CN111849358A - Environment-friendly negative ion zeolite surface coating agent and preparation method thereof - Google Patents
Environment-friendly negative ion zeolite surface coating agent and preparation method thereof Download PDFInfo
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- CN111849358A CN111849358A CN202010799646.6A CN202010799646A CN111849358A CN 111849358 A CN111849358 A CN 111849358A CN 202010799646 A CN202010799646 A CN 202010799646A CN 111849358 A CN111849358 A CN 111849358A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8687—Organic components
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses an environment-friendly anion zeolite surface coating agent, which is prepared from the following raw materials in parts by weight: 250 parts of purified water 220-containing material, 3-7 parts of dispersing agent, 2-6 parts of wetting agent, 1-3 parts of preservative, 1-3 parts of mildew preventive, 45-55 parts of polyethylene glycol, 2-4 parts of hydroxyethyl cellulose, 4-10 parts of defoaming agent, 45-55 parts of titanium dioxide, 160 parts of zeolite 140-containing material, 400 parts of finishing paint emulsion 340-containing material, 70-90 parts of plant additive, 12-18 parts of film-forming auxiliary agent, 15-25 parts of stabilizing agent, 4-10 parts of flatting agent and 1-3 parts of thickening agent. The invention also discloses a preparation method of the environment-friendly anion zeolite surface coating agent.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to an environment-friendly negative ion zeolite surface coating agent and a preparation method thereof.
Background
Aiming at the current situation that the adhesive releases formaldehyde for a long time, the existing technical level does not have a very effective method to completely cure formaldehyde, and the content and the release amount of substances such as formaldehyde can only be minimized by controlling the dosage of harmful substances and a good process means, but the effect is very unobvious.
Most of the formaldehyde sealing products in the market at the present stage are latex paints added with formaldehyde removing substances. Although the functional coating has a certain formaldehyde removing effect, the functional coating only depends on the coating of the common water-based paint on the surface of a plate, and can play a certain sealing effect on formaldehyde to reduce the release amount of the formaldehyde, but the sealing effect is very limited, and the defects of poor permeability, untight coating film structure and the like exist. In addition, the paint film of the latex paint is difficult to remove, and the functional paint can not be applied to the wooden furniture which does not need to be painted.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides an environment-friendly anion zeolite surface coating agent and a preparation method thereof, wherein the environment-friendly anion zeolite surface coating agent can continuously release negative oxygen ions for a long time at high strength and has the functions of purifying formaldehyde, PM2.5, methylbenzene, VOC and the like.
The technical scheme adopted by the invention is as follows:
an environment-friendly anion zeolite surface coating agent is prepared from the following raw materials in parts by weight: 250 parts of purified water 220-containing material, 3-7 parts of dispersing agent, 2-6 parts of wetting agent, 1-3 parts of preservative, 1-3 parts of mildew preventive, 45-55 parts of polyethylene glycol, 2-4 parts of hydroxyethyl cellulose, 4-10 parts of defoaming agent, 45-55 parts of titanium dioxide, 160 parts of zeolite 140-containing material, 400 parts of finishing paint emulsion 340-containing material, 70-90 parts of plant additive, 12-18 parts of film-forming auxiliary agent, 15-25 parts of stabilizing agent, 4-10 parts of flatting agent and 1-3 parts of thickening agent.
Preferably, the feed additive is prepared from the following raw materials in parts by weight: 240 parts of purified water 230-containing organic solvent, 4-6 parts of dispersing agent, 3-5 parts of wetting agent, 1.5-2.5 parts of preservative, 1.5-2.5 parts of mildew preventive, 48-52 parts of polyethylene glycol, 2.5-3.5 parts of hydroxyethyl cellulose, 6-8 parts of defoaming agent, 48-52 parts of titanium dioxide, 155 parts of zeolite 145-containing organic solvent, 350-390 parts of finishing paint emulsion, 75-85 parts of plant additive, 14-16 parts of film-forming auxiliary agent, 18-22 parts of stabilizing agent, 6-8 parts of flatting agent and 1.5-2.5 parts of thickening agent.
Preferably, the feed additive is prepared from the following raw materials in parts by weight: 233 parts of purified water, 5 parts of dispersing agent, 4 parts of wetting agent, 2 parts of preservative, 2 parts of mildew preventive, 50 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, 7 parts of defoaming agent, 50 parts of titanium dioxide, 150 parts of zeolite, 370 parts of finish emulsion, 80 parts of plant additive, 15 parts of film-forming assistant, 20 parts of stabilizer, 7 parts of flatting agent and 2 parts of thickening agent.
Dispersing agent: the selected nonionic alkyne diol series surfactant has dual effects of wetting and dispersing, contains no APEO and is nontoxic.
Wetting agent: the selected nonionic alkyne diol modified surfactant can improve the dynamic wetting ability of the system to various base materials, promote flow leveling, and is free of silicon, oil and toxicity, and does not contain alkylphenol polyoxyethylene ether compounds.
Preservative: the methyl-4-isothiazoline-3-ketone can be selected, has no toxicity, broad-spectrum bacteriostasis and sterilization, long lasting effect, can effectively inhibit and kill fungi and various microorganisms, and does not contain any heavy metal.
Mildew preventive: the modified pentachlorophenol can be selected, the fungicide is environment-friendly and low in toxicity, has special effects on microorganisms such as mould, microzyme, algae and the like, and has high-efficiency and lasting bactericidal and mildew-proof capabilities.
Polyethylene glycol: the ethylene glycol polyoxyethylene ether can be selected, has no toxicity, no irritation, good water solubility, good intermiscibility with a plurality of organic matter components, and excellent lubricity, moisture retention, dispersibility, adhesiveness, antistatic property and softness.
Hydroxyethyl cellulose: is a white or light yellow, tasteless and nontoxic fibrous or powdery solid, is prepared by etherification reaction of alkali cellulose and ethylene oxide (or chloroethanol), and belongs to nonionic soluble cellulose ether. Hydroxyethyl cellulose has good properties of thickening, suspending, dispersing, emulsifying, binding, film forming, moisture protecting and protective colloid providing.
Defoaming agent: the water-based organic silicon can be selected, has good defoaming performance, can eliminate micro bubbles, is free of bubbles for a long time, and does not contain alkylphenol polyoxyethylene ether compounds.
Titanium dioxide: has the characteristics of no toxicity, reinforcement, aging resistance, filling effect, strong weather resistance, strong covering power and the like.
Zeolite: has the performances of adsorptivity, ion exchange property, catalysis, acid resistance, heat resistance and the like, so the catalyst is widely used as an adsorbent, an ion exchanger and a catalyst, and can also be used for the aspects of drying and purifying gas, sewage treatment and the like.
Finishing paint emulsion: taking liquid monomer + water + initiator + surfactant to produce solid particles dispersed in water. Is prepared from water-insoluble solution polymer and surfactant through high-speed stirring.
Plant additive: is prepared by extracting essence from lemongrass, wormwood, aloe, dwarf bamboo leaf, camphor leaf, tea tree shell, bamboo charcoal, lavender and inulin, adding kaolin, titanium dioxide, barium sulfate and heavy calcium, and mixing; the natural plant components in the plant additive can release anions beneficial to human bodies in a passive state for 8-10 years, the temperature in winter is 18-25 ℃, and the humidity is 50-70%; the temperature in summer is 23-28 ℃, the humidity is 50-75%, and the release capacity is 2500-5000 pieces/m in the range3。
Film-forming auxiliary agent: the alcohol ester twelve can be selected, has certain volatility, can be retained in a coating film to play a role in the film forming process, and can be completely volatilized after film forming, so that the performance of the coating film is not influenced.
A stabilizer: can increase the stability of solution, colloid, solid and mixture, slow down reaction, maintain chemical balance, reduce surface tension, and prevent light, thermal decomposition or oxidative decomposition.
Leveling agent: is a common coating additive and can promote the coating to form a flat, smooth and uniform coating film in the process of drying and film forming. Can effectively reduce the surface tension of the finishing liquid and improve the leveling property and uniformity of the finishing liquid. Can improve the permeability of the coating liquid, reduce the possibility of generating spots and stains during the brush coating, increase the coverage and ensure that the formed film is uniform and natural.
Thickening agent: the rheological additive is a rheological additive, can thicken the coating, prevent sagging phenomenon in construction, and endow the coating with excellent mechanical property and storage stability. The additive is a very important class of additives for aqueous coatings with low viscosity.
The preparation method of the environment-friendly negative ion zeolite surface coating agent comprises the following steps:
a. preparing essence extracted from herba Cymbopogonis Citrari, folium Artemisiae Argyi, Aloe, herba Lophatheri, folium Cinnamomi Camphorae, tea tree shell, bamboo charcoal, Lavender, and inulin, adding Kaolin, titanium dioxide, barium sulfate, and heavy calcium, and mixing to obtain plant additive;
b. the finished product is obtained by uniformly mixing purified water, a dispersing agent, a wetting agent, a preservative, a mildew preventive, polyethylene glycol, hydroxyethyl cellulose, a defoaming agent, titanium dioxide, zeolite, a finish emulsion, a plant additive, a film-forming auxiliary agent, a stabilizer, a leveling agent and a thickening agent according to the proportion.
The invention has the beneficial effects that: the natural plant components in the plant additive can continuously release negative oxygen ions with high strength for a long time, have the functions of purifying formaldehyde, PM2.5, methylbenzene, VOC and the like, can promote blood circulation, help sleep and prevent body diseases.
Detailed Description
The following provides a detailed description of embodiments of the invention.
Example 1
An environment-friendly anion zeolite surface coating agent is prepared from the following raw materials in parts by weight: 220 parts of purified water, 3 parts of dispersing agent, 2 parts of wetting agent, 1 part of preservative, 1 part of mildew preventive, 45 parts of polyethylene glycol, 2 parts of hydroxyethyl cellulose, 4 parts of defoaming agent, 45 parts of titanium dioxide, 140 parts of zeolite, 340 parts of finishing paint emulsion, 70 parts of plant additive, 12 parts of film-forming assistant, 15 parts of stabilizer, 4 parts of flatting agent and 1 part of thickening agent.
Example 2
An environment-friendly anion zeolite surface coating agent is prepared from the following raw materials in parts by weight: 233 parts of purified water, 5 parts of dispersing agent, 4 parts of wetting agent, 2 parts of preservative, 2 parts of mildew preventive, 50 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, 7 parts of defoaming agent, 50 parts of titanium dioxide, 150 parts of zeolite, 370 parts of finish emulsion, 80 parts of plant additive, 15 parts of film-forming assistant, 20 parts of stabilizer, 7 parts of flatting agent and 2 parts of thickening agent.
Example 3
An environment-friendly anion zeolite surface coating agent is prepared from the following raw materials in parts by weight: 250 parts of purified water, 7 parts of dispersing agent, 6 parts of wetting agent, 3 parts of preservative, 3 parts of mildew preventive, 55 parts of polyethylene glycol, 4 parts of hydroxyethyl cellulose, 10 parts of defoaming agent, 55 parts of titanium pigment, 160 parts of triple superphosphate, 400 parts of finishing paint emulsion, 90 parts of plant additive, 18 parts of film-forming assistant, 25 parts of stabilizer, 10 parts of flatting agent and 3 parts of thickening agent.
Example 4
The preparation method of the environment-friendly negative ion zeolite surface coating agent in the embodiment comprises the following steps:
a. preparing essence extracted from herba Cymbopogonis Citrari, folium Artemisiae Argyi, Aloe, herba Lophatheri, folium Cinnamomi Camphorae, tea tree shell, bamboo charcoal, Lavender, and inulin, adding Kaolin, titanium dioxide, barium sulfate, and heavy calcium, and mixing to obtain plant additive;
b. the finished product is obtained by uniformly mixing purified water, a dispersing agent, a wetting agent, a preservative, a mildew preventive, polyethylene glycol, hydroxyethyl cellulose, a defoaming agent, titanium dioxide, zeolite, a finish emulsion, a plant additive, a film-forming auxiliary agent, a stabilizer, a leveling agent and a thickening agent according to the proportion.
The above-mentioned embodiments only express the specific embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.
Claims (5)
1. The environment-friendly negative ion zeolite surface coating agent is characterized by being prepared from the following raw materials in parts by weight: 250 parts of purified water 220-containing material, 3-7 parts of dispersing agent, 2-6 parts of wetting agent, 1-3 parts of preservative, 1-3 parts of mildew preventive, 45-55 parts of polyethylene glycol, 2-4 parts of hydroxyethyl cellulose, 4-10 parts of defoaming agent, 45-55 parts of titanium dioxide, 160 parts of zeolite 140-containing material, 400 parts of finishing paint emulsion 340-containing material, 70-90 parts of plant additive, 12-18 parts of film-forming auxiliary agent, 15-25 parts of stabilizing agent, 4-10 parts of flatting agent and 1-3 parts of thickening agent.
2. The environment-friendly anion zeolite surface coating agent as claimed in claim 1, which is prepared from the following raw materials in parts by weight: 240 parts of purified water 230-containing organic solvent, 4-6 parts of dispersing agent, 3-5 parts of wetting agent, 1.5-2.5 parts of preservative, 1.5-2.5 parts of mildew preventive, 48-52 parts of polyethylene glycol, 2.5-3.5 parts of hydroxyethyl cellulose, 6-8 parts of defoaming agent, 48-52 parts of titanium dioxide, 155 parts of zeolite 145-containing organic solvent, 350-390 parts of finishing paint emulsion, 75-85 parts of plant additive, 14-16 parts of film-forming auxiliary agent, 18-22 parts of stabilizing agent, 6-8 parts of flatting agent and 1.5-2.5 parts of thickening agent.
3. The environment-friendly anion zeolite surface coating agent as claimed in claim 1, which is prepared from the following raw materials in parts by weight: 233 parts of purified water, 5 parts of dispersing agent, 4 parts of wetting agent, 2 parts of preservative, 2 parts of mildew preventive, 50 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, 7 parts of defoaming agent, 50 parts of titanium dioxide, 150 parts of zeolite, 370 parts of finish emulsion, 80 parts of plant additive, 15 parts of film-forming assistant, 20 parts of stabilizer, 7 parts of flatting agent and 2 parts of thickening agent.
4. The environmental-friendly negative ion zeolite facial coating agent as claimed in any one of claims 1 to 3, wherein the plant additive is prepared by mixing essence extracted from lemongrass, wormwood, aloe, dwarf bamboo leaves, camphor leaves, tea tree shells, bamboo charcoal, lavender and inulin, and adding kaolin, titanium dioxide, barium sulfate and zeolite.
5. The preparation method of the environment-friendly negative ion zeolite finishing agent as claimed in claim 4, characterized by comprising the following steps:
a. preparing essence extracted from herba Cymbopogonis Citrari, folium Artemisiae Argyi, Aloe, herba Lophatheri, folium Cinnamomi Camphorae, tea tree shell, bamboo charcoal, Lavender, and inulin, and adding Kaolin, titanium dioxide, barium sulfate, and zeolite to obtain plant additive;
b. the finished product is obtained by uniformly mixing purified water, a dispersing agent, a wetting agent, a preservative, a mildew preventive, polyethylene glycol, hydroxyethyl cellulose, a defoaming agent, titanium dioxide, zeolite, a finish emulsion, a plant additive, a film-forming auxiliary agent, a stabilizer, a leveling agent and a thickening agent according to the proportion.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010799646.6A CN111849358A (en) | 2020-08-11 | 2020-08-11 | Environment-friendly negative ion zeolite surface coating agent and preparation method thereof |
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| CN202010799646.6A CN111849358A (en) | 2020-08-11 | 2020-08-11 | Environment-friendly negative ion zeolite surface coating agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115785753A (en) * | 2022-12-22 | 2023-03-14 | 亚士漆(上海)有限公司 | Bamboo charcoal negative ion coating and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118141A (en) * | 2016-06-20 | 2016-11-16 | 王聚会 | A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method |
| CN110511677A (en) * | 2019-09-17 | 2019-11-29 | 四川圣达高环保科技有限公司 | A kind of environmental protection anion face paint and preparation method thereof |
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2020
- 2020-08-11 CN CN202010799646.6A patent/CN111849358A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118141A (en) * | 2016-06-20 | 2016-11-16 | 王聚会 | A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method |
| CN110511677A (en) * | 2019-09-17 | 2019-11-29 | 四川圣达高环保科技有限公司 | A kind of environmental protection anion face paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115785753A (en) * | 2022-12-22 | 2023-03-14 | 亚士漆(上海)有限公司 | Bamboo charcoal negative ion coating and preparation method and application thereof |
| CN115785753B (en) * | 2022-12-22 | 2024-01-19 | 亚士漆(上海)有限公司 | Bamboo charcoal negative ion coating and preparation method and application thereof |
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