CN112080196A - Water-based strippable coating and preparation method thereof - Google Patents
Water-based strippable coating and preparation method thereof Download PDFInfo
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- CN112080196A CN112080196A CN202011012056.0A CN202011012056A CN112080196A CN 112080196 A CN112080196 A CN 112080196A CN 202011012056 A CN202011012056 A CN 202011012056A CN 112080196 A CN112080196 A CN 112080196A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention provides a water-based strippable coating which comprises the following components in parts by weight: 70-90 parts of aqueous polyurethane dispersoid, 0.2-0.5 part of pH regulator, 5-10 parts of film-forming assistant, 0.1-0.3 part of defoaming agent, 0.3-0.5 part of base material wetting agent, 5-20 parts of deionized water and 1-5 parts of thickening agent, wherein the film-forming assistant comprises: 2-3 parts of dipropylene glycol methyl ether and 1-3 parts of glycerol hydroxystearate. The invention provides a water-based strippable coating with low VOC, high tensile strength of a paint film, good film-forming property and good film-strippable property and a preparation method thereof.
Description
Technical Field
The invention relates to the field of coatings, in particular to a strippable water-based coating for a stainless steel substrate and a preparation method thereof.
Background
Along with the improvement of the quality of life at present and the improvement of the environmental protection concept, people have higher and higher requirements on articles contacted in life, the requirements on strippable protective film coatings for protecting the articles are stricter, the coatings suitable for being stripped at present are basically oil-based paints, the oil-based paints have large odor and toxicity, the high content of organic volatile compounds (VOC) has great influence on the bodies of workers and the environment, and therefore the water-based strippable paints with small odor and low content of organic volatile compounds (VOC) and are more environment-friendly are produced at the beginning.
Therefore, the research on the water-based strippable coating with low VOC, high tensile strength of a paint film, good film-forming performance and good film-strippable performance and the preparation method thereof are needed.
Disclosure of Invention
The invention aims to provide a water-based strippable coating with low VOC, high tensile strength of a paint film, good film-forming property and good film strippability and a preparation method thereof.
The technical purpose of the invention is realized by the following technical scheme:
the water-based strippable coating comprises the following components in parts by weight: 70-90 parts of aqueous polyurethane dispersoid, 0.2-0.5 part of pH regulator, 5-10 parts of film-forming assistant, 0.1-0.3 part of defoaming agent, 0.3-0.5 part of base material wetting agent, 5-20 parts of deionized water and 1-5 parts of thickening agent, wherein the film-forming assistant comprises: 2-3 parts of dipropylene glycol methyl ether and 1-3 parts of glycerol hydroxystearate.
As a further improvement of the invention, the detergent also comprises 1-5 parts of active agent ethylhexyl hydroxystearate by weight.
As a further improvement of the invention, the film-forming additive is 2-4 parts of 4-amino-3-hydroxybutyric acid in parts by weight.
As a further improvement of the invention, the aqueous polyurethane dispersion is Crysol 6110.
As a further improvement of the invention, the pH regulator is one or more of dimethylethanolamine and multifunctional auxiliary AMP-95.
As a further improvement of the invention, the defoaming agent is a polyester modified polyphosphate defoaming agent.
As a further improvement of the invention, the substrate wetting agent is a wetting agent of polyether modified polysiloxane, and the wetting agent of polyether modified polysiloxane is one or two of Tego-100 and BYK-346.
As a further improvement of the invention, the thickener is a polyurethane thickener.
The invention also provides a preparation method of the water-based strippable coating, which comprises the following steps: according to the raw material proportion, the aqueous polyurethane dispersion, the film-forming assistant, the deionized water, the pH value regulator, the defoaming agent, the thickening agent and the activator are sequentially added under the stirring condition of the speed of 600r/min and 500-600r/min, the stirring is carried out for 30-40min, and the viscosity is adjusted to be qualified.
The invention has the beneficial effects that:
1. the invention selects the aqueous dispersion and the high-boiling-point environment-friendly film-forming auxiliary agent to obtain the high-gloss, high-decoration and strippable aqueous paint coating, wherein the VOC of the prepared aqueous paint is less than or equal to 60g/L, the odor is very low, and the environment pollution is prevented.
2. According to the invention, the environment-friendly high-boiling-point film-forming aid dipropylene glycol methyl ether film-forming aid is selected, both film-forming aids are environment-friendly aids and are strong solvents of emulsion polymers, and glycerol hydroxystearate is added into the film-forming aid and interacts with dipropylene glycol methyl ether, so that the lowest film-forming temperature of the water-based paint is effectively reduced, the film-forming property is obviously improved, and the scrubbing resistance and the film coating quality of the water-based paint are improved.
3. According to the invention, the aqueous polyurethane dispersion is used as a film forming substance, and ethylhexyl hydroxystearate is added in the formula, and the ethylhexyl hydroxystearate has oleophilic and hydrophilic groups, so that the acting force between the aqueous polyurethane dispersions can be improved, the film forming performance of the aqueous polyurethane is effectively improved, the smoothness of the film forming surface is increased, the tensile strength after film forming is improved, and the strippability of a paint film is improved.
4. According to the invention, 4-amino-3-hydroxybutyric acid is added into the film-forming assistant, so that the acting force of glycerol hydroxystearate, dipropylene glycol methyl ether and propylene glycol methyl ether can be improved by the 4-amino-3-hydroxybutyric acid, the film-forming performance is further improved, the tensile property of the formed film is improved, and the glossiness and the ageing resistance of the paint film can be effectively improved by the 4-amino-3-hydroxybutyric acid.
5. The pH regulator adopted by the scheme is dimethylethanolamine produced by Germany Basff company and/or multifunctional assistant AMP-95 produced by American Dow chemical industry to regulate the pH value of a regulating system to 8-9, and the two pH regulators not only have the effect of regulating the pH value, but also are organic substances and can be mutually agglomerated with the aqueous polyurethane dispersion to further improve the film forming property of the aqueous polyurethane dispersion.
Detailed Description
The technical solution of the present invention will be clearly and completely described below with reference to specific embodiments. It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without any inventive step, are within the scope of the present invention.
First, an embodiment
Example 1
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of a speed of 500 r/min: 611070 parts of waterborne polyurethane dispersion, 0.2 part of pH regulator dimethyl ethanol, 5 parts of a film-forming assistant, 5 parts of a defoaming agent BYK-0280.1, 5 parts of substrate wetting agent Tego-1000.3, 5 parts of deionized water, 1 part of RM-8W thickener and 1 part of active agent ethylhexyl hydroxystearate, wherein the film-forming assistant comprises: 2 parts of dipropylene glycol methyl ether, 1 part of glycerol hydroxystearate and 2 parts of 4-amino-3-hydroxybutyric acid, stirring at the speed of 500r/min for 30min, and adjusting the viscosity to be qualified.
Example 2
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of a speed of 600 r/min: the waterborne polyurethane coating comprises, by weight, 611090 parts of waterborne polyurethane dispersion, 950.5 parts of multifunctional auxiliary agent AMP-950.5 parts of pH regulator, 10 parts of film-forming auxiliary agent, 0280.3 parts of defoaming agent BYK-3460.5 parts of base material wetting agent, 20 parts of deionized water, 5 parts of RM-8W thickening agent and 3 parts of active agent ethylhexyl hydroxystearate, wherein the film-forming auxiliary agent comprises: 3 parts of dipropylene glycol methyl ether, 3 parts of glycerol hydroxystearate and 4 parts of 4-amino-3-hydroxybutyric acid, stirring at the speed of 600r/min for 40min, and adjusting the viscosity to be qualified.
Example 3
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of the speed of 550 r/min: 611080 parts of waterborne polyurethane dispersion, 0.3 part of dimethyl ethanolamine as a pH regulator, 7 parts of a film-forming assistant, 7 parts of a defoaming agent BYK-0280.2 parts, 3 parts of a base material wetting agent Tego-1000.4 parts, 10 parts of deionized water, 3 parts of an RM-8W thickening agent and 3 parts of ethylhexyl hydroxystearate as an active agent, wherein the film-forming assistant comprises: 2.5 parts of dipropylene glycol methyl ether, 1.5 parts of glycerol hydroxystearate and 3 parts of 4-amino-3-hydroxybutyric acid, stirring at the speed of 550r/min for 35min, and adjusting the viscosity to be qualified.
Example 4
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of the speed of 550 r/min: 611080 parts of waterborne polyurethane dispersion, 0.3 part of dimethyl ethanolamine as a pH regulator, 7 parts of a film-forming assistant, 7 parts of a defoaming agent BYK-0280.2 parts, 3 parts of a base material wetting agent Tego-1000.4 parts, 10 parts of deionized water, 3 parts of an RM-8W thickening agent and 3 parts of ethylhexyl hydroxystearate as an active agent, wherein the film-forming assistant comprises: 2.5 parts of dipropylene glycol methyl ether, 3 parts of 4-amino-3-hydroxybutyric acid, stirring at the speed of 550r/min for 35min, and adjusting the viscosity to be qualified.
Example 5
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of the speed of 550 r/min: 611080 parts of waterborne polyurethane dispersion Crysol, 0.3 part of pH regulator dimethylethanolamine, 7 parts of a film-forming aid, 7 parts of a defoaming agent BYK-0280.2 parts, 10 parts of deionized water and 3 parts of an RM-8W thickening agent, wherein the film-forming aid comprises: 2.5 parts of dipropylene glycol methyl ether, 1.5 parts of glycerol hydroxystearate and 3 parts of 4-amino-3-hydroxybutyric acid, stirring at the speed of 550r/min for 35min, and adjusting the viscosity to be qualified.
Example 6
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of the speed of 550 r/min: 611080 parts of waterborne polyurethane dispersion, 0.3 part of dimethyl ethanolamine as a pH regulator, 7 parts of a film-forming assistant, 7 parts of a defoaming agent BYK-0280.2 parts, 3 parts of a base material wetting agent Tego-1000.4 parts, 10 parts of deionized water, 3 parts of an RM-8W thickening agent and 3 parts of ethylhexyl hydroxystearate as an active agent, wherein the film-forming assistant comprises: 2.5 parts of dipropylene glycol methyl ether and 1.5 parts of glycerol hydroxystearate, stirring at the speed of 550r/min for 35min, and adjusting the viscosity to be qualified.
Example 7
A preparation method of a water-based strippable coating comprises the following steps: according to the raw material ratio, the raw materials are sequentially added under the stirring condition of the speed of 550 r/min: 611080 parts of waterborne polyurethane dispersion Crysol, 0.3 part of pH regulator dimethylethanolamine, 7 parts of a film-forming aid, 7 parts of a defoaming agent BYK-0280.2 parts, 10 parts of deionized water and 3 parts of an RM-8W thickening agent, wherein the film-forming aid comprises: 2.5 parts of dipropylene glycol methyl ether, stirring at the speed of 550r/min for 35min, and adjusting the viscosity to be qualified.
Film formation time test method: and respectively calculating the surface drying time and the actual drying time of the film body by adopting a finger touch method and a blade method. After the coating is uniformly coated on the sample wafer, the sample wafer is placed under the set ventilation condition of 30 ℃, and the surface drying time of film forming of the film body is observed according to the measurement.
The samples of examples 1 to 7 were tested for tensile properties of film bodies according to GB/T1040.1 to 2006 and for film-forming properties according to the film-forming time test method:
TABLE 1 test results of mechanical properties and film-forming properties of each sample
| DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION | Tensile strength/MPa | Tensile deformation rate/%) | Film formation time/min |
| Example 1 | 45.6 | 294.6 | 42 |
| Example 2 | 52.7 | 321.4 | 39 |
| Example 3 | 50.2 | 317.1 | 40 |
| Example 4 | 32.7 | 224.7 | 72 |
| Example 5 | 30.1 | 201.3 | 62 |
| Example 6 | 33.6 | 235.4 | 60 |
| Example 7 | 25.2 | 166.4 | 92 |
The principles and embodiments of the present invention are explained herein using specific examples, which are set forth only to help understand the method and its core ideas of the present invention. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
Claims (9)
1. An aqueous strippable coating material characterized by: the paint comprises the following components in parts by weight: 70-90 parts of aqueous polyurethane dispersoid, 0.2-0.5 part of pH regulator, 5-10 parts of film-forming assistant, 0.1-0.3 part of defoaming agent, 0.3-0.5 part of base material wetting agent, 5-20 parts of deionized water and 1-5 parts of thickening agent, wherein the film-forming assistant comprises: 2-3 parts of dipropylene glycol methyl ether and 1-3 parts of glycerol hydroxystearate.
2. An aqueous strippable coating material according to claim 1, characterized in that: according to the parts by weight, the detergent also comprises 1-5 parts of active agent ethylhexyl hydroxystearate.
3. An aqueous strippable coating material according to claim 1, characterized in that: 2-4 parts of 4-amino-3-hydroxybutyric acid as a film-forming aid.
4. An aqueous strippable coating material according to claim 1, characterized in that: the aqueous polyurethane dispersion is Crysol 6110.
5. An aqueous strippable coating material according to claim 1, characterized in that: the pH regulator is one or more of dimethylethanolamine and multifunctional assistant AMP-95.
6. An aqueous strippable coating material according to claim 1, characterized in that: the defoaming agent is a polyester modified polyphosphate defoaming agent.
7. An aqueous strippable coating material according to claim 1, characterized in that: the base material wetting agent is polyether modified polysiloxane wetting agent, and the polyether modified polysiloxane wetting agent is one or two of Tego-100 and BYK-346.
8. An aqueous strippable coating material according to claim 1, characterized in that: the thickening agent is a polyurethane thickening agent.
9. A method of preparing the aqueous strippable paint of claims 1-8, characterized in that: the method comprises the following steps: according to the raw material ratio, the waterborne polyurethane dispersion, the film-forming auxiliary agent, the deionized water, the pH value regulator, the defoaming agent, the thickening agent and the activator are sequentially added under the stirring condition of the speed of 600r/min and 500-600r/min, the stirring is carried out for 30-40min, and the viscosity is adjusted to be qualified.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116102961A (en) * | 2021-11-09 | 2023-05-12 | 深圳富桂精密工业有限公司 | Water-based protective film and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101631831A (en) * | 2007-03-12 | 2010-01-20 | 禾大新加坡私人有限公司 | Dispersion, gel and emulsification system |
| EP2177209A1 (en) * | 2008-10-17 | 2010-04-21 | Ferrer Internacional, S.A. | Intravenous solutions and uses |
| CN103396718A (en) * | 2013-08-02 | 2013-11-20 | 武汉双虎涂料有限公司 | Preparation method of fastener cathode electrophoretic paint |
| CN103740248A (en) * | 2013-11-04 | 2014-04-23 | 安庆菱湖涂料有限公司 | Smooth wear-resistant high-hardness one-component water-based woodenware paint and preparation method thereof |
| CN105696008A (en) * | 2016-02-18 | 2016-06-22 | 东莞市伟思化学科技有限公司 | Ultrasonic water-based cleaning fluid for hardware products and preparation method thereof |
| KR20170061643A (en) * | 2017-05-16 | 2017-06-05 | 주식회사 케이씨텍 | Slurry composition for tungsten polishing |
| CN108342150A (en) * | 2018-03-13 | 2018-07-31 | 湖北天鹅科技有限公司 | A kind of high salt fog bi-component epoxy priming paint of aqueous acidic and preparation method thereof |
| CN108690427A (en) * | 2018-03-12 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of aqueous mallear stria baking vanish and preparation method thereof |
| CN110483728A (en) * | 2019-09-10 | 2019-11-22 | 青岛水性七彩新材料有限公司 | A kind of preparation method of strippable water-soluble polyurethane resin and the application in coating |
-
2020
- 2020-09-23 CN CN202011012056.0A patent/CN112080196A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101631831A (en) * | 2007-03-12 | 2010-01-20 | 禾大新加坡私人有限公司 | Dispersion, gel and emulsification system |
| EP2177209A1 (en) * | 2008-10-17 | 2010-04-21 | Ferrer Internacional, S.A. | Intravenous solutions and uses |
| CN103396718A (en) * | 2013-08-02 | 2013-11-20 | 武汉双虎涂料有限公司 | Preparation method of fastener cathode electrophoretic paint |
| CN103740248A (en) * | 2013-11-04 | 2014-04-23 | 安庆菱湖涂料有限公司 | Smooth wear-resistant high-hardness one-component water-based woodenware paint and preparation method thereof |
| CN105696008A (en) * | 2016-02-18 | 2016-06-22 | 东莞市伟思化学科技有限公司 | Ultrasonic water-based cleaning fluid for hardware products and preparation method thereof |
| KR20170061643A (en) * | 2017-05-16 | 2017-06-05 | 주식회사 케이씨텍 | Slurry composition for tungsten polishing |
| CN108690427A (en) * | 2018-03-12 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of aqueous mallear stria baking vanish and preparation method thereof |
| CN108342150A (en) * | 2018-03-13 | 2018-07-31 | 湖北天鹅科技有限公司 | A kind of high salt fog bi-component epoxy priming paint of aqueous acidic and preparation method thereof |
| CN110483728A (en) * | 2019-09-10 | 2019-11-22 | 青岛水性七彩新材料有限公司 | A kind of preparation method of strippable water-soluble polyurethane resin and the application in coating |
Non-Patent Citations (3)
| Title |
|---|
| 刘有常等: "《汉英药物词汇》", 31 May 1990, 广东科技出版社 * |
| 罗希权等: "《表面活性剂手册》", 31 March 1997, 中国轻工业出版社 * |
| 高志红: "《现代化妆品科学与技术》", 31 March 2016, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116102961A (en) * | 2021-11-09 | 2023-05-12 | 深圳富桂精密工业有限公司 | Water-based protective film and preparation method thereof |
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Application publication date: 20201215 |