CN111864233B - Hydrogen purity detection device of hydrogen supply system - Google Patents

Hydrogen purity detection device of hydrogen supply system Download PDF

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Publication number
CN111864233B
CN111864233B CN202010768303.3A CN202010768303A CN111864233B CN 111864233 B CN111864233 B CN 111864233B CN 202010768303 A CN202010768303 A CN 202010768303A CN 111864233 B CN111864233 B CN 111864233B
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hydrogen
molar mass
hydrogen supply
value
supply pipeline
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CN111864233A (en
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何晓波
翟双
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Shanghai Re Fire Energy and Technology Co Ltd
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Shanghai Re Fire Energy and Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N7/00Analysing materials by measuring the pressure or volume of a gas or vapour
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0432Temperature; Ambient temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0438Pressure; Ambient pressure; Flow
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The invention provides a hydrogen purity detection device of a hydrogen supply system, which comprises: the hydrogen supply assembly comprises a hydrogen cylinder assembly and a hydrogen supply pipeline connected with the hydrogen cylinder assembly, and a pressure reducing valve is arranged on the hydrogen supply pipeline; the detection assembly comprises a controller, a flow sensor, a first pressure sensor and a temperature sensor, wherein the flow sensor, the first pressure sensor and the temperature sensor are arranged on a hydrogen supply pipeline and behind a pressure reducing valve, the controller is connected with the flow sensor, the first pressure sensor and the temperature sensor, the current gas molar mass in the hydrogen supply pipeline is obtained through real-time calculation, the current gas molar mass is compared with the boundary molar mass value of preset hydrogen, and if the current gas molar mass value is larger than the boundary molar mass value of the hydrogen, a signal that the hydrogen is impure is output. The method can efficiently and accurately judge the gas purity, and can be applied to the judgment of the hydrogen purity in the hydrogen supply system of the fuel cell automobile.

Description

Hydrogen purity detection device of hydrogen supply system
Technical Field
The invention relates to the field of a hydrogen supply system of a fuel cell automobile, in particular to a hydrogen purity detection device of the hydrogen supply system.
Background
The fuel cell vehicle is a new energy power vehicle which directly converts chemical energy in fuel and oxide into electric energy to drive a motor through electrochemical reaction of the fuel cell without fuel combustion. The fuel used in the current vehicle-mounted fuel cell system is generally high-purity hydrogen gas with a purity of 99% or more or high-purity hydrogen reformed gas obtained by reforming a hydrogen-containing fuel. Several main methods for obtaining high-purity hydrogen reformed gas from hydrogen-containing fuel reforming include hydrogen production from byproducts in the chlor-alkali industry, hydrogen production from chemical raw materials (methanol cracking, ethanol cracking, liquid ammonia cracking, etc.), novel hydrogen production methods (biomass, photochemistry, etc.), and hydrogen production from petrochemical resources (petroleum cracking, water gas method, etc.).
When the replacement of the hydrogen bottle of the fuel cell is carried out or the reformed hydrogen adopted is not strictly detected, the gas in the hydrogen bottle has more gas impurities, such as N2、O2、H2O, CO, nitrogen oxides, chlorides, methane, etc.; and the excessive content of hydrogen-supplying gas impurities can directly cause the poisoning of the anode catalyst of the vehicle hydrogen fuel cell, the serious performance reduction is caused, and the service life of the vehicle fuel cell is greatly reduced. Therefore, it is necessary to detect and identify impurities in the hydrogen gas of the fuel cell vehicle air supply system in advance to ensure that the back end of the hydrogen gas is supplied to the fuel cell systemThe quality of the hydrogen reaches the use requirement.
The traditional method for detecting impurity in gas mainly comprises collecting target gas, and analyzing and detecting the gas sample on a specific mass spectrometer device to determine the content of each component in the gas, such as patent CN 201911102094.2; although this method can accurately determine the specific content of each gas, the complicated collection and detection process requires a lot of time and labor.
Secondly, there is also patent CN201810634256.6 that component content in the anode subsystem is detected by the anode model of the fuel cell system, and then component content of new hydrogen is calculated back by the components of the anode subsystem, but the method needs a fuel cell anode component estimation model with sufficient accuracy, and from the perspective of engineering application, the method is complicated, and the model involves many physical field calculation processes such as fuel cell, etc., and needs a large amount of system and stack test data to verify the model estimation accurately.
With the increasing of fuel cell vehicles in online operation at home and abroad, in order to avoid the great reduction of the performance and the service life of a fuel cell stack caused by impure front-end hydrogen gas sources of the fuel cell, the hydrogen entering a fuel cell system needs to be subjected to advanced purity detection so as to avoid unnecessary damage of the stack.
Disclosure of Invention
In view of the above-mentioned shortcomings of the prior art, an object of the present invention is to provide a hydrogen purity detection apparatus for a hydrogen supply system, which is used to solve the problem in the prior art that the hydrogen purity in the hydrogen supply system cannot be detected quickly and accurately.
In order to solve the above technical problem, the present invention provides a hydrogen purity detection device for a hydrogen supply system, comprising:
the hydrogen supply assembly comprises a hydrogen cylinder assembly and a hydrogen supply pipeline connected with the hydrogen cylinder assembly, and a pressure reducing valve is arranged on the hydrogen supply pipeline;
the detection assembly comprises a controller, a flow sensor, a first pressure sensor and a temperature sensor, wherein the flow sensor, the first pressure sensor and the temperature sensor are arranged on the hydrogen supply pipeline and behind the pressure reducing valve, the controller is connected with the flow sensor, the first pressure sensor and the temperature sensor, the current gas molar mass in the hydrogen supply pipeline is obtained through real-time calculation, the current gas molar mass is compared with the boundary molar mass value of preset hydrogen, and if the boundary molar mass value is larger than the boundary molar mass value of the hydrogen, a signal that the hydrogen is impure is output.
Preferably, the preset boundary molar mass value of hydrogen comprises three threshold values, the first threshold value is smaller than the second threshold value, the second threshold value is smaller than the third threshold value, and when the current gas molar mass is larger than the third threshold value, a signal that the hydrogen gas is impure and the gas cylinder needs to be replaced is output.
Preferably, when the current gas molar mass is between the second threshold value and the third threshold value, an alarm signal is output.
Preferably, when the current gas molar mass is between the first threshold value and the second threshold value, a prompt signal containing trace impurities is output.
Preferably, said current gas molar mass MxThe specific calculation process is as follows: the output end of the hydrogen supply pipeline is closed, and the controller calculates the initial molar quantity N in the hydrogen supply pipeline according to the pressure value of the first pressure sensor, the temperature value of the temperature sensor and the volume of the hydrogen supply pipeline0(ii) a Opening the pressure reducing valve, filling hydrogen into the hydrogen supply pipeline by the hydrogen cylinder assembly, collecting the flow value of the flow sensor in real time by the controller, stabilizing for a certain time when the pressure value of the first pressure sensor reaches a preset value, and calculating by the controller to obtain the current molar quantity N in the hydrogen supply pipeline1Using the current molar amount N1Subtracting the initial molar amount N0Obtaining the molar quantity N of the charged gas and integrating the flow value to obtain the total mass M of the gas charged in the hydrogen supply pipeline according to the formula MxThe current gas molar mass was calculated as m/N.
Preferably, said current gas molar mass MxThe specific calculation process is as follows: the output end of the hydrogen supply pipeline is closed, the pressure reducing valve is opened, the hydrogen bottle assembly charges hydrogen into the hydrogen supply pipeline, and after the hydrogen charging is finishedAnd closing the pressure reducing valve, opening the output end of the hydrogen supply pipeline to exhaust until the pressure value of the first pressure sensor reaches a preset value, and calculating the molar mass of the exhaust gas by using the molar mass as the current gas molar mass by using the controller.
Preferably, the hydrogen supply pipeline is connected with a hydrogen inlet pipe in the fuel cell system, and a proportional valve is arranged on the hydrogen inlet pipe.
Preferably, the detection assembly further comprises an alarm unit connected with the controller, and when the controller judges that the hydrogen is not pure, the alarm unit is controlled to give an alarm.
Preferably, the boundary molar mass value of the hydrogen gas is the standard molar mass value of the hydrogen gas, and the standard molar mass value of the hydrogen gas is 2.0 g/mole; comparing the current gas molar mass with the standard molar mass value of the hydrogen, and if the current gas molar mass is different from the standard molar mass value of the hydrogen, outputting a signal of hydrogen impurity.
Preferably, an air containing cavity chamber with a certain containing cavity is arranged in series on the hydrogen supply pipeline behind the pressure reducing valve.
As described above, the hydrogen purity detection device of the hydrogen supply system according to the present invention has the following advantageous effects: the purity of the hydrogen in the current hydrogen supply pipeline is judged by comparing the current gas molar mass in the hydrogen supply pipeline with the boundary molar mass value of the preset hydrogen, so that the purity of the hydrogen is known in advance, and the hydrogen bottle is replaced in time or new high-purity hydrogen is input to prolong the service life of the fuel cell system.
Drawings
FIG. 1 is a schematic diagram of a hydrogen purity detection device of a hydrogen supply system according to the present invention;
description of the element reference numerals
1 hydrogen cylinder component
2 pressure reducing valve
3 high-pressure block valve
4 proportional valve
5 circulating pump
6 water knockout drum
7 electric pile
Detailed Description
The following description of the embodiments of the present invention is provided for illustrative purposes, and other advantages and effects of the present invention will become apparent to those skilled in the art from the present disclosure.
It should be understood that the structures, ratios, sizes, and the like shown in the drawings are only used for matching the disclosure of the present disclosure, and are not used for limiting the conditions that the present disclosure can be implemented, so that the present disclosure is not limited to the technical essence, and any structural modifications, ratio changes, or size adjustments should still fall within the scope of the present disclosure without affecting the efficacy and the achievable purpose of the present disclosure. In addition, the terms "upper", "lower", "left", "right", "middle" and "one" used in the present specification are for clarity of description, and are not intended to limit the scope of the present invention, and the relative relationship between the terms and the terms is not to be construed as a scope of the present invention.
As shown in fig. 1, the present embodiment provides a hydrogen purity detection apparatus for a hydrogen system, which includes:
the hydrogen supply assembly comprises a hydrogen cylinder assembly 1 and a hydrogen supply pipeline connected with the hydrogen cylinder assembly 1, and a pressure reducing valve 2 is arranged on the hydrogen supply pipeline;
the detection assembly comprises a controller, a flow sensor m, a first pressure sensor P2 and a temperature sensor T, wherein the flow sensor m, the first pressure sensor P2 and the temperature sensor T are arranged on a hydrogen supply pipeline and are positioned behind the pressure reducing valve 2, the controller is connected with the flow sensor m, the first pressure sensor P2 and the temperature sensor T, the current gas molar mass in the hydrogen supply pipeline is obtained through real-time calculation, the current gas molar mass is compared with the boundary molar mass value of preset hydrogen, and if the current gas molar mass value is larger than the boundary molar mass value of the hydrogen, a hydrogen impure signal is output.
The embodiment compares the current gas molar mass in the hydrogen supply pipeline with the boundary molar mass value of the preset hydrogen so as to judge the purity of the hydrogen in the current hydrogen supply pipeline, and obtains the impurity of the hydrogen in advance, so that the hydrogen bottle can be replaced in time, or new high-purity hydrogen is input, and the service life of the fuel cell system is prolonged.
In this embodiment, a second pressure sensor P1 is further disposed on the hydrogen supply pipeline near the hydrogen cylinder, the high-pressure air flow in the hydrogen cylinder enters the medium-pressure hydrogen supply pipeline through the pressure reducing valve 2, and a high-pressure stop valve 3 and a filter element may be further disposed behind the pressure reducing valve 2. The hydrogen supply pipeline is connected with the electric pile 7 through a hydrogen inlet pipeline of the fuel cell system, the hydrogen inlet pipeline is generally provided with a proportional valve 4, a circulation branch is divided behind the proportional valve 4 for hydrogen recycling, and the circulation branch is provided with structural components such as a circulation pump 5, a water separator 6 and the like. In the embodiment, the hydrogen supply pipeline is used as a container with a known volume V, and the on-off of the hydrogen supply pipeline is controlled by the pressure reducing valve 2 and the proportional valve 4, so that two methods are adopted in the embodiment to obtain the current gas molar mass MxThe method comprises the following steps:
method for obtaining molar mass M of front gas by adopting cavity inflation methodxThe specific calculation process is as follows: the output end of the hydrogen supply pipeline is closed, the proportional valve 4 is closed in the embodiment, and the controller calculates the initial molar quantity N in the hydrogen supply pipeline according to the pressure value of the first pressure sensor P2, the temperature value of the temperature sensor T and the actual volume V of the hydrogen supply pipeline0(ii) a Opening the pressure reducing valve 2, filling hydrogen into the hydrogen supply pipeline by the hydrogen cylinder assembly 1, collecting the flow value of the flow sensor m in real time by the controller, stabilizing for a certain time when the pressure value of the first pressure sensor P2 reaches a preset value, and calculating by the controller to obtain the current molar quantity N in the hydrogen supply pipeline1Using the current molar amount N1Subtracting the initial molar amount N0Obtaining the molar quantity N of the charged gas, and integrating the flow value to obtain the total mass M of the gas charged in the hydrogen supply pipeline according to the formula MxThe current gas molar mass was calculated as m/N.
Method for obtaining current gas molar mass M by adopting cavity exhaust methodxThe specific calculation process is as follows: the output end of the hydrogen supply pipeline is closed, in the embodiment, the proportional valve 4 is closed, the pressure reducing valve 2 is opened, and the hydrogen bottleThe component 1 charges hydrogen into the hydrogen supply pipeline, after the hydrogen charging is finished, the hydrogen is taken as an initial state, and the controller calculates the initial molar quantity N in the hydrogen supply pipeline according to the pressure value of the first pressure sensor P2 and the temperature value of the temperature sensor T0(ii) a Closing the pressure reducing valve 2, opening the output end of the hydrogen supply pipeline for exhausting, namely opening the proportional valve 4 for exhausting until the pressure value of the first pressure sensor P2 reaches a preset value, stabilizing for a certain time, and calculating by the controller to obtain the current molar weight N in the hydrogen supply pipeline1Using the initial molar amount N0Minus the current molar quantity N1Obtaining the molar quantity N of the exhaust gas, and integrating the flow value of the exhaust gas to obtain the total gas mass M of the exhaust gas according to the formula MxThe molar mass of the exhaust gas was calculated as m/N as the current gas molar mass.
In order to facilitate calculation and judgment, in this embodiment, an air-accommodating chamber having a certain accommodating cavity is serially arranged on the hydrogen supply pipeline behind the pressure reducing valve 2, so as to increase the actual volume of the hydrogen supply pipeline, improve the difference between the hydrogen supply pipeline and the hydrogen supply pipeline before and after air charging and discharging, make the calculated change of the current gas molar mass number value more obvious, and facilitate identification and judgment. In addition, the arrangement of the air containing cavity can also be used as a pressure stabilizing cavity, when the fuel cell is subjected to load pulling and pressure flow fluctuation occurs, the pressure fluctuation at the front end of the proportional valve 4 can be reduced, and the required medium-pressure pipeline pressure can be maintained. The gas containing cavity chamber in the embodiment can be circular, oval or other streamline shape, and is provided with a gas inlet and a gas outlet which are oppositely arranged, and the gas inlet and the gas outlet are serially arranged on the hydrogen supply pipeline.
In order to realize in time changing the hydrogen bottle, the detection subassembly still includes the alarm unit who links to each other with the controller in this embodiment, and when the controller judged that hydrogen is impure, control alarm unit sends out the police dispatch newspaper. The user can replace the hydrogen bottle when receiving the alarm.
As an embodiment, in this embodiment, the boundary molar mass value of the preset hydrogen includes three threshold values, the first threshold value is smaller than the second threshold value, the second threshold value is smaller than the third threshold value, if the first threshold value is 2, the second threshold value is 6, and the third threshold value is 18, when the current gas molar mass is larger than the third threshold value, a signal that the hydrogen gas is not pure and the gas cylinder needs to be replaced is output, that is, it indicates that there are more impurity gases, the system needs to be shut down to perform troubleshooting, and the gas cylinder is replaced; when the current gas molar mass is between the second threshold value and the third threshold value, an alarm signal is output, namely a small amount of impurity gas exists, and the system prompts a gas impurity yellow alarm to enable a user to pay high attention to the gas impurity yellow alarm; when the current gas molar mass is between the first threshold value and the second threshold value, outputting a prompt signal containing trace impurities. The user can carry out corresponding operation according to the signal of difference to in time change the gas cylinder. As another example, the above-mentioned boundary molar mass value of hydrogen gas is a standard molar mass value of hydrogen gas, and the standard molar mass value of hydrogen gas is 2.0 g/mole; comparing the current gas molar mass with the standard molar mass value of the hydrogen, and if the current gas molar mass is different from the standard molar mass value of the hydrogen, outputting a signal of hydrogen impurity so as to remind a user of paying attention to the hydrogen impurity.
Therefore, the invention effectively overcomes various defects in the prior art and has high industrial utilization value.
The foregoing embodiments are merely illustrative of the principles and utilities of the present invention and are not intended to limit the invention. Any person skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Accordingly, it is intended that all equivalent modifications or changes which can be made by those skilled in the art without departing from the spirit and technical spirit of the present invention be covered by the claims of the present invention.

Claims (8)

1. A hydrogen purity detection device of a hydrogen supply system, characterized by comprising:
the hydrogen supply assembly comprises a hydrogen cylinder assembly and a hydrogen supply pipeline connected with the hydrogen cylinder assembly, and a pressure reducing valve is arranged on the hydrogen supply pipeline;
the detection assembly comprises a controller, a flow sensor, a first pressure sensor and a temperature sensor, wherein the flow sensor, the first pressure sensor and the temperature sensor are arranged on the hydrogen supply pipeline and behind the pressure reducing valve, the controller is connected with the flow sensor, the first pressure sensor and the temperature sensor, the current gas molar mass in the hydrogen supply pipeline is calculated and obtained in real time, the current gas molar mass is compared with a preset boundary molar mass value of hydrogen, and if the current gas molar mass is larger than the boundary molar mass value of the hydrogen, a signal of hydrogen impurity is output;
wherein the current gas molar mass MxThe specific calculation process is as follows: the output end of the hydrogen supply pipeline is closed, and the controller calculates the initial molar quantity N in the hydrogen supply pipeline according to the pressure value of the first pressure sensor, the temperature value of the temperature sensor and the volume of the hydrogen supply pipeline0(ii) a Opening the pressure reducing valve, filling hydrogen into the hydrogen supply pipeline by the hydrogen cylinder assembly, collecting the flow value of the flow sensor in real time by the controller, stabilizing for a certain time when the pressure value of the first pressure sensor reaches a preset value, and calculating by the controller to obtain the current molar quantity N in the hydrogen supply pipeline1Using the current molar amount N1Subtracting the initial molar amount N0Obtaining the molar quantity N of the charged gas and integrating the flow value to obtain the total mass M of the gas charged in the hydrogen supply pipeline according to the formula MxCalculating the current gas molar mass by using the mass of the gas in the unit of = m/N; or the one or more of the following components,
the output end of the hydrogen supply pipeline is closed, the pressure reducing valve is opened, the hydrogen bottle assembly charges hydrogen into the hydrogen supply pipeline, after the hydrogen charging is completed, the pressure reducing valve is closed, the output end of the hydrogen supply pipeline is opened to exhaust the gas until the pressure value of the first pressure sensor reaches a preset value, and the controller calculates and obtains the current molar quantity N in the hydrogen supply pipeline1Using the initial molar amount N0Minus the current molar quantity N1Obtaining the molar quantity N of the exhaust gas, and integrating the flow value of the exhaust gas to obtain the total gas mass M of the exhaust gas according to the formula MxThe molar mass of the exhaust gas was calculated as the current gas molar mass in terms of m/N.
2. The hydrogen purity detection device of a hydrogen supply system according to claim 1, characterized in that: the preset boundary molar mass value of the hydrogen comprises three threshold values, the first threshold value is smaller than the second threshold value, the second threshold value is smaller than the third threshold value, and when the current gas molar mass is larger than the third threshold value, a signal that the hydrogen is impure and the gas cylinder needs to be replaced is output.
3. The hydrogen purity detection device of a hydrogen supply system according to claim 2, characterized in that: and when the current gas molar mass is between the second threshold value and the third threshold value, outputting an alarm signal.
4. The hydrogen purity detection device of a hydrogen supply system according to claim 2, characterized in that: when the current gas molar mass is between the first threshold value and the second threshold value, outputting a prompt signal containing trace impurities.
5. The hydrogen purity detection device of a hydrogen supply system according to claim 1, characterized in that: the hydrogen supply pipeline is connected with a hydrogen inlet pipe in the fuel cell system, and a proportional valve is arranged on the hydrogen inlet pipe.
6. The hydrogen purity detection device of a hydrogen supply system according to claim 1, characterized in that: the detection assembly further comprises an alarm unit connected with the controller, and when the controller judges that the hydrogen is impure, the alarm unit is controlled to give an alarm.
7. The hydrogen purity detection device of a hydrogen supply system according to claim 1, characterized in that: the boundary molar mass value of the hydrogen is the standard molar mass value of the hydrogen, and the standard molar mass value of the hydrogen is 2.0 g/mole; comparing the current gas molar mass with the standard molar mass value of the hydrogen, and if the current gas molar mass is different from the standard molar mass value of the hydrogen, outputting a signal of hydrogen impurity.
8. The hydrogen purity detection device of a hydrogen supply system according to claim 1, characterized in that: and a gas containing cavity chamber with a certain containing cavity is arranged on the hydrogen supply pipeline behind the pressure reducing valve in series.
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