CN112021576A - 除菌性食品添加剂及包含其的除菌性食品 - Google Patents
除菌性食品添加剂及包含其的除菌性食品 Download PDFInfo
- Publication number
- CN112021576A CN112021576A CN201910738493.1A CN201910738493A CN112021576A CN 112021576 A CN112021576 A CN 112021576A CN 201910738493 A CN201910738493 A CN 201910738493A CN 112021576 A CN112021576 A CN 112021576A
- Authority
- CN
- China
- Prior art keywords
- silver
- bactericidal
- food additive
- sintered
- chewing gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 61
- 235000013373 food additive Nutrition 0.000 title claims abstract description 54
- 239000002778 food additive Substances 0.000 title claims abstract description 54
- 235000013305 food Nutrition 0.000 title claims abstract description 21
- 229910052709 silver Inorganic materials 0.000 claims abstract description 56
- 239000004332 silver Substances 0.000 claims abstract description 56
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 54
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000012298 atmosphere Substances 0.000 claims abstract description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
- 239000012299 nitrogen atmosphere Substances 0.000 claims abstract description 25
- 229910001923 silver oxide Inorganic materials 0.000 claims abstract description 24
- 239000002344 surface layer Substances 0.000 claims abstract description 23
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 235000015218 chewing gum Nutrition 0.000 claims description 56
- 229940112822 chewing gum Drugs 0.000 claims description 55
- 239000000454 talc Substances 0.000 claims description 21
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- -1 silver salt compound Chemical class 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 11
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
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- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
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- 235000019808 microcrystalline wax Nutrition 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 6
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 5
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- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 claims description 2
- RBWNDBNSJFCLBZ-UHFFFAOYSA-N 7-methyl-5,6,7,8-tetrahydro-3h-[1]benzothiolo[2,3-d]pyrimidine-4-thione Chemical compound N1=CNC(=S)C2=C1SC1=C2CCC(C)C1 RBWNDBNSJFCLBZ-UHFFFAOYSA-N 0.000 claims description 2
- PLNJNALNCZDQNM-UHFFFAOYSA-N [Ag+2].[O-][Mn]([O-])(=O)=O Chemical compound [Ag+2].[O-][Mn]([O-])(=O)=O PLNJNALNCZDQNM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- OJKANDGLELGDHV-UHFFFAOYSA-N disilver;dioxido(dioxo)chromium Chemical compound [Ag+].[Ag+].[O-][Cr]([O-])(=O)=O OJKANDGLELGDHV-UHFFFAOYSA-N 0.000 claims description 2
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- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 claims description 2
- 229910001958 silver carbonate Inorganic materials 0.000 claims description 2
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 claims description 2
- KKKDGYXNGYJJRX-UHFFFAOYSA-M silver nitrite Chemical compound [Ag+].[O-]N=O KKKDGYXNGYJJRX-UHFFFAOYSA-M 0.000 claims description 2
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 claims description 2
- 229940019931 silver phosphate Drugs 0.000 claims description 2
- 229910000161 silver phosphate Inorganic materials 0.000 claims description 2
- RAVDHKVWJUPFPT-UHFFFAOYSA-N silver;oxido(dioxo)vanadium Chemical compound [Ag+].[O-][V](=O)=O RAVDHKVWJUPFPT-UHFFFAOYSA-N 0.000 claims description 2
- 229910021607 Silver chloride Inorganic materials 0.000 claims 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims 1
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/015—Inorganic compounds
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/12—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
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- A—HUMAN NECESSITIES
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- A61K9/0012—Galenical forms characterised by the site of application
- A61K9/0053—Mouth and digestive tract, i.e. intraoral and peroral administration
- A61K9/0056—Mouth soluble or dispersible forms; Suckable, eatable, chewable coherent forms; Forms rapidly disintegrating in the mouth; Lozenges; Lollipops; Bite capsules; Baked products; Baits or other oral forms for animals
- A61K9/0058—Chewing gums
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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Abstract
本发明涉及除菌性食品添加剂及包含其的除菌性食品,更详细地涉及如下的除菌性食品添加剂,即,包括含有烧结在食品添加剂用基材的银的表面层,上述烧结的银包含氮气氛下烧结的银或氧气氛下烧结的氧化银,并且包含上述除菌性食品添加剂的除菌性食品具有优异的除菌效果。
Description
技术领域
本发明涉及除菌性食品添加剂及包含其的除菌性食品,更详细地涉及如下的除菌性食品添加剂,即,包括含有在食品添加剂用基材上烧结的银的表面层,烧结的银包含氮气氛下烧结的银或氧气氛下烧结的氧化银。
背景技术
作为除菌性食品的示例,含有木糖醇的口香糖对蛀牙以及其他口腔疾病具有除菌效果。事实上,自20世纪70年代早期以来,木糖醇对蛀牙和其他口腔疾病所带来的效果已通过多种体内或体外实验、临床及实际调查等研究结果来证实了其有效性。但是,含有木糖醇的口香糖在其除菌效果方面上存在不完善的部分。
牙科医学上的包括蛀牙、牙龈炎、牙周病等的各种口腔疾病可以由各种原因引起。上述原因可分为全身性原因及局部性原因,众所周知,更重要的原因为局部性原因。局部性原因中最重要的一点在于经常存在于口腔内的细菌,即病原性微生物。
另一方面,在自然界中,成千上万的微生物广泛存在于各种生态***中,并且这种微生物引起各种疾病及污染。例如,到目前为止,已知在人的口腔内大约有300多种微生物驻留在牙齿表面、牙根部的牙齿与牙龈之间、舌头的表面等,当进行适当的口腔卫生活动时,这种微生物的存在可以说是正常现象。
但是,若不进行适当的口腔卫生活动,则有可能因上述的微生物中的病原性微生物而引起蛀牙、口臭,牙龈炎或牙周病等各种口腔疾病,并且在严重的情况下有可能失去牙齿。作为一例,因驻留在口腔内的病原性微生物的发酵作用而使附着于牙齿上的食物残渣的糖或淀粉等的碳水化合物降解,由此产生的乳酸有可能使牙齿硬组织的石灰脱壳并产生蛀牙,当大量增殖厌氧性病原菌体时,有可能称为各种口腔疾病的原因。
驻留在口腔内的病原性微生物附着于牙齿表面上,经过几小时后形成被称为齿菌斑的细菌群体并及进行增殖,刚开始病原性微生物集中附着于可见的牙龈上部的牙齿表面并形成齿菌斑,但逐渐发展成在牙龈下部的牙齿表面也形成齿菌斑。当上述齿菌斑在牙齿表面形成时,病原性微生物利用进入口腔内的糖来产生酸,该酸使作为牙齿主成分的矿物质进行脱碳酸钙,从而可引发破坏牙齿的蛀牙。
另一方面,在存在于牙龈下部的齿菌斑的细菌中,特别时厌氧性革兰氏阴性微生物分泌毒素、蛋白水解酶等来直接破坏牙周组织或与我们身体的免疫细胞反应,从而诱导多种免疫物质的生产,并且这些物质有可能引起牙周组织的炎症和破坏。
牙齿或牙周组织被破坏一次可以得到治疗,但无法恢复成原来的组织状态,在这一点上存在严重性,因此,在根源上阻断作为这些局部原因的典型因素的病原性微生物在口腔内的繁殖过程可以为预防或快速治疗口腔疾病的方法。
引起如上所述的口腔疾病的微生物具有变形链球菌、牙龈卟啉单胞菌等。变形链球菌为蛀牙的致病菌并且为多种口腔疾病的原因。尤其,变形链球菌的生长过程中所产生的葡聚糖和乳酸破坏牙齿的牙釉质并产生牙菌斑并引发蛀牙。
在以往,作为除菌性酶使用如叶绿素铜钠、氟化钠或苄索氯铵等的含有氟和氯成分的复合物、包含苯甲酸等的芳香羧酸、尿囊素、醋酸生育酚、抗纤维蛋白酶或抗生素等。
但是,在含有上述氟和氯成分的复合物的情况下,对人体的安全性存在问题,在抗生素的情况下存在如下缺点,即,有可能引起包括腹泻、呕吐等的对全身的全身性副作用,并且有可能引发口腔内耐药菌的出现及菌***替症,因此难以长期使用,而仅用于治疗剂。因此,实际情况为迫切需要研究开发出易于预防或治疗且即使长期使用也不出现如抗生素等的耐药性或安全性问题,并且如含有氟和氯成分的复合物等的副作用也不成为问题的源自天然物质的预防或治疗口腔疾病的组合物。并且,现有的除菌性食品添加剂及酶等的除菌效果在即刻感受除菌效果的方面上具有局限性。
(现有技术文献)
(专利文献)
(专利文献1)韩国授权专利第10-1046621号
发明内容
要解决的技术问题
为了改善现有的难以感受除菌性食品的即刻性除菌效果的问题,本发明的目的在于,提供通过包括具有含有烧结的银的表面层的滑石来在数分钟的短时间内具有优异的除菌效果的食品添加剂及包含其的除菌性食品。
但是,本发明所要解决的技术问题不限定于在上文中所提出的技术问题,本领域的技术人员从下文描述来明确理解未提及的其他技术问题。
解决问题的方案
本发明一实施方式提供如下的除菌性食品添加剂,即,包括含有在食品添加剂用基材上烧结的银的表面层,并且上述烧结的银为氮气氛下烧结的银或氧气氛下烧结的氧化银。
并且,本发明一实施方式提供除菌性食品添加剂的制备方法,上述除菌性食品添加剂的制备方法包括:第一工序,将银盐类化合物粉末加入水中溶解以制备银盐类溶解液;第二工序,将上述银盐类溶解液涂敷于除菌性食品添加剂用基材上;以及第三工序,在氮气氛下或氧气氛下以440℃至500℃的温度对涂敷于上述除菌性食品添加剂用基材上的银盐类化合物进行烧结以在上述除菌性食品添加剂用基材上形成含有烧结的银的表面层。
并且,本发明一实施方式提供包含除菌性食品添加剂的除菌性食品。
发明的效果
本发明的除菌性食品添加剂及包含其的除菌性食品具有优异的除菌效果,尤其在食品中的口香糖、糖果、糖稀、巧克力、羊羹及棉花糖等中具有优异的除菌效果。
具体实施方式
以下,详细说明本发明的实例以便本发明所属技术领域的普通技术人员可容易实施。但是,本发明可实现为多种不同形式,而并不限定于在此说明的实例。
除菌性食品添加剂
本发明的除菌性食品添加剂为包括含有在食品添加剂用基材上烧结的银的表面层且上述烧结的银为氮气氛下烧结的银或氧气氛下烧结的氧化银的除菌性食品添加剂。
具体地,在本发明中,在包含滑石的食品添加剂用基材上涂敷银,上述银可以为氮气氛下烧结的银或氧气氛下烧结的氧化银。并且,还可理解成在滑石上涂敷银的方法。
上述含有烧结的银的表面层包含层状的氮气氛下烧结的银或氧气氛下烧结的氧化银,可以为位于含有烧结的银的表面层的层(以下,“含有层状氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层”)。
上述含有氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层可包含以颗粒状暴露于基材的表面的氮气氛下烧结的银或氧气氛下烧结的氧化银,并且可包含以颗粒状暴露于基材的表面的氮气氛下烧结的银或氧气氛下烧结的氧化银以及以颗粒状分散于基材内的氮气氛下烧结的银或氧气氛下烧结的氧化银,可以为位于食品添加剂用基材的表面的层(以下,“含有颗粒状的氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层”)。
在滑石颗粒上含有氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层的厚度可以为0.1μm至100μm。在此范围的情况下,除菌效果优秀。
相对于含有层状的氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层的总重量,可包含1重量百分比至50重量百分比的氮气氛下烧结的银或氧气氛下烧结的氧化银。在上述范围内,初期除菌性的效果优秀。在含有层状的氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层中可包含如氧化银等的银化合物、其他杂质等,还可包含除了银化合物之外的其他除菌剂成分。
滑石为粉状滑石,其成分为3MgO·4SiO·H2O。具有从白色到淡黄白色的如油脂(grease)的滑润感。滑石颗粒与氮气氛下烧结的银或氧气氛下烧结的氧化银的重量比为100:0.1至50,优选地,可以为100:1至40。
当上述滑石颗粒状的包含氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层包含上述范围内的任一范围的上述氮气氛下烧结的银及氧气氛下烧结的氧化银时,初期除菌性优秀。
具有含有氮气氛下烧结的银或氧气氛下烧结的氧化银的表面层的滑石颗粒的直径可以为1μm至20μm。并且,除了滑石之外,还可使用二氧化硅、硬脂酸镁等来作为食品添加剂用基材。
作为除菌性食品添加剂,优选地,相对于食品用组合物总重量,包含0.03重量百分比以上且5重量百分比以下的范围内的具有含有烧结的银或氧气氛下烧结的氧化银的表面层的滑石颗粒。其中,所谓食品用是指在选自由口香糖、糖果、糖稀、巧克力、羊羹及棉花糖组成的组中的一种中使用。
除菌性食品添加剂的制备方法
本发明的除菌性食品添加剂的制备方法包括:第一工序,将银盐类化合物粉末加入水中溶解以制备银盐类溶解液;第二工序,将上述银盐类溶解液涂敷于除菌性食品添加剂用基材上;以及第三工序,在氮气氛下或在氧气氛下对涂敷于上述除菌性食品添加剂用基材上的银盐类化合物进行烧结以在上述除菌性食品添加剂用基材上形成含有烧结的银的表面层。其中,在上述第一工序中,可向100重量份的水中添加1重量份至10重量份的银盐类化合物粉末。
上述银盐类化合物可选自由碳酸银、氯酸银、铬酸银、钒酸银、锰酸银、硝酸银、亚硝酸银、高氯酸银、磷酸银、乙酸银等及它们的混合物。
在上述第三工序中,烧结温度可以为440℃至500℃。烧结温度可根据银盐类化合物的种类和除菌性食品添加剂用基材而不同。
如此制备的除菌性食品添加剂通过水分洗脱的银离子来对存在于身体各部位,尤其对存在于口腔内的许多口腔中的有害菌类进行除菌,并清洁口腔卫生。
除菌性食品
本发明的除菌性食品可包含除菌性食品添加剂。具体地,除菌性食品可以为选自由口香糖、糖果、糖稀、巧克力、羊羹及棉花糖组成的组中的一种。
尤其,优选用作口香糖的除菌性食品添加剂。在口腔中咀嚼规定时间口香糖之后,唾液流出,唾液与包含于口香糖中的具有银烧结涂覆层的滑石相接触,使得具有除菌性。因此,可在咀嚼口香糖期间明显减少口腔内细菌。尤其,对变形链球菌或牙龈卟啉单胞菌的除菌效果优秀。咀嚼口香糖的时间可根据口香糖胶基的种类而不同,但可在1分钟以上起到效果,优选地,为3分钟以上,更优选地,为咀嚼5分钟以上口香糖时可起到除菌效果。
除菌性口香糖包含口香糖胶基及口香糖涂层。作为上述口香糖胶基,可包含选自由天然胶、聚异丁烯、聚乙酸乙烯酯、胶酯、微晶蜡、增塑剂以及重量剂组成的组中的至少一种,但不限定于此。例如,口口香糖胶基包含5~15重量百分比的天然胶、5~20重量百分比的聚异丁烯、30~50重量百分比的聚乙酸乙烯酯以及3~10重量百分比的胶酯作为主要成分,并且包含5~15重量百分比的微晶蜡、5~15重量百分比的增塑剂、10~20重量百分比的增量剂。
天然胶可包含选自由树胶、节路顿胶、索马树胶及香豆胶乳组成的组中的至少一种,其起到在口腔温度下具有适当的质地感的作用。优选地,相对于口香糖胶基总重量,使用5~15重量百分比的天然胶。当天然胶的含量小于5重量百分比时,在赋予粘性质地感的方面上存在局限性,当天然胶的含量大于20重量百分比时,粘性过强且弹性强,因此不适合咀嚼。
聚异丁烯具有赋予口香糖组织的粘性和弹性的作用,相对于口香糖胶基总重量,包含5~20重量百分比为优选。当聚异丁烯的含量小于5重量百分比时,在赋予粘性质地感的方面上存在局限性,当聚异丁烯的含量大于20重量百分比时,粘性过强且弹性强,因此不适合咀嚼。
聚乙酸乙烯酯具有赋予口香糖弹性和口香糖的硬度的作用,相对于口香糖胶基总重量,包含30~50重量百分比为优选。当聚乙酸乙烯酯的含量小于30重量百分比时,口香糖组织变得松软并易受如热、湿气等的外部环境的影响,因此有可能引起口香糖胶基的渗漏,当聚乙酸乙烯酯的含量大于50重量百分比时,口香糖的咀嚼感不柔软。
胶酯具有赋予口香糖组织的柔软性及形成泡泡口香糖的涂层的作用,相对于口香糖胶基总重量,使用3~10重量百分比为优选。当胶酯的含量小于3重量百分比时,存在口香糖的咀嚼感不柔软的局限性,当胶酯的含量大于10重量百分比时,口香糖组织变得松软。
微晶蜡具有增强天然树脂的转换点及改善混合性能的作用,相对于口香糖胶基总重量,使用5~15重量百分比为优选。当微晶蜡的含量小于5重量百分比时,在保持柔软的咀嚼感的方面上存在局限性,当微晶蜡的含量大于15重量百分比时,在改善弹性体及树脂之间的混合性能的方面上存在局限性。
增塑剂具有赋予口香糖胶基的柔软性的软化剂作用,相对于口香糖胶基总重量,包含5~15重量百分比为优选。当增塑剂的含量小于5重量百分比时,口香糖胶基的质地感很硬,或者因口香糖胶基进行冲压时的接缝变弱而发生糖浆的渗漏,当增塑剂的含量大于15重量百分比时,口香糖胶基的外皮部分易受外部温度、湿度影响而有可能发生糖浆的渗漏。
增量剂具有改善口香糖整体的立体感的作用,可使用碳酸钙,相对于口香糖胶基总重量,使用10~20重量百分比为优选。当增量剂的含量小于10重量百分比时,口香糖的立体感降低,当增量剂的含量大于20重量百分比时,口香糖的弹性降低。
本发明的口香糖胶基可包含弹性体(a)和树脂(b),弹性体(a)包含天然口香糖及聚异丁烯,树脂(b)包含聚乙酸乙烯酯及胶酯。优选地,这种弹性体和树脂以1:2~1:4的重量比混合使用。当混合比率小于1:2时,存在口香糖组织变弱的问题,当混合比率大于1:4时,口香糖过硬不柔软,因此有可能发生糖浆的渗漏。
并且,在以上述范围内混合的口香糖胶基在常温(25℃)下可具有1000000~5000000cp(布氏粘度计(Brookfield Viscometer),110℃温度,0.5RPM)的粘度。当粘度大于5000000cp时,口香糖质地感有可能***,当粘度小于1000000cp时,口香糖组织有可能变弱。
优选地,相对于除菌性口香糖总重量,包含20~40重量百分比的口香糖胶基。当口香糖胶基的含量小于20重量百分比时,口香糖的组织的强度变弱,因此有可能发生口香糖胶基的渗漏,当口香糖胶基的含量大于40重量百分比时,存在咀嚼感及制备工序上的问题,因此因口香糖胶基之间的接缝变弱而有可能发生渗漏。
除菌性口香糖的涂层还可额外地包含选自由保湿剂、乳化剂、香料及酸味剂组成的组中的至少一种添加剂。
具有含有烧结的银的表面层的滑石颗粒可包含在除菌性口香糖的口香糖胶基及口香糖涂层的一侧或两侧。优选地,相对于除菌性口香糖的总重量,使用0.03重量百分比~5重量百分比的具有含有烧结的银的表面层的滑石颗粒,当小于0.03重量百分比时,除菌效果降低,当大于5重量百分比时,口香糖的口感不佳,有可能存在作为口香糖组合物的使用限制。并且,除了滑石之外,可使用二氧化硅、硬脂酸镁等作为食品添加剂用基材。
并且,根据需要,作为口香糖的添加剂,可包含白糖、糖稀、果糖或转化糖或它们的混合物及纯净水。
根据本发明的除菌性口香糖组合物通过原料计量、投入、混合、提取、成型、冲压、冷却、熟化、包装的方法制备而成,并且本领域可应用的方法不受限制。
以下,利用本发明的实验例来进一步详细说明,本发明的范围不受限于下文中的实验例。
【实验例】包含本发明的除菌性食品添加剂的试验液的除菌性评价
接下来进行了本发明的具有银烧结的涂覆层的球体的除菌性实验。试验在日本食品分析中心进行。
在35℃(±1℃)温度下,在普通的琼脂培养基(日本荣研化学株式会社)中培养单胞菌及变形链球菌测试细菌18小时~24小时之后,悬浮于纯净水(金黄色葡萄球菌的情况下为悬浮于生理盐水中)中,进行调配以使细菌数量为107~108/ml并作为测试细菌液。临床标本如下:
临床标本:具有烧结的银的涂覆层的球体
对照:减菌合成树脂制成的容器中加入纯净水
试验液:向经干热灭菌(170℃,1小时)的临床标本中盛有200ml矿泉水的试样中接种2ml的测试细菌液以作为试验液。在20℃(±1℃)储存,6小时及24小时之后在SCDLP培养基(日本制药株式会社)中直接将试验液稀释10倍,利用细菌数量测定用培养基来测定了试验液中的活细胞计数。
试验结果示于下表1、表2中。除菌性试验的结果确认了对单胞菌及变形链球菌具有充分的除菌效果。表1为在试验液的单胞菌测试细菌下的根据时间的活细胞计数测定结果,表2为在试验液的变形链球菌测试细菌下的根据时间的活细胞计数测定结果。
表1.试验液的活细胞计数测定结果
*(<10000:表示未检测出)储存温度:20℃
如上表1所示,可确认到,就单胞菌而言,本发明的试验液从5~10分钟开始出现与对照组具有明显差异的活细胞计数。并且确认到,从20分钟以后活细胞计数几乎未检测出。
表2.试验液的活细胞计数测定结果
*(<10000:表示未检测出)储存温度:20℃
如上表2所示,可确认到,就变形链球菌而言,本发明的试验液从10~15分钟开始出现与对照组具有明显差异的活细胞计数,并且确认到,从20分钟以后活细胞计数几乎未检测出。
接着,为了研究具有含有烧结银的涂覆层的滑石在口腔中具有何种效果,进行了银离子检测试验。所使用的银原料使用了硝酸银粉末水溶液。并且,滑石使用了食品添加剂No.194矿物滑石。首先,将100g硝酸银粉末投入到1升水中以制备了溶解液。之后,投入滑石粉末以制备了食品添加剂银溶解液的混合物,并且以450℃的平均温度加热烧结,由此获得了涂敷了银烧结涂层的滑石粉末。接着,以99.95:0.05的重量比混合了口香糖和涂敷有银烧结涂层的滑石粉末。
在口腔中咀嚼含有以如上所述的方法制备的滑石粉末的口香糖之后,用银离子含量测定仪测定了在口腔中从含有涂敷有银烧结涂层的滑石粉末的口香糖洗脱的银离子值。在口腔中开始咀嚼后的5分钟后的银离子含量为0.01ppm,10分钟后的银离子含量为0.02ppm。因此,可通过测定银离子含量,来确认了对于作为口腔中的有害菌的单胞菌、变形链球菌等的银离子的除菌效果。因此,确认了包含本发明的除菌性食品添加剂的除菌性食品具有优异的除菌效果。
Claims (11)
1.一种除菌性食品添加剂,其特征在于,
包括含有在食品添加剂用基材上烧结的银的表面层,
上述烧结的银为氮气氛下烧结的银或为氧气氛下烧结的氧化银。
2.根据权利要求1所述的除菌性食品添加剂,其特征在于,上述食品添加剂用基材包含滑石颗粒。
3.根据权利要求2所述的除菌性食品添加剂,其特征在于,含有在上述滑石颗粒上烧结的银的表面层的厚度为0.1μm至100μm。
4.根据权利要求2所述的除菌性食品添加剂,其特征在于,上述滑石颗粒与上述氮气氛下烧结的银或氧气氛下烧结的氧化银的重量比为100:0.1~50。
5.一种除菌性食品添加剂的制备方法,其特征在于,包括:
第一工序,将银盐类化合物粉末加入水中溶解以制备银盐类溶解液;
第二工序,将上述银盐类溶解液涂敷于除菌性食品添加剂用基材上;以及
第三工序,在氮气氛下或氧气氛下以440℃至500℃的温度对涂敷于上述除菌性食品添加剂用基材上的银盐类化合物进行烧结以在上述除菌性食品添加剂用基材上形成含有烧结的银的表面层。
6.根据权利要求5所述的除菌性食品添加剂的制备方法,其特征在于,在上述第一工序中,向100重量份的上述水中添加1重量份至10重量份的上述银盐类化合物粉末。
7.根据权利要求5所述的除菌性食品添加剂的制备方法,其特征在于,上述银盐类化合物为选自由碳酸银、氯酸银、氯化银、铬酸银、钒酸银、锰酸银、硝酸银、亚硝酸银、高氯酸银、磷酸银、乙酸银及它们的混合物。
8.一种除菌性食品,其特征在于,包含权利要求1至4中任一项的除菌性食品添加剂。
9.根据权利要求8所述的除菌性食品,其特征在于,上述食品为选自由口香糖、糖果、糖稀、巧克力、羊羹及棉花糖组成的组中的一种。
10.根据权利要求9所述的除菌性食品,其特征在于,上述口香糖包含口香糖胶基及口香糖涂层,上述口香糖胶基包含选自由天然胶、聚异丁烯、聚乙酸乙烯酯、胶酯、微晶蜡、增塑剂及重量剂组成的组中的至少一种。
11.根据权利要求10所述的除菌性食品,其特征在于,上述口香糖涂层包含选自由保湿剂、乳化剂、香料及酸味剂组成的组中的至少一种添加剂。
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