CN107523113A - Purify antimicrobial form emulsion paint - Google Patents
Purify antimicrobial form emulsion paint Download PDFInfo
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- CN107523113A CN107523113A CN201710791915.2A CN201710791915A CN107523113A CN 107523113 A CN107523113 A CN 107523113A CN 201710791915 A CN201710791915 A CN 201710791915A CN 107523113 A CN107523113 A CN 107523113A
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- emulsion paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to one kind to purify antimicrobial form emulsion paint, includes the component of following parts by weight：10~30 parts of alkide resin emulsion；20~60 parts of acrylic emulsion；1~15 part of antiseptic；1~15 part of filler；0.05~0.1 part of polyvinyl alcohol；1~5 part of lauryl sodium sulfate；0.1~3 part of hydroxypropyl starch ether；0.1~5 part of thickener；0.1~0.3 part of preservative；0.1~3 part of dispersant；0.2~0.4 part of defoamer；0.1~3 part of composite fibre；1~30 part of water.Purification antimicrobial form emulsion paint of the present invention, by using two kinds of resins as film forming matter, utilize bactericide and resin, the synergy of composite fibre, so that the emulsion paint can not only have certain inner wall decoration effect, and have the characteristics that to be firmly bonded, pernicious gas, the purification air such as the formaldehyde in indoor air, benzene, which can also effectively be dispelled, improves human respiratory, beneficial health.
Description
Technical field
The present invention relates to building coating field, and in particular to one kind purification antimicrobial form emulsion paint.
Background technology
Emulsion paint is being commonly called as latex paint, is the major class synthetic resin emulsion using acrylate copolymer emulsion as representative
Coating.Emulsion paint is water-dispersible paint, and it is using synthetic resin emulsion as base-material, and filler adds various after grinding distribution
The refined coating formed of auxiliary agent.Emulsion paint possesses many merits different from traditional metope coating, be such as easy to brush, drying it is fast
Speed, the advantages that paint film is water-fast, scrub resistance is good, widely liked by people.
With the development of the society, requirement of the people to finishing yet more and more higher, do not require nothing more than beautiful attractive in appearance, also require environmental protection
Health.After finishing, some peculiar smell are had indoors and the gas being detrimental to health is present, such as formaldehyde.Generally use
The method of windowing ventilation comes discharge of noxious gases and peculiar smell, or reduces indoor dirt using methods such as adsorbent, cultivation flowers and plants
Dye, but above-mentioned method can not be inherently eliminated pollution, and efficiency is low, and cost is high, and the operating time is longer.
The content of the invention
Based on this, the present invention provides a kind of purification antimicrobial form emulsion paint, the emulsion paint have the harmful physical capacity of absorption it is strong,
Strong antibacterial, it is environment friendly and pollution-free the advantages that.
In order to realize the purpose of the present invention, the present invention uses following technical scheme：
One kind purification antimicrobial form emulsion paint, include the component of following parts by weight：
Purification antimicrobial form emulsion paint of the present invention, using the formula of uniqueness, by using two kinds of resins as film forming
Material, acrylic resin have the advantages that quick-drying, chemical resistance are strong, hardness is high, and alkyd resin has good luster, good toughness and attached
Put forth effort the advantages that strong so that the interior wall coated by the emulsion paint has the two-fold advantages such as acrylic resin and alkyd resin, utilizes
The synergy of the material such as bactericide and resin, composite fibre so that the emulsion paint can not only have certain inner wall decoration
Effect, and with being firmly bonded, production is simple, the features such as facilitating, can also effectively dispel formaldehyde in indoor air, benzene,
The pernicious gases such as ammonia, purification air improves human respiratory, beneficial to health.
In wherein some embodiments, the purification antimicrobial form emulsion paint includes the component of following parts by weight：
In wherein some embodiments, the antiseptic is modification infusorial earth load nano-titanium dioxide composite.
In wherein some embodiments, the modification infusorial earth is 10 by mass ratio：3：5 diatomite, calcium oxide and oxygen
Change magnesium to be process by high-temperature calcination.
In wherein some embodiments, modification infusorial earth in the antiseptic：The mass ratio of nano titanium oxide is 5：1~
10。
In wherein some embodiments, the filler includes the component of following parts by weight：0.3~4 part of calcium carbonate；0.2~3
Part titanium dioxide；0.5~8 part of talcum powder.
In wherein some embodiments, the thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with
3：1：5：10 mass ratio mixes.
In wherein some embodiments, the composite fibre is by cellulose sodium rice fibril and sodium alginate with 1~10：100
Mass ratio compounding form.
In wherein some embodiments, the sodium alginate is grafted 10%~40% group containing sulfydryl by sodium alginate
Modification forms.
In wherein some embodiments, the dispersant is glyceryl monostearate or glyceryl tristearate.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But the present invention can be with perhaps
More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make
Understanding more thorough and comprehensive to the disclosure.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention
The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The purification antimicrobial form emulsion paint of the present invention, include the component of following parts by weight：
Purification antimicrobial form emulsion paint of the present invention, using the formula of uniqueness, by using two kinds of resins as film forming
Material, acrylic resin have the advantages that quick-drying, chemical resistance are strong, hardness is high, and alkyd resin has good luster, good toughness and attached
Put forth effort the advantages that strong so that the interior wall coated by the emulsion paint has a two-fold advantages such as acrylic resin and alkyd resin, then
Bactericide is added in resin so that the emulsion paint there can not only be certain inner wall decoration effect, can also effectively dispel residence
The pernicious gases such as formaldehyde, benzene in room air, purification air improves human respiratory, beneficial to health, and with viscous
Knot is firm, and production is simple, the features such as facilitating.
In a wherein embodiment, the purification antimicrobial form emulsion paint includes the component of following parts by weight：
In another embodiment, the purification antimicrobial form emulsion paint includes the component of following parts by weight：
Specifically, the antiseptic is modification infusorial earth load nano-titanium dioxide composite, the modification infusorial earth be by
Mass ratio is 10:3:5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, and the modification infusorial earth is porous
Siliceous powder body material；The preparation method of the antiseptic is：Nano titanium oxide is added drop-wise in cosolvent, is equipped to molten containing zinc
Liquid, modification infusorial earth is then added into water stirring pulping, then zinc-containing solution is added in above-mentioned modification infusorial earth slurries and formed
The slurries of titaniferous are wrapped up with the diatomite of core shell structure, finally add pH value conditioning agent, and by filtering, washing, drying and forging
Burn, produce modification infusorial earth load nano-titanium dioxide photocatalysis composite.Wherein, the particle size range of nano titanium oxide is
10nm~20nm, modification infusorial earth：The mass ratio of nano titanium oxide is 5:1~10；Cosolvent can be that acidic materials can also
For alkaline matter.
Optionally, diatomite is the diatomite of the mesh of 300 mesh~900 used by modification infusorial earth, diatomaceous aqueous
Rate is less than 0.5%, and diatomaceous specific surface area is 40m2/g~65m2/g.
In another embodiment, titanium dioxide is rutile type titanium white；Talcum powder is the high-quality talcum powder of 1250 mesh；Calcium carbonate
For the powdered whiting of the mesh of granularity about 400；Dispersant is glyceryl monostearate or glyceryl tristearate；Preservative is mountain
Pears acid sodium；Defoamer is one kind in enuatrol, oleic acid or organosilicon；Thickener is by PPG, n-hexane, poly- second two
Alcohol is with triethanolamine with 3：1：5：10 mass ratio mixes.
Optionally, composite fibre by cellulose sodium rice fibril and sodium alginate with 1~10：100 mass ratio compounding forms,
Wherein, cellulose sodium rice fibril be using the native cellulose from plant, animal or microorganism as raw material, it is water-soluble by phosphoric acid
After liquid, sodium chlorate sodium nitrate are to hydroxyl selective oxidation in cellulose, then after drying, shear crushing, resulting fiber
Plain sodium rice fibril；Sodium alginate is the modified sodium alginate of the group containing sulfydryl of grafting 10%~40%；Modified sodium alginate
Viscosity be 50mPas~1200mPas, the relative molecular weight of modified sodium alginate is 50,000~500,000；The composite fibre
Preparation method is：It is dispersed in the presence of ultrasonic wave first toward adding deionized water in cellulose sodium rice fibril, then to above-mentioned
Solution add sodium alginate, stir, stand a period of time after, after removing impurity by filter, obtain sodium cellulosate
The composite fibre of rice fibril-sodium alginate.
A kind of preparation method for purifying antimicrobial form emulsion paint, comprises the following steps：
Water, acrylic emulsion, filler, polyvinyl alcohol, dispersant and hydroxypropyl starch ether are mixed, stir one section
Time, alkide resin emulsion, lauryl sodium sulfate, composite fibre and antiseptic are added after above-mentioned solution is scattered completely, then
Secondary stirring a period of time, thickener, preservative and defoamer are eventually adding, is stirred, obtain the purification antimicrobial form latex
Paint.
Purification antimicrobial form emulsion paint of the present invention, using the formula of uniqueness, by using two kinds of resins as film forming
Material, acrylic resin have the advantages that quick-drying, chemical resistance are strong, hardness is high, and alkyd resin has good luster, good toughness and attached
Put forth effort the advantages that strong so that the interior wall coated by the emulsion paint has the two-fold advantages such as acrylic resin and alkyd resin, utilizes
The synergy of the material such as bactericide and resin, composite fibre so that the emulsion paint can not only have certain inner wall decoration
Effect, and with being firmly bonded, production is simple, the features such as facilitating, can also effectively dispel formaldehyde in indoor air, benzene,
The pernicious gases such as ammonia, purification air improves human respiratory, beneficial to health.
Wherein, by the composite fibre to being formed with cellulose sodium rice fibril and sodium alginate, added with solo fibre,
The composite fibre can form network-like filament layer, further improve the cracking resistance of emulsion paint, improve the emulsion paint
Service life.Using modification infusorial earth load nano-titanium dioxide composite, the photocatalysis performance of nano titanium oxide is improved,
The degradation rate of PARA FORMALDEHYDE PRILLS(91,95) is up to more than 90% under visible light conditions, and makes its deodorization and sterilization effect stronger.
Technical scheme will be further illustrated by several embodiments below.
Embodiment 1：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
10 parts of alkide resin emulsion；20 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 1
Part；0.3 part of titanium dioxide；0.2 part of talcum powder；0.5 part of calcium carbonate；0.05 part of polyvinyl alcohol；1 part of lauryl sodium sulfate；Hydroxypropyl
0.1 part of base starch ether；0.1 part of thickener；0.1 part of sodium sorbate；0.1 part of glyceryl monostearate；0.2 part of enuatrol；It is compound
0.1 part of fiber；1 part of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：100 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 5：1, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 10%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl monostearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and enuatrol, stir, and obtain the purification antimicrobial form emulsion paint.
Embodiment 2：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
20 parts of alkide resin emulsion；40 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 8
Part；2.1 parts of titanium dioxide；1.6 parts of talcum powder；4.2 parts of calcium carbonate；0.08 part of polyvinyl alcohol；3 parts of lauryl sodium sulfate；Hydroxypropyl
1.5 parts of base starch ether；3 parts of thickener；0.2 part of sodium sorbate；1.5 parts of glyceryl monostearate；0.3 part of enuatrol；Compound fibre
1.5 parts of dimension；16 parts of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：20 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 1：10, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 25%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl monostearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and enuatrol, stir, and obtain the purification antimicrobial form emulsion paint.
Embodiment 3：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
30 parts of alkide resin emulsion；60 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 15
Part；4 parts of titanium dioxide；3 parts of talcum powder；8 parts of calcium carbonate；0.1 part of polyvinyl alcohol；5 parts of lauryl sodium sulfate；Hydroxypropyl starch ether
3 parts；5 parts of thickener；0.3 part of sodium sorbate；3 parts of glyceryl tristearate；0.4 part of organosilicon；3 parts of composite fibre；30 parts of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：10 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 1：20, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 40%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl tristearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and organosilicon, stir, and obtain the purification antimicrobial form emulsion paint.
Embodiment 4：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
15 parts of alkide resin emulsion；30 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 3
Part；0.3 part of titanium dioxide；0.2 part of talcum powder；0.5 part of calcium carbonate；0.05 part of polyvinyl alcohol；1 part of lauryl sodium sulfate；Hydroxypropyl
0.1 part of base starch ether；0.1 part of thickener；0.1 part of sodium sorbate；0.1 part of glyceryl monostearate；0.2 part of enuatrol；It is compound
0.1 part of fiber；1 part of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：100 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 5：1, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 10%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl monostearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and enuatrol, stir, and obtain the purification antimicrobial form emulsion paint.
Embodiment 5：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
20 parts of alkide resin emulsion；40 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 6.5
Part；2.1 parts of titanium dioxide；1.6 parts of talcum powder；4.2 parts of calcium carbonate；0.08 part of polyvinyl alcohol；3 parts of lauryl sodium sulfate；Hydroxypropyl
1.5 parts of base starch ether；3 parts of thickener；0.2 part of sodium sorbate；1.5 parts of glyceryl tristearate；0.3 part of enuatrol；Compound fibre
1.5 parts of dimension；16 parts of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：20 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 1：10, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 25%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl tristearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and enuatrol, stir, and obtain the purification antimicrobial form emulsion paint.
Embodiment 6：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
25 parts of alkide resin emulsion；50 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 10
Part；4 parts of titanium dioxide；3 parts of talcum powder；8 parts of calcium carbonate；0.1 part of polyvinyl alcohol；5 parts of lauryl sodium sulfate；Hydroxypropyl starch ether
3 parts；5 parts of thickener；0.3 part of sodium sorbate；3 parts of glyceryl tristearate；0.4 part of organosilicon；3 parts of composite fibre；30 parts of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：10 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 1：20, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 40%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl tristearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and organosilicon, stir, and obtain the purification antimicrobial form emulsion paint.
Embodiment 7：
The purification antimicrobial form emulsion paint of the present invention, it includes the component of following parts by weight：
38 parts of alkide resin emulsion；34 parts of acrylic emulsion；Modification infusorial earth load nano-titanium dioxide composite 4
Part；4 parts of titanium dioxide；3 parts of talcum powder；8 parts of calcium carbonate；0.06 part of polyvinyl alcohol；2 parts of lauryl sodium sulfate；Hydroxypropul starch
0.6 part of ether；1 part of thickener；0.2 part of sodium sorbate；0.5 part of glyceryl tristearate；0.2 part of organosilicon；3 parts of composite fibre；
30 parts of water.
Wherein, thickener by PPG, n-hexane, polyethylene glycol and triethanolamine with 3：1：5：10 mass ratio mixes
Conjunction forms；Composite fibre is by cellulose sodium rice fibril and sodium alginate with 1：10 mass ratio compounding forms；Modification infusorial earth by
Mass ratio is 10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, modification infusorial earth：Nano-silica
The mass ratio for changing titanium is 1：20, sodium alginate is formed by group modified containing sulfydryl of sodium alginate grafting 40%.
The method for preparing above-mentioned purification antimicrobial form emulsion paint is：
By water, acrylic emulsion, titanium dioxide, talcum powder, calcium carbonate, polyvinyl alcohol, glyceryl tristearate and hydroxypropyl
Starch ether mixes, and stirring a period of time, alkide resin emulsion, dodecyl sulphur is added after above-mentioned solution is scattered completely
Sour sodium, composite fibre and modification infusorial earth load nano-titanium dioxide composite, a period of time is again stirring for, is eventually adding increasing
Thick dose, sodium sorbate and organosilicon, stir, and obtain the purification antimicrobial form emulsion paint.
In order to contrast the performance of the emulsion paint of the performance of the emulsion paint described in each embodiment of the present invention and prior art, enter
Row is following to be examined：
Comparative example 1：
Latex paint formulation 1 more general at present, include the component of following parts by weight：
The performance test results of emulsion paint obtained by the embodiment 1 to 7 and comparative example are as shown in table 1 below.
Table 1
Note：The purifying property test experiments be coated with respectively the present invention emulsion paint and the emulsion paint of comparative example be placed in
1m3Space in, and injecting formaldehyde and toluene makes the concentration of the two be respectively 1.7mg/m3And 2.0mg/m3, pass through gas-chromatography
Method tests the coating PARA FORMALDEHYDE PRILLS(91,95) and first according to JC/T 1074-2008 " function of purifying indoor air coating material purifying property "
The purification efficiency of benzene.
By above comparative analysis, the emulsion paint of embodiments of the invention 1~7 compared with the emulsion paint of comparative example,
Emulsion paint film formation time of the present invention greatly reduces, and filming performance is superior to prior art, and formaldehyde, toluene purification efficiency have
It is obvious to improve, wherein, the best results of embodiment 7.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. one kind purification antimicrobial form emulsion paint, it is characterised in that include the component of following parts by weight：
2. purification antimicrobial form emulsion paint according to claim 1, it is characterised in that include the component of following parts by weight：
3. purification antimicrobial form emulsion paint according to claim 2, it is characterised in that the antiseptic is born for modification infusorial earth
Carry nanometer titanium dioxide composite material.
4. purification antimicrobial form emulsion paint according to claim 3, it is characterised in that the modification infusorial earth is by mass ratio
10：3：5 diatomite, calcium oxide and magnesia is process by high-temperature calcination.
5. according to the purification antimicrobial form emulsion paint described in claim 4, it is characterised in that modified diatom in the antiseptic
Soil：The mass ratio of nano titanium oxide is 5：1~10.
6. according to the purification antimicrobial form emulsion paint described in claim 2, it is characterised in that the filler includes following parts by weight
Component：0.3~4 part of calcium carbonate；0.2~3 part of titanium dioxide；0.5~8 part of talcum powder.
7. according to the purification antimicrobial form emulsion paint described in claim 2, it is characterised in that the thickener is by polyether polyols
Alcohol, n-hexane, polyethylene glycol and triethanolamine are with 3：1：5：10 mass ratio mixes.
8. according to the purification antimicrobial form emulsion paint described in claim 2, it is characterised in that the composite fibre is by sodium cellulosate
Rice fibril is with sodium alginate with 1~10：100 mass ratio compounding forms.
9. according to the purification antimicrobial form emulsion paint described in claim 8, it is characterised in that the sodium alginate is by sodium alginate
Group modified containing sulfydryl of grafting 10%~40% forms.
10. according to the purification antimicrobial form emulsion paint described in claim 2, it is characterised in that the dispersant is stearic acid list
Glyceride or glyceryl tristearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710791915.2A CN107523113A (en) | 2017-09-05 | 2017-09-05 | Purify antimicrobial form emulsion paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710791915.2A CN107523113A (en) | 2017-09-05 | 2017-09-05 | Purify antimicrobial form emulsion paint |
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| CN107523113A true CN107523113A (en) | 2017-12-29 |
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| CN201710791915.2A Pending CN107523113A (en) | 2017-09-05 | 2017-09-05 | Purify antimicrobial form emulsion paint |
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| CN (1) | CN107523113A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314989A (en) * | 2018-02-26 | 2018-07-24 | 重庆建工第七建筑工程有限责任公司 | A kind of purification air-conditioning air hose fluid sealant and preparation method thereof |
| CN112126258A (en) * | 2020-09-23 | 2020-12-25 | 佛山绿森林环保科技有限公司 | Preparation method of aldehyde-removing and bacteriostatic negative ion coating |
-
2017
- 2017-09-05 CN CN201710791915.2A patent/CN107523113A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314989A (en) * | 2018-02-26 | 2018-07-24 | 重庆建工第七建筑工程有限责任公司 | A kind of purification air-conditioning air hose fluid sealant and preparation method thereof |
| CN108314989B (en) * | 2018-02-26 | 2021-05-04 | 重庆建工第七建筑工程有限责任公司 | Sealant for purifying air-conditioning air duct and preparation method thereof |
| CN112126258A (en) * | 2020-09-23 | 2020-12-25 | 佛山绿森林环保科技有限公司 | Preparation method of aldehyde-removing and bacteriostatic negative ion coating |
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Application publication date: 20171229 |