12-11 | 2014-04-02 | 青岛益群漆业集团有限公司 | Anti-graffiti children wall paint |
| CN109337457A (en) * | 2018-08-24 | 2019-02-15 | 山东北方现代化学工业有限公司 | A kind of super-hydrophobic lotus leaf effect emulsion paint of wear-resisting waterproof automatically cleaning and preparation method thereof |
-
2020
- 2020-10-14 CN CN202011098141.3A patent/CN112210295A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5536582A (en) * | 1993-05-13 | 1996-07-16 | American Cyanamid Company | Aqueous silicone coating compositions, method of coating substrates with the same and coated surgical needles produced thereby |
| CN103694887A (en) * | 2013-12-11 | 2014-04-02 | 青岛益群漆业集团有限公司 | Anti-graffiti children wall paint |
| CN109337457A (en) * | 2018-08-24 | 2019-02-15 | 山东北方现代化学工业有限公司 | A kind of super-hydrophobic lotus leaf effect emulsion paint of wear-resisting waterproof automatically cleaning and preparation method thereof |
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