CN111943573A - Method for preparing lightweight concrete aerated building block from lithium slag - Google Patents

Method for preparing lightweight concrete aerated building block from lithium slag Download PDF

Info

Publication number
CN111943573A
CN111943573A CN202010684173.5A CN202010684173A CN111943573A CN 111943573 A CN111943573 A CN 111943573A CN 202010684173 A CN202010684173 A CN 202010684173A CN 111943573 A CN111943573 A CN 111943573A
Authority
CN
China
Prior art keywords
lithium slag
admixture
preparing
lightweight concrete
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010684173.5A
Other languages
Chinese (zh)
Inventor
李良彬
彭琴
郁兴国
陈超
艾刚华
王彬
付晓春
朱志全
李忠
肖成
廖海
刘小康
王计江
邓永根
陈玲
王春云
谢柳凤
符礼冬
黄小强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGXI GANFENG LITHIUM CO Ltd
Original Assignee
JIANGXI GANFENG LITHIUM CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGXI GANFENG LITHIUM CO Ltd filed Critical JIANGXI GANFENG LITHIUM CO Ltd
Priority to CN202010684173.5A priority Critical patent/CN111943573A/en
Publication of CN111943573A publication Critical patent/CN111943573A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention provides a method for preparing a lightweight concrete aerated building block from lithium slag. The method for preparing the lightweight concrete aerated building block from the lithium slag comprises the following steps of (1) drying the lithium slag at normal temperature to obtain dry lithium slag; (2) grinding the dried lithium slag to obtain ground lithium slag; (3) mixing the ground lithium slag, aluminum powder paste and quicklime, and adding an additive to obtain a concrete admixture; (4) introducing low-pressure saturated steam into the concrete admixture, heating and stirring the concrete admixture to obtain a stirred condensed soil admixture; (5) and placing the stirred condensed soil admixture into a mould for forming to obtain the formed condensed soil admixture. The building block of the method for preparing the lightweight concrete aerated building block by using the lithium slag mainly comprises the materials such as the lithium slag, the quicklime, the foaming agent and the like, has the advantages of low dry density, high compressive strength, low heat conductivity coefficient, convenience in transportation and the like, and can be widely used as building materials.

Description

Method for preparing lightweight concrete aerated building block from lithium slag
Technical Field
The invention relates to the field of concrete preparation and solid waste resource application, in particular to a method for preparing a lightweight concrete aerated block from lithium slag.
Background
The lithium slag is a by-product from the processing of spodumene (lepidolite) to produce lithium salts. And (2) carrying out high-temperature transformation roasting on spodumene (lepidolite) at 1100-1200 ℃, then carrying out acidification roasting on the spodumene by concentrated sulfuric acid, neutralizing and leaching, and the like, so as to convert lithium in the spodumene into a soluble lithium sulfate solution, and drying the separated insoluble slag to obtain the lithium slag. The process and technical conditions for extracting lithium from the lithium ore by the sulfuric acid method are relatively mature and stable, so that the chemical components and properties of the lithium slag are basically uniform and stable, the lithium slag mainly comprises SiO2, Al2O3, CaO and the like (shown in the following table), and the chemical components of the lithium slag are basically similar to those of clay. And most of SiO2 and Al2O3 in the lithium slag exist in an amorphous form, so that the slag has high volcanic ash activity and is an ideal building material. Because the lithium content in the lithium ore is very low, a large amount of lithium slag is generated after processing treatment, and 8-10 tons of lithium slag are generated every 1 ton of lithium salt is produced.
The most serious problem of the existing spodumene slag which is mainly used as a building material and a ceramic raw material and used for preparing a ceramic material is that the alkalinity is too strong, and the acidified spodumene needs to be neutralized by adding excessive soda ash in the process of extracting lithium, so the spodumene slag generally has strong alkalinity which can influence the ceramic performance, and the spodumene slag contains more impurities such as Fe2O3, Li2O and the like which can influence the whiteness of the ceramic, and the dosage of the spodumene slag is low, and the spodumene slag can only be used as an additive to be doped into the ceramic in a small amount. The lithium slag can replace cement to prepare concrete due to the volcanic ash activity, but needs to be mixed with other materials, so that the consumption is less and the economic benefit is low. A large amount of lithium slag can only be accumulated and treated, and the environment is polluted.
Disclosure of Invention
In view of the above, it is necessary to provide a method for preparing lightweight concrete aerated concrete blocks from lithium slag.
A method for preparing a lightweight concrete aerated building block from lithium slag comprises the following steps: (1) drying the lithium slag at normal temperature to obtain dry lithium slag; (2) grinding the dried lithium slag to obtain ground lithium slag; (3) mixing the ground lithium slag, aluminum powder paste and quicklime, and adding an additive to obtain a concrete admixture; (4) introducing low-pressure saturated steam into the concrete admixture, heating and stirring the concrete admixture to obtain a stirred condensed soil admixture; (5) placing the stirred condensed soil admixture into a mould for forming to obtain a formed condensed soil admixture; (6) standing the formed condensed soil admixture to obtain a solidified condensed soil admixture; (7) cutting the solidified clotted-soil admixture to obtain a cut clotted-soil admixture; (8) and putting the cut condensed soil admixture into a reaction kettle for autoclaving to obtain the lithium slag lightweight concrete aerated building block.
Further, the ground lithium slag, the aluminum powder paste and the quick lime are mixed in a ratio of 1:1: 1.
Further, the specific surface area of the ground lithium slag is 800 to 1200kg/m 2.
Further, the additive is at least one of a slurry stabilizer, a cement coagulant, a water repellent agent and a bubble regulator.
Further, the pressure of the low pressure saturated steam is 0.1 to 0.5Mpa, and the temperature of the low pressure saturated steam is 100 to 200 ℃.
Further, introducing the low-pressure saturated steam into the concrete admixture, heating to 40-60 ℃, and stirring.
And further, adding the formed condensed soil admixture into the aerated concrete block, and standing for 2 to 20 hours.
Further, steaming and pressing the cut condensed soil admixture in a vacuumizing, heating, constant temperature and cooling mode, wherein the steaming and pressing time is 8-12 hours.
The method for preparing the lightweight concrete aerated building block by using the lithium slag takes the lithium slag as a raw material, has heat preservation and heat insulation performance, mainly comprises the lithium slag, the quicklime, the foaming agent and other materials, has the advantages of low dry density, high compressive strength, low heat conductivity coefficient, convenience in transportation and the like, and can be widely used for building materials.
According to the method for preparing the lightweight concrete aerated building block by using the lithium slag, the lightweight concrete aerated building block takes the industrial waste lithium slag as a raw material, so that the environmental pollution can be reduced, the resource recycling is realized, and meanwhile, the building block can be adjusted in size and shape, can be made of local materials, and is low in cost and good in flexibility.
Furthermore, the lithium slag can be improved by physical excitation through the grinding of the ball mill, the fineness of the lithium slag particles can be improved through the grinding, and dislocation, defects, recrystallization and the like of crystal lattices in the minerals can be generated to different degrees, so that an amorphous structure which is easy to dissolve in water is formed on the surface of the minerals. The grinding treatment increases the contact area of the mineral particles and water, enhances the acting force of the mineral particles and water, accelerates the hydration reaction degree in the mineral particles and improves the activity of the mineral particles.
Furthermore, the lightweight concrete aerated block raw material consists of four parts of a gel material (such as cement), a foaming agent, aggregates (waste residues, silt and the like), and additives (a stabilizing agent, a water repellent agent and the like). The lithium slag in the lightweight concrete aerated building block prepared from the lithium slag is used as a gel material and an aggregate. Considering that the poor stability of the concrete caused by the high content of S03 in the lithium slag, the quick lime with low price is added for blending. The method has the advantages of large lithium slag consumption, cost saving, good gel performance of the lightweight concrete aerated block, high strength and good stability.
Furthermore, the lightweight concrete aerated block belongs to a porous material and has a lower elastic modulus, so that the lightweight concrete aerated block has good absorption and dispersion effects on vibration impact load, and meanwhile, the environment-friendly lightweight concrete aerated block has lighter weight and can effectively reduce the load of a building. Not easy to crack, long service life and good heat and sound insulation performance.
Drawings
FIG. 1 is a process flow chart of a method for preparing lightweight concrete aerated concrete blocks by using lithium slag.
Detailed Description
To facilitate an understanding of the invention, the invention will now be described more fully with reference to the accompanying drawings. Preferred embodiments of the present invention are shown in the drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
It will be understood that when an element is referred to as being "secured to" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The invention provides a method for preparing a lightweight concrete aerated building block from lithium slag, and with reference to a figure 1, the method comprises the following steps: (1) drying the lithium slag at normal temperature to obtain dry lithium slag; (2) grinding the dried lithium slag to obtain ground lithium slag; (3) mixing the ground lithium slag, aluminum powder paste and quicklime, and adding an additive to obtain a concrete admixture; (4) introducing low-pressure saturated steam into the concrete admixture, heating and stirring the concrete admixture to obtain a stirred condensed soil admixture; (5) placing the stirred condensed soil admixture into a mold for molding, and scraping the surface after pouring to ensure that the surface is smooth to obtain the molded condensed soil admixture; (6) standing the formed condensed soil admixture to obtain a solidified condensed soil admixture; (7) cutting the solidified clotted-soil admixture to obtain a cut clotted-soil admixture; (8) and putting the cut condensed soil admixture into a reaction kettle for steam pressure curing to obtain the lithium slag lightweight concrete aerated building block.
Wherein the ground lithium slag, the aluminum powder paste and the quicklime are mixed in a ratio of 1:1:1, and a small amount of additive is added. The lithium slag is a gel material and an aggregate, and the aluminum powder paste is added as a foaming agent to generate fine uniform foam. Because S03 content in the lithium slag is higher, S03 can cause the problem of poor stability of concrete, so that the lithium slag can be mixed with cheap quicklime and other industrial wastes.
Wherein the specific surface area of the ground lithium slag is 800 to 1200kg/m 2.
Wherein the additive is at least one of a slurry stabilizer, a cement coagulant, a water repellent agent and a bubble regulator. That is, the additive may be any one of a slurry stabilizer, a cement accelerator, a water repellent agent, and a bubble controlling agent, or may be a combination of two or more of the above agents.
Wherein the pressure of the low pressure saturated steam is 0.1 to 0.5Mpa, and the temperature of the low pressure saturated steam is 100 to 200 ℃.
Wherein the low-pressure saturated steam is introduced into the concrete admixture and is stirred after being heated to 40-60 ℃.
Wherein, the formed condensed soil admixture is added into the aerated block and then is kept stand for 2 to 20 hours, and then the demoulding can be carried out.
And autoclaving the cut condensed soil admixture in a vacuum-pumping, heating, constant-temperature and cooling curing manner, wherein the duration of the curing process is 8-12 hours.
According to the method for preparing the lightweight concrete aerated building block by using the lithium slag, the lightweight concrete aerated building block takes the industrial waste lithium slag as a raw material, so that the environmental pollution can be reduced, the resource recycling is realized, and meanwhile, the building block can be adjusted in size and shape, can be made of local materials, and is low in cost and good in flexibility.
Furthermore, the lithium slag can be improved by physical excitation through the grinding of the ball mill, the fineness of the lithium slag particles can be improved through the grinding, and dislocation, defects, recrystallization and the like of crystal lattices in the minerals can be generated to different degrees, so that an amorphous structure which is easy to dissolve in water is formed on the surface of the minerals. The grinding treatment increases the contact area of the mineral particles and water, enhances the acting force of the mineral particles and water, accelerates the hydration reaction degree in the mineral particles and improves the activity of the mineral particles.
Furthermore, the lightweight concrete aerated block raw material consists of four parts of a gel material (such as cement), a foaming agent, aggregates (waste residues, silt and the like), and additives (a stabilizing agent, a water repellent agent and the like). The lithium slag in the lightweight concrete aerated building block prepared from the lithium slag is used as a gel material and an aggregate. Considering that the poor stability of the concrete caused by the high content of S03 in the lithium slag, the quick lime with low price is added for blending. The method has the advantages of large lithium slag consumption, cost saving, good gel performance of the lightweight concrete aerated block, high strength and good stability.
Furthermore, the lightweight concrete aerated block belongs to a porous material and has a lower elastic modulus, so that the lightweight concrete aerated block has good absorption and dispersion effects on vibration impact load, and meanwhile, the environment-friendly lightweight concrete aerated block has lighter weight and can effectively reduce the load of a building. Not easy to crack, long service life and good heat and sound insulation performance.
Example one
And grinding 10kg of lithium slag by a ball mill for 2 hours, uniformly mixing the ground materials with 10kg of aluminum powder paste and 10kg of quicklime, adding 20L of water and 80g of stabilizer to prepare slurry, heating the slurry to 45 ℃ under low-pressure saturated steam, pouring the slurry into 600mm square blocks of 250mm x 200mm, standing the slurry for 5 hours, and demolding and maintaining the slurry to obtain the lightweight concrete aerated block sample 1.
Example two
And grinding 50kg of lithium slag by using a ball mill for 3 hours, uniformly mixing the ground materials with 50kg of aluminum powder paste and 50kg of quick lime, adding 120L of water, 250g of stabilizer and 100g of water repellent agent to prepare slurry, heating the slurry to 55 ℃ under low-pressure saturated steam, pouring the slurry into 600mm square blocks with the thickness of 250mm x 200mm, standing the square blocks for 3 hours, and demolding and maintaining the square blocks to obtain the lightweight concrete aerated block sample 2.
EXAMPLE III
And grinding 100kg of lithium slag by a ball mill until the specific surface area is 1200kg/m2, uniformly mixing the lithium slag with 100kg of aluminum powder paste and 100kg of quicklime, adding 250L of water and 500g of stabilizer to prepare slurry, heating the slurry to 60 ℃ under low-pressure saturated steam, pouring the slurry into a square block, standing the square block for 3 hours, and demolding and maintaining the square block to obtain a light concrete aerated block sample 3.
Example four
And grinding 10kg of lithium slag by using a ball mill for 2 hours, uniformly mixing the ground lithium slag with 10kg of aluminum powder paste and 10kg of quicklime/10 kg of fly ash, adding 30L of water and 60g of stabilizer to prepare slurry, heating the slurry to 45 ℃ under low-pressure saturated steam, pouring the slurry into 600mm250mm x 200mm square blocks, standing the square blocks for 4 hours, and demolding and maintaining the square blocks to obtain a light concrete aerated block sample 4.
EXAMPLE five
And grinding 100kg of lithium slag by a ball mill until the specific surface area is 1000 kg/m2, uniformly mixing the ground materials with 100kg of aluminum powder paste, 100kg of quicklime and 20kg of gypsum, adding 300L of water and 400g of bubble regulator to prepare slurry, heating the slurry to 50 ℃ under low-pressure saturated steam, pouring the slurry into 600mm square blocks of 250mm mm and 200mm square blocks, standing the slurry for 4.5 hours, and demolding and maintaining the square blocks to obtain the lightweight concrete aerated block sample 5.
The measurement results of the performance parameters of the lithium slag lightweight concrete aerated block samples prepared in the embodiment examples 1 to 5 are shown in the following table:
name (R) Dry density/kg/m3 Compressive strength/Mpa Dry shrinkage value Freezing resistance/MPa Thermal conductivity/W/(m X K)
Sample 1 565 5.2 0.47 4.17 0.12
Sample 2 544 5.4 0.49 4.65 0.12
Sample 3 547 5.9 0.47 4.33 0.13
Sample No. 4 552 5.7 0.46 4.22 0.12
Sample No. 5 533 5.5 0.45 4.45 0.14
The experiment prepares the building block into 600mm250mm x 200mm square building block, actually makes arbitrary shape according to the demand. According to the standards of the strength grade division and the density grade division of the lightweight concrete, the lithium slag lightweight concrete aerated building block prepared by the method can meet the A5.0 and B06 grades. The product has small volume weight and higher compressive strength, and is a qualified concrete material.
Environment-friendly lightweight concrete aerated block strength grade
Grade A0.5 A1.0 A1.5 A2.5 A3.5 A5.0 A7.5
Compressive strength ≥0.5 ≥1.0 ≥1.5 ≥2.5 ≥3.5 ≥5.0 ≥7.5
Environmental protection lightweight concrete aerated block density grade
Grade B03 B04 B05 B06 B07 B08 B09 B10
Density/kg/m3 ≤330 ≤430 ≤530 ≤630 ≤730 ≤830 ≤930 ≤1030
Coefficient of thermal conductivity w/m.k ≤0.08 ≤0.10 ≤0.12 ≤0.14 ≤0.18 ≤0.21 ≤0.24 ≤0.27
The experimental detection result shows that the method for extracting lithium has high lithium recovery rate, and the lithium recovery rate is over 90 percent and can reach 95 percent at most. Meanwhile, the content of lithium oxide in the filter residue is lower than 0.2%, and the content of soluble lithium can be ignored. However, clay leachate contains more Na and K ions, and other lithium compounds need to be prepared by further removing impurities.
The above examples only express embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (8)

1. The method for preparing the lightweight concrete aerated building block by using the lithium slag is characterized by comprising the following steps of:
(1) drying the lithium slag at normal temperature to obtain dry lithium slag;
(2) grinding the dried lithium slag to obtain ground lithium slag;
(3) mixing the ground lithium slag, aluminum powder paste and quicklime, and adding an additive to obtain a concrete admixture;
(4) introducing low-pressure saturated steam into the concrete admixture, heating and stirring the concrete admixture to obtain a stirred condensed soil admixture;
(5) placing the stirred condensed soil admixture into a mould for forming to obtain a formed condensed soil admixture;
(6) standing the formed condensed soil admixture to obtain a solidified condensed soil admixture;
(7) cutting the solidified clotted-soil admixture to obtain a cut clotted-soil admixture;
(8) and putting the cut condensed soil admixture into a reaction kettle for autoclaving to obtain the lithium slag lightweight concrete aerated building block.
2. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: and mixing the ground lithium slag, the aluminum powder paste and the quicklime in a ratio of 1:1: 1.
3. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: the specific surface area of the ground lithium slag is 800 to 1200kg/m 2.
4. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: the additive is at least one of a slurry stabilizer, a cement coagulant, a water repellent agent and a bubble regulator.
5. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: the pressure of the low-pressure saturated steam is 0.1 to 0.5Mpa, and the temperature of the low-pressure saturated steam is 100 to 200 ℃.
6. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: and introducing the low-pressure saturated steam into the concrete admixture, heating to 40-60 ℃, and stirring.
7. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: and adding the formed condensed soil admixture into the air building block, and standing for 2 to 20 hours.
8. The method for preparing the lightweight concrete aerated concrete block by using the lithium slag as claimed in claim 1, which is characterized by comprising the following steps of: and (3) autoclaving the cut condensed soil admixture in a vacuumizing, heating, constant temperature and cooling manner, wherein the autoclaving time is 8-12 hours.
CN202010684173.5A 2020-07-16 2020-07-16 Method for preparing lightweight concrete aerated building block from lithium slag Pending CN111943573A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010684173.5A CN111943573A (en) 2020-07-16 2020-07-16 Method for preparing lightweight concrete aerated building block from lithium slag

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010684173.5A CN111943573A (en) 2020-07-16 2020-07-16 Method for preparing lightweight concrete aerated building block from lithium slag

Publications (1)

Publication Number Publication Date
CN111943573A true CN111943573A (en) 2020-11-17

Family

ID=73339941

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010684173.5A Pending CN111943573A (en) 2020-07-16 2020-07-16 Method for preparing lightweight concrete aerated building block from lithium slag

Country Status (1)

Country Link
CN (1) CN111943573A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116514571A (en) * 2022-12-21 2023-08-01 咸阳陶瓷研究设计院有限公司 Method for preparing inorganic sound absorbing material by using lithium slag
CN116675479A (en) * 2023-04-26 2023-09-01 佛山市交通科技有限公司 Soil cementing material and preparation method thereof
CN117263641A (en) * 2023-10-07 2023-12-22 生态环境部南京环境科学研究所 Autoclaved aerated concrete material prepared by efficiently utilizing sulfur-alkali component in reprocessed lithium slag and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105645851A (en) * 2016-01-12 2016-06-08 四川天齐锂业股份有限公司 Lithium slag aerated brick and preparation method thereof
CN106187289A (en) * 2016-07-04 2016-12-07 盐城工学院 A kind of method utilizing nickel slag and biomass powder to prepare light foamed ceramic
CN106242441A (en) * 2016-09-05 2016-12-21 荆门市格林美新材料有限公司 Use the method that lithium slag prepares air-entrained concrete building block
CN109293328A (en) * 2018-09-19 2019-02-01 贵州师范大学 The production method of the steam pressurized lithium dreg concrete building block of light transmission
CN109665859A (en) * 2018-09-19 2019-04-23 贵州师范大学 The production method of rice-straw fibre air entrained concrete
CN110950619A (en) * 2019-05-29 2020-04-03 湖北大学 Preparation method for producing autoclaved aerated concrete from lithium slag and product thereof
CN111116156A (en) * 2019-12-19 2020-05-08 江苏盐砼新材料科技有限公司 Low-damage high-strength aerated concrete block and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105645851A (en) * 2016-01-12 2016-06-08 四川天齐锂业股份有限公司 Lithium slag aerated brick and preparation method thereof
CN106187289A (en) * 2016-07-04 2016-12-07 盐城工学院 A kind of method utilizing nickel slag and biomass powder to prepare light foamed ceramic
CN106242441A (en) * 2016-09-05 2016-12-21 荆门市格林美新材料有限公司 Use the method that lithium slag prepares air-entrained concrete building block
CN109293328A (en) * 2018-09-19 2019-02-01 贵州师范大学 The production method of the steam pressurized lithium dreg concrete building block of light transmission
CN109665859A (en) * 2018-09-19 2019-04-23 贵州师范大学 The production method of rice-straw fibre air entrained concrete
CN110950619A (en) * 2019-05-29 2020-04-03 湖北大学 Preparation method for producing autoclaved aerated concrete from lithium slag and product thereof
CN111116156A (en) * 2019-12-19 2020-05-08 江苏盐砼新材料科技有限公司 Low-damage high-strength aerated concrete block and preparation method thereof

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
LUO Q: ""Influence of lithium slag from lepidolite on the durability of concrete"", 《3RD INTERNATIONAL CONFERENCE ON ENERGY MATERIALS AND ENVIRONMENT ENGINEERING》 *
侯勇辉: ""掺锂渣再生粗骨料混凝土力学性能试验研究"", 《新型建筑材料》 *
卓维松: "《建筑施工技术》", 30 June 2013, 厦门大学出版社 *
闫振甲: "《高性能泡沫混凝土保温制品实用技术》", 30 June 2015, 中国建材工业出版社 *
高连玉: "《蒸压加气混凝土建筑制品生产及应用》", 31 August 2015, 中国建材工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116514571A (en) * 2022-12-21 2023-08-01 咸阳陶瓷研究设计院有限公司 Method for preparing inorganic sound absorbing material by using lithium slag
CN116675479A (en) * 2023-04-26 2023-09-01 佛山市交通科技有限公司 Soil cementing material and preparation method thereof
CN116675479B (en) * 2023-04-26 2024-03-22 佛山市交通科技有限公司 Soil cementing material and preparation method thereof
CN117263641A (en) * 2023-10-07 2023-12-22 生态环境部南京环境科学研究所 Autoclaved aerated concrete material prepared by efficiently utilizing sulfur-alkali component in reprocessed lithium slag and preparation method thereof

Similar Documents

Publication Publication Date Title
CN111943573A (en) Method for preparing lightweight concrete aerated building block from lithium slag
CN110218051A (en) A kind of high strength lightweight aggregate concrete and its preparation process
CN105777184B (en) Autoclaved aerated concrete building block adopting ceramic polishing waste and preparation method thereof
CN101289332A (en) Low-temperature ceramic foam material and production method thereof
JP2009518276A (en) MULTIFUNCTIONAL COMPOSITION FOR COAGABLE COMPOSITE MATERIAL AND METHOD FOR PRODUCING THE COMPOSITION
CN109896808B (en) Magnesium silicate system gel material prepared based on magnesite tailings and application thereof
CN108975815A (en) Recycled concrete manufacturing process
CN110655338A (en) Copper slag-based cementing material, preparation method and application
CN101519896A (en) Vapor-pressing plaster brick and preparation method thereof
KR101151605B1 (en) A composition of waste gypsum block for pubric works, waste gypsum block using the same and a manufacturing method thereof
CN110950619A (en) Preparation method for producing autoclaved aerated concrete from lithium slag and product thereof
CN109250980A (en) A kind of steel slag concrete and preparation method thereof
CN112142400A (en) Concrete with steel slag and waste rubber as fine aggregate and application thereof
CN114890765A (en) Plastering gypsum and preparation method thereof
CN112592148B (en) Method for preparing structural material by utilizing brick-concrete building solid waste reclaimed sand powder with high doping amount
CN115849824B (en) Electric furnace nickel slag carbon fixation and high-value utilization method thereof in concrete
CN115259823B (en) Lightweight high-strength low-thermal-conductivity aerated concrete and preparation method thereof
CN109336428B (en) Preparation method of layered cement and MSWI bottom ash alkali-activated double-gelling system material
CN114621023B (en) Method for preparing autoclaved aerated block by using phosphogypsum and dredging sediment and product
CN111003982A (en) Ultrafine silica sand tailing powder autoclaved aerated concrete and preparation method thereof
CN112592077B (en) Brick-concrete building waste residue cold-recycling cementing material and use method thereof
CN106631107A (en) Mica tailings aerated building block and preparation method thereof
CN112094084A (en) Inorganic artificial stone and preparation method thereof
CN104311112B (en) Add gas concrete of industrial residue and preparation method thereof
CN117430390B (en) Method for preparing water permeable brick by using granite stone waste

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20201117