CN112117020A - Method for treating tritium water by photo-thermal concerted catalysis - Google Patents
Method for treating tritium water by photo-thermal concerted catalysis Download PDFInfo
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 57
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 title claims abstract description 39
- 229910052722 tritium Inorganic materials 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 18
- 230000002153 concerted effect Effects 0.000 title claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims abstract description 46
- 238000006243 chemical reaction Methods 0.000 claims abstract description 36
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 claims abstract description 16
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052724 xenon Inorganic materials 0.000 claims description 17
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 12
- 239000003463 adsorbent Substances 0.000 claims description 11
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 6
- 235000019253 formic acid Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 230000004913 activation Effects 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 230000007547 defect Effects 0.000 claims description 5
- YTZVWGRNMGHDJE-UHFFFAOYSA-N tetralithium;silicate Chemical compound [Li+].[Li+].[Li+].[Li+].[O-][Si]([O-])([O-])[O-] YTZVWGRNMGHDJE-UHFFFAOYSA-N 0.000 claims description 5
- 230000009466 transformation Effects 0.000 claims description 5
- 230000006690 co-activation Effects 0.000 claims description 4
- 230000001939 inductive effect Effects 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 239000004065 semiconductor Substances 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 4
- 230000004927 fusion Effects 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 9
- 229910021650 platinized titanium dioxide Inorganic materials 0.000 description 4
- 208000012839 conversion disease Diseases 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 238000009790 rate-determining step (RDS) Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910003081 TiO2−x Inorganic materials 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005372 isotope separation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002901 radioactive waste Substances 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/20—Disposal of liquid waste
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Abstract
The invention discloses a method for treating tritiated water by photo-thermal concerted catalysis, which adopts a semiconductor material with response to ultraviolet light as a catalyst carrier such as TiO2，Co3O4And the like, a light source is introduced to assist thermal catalysis, so that the reaction temperature is reduced, and the tritium water is quickly treated at a lower temperature. The method can be applied to places where tritium water is generated, such as fusion devices, nuclear power stations and the like.
Description
Technical Field
The invention belongs to the field of radioactive waste treatment, and particularly relates to a method for treating tritium water by photo-thermal concerted catalysis.
Background
For tritium water treatment, VPCE, LPCE and CECE are currently common treatment methods, and H is utilized as the core2And (3) replacing tritium in the tritium-containing water to finish tritium removal treatment of the tritium-containing water. However, to increase the efficiency of the replacement, H2The ratio to tritiated water is often 3: 1 or higher, so that tritium is displaced in H2Is diluted, resulting in an increased burden on the isotope separation unit. In addition, VPCE is generally operated at about 200 ℃, energy consumption is large, LPCE relates to preparation of a hydrophobic catalyst, the process is complicated, the catalyst is easily covered by liquid water to be deactivated, CECE needs to be introduced into electrolysis equipment, and energy consumption is also too high.
In recent years, scholars replace hydrogen isotope exchange reaction with water vapor exchange reaction without introducing H2So that the HT produced is not diluted. Water-vapor transformation reaction: HTO + CO → CO2And + HT, the reaction principle is that a certain amount of CO is introduced, and T of the tritiated water is replaced, so that tritium removal operation of the tritiated water is realized. The catalyst used in the reaction is a conventional hydrophilic catalyst, and has the advantages of simple preparation and high stability.
For the water-vapor shift reaction, the reaction is exothermic from a thermodynamic point of view, i.e., the equilibrium conversion decreases as the temperature increases, so that a lower reaction temperature is advantageous for obtaining a higher conversion. In addition, because tritium is radioactive, it easily permeates into the environment through the container wall under high temperature conditions, causing radioactive contamination, and thus lower operating temperatures are safer. However, from the aspect of dynamics, the temperature is reduced, the chemical reaction rate is reduced, and the high-efficiency treatment of the tritiated water is difficult to realize in engineering application. Therefore, the conventional technology at present cannot simultaneously meet the requirements of high conversion rate, low tritium permeation quantity and high reaction rate when the tritium water is treated by adopting a water-vapor shift reaction.
Disclosure of Invention
In order to overcome the problem of slow reaction rate under the low temperature condition (50-150 ℃), the invention provides a method for treating tritiated water by photo-thermal concerted catalysis.
The following technical scheme is adopted specifically:
a method for treating tritium water by photo-thermal concerted catalysis is characterized by comprising the following steps:
a. uniformly mixing a catalyst and an adsorbent, adding the mixture into a reactor, turning on a heater, and heating the reactor;
b. converting tritium water HTO into water vapor and CO through a gasifier, uniformly mixing, and introducing into a reactor;
c. arranging a xenon lamp above a transparent window at the central position of the upper end surface of the reactor, turning on the xenon lamp and providing a light source for the reactor;
when the light source irradiates the surface of the catalyst, a catalyst defect structure is formed, and water vapor activation is promoted; CO molecules activated on the surface of the catalyst and water molecules generate a water-vapor transformation reaction to generate a product CO2And HT; the reaction process is characterized in that xenon lamp irradiates the surface of the catalyst, electrons of the catalyst jump from a valence band to a conduction band position, and photo-generated electrons e are formed in the conduction band-Formation of photogenerated holes h in the valence band+And inducing the generation of oxygen vacancies Ov(ii) a Photoproduction electrons are transferred to the surface of Pt to promote CO activation, tritium water molecules are adsorbed on oxygen vacancies to be activated, the activated CO and the tritium water molecules are combined to generate a formic acid intermediate, and the formic acid intermediate is heated to be decomposed into CO2And HT, product CO2And the product HT flows out of the reactor.
Further, the wavelength of a light source of the xenon lamp is 300-700 nm, and the power is 100-300W;
furthermore, the transparent window material of reactor is organic glass to the light source gets into inside the reactor.
Furthermore, the catalyst is a supported catalyst, and the carrier of the supported catalyst is TiO2Or Co3O4Semiconductor device and method for manufacturing the sameAnd the supported metal is Pt or Pd. For semiconductor carrier TiO2、Co3O4The light irradiation semiconductor carrier promotes the light irradiation semiconductor carrier to generate oxygen vacancy, the oxygen vacancy is greatly beneficial to the dissociation process of water molecules in the reaction rate determining step, and the activity of the catalyst can be obviously improved.
Further, the adsorbent is lithium orthosilicate or calcium oxide;
further, the temperature of the reactor in the step (a) is 50-150 ℃.
The invention uses a semiconductor material responsive to ultraviolet light as a catalyst support such as TiO2，Co3O4And introducing a light source for assisting thermal catalysis, reducing the reaction temperature and realizing the rapid treatment of tritiated water at the temperature close to normal temperature. The method can be applied to places where tritium water is generated, such as fusion devices, nuclear power stations and the like.
Drawings
FIG. 1 is a schematic view of an apparatus for photo-thermal concerted catalytic treatment of tritiated water according to the present invention;
FIG. 2 is a schematic diagram of photo-thermal concerted catalytic treatment of tritiated water according to example 1;
in the figure, 1, a heater 2, a vaporizer 3, a reactor 4, a xenon lamp 5, a catalyst 6 and an adsorbent.
Detailed Description
The invention is explained in more detail below with reference to the figures and the examples.
Based on the device for treating tritium water by photo-thermal concerted catalysis shown in figure 1, the method for treating tritium water by photo-thermal concerted catalysis comprises the following steps:
a. uniformly mixing a catalyst 5 and an adsorbent 6, adding the mixture into a reactor 3, turning on a heater 1, and heating the reactor;
b. converting tritium water HTO into water vapor and CO through a gasifier 2, uniformly mixing, and introducing into a reactor 3;
c. arranging a xenon lamp 4 above a transparent window at the central position of the upper end surface of the reactor 3, turning on the xenon lamp 4 and providing a light source for the reactor 3; when the light source irradiates the surface of the catalyst 5, a catalyst defect structure is formed, and water vapor activation is promoted; CO molecules activated on the surface of the catalyst generate water with water moleculesSteam shift reaction to produce CO product2And HT; the reaction process is specifically that the xenon lamp 4 irradiates the surface of the catalyst 5, the catalyst electron jumps from a valence band to a conduction band position, and a photo-generated electron e is formed in the conduction band-Formation of photogenerated holes h in the valence band+And inducing the generation of oxygen vacancies Ov(ii) a Photoproduction electrons are transferred to the surface of Pt to promote CO activation, tritium water molecules are adsorbed on oxygen vacancies to be activated, the activated CO and the tritium water molecules are combined to generate a formic acid intermediate, and the formic acid intermediate is heated to be decomposed into CO2And HT, product CO2Is adsorbed and removed after contacting with the adsorbent 6, and the product HT flows out of the reactor 3.
The invention uses a semiconductor material responsive to ultraviolet light as a catalyst support such as TiO2，Co3O4And introducing a light source for assisting thermal catalysis, reducing the reaction temperature and realizing the rapid treatment of tritiated water at the temperature close to normal temperature. The method can be applied to places where tritium water is generated, such as fusion devices, nuclear power stations and the like.
Further, the light source wavelength of the xenon lamp 4 is 300-700 nm, and the power is 100-300W;
further, the transparent window of the reactor 3 is made of organic glass, so that the light source can enter the reactor.
Further, the catalyst 5 is a supported catalyst, and the carrier of the supported catalyst is TiO2Or Co3O4And the supported metal is Pt or Pd. For semiconductor carrier TiO2、Co3O4The light irradiation semiconductor carrier promotes the light irradiation semiconductor carrier to generate oxygen vacancy, the oxygen vacancy is greatly beneficial to the dissociation process of water molecules in the reaction rate determining step, and the activity of the catalyst can be obviously improved.
Further, the adsorbent 6 is lithium orthosilicate or calcium oxide;
further, the temperature of the reactor in the step a is 50-150 ℃.
The method of the invention can obviously improve the activity of the water-gas shift reaction catalyst. Oxygen vacancies, a common defect structure of catalysts, can be used to activate water molecules and participate in chemical reactions therewith. Conventional thermal catalysis, which requires high temperatures of greater than 1000 ℃ to generate oxygen vacancies in metal oxides, is clearly not applicable in the field of tritium water treatment. After the light source is introduced, the catalyst can generate a large amount of oxygen vacancies at the temperature of 50-150 ℃. The invention realizes the water-vapor transformation reaction at the near normal temperature by means of light source assisted thermal catalysis, and can realize safe, efficient and rapid treatment of tritium water.
Example 1
With Pt/TiO2The catalyst is used for example for photo-thermal concerted catalysis treatment of tritiated water, and the specific principle is as shown in figure 2, wherein the method comprises the following steps:
a. catalyst Pt/TiO2Uniformly mixing the adsorbent lithium orthosilicate according to the ratio of 2: 1, adding the mixture into a reactor (3), turning on a heater (1), and heating the reactor at the set temperature of 100 ℃;
b. tritiated water HTO is changed into water vapor through a gasifier (2), and is uniformly mixed with CO according to the ratio of 1: 1, and then the mixture is introduced into a reactor (3);
c. arranging a xenon lamp above the transparent window at the central position of the upper end surface of the reactor, turning on the xenon lamp and providing a light source for the reactor (3); when the light source irradiates on the catalyst Pt/TiO2When the surface is coated, a catalyst defect structure is formed, and water vapor activation is promoted; CO molecules activated on the surface of the catalyst and HTO molecules generate a water-vapor transformation reaction to generate a product CO2And HT. The reaction process is concretely that a xenon lamp (4) irradiates on a catalyst Pt/TiO2(5) Surface, catalyst support TiO2The electrons transit from the valence band to the conduction band position to form a photogenerated electron e in the conduction band-Formation of photogenerated holes h in the valence band+And inducing the generation of oxygen vacancies OvThe reaction formula is TiO2→TiO2-x+Ov+x/2O2(ii) a Photoproduction electrons are transferred to the surface of Pt to promote CO activation, and HTO molecules are adsorbed on TiO2Activating oxygen vacancy, combining CO and HTO molecules after activation to generate formic acid intermediate HCOOT, and decomposing into CO by heating2And HT, product CO2Is adsorbed and removed after contacting with the adsorbent lithium orthosilicate (6), and a product HT flows out of the reactor (3).
Under the condition, the reaction conversion rate is 80.4 percent, the reaction rate of tritium and water is 42mmol/min, and the calculated value of the tritium permeation rateIs 3.95X 10-11mol·m-2·s-1
Example 2
The xenon lamp in the step c of example 1 was turned off, the other conditions were unchanged, the reaction conversion rate was 1.8%, the tritium-water reaction rate was 0.9mmol/min, and the calculated tritium permeation rate was 3.95 × 10-11mol·m-2·s-1。
Example 3
The reaction temperature in example 2 was adjusted to 300 ℃ and the other conditions were unchanged, resulting in a reaction conversion of 30.6%, a tritium-water reaction rate of 16mmol/min and a calculated tritium permeation rate of 3.41X 10-8mol·m-2·s-1。
Therefore, the invention can realize higher tritium-water conversion rate at lower temperature, and simultaneously keep lower tritium permeation rate.
Claims (7)
1. A method for treating tritium water by photo-thermal concerted catalysis is characterized by comprising the following steps:
a. uniformly mixing a catalyst (5) and an adsorbent (6), adding the mixture into a reactor (3), turning on a heater (1), and heating the reactor;
b. converting tritium water HTO into water vapor through a gasifier (2), uniformly mixing the water vapor with CO, and introducing the mixture into a reactor (3);
c. arranging a xenon lamp (4) above a transparent window at the central position of the upper end surface of the reactor (3), turning on the xenon lamp (4), and providing a light source for the reactor (3); when a light source irradiates the surface of the catalyst (5), the catalyst (5) forms a defect structure to promote water vapor activation; CO molecules activated on the surface of the catalyst and water molecules generate a water-vapor transformation reaction to generate a product CO2And HT; the reaction process is concretely characterized in that a xenon lamp (4) irradiates the surface of a catalyst (5), the electrons of the catalyst jump from a valence band to a conduction band position, and photo-generated electrons e are formed in the conduction band-Formation of photogenerated holes h in the valence band+And inducing the generation of oxygen vacancies Ov(ii) a Photoproduction electrons are transferred to the surface of Pt to promote CO activation, tritium water molecules are adsorbed on oxygen vacancies to be activated, and CO and the tritium water molecules are combined to generate a formic acid intermediate after activationDecomposition to CO by heating2And HT, product CO2Is adsorbed and removed after contacting with the adsorbent (6), and a product HT flows out of the reactor (3).
2. The photo-thermal concerted catalysis tritiated water treatment method according to claim 1, characterized in that the light source wavelength of the xenon lamp (4) is 300-700 nm, and the power is 100-300W.
3. The photo-thermal concerted catalysis tritium water treatment method according to claim 1, characterized in that the transparent window of the reactor (3) is made of organic glass so that a light source can enter the reactor.
4. A method for the photothermal concerted catalytic treatment of tritiated water according to claim 1, characterized in that the catalyst (5) is a supported catalyst.
5. Method for the photothermal concerted catalytic treatment of tritiated water according to claim 1, characterized in that the catalyst (5) carrier is TiO2Or Co3O4And the supported metal is Pt or Pd.
6. A method for the photothermal concerted catalytic treatment of tritiated water according to claim 1, characterized in that the adsorbent (6) is lithium orthosilicate or calcium oxide.
7. A method for treating tritium water by photo-thermal concerted catalysis according to claim 1, characterized in that the reactor temperature in step (a) is 50-150 ℃.
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| CN112691689A (en) * | 2020-12-28 | 2021-04-23 | 中国工程物理研究院核物理与化学研究所 | Steam irradiation reduction synthesis method of monatomic catalyst |
Citations (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4411755A (en) * | 1980-11-28 | 1983-10-25 | Herman Irving P | Laser-assisted isotope separation of tritium |
| CN1803580A (en) * | 2006-01-23 | 2006-07-19 | 福州大学 | Technique for highly selective oxidation of carbon monoxide in hydrogen-enriched gas by light heat synergetic action |
| CN1930662A (en) * | 2004-06-10 | 2007-03-14 | 应用材料股份有限公司 | Low temperature epitaxial growth of silicon-containing films using UV radiation |
| CN101618292A (en) * | 2008-11-10 | 2010-01-06 | 李元胜 | System for comprehensive utilization of three industrial wastes |
| CN101679025A (en) * | 2007-04-24 | 2010-03-24 | 布莱克光电有限公司 | hydrogen-catalyst reactor |
| CN101856618A (en) * | 2010-05-18 | 2010-10-13 | 武汉理工大学 | Method for preparing platinum/semiconductor oxide catalyst having photo-thermal synergistic effect |
| CN101947462A (en) * | 2010-09-03 | 2011-01-19 | 天津工业大学 | Visible light responding selenium-doped sulphide photocatalyst and preparation method thereof |
| CN102503817A (en) * | 2011-03-10 | 2012-06-20 | 中国科学院福建物质结构研究所 | Photo-thermo concerted catalysis technology and application thereof on carbon monoxide catalytic coupling |
| CN102694186A (en) * | 2012-06-01 | 2012-09-26 | 福州大学 | Method for improving catalytic performance of Ru catalyst to CO methanation |
| US20120308821A1 (en) * | 2010-02-02 | 2012-12-06 | Renbi Bai | Buoyant Multifunctional Composite Material For Effective Removal Of Organic Compounds In Water And Wastewater |
| WO2013166505A2 (en) * | 2012-05-04 | 2013-11-07 | Lawrence Livermore National Security, Llc | LITHIUM TRITIDE (LiT) ELECTROLYSIS CELL FOR REMOVING TRITIUM FROM LITHIUM METAL |
| JP2014215258A (en) * | 2013-04-27 | 2014-11-17 | 株式会社ナチュル | Radioactive material removal device and radioactive material removal method |
| CN104318969A (en) * | 2014-11-19 | 2015-01-28 | 清华大学 | High temperature gas cooled reactor tritium-contained wastewater optimization collection system and technology |
| CN104485146A (en) * | 2014-12-12 | 2015-04-01 | 中国工程物理研究院材料研究所 | High-efficiency tritium removal purification device and tritium removal method thereof |
| CN105609152A (en) * | 2016-03-25 | 2016-05-25 | 中国工程物理研究院材料研究所 | System for realizing detritiation of water and realizing method of system |
| CN105702309A (en) * | 2016-04-20 | 2016-06-22 | 中国工程物理研究院材料研究所 | SPE (Solid Polymer Electrolyte) electrolysis system used for tritium concentration and realization method for electrolysis system |
| CN105976884A (en) * | 2016-06-29 | 2016-09-28 | 中国工程物理研究院材料研究所 | Treatment device and treatment method for tritium-containing wastewater |
| CN106076118A (en) * | 2016-08-23 | 2016-11-09 | 中国工程物理研究院核物理与化学研究所 | Tritium pollutes metal decontamination purification and tritium recovery system |
| CN106179330A (en) * | 2016-06-29 | 2016-12-07 | 中国工程物理研究院材料研究所 | The method for preparing catalyst that a kind of tritium-containing liquid waste processes |
| JP2017015542A (en) * | 2015-06-30 | 2017-01-19 | 三菱重工業株式会社 | Tritium separation system and tritium separation method |
| CN107020138A (en) * | 2017-05-09 | 2017-08-08 | 福州大学 | A kind of Supported Pd-Catalyst and its preparation method and application |
| CN107705867A (en) * | 2017-11-09 | 2018-02-16 | 中国工程物理研究院核物理与化学研究所 | It is a kind of to go tritiated processing unit and method containing HTO |
| CN107986380A (en) * | 2017-12-02 | 2018-05-04 | 延海平 | A kind of N doping coateds TiO2The technique of photocatalyst for degrading waste water |
| CN108053908A (en) * | 2017-11-16 | 2018-05-18 | 中国核电工程有限公司 | Airborne tritium concentration reduces system in a kind of nuclear power plant's workshop |
| US20180318795A1 (en) * | 2015-09-30 | 2018-11-08 | Daegu Gyeongbuk Institute Of Science & Technology | Method for reducing metal oxide and method for producing photocatalyst using same |
| CN109264814A (en) * | 2018-09-13 | 2019-01-25 | 江苏大学 | A kind of device and method of photo-thermal concerted catalysis processing organic sewage |
| CN109569561A (en) * | 2018-11-22 | 2019-04-05 | 华南农业大学 | A kind of graphene/ZnAlTi hydrotalcite-like composite material and its preparation method and application |
| CN110330202A (en) * | 2019-07-19 | 2019-10-15 | 武汉理工大学 | One kind being based on TiO2The method of photocatalysis treatment livestock waste antibiotic |
| CN110560149A (en) * | 2019-09-03 | 2019-12-13 | 中国工程物理研究院核物理与化学研究所 | Zeolite-supported metal type catalyst for dehydrogenation and tritium removal and application thereof |
| WO2020065133A1 (en) * | 2018-09-26 | 2020-04-02 | Teknologian Tutkimuskeskus Vtt Oy | A METHOD OF SELECTIVELY CATALYTICALLY OXIDIZING DINITROGEN OXIDE, A METHOD OF DETECTING RADIOCARBON, AN APPARATUS, AND USE OF A NiO CATALYST |
| CN111111434A (en) * | 2020-01-15 | 2020-05-08 | 上海第二工业大学 | Equipment for catalytic degradation of VOCs gas through infrared heating |
| CN111139108A (en) * | 2020-01-10 | 2020-05-12 | 湘潭大学 | Carbon monoxide steam conversion reaction method using Pt-based catalyst |
| CN111420685A (en) * | 2019-01-10 | 2020-07-17 | 欧阳峰 | FSBi-doped TiO for efficiently degrading acrylonitrile wastewater by sunlight catalysis2/SiO2Preparation and use of the catalyst |
-
2020
- 2020-09-09 CN CN202010944213.5A patent/CN112117020B/en active Active
Patent Citations (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4411755A (en) * | 1980-11-28 | 1983-10-25 | Herman Irving P | Laser-assisted isotope separation of tritium |
| CN1930662A (en) * | 2004-06-10 | 2007-03-14 | 应用材料股份有限公司 | Low temperature epitaxial growth of silicon-containing films using UV radiation |
| CN1803580A (en) * | 2006-01-23 | 2006-07-19 | 福州大学 | Technique for highly selective oxidation of carbon monoxide in hydrogen-enriched gas by light heat synergetic action |
| CN101679025A (en) * | 2007-04-24 | 2010-03-24 | 布莱克光电有限公司 | hydrogen-catalyst reactor |
| CN101618292A (en) * | 2008-11-10 | 2010-01-06 | 李元胜 | System for comprehensive utilization of three industrial wastes |
| US20120308821A1 (en) * | 2010-02-02 | 2012-12-06 | Renbi Bai | Buoyant Multifunctional Composite Material For Effective Removal Of Organic Compounds In Water And Wastewater |
| CN101856618A (en) * | 2010-05-18 | 2010-10-13 | 武汉理工大学 | Method for preparing platinum/semiconductor oxide catalyst having photo-thermal synergistic effect |
| CN101947462A (en) * | 2010-09-03 | 2011-01-19 | 天津工业大学 | Visible light responding selenium-doped sulphide photocatalyst and preparation method thereof |
| CN102503817A (en) * | 2011-03-10 | 2012-06-20 | 中国科学院福建物质结构研究所 | Photo-thermo concerted catalysis technology and application thereof on carbon monoxide catalytic coupling |
| WO2013166505A2 (en) * | 2012-05-04 | 2013-11-07 | Lawrence Livermore National Security, Llc | LITHIUM TRITIDE (LiT) ELECTROLYSIS CELL FOR REMOVING TRITIUM FROM LITHIUM METAL |
| CN102694186A (en) * | 2012-06-01 | 2012-09-26 | 福州大学 | Method for improving catalytic performance of Ru catalyst to CO methanation |
| JP2014215258A (en) * | 2013-04-27 | 2014-11-17 | 株式会社ナチュル | Radioactive material removal device and radioactive material removal method |
| CN104318969A (en) * | 2014-11-19 | 2015-01-28 | 清华大学 | High temperature gas cooled reactor tritium-contained wastewater optimization collection system and technology |
| CN104485146A (en) * | 2014-12-12 | 2015-04-01 | 中国工程物理研究院材料研究所 | High-efficiency tritium removal purification device and tritium removal method thereof |
| JP2017015542A (en) * | 2015-06-30 | 2017-01-19 | 三菱重工業株式会社 | Tritium separation system and tritium separation method |
| US20180318795A1 (en) * | 2015-09-30 | 2018-11-08 | Daegu Gyeongbuk Institute Of Science & Technology | Method for reducing metal oxide and method for producing photocatalyst using same |
| CN105609152A (en) * | 2016-03-25 | 2016-05-25 | 中国工程物理研究院材料研究所 | System for realizing detritiation of water and realizing method of system |
| CN105702309A (en) * | 2016-04-20 | 2016-06-22 | 中国工程物理研究院材料研究所 | SPE (Solid Polymer Electrolyte) electrolysis system used for tritium concentration and realization method for electrolysis system |
| CN106179330A (en) * | 2016-06-29 | 2016-12-07 | 中国工程物理研究院材料研究所 | The method for preparing catalyst that a kind of tritium-containing liquid waste processes |
| CN105976884A (en) * | 2016-06-29 | 2016-09-28 | 中国工程物理研究院材料研究所 | Treatment device and treatment method for tritium-containing wastewater |
| CN106076118A (en) * | 2016-08-23 | 2016-11-09 | 中国工程物理研究院核物理与化学研究所 | Tritium pollutes metal decontamination purification and tritium recovery system |
| CN107020138A (en) * | 2017-05-09 | 2017-08-08 | 福州大学 | A kind of Supported Pd-Catalyst and its preparation method and application |
| CN107705867A (en) * | 2017-11-09 | 2018-02-16 | 中国工程物理研究院核物理与化学研究所 | It is a kind of to go tritiated processing unit and method containing HTO |
| CN108053908A (en) * | 2017-11-16 | 2018-05-18 | 中国核电工程有限公司 | Airborne tritium concentration reduces system in a kind of nuclear power plant's workshop |
| CN107986380A (en) * | 2017-12-02 | 2018-05-04 | 延海平 | A kind of N doping coateds TiO2The technique of photocatalyst for degrading waste water |
| CN109264814A (en) * | 2018-09-13 | 2019-01-25 | 江苏大学 | A kind of device and method of photo-thermal concerted catalysis processing organic sewage |
| WO2020065133A1 (en) * | 2018-09-26 | 2020-04-02 | Teknologian Tutkimuskeskus Vtt Oy | A METHOD OF SELECTIVELY CATALYTICALLY OXIDIZING DINITROGEN OXIDE, A METHOD OF DETECTING RADIOCARBON, AN APPARATUS, AND USE OF A NiO CATALYST |
| CN109569561A (en) * | 2018-11-22 | 2019-04-05 | 华南农业大学 | A kind of graphene/ZnAlTi hydrotalcite-like composite material and its preparation method and application |
| CN111420685A (en) * | 2019-01-10 | 2020-07-17 | 欧阳峰 | FSBi-doped TiO for efficiently degrading acrylonitrile wastewater by sunlight catalysis2/SiO2Preparation and use of the catalyst |
| CN110330202A (en) * | 2019-07-19 | 2019-10-15 | 武汉理工大学 | One kind being based on TiO2The method of photocatalysis treatment livestock waste antibiotic |
| CN110560149A (en) * | 2019-09-03 | 2019-12-13 | 中国工程物理研究院核物理与化学研究所 | Zeolite-supported metal type catalyst for dehydrogenation and tritium removal and application thereof |
| CN111139108A (en) * | 2020-01-10 | 2020-05-12 | 湘潭大学 | Carbon monoxide steam conversion reaction method using Pt-based catalyst |
| CN111111434A (en) * | 2020-01-15 | 2020-05-08 | 上海第二工业大学 | Equipment for catalytic degradation of VOCs gas through infrared heating |
Non-Patent Citations (5)
| Title |
|---|
| 但贵萍 等: "疏水催化剂用于水中氚回收的实验研究", 《辐射防护通讯》 * |
| 孔淑青: "光催化反应在环境保护上的应用", 《环境与开发》 * |
| 巫泉文等: "空气除氚***中氚氧化催化剂的研究进展", 《核化学与放射化学》 * |
| 成泽伟等: "氧化剂强化光催化处理焦化废水研究", 《水处理技术》 * |
| 李亚峰等: "负载型TiO_2光催化剂的制备及光催化活性研究", 《沈阳建筑大学学报(自然科学版)》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112691689A (en) * | 2020-12-28 | 2021-04-23 | 中国工程物理研究院核物理与化学研究所 | Steam irradiation reduction synthesis method of monatomic catalyst |
| CN112691689B (en) * | 2020-12-28 | 2022-07-15 | 中国工程物理研究院核物理与化学研究所 | Steam irradiation reduction synthesis method of monatomic catalyst |
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