CN111792657A - Method for preparing lithium carbonate by adopting salt lake brine - Google Patents
Method for preparing lithium carbonate by adopting salt lake brine Download PDFInfo
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- CN111792657A CN111792657A CN202010669364.4A CN202010669364A CN111792657A CN 111792657 A CN111792657 A CN 111792657A CN 202010669364 A CN202010669364 A CN 202010669364A CN 111792657 A CN111792657 A CN 111792657A
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- lithium
- salt lake
- lake brine
- lithium carbonate
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/501—Preparation of sulfur dioxide by reduction of sulfur compounds
- C01B17/506—Preparation of sulfur dioxide by reduction of sulfur compounds of calcium sulfates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
- C01F11/08—Oxides or hydroxides by reduction of sulfates
Abstract
The invention discloses a method for preparing lithium carbonate by adopting salt lake brine, which comprises the following steps: s01: concentrating the lithium-rich solution I to obtain a lithium-rich solution II; s02: adding calcium oxide into the lithium-rich solution II to adjust the pH value to 10-13, and performing solid-liquid separation to obtain filtrate and filter residue; s03: adding sodium carbonate into the filtrate, filtering and washing with water to obtain lithium carbonate; s04: and after the filter residue is placed and dried, performing carbon burning at a high temperature to obtain calcium oxide and sulfur dioxide gas. According to the method for preparing lithium carbonate by adopting salt lake brine, provided by the invention, impurity ions can be effectively removed by adopting calcium oxide without introducing new impurities, the whole process is simple, the operation is convenient, and the preparation efficiency and the purity of lithium carbonate are effectively improved.
Description
Technical Field
The invention relates to the field of lithium ion purification, and particularly relates to a method for preparing lithium carbonate by adopting salt lake brine.
Background
Lithium is the lightest metal element in nature, and is the lightest and most active alkali metal in the group IA alkali metal head position in the periodic table. Because of its wide application field, it is praised as "industrial monosodium glutamate"; lithium is also known as an "energy metal" because it has the highest standard oxidation potential of various elements and is therefore the most undeniable element in the battery and power field.
According to different raw materials, the lithium extraction process can be divided into two process routes of ore lithium extraction and brine lithium extraction. The process route adopted for extracting lithium from ores is the earliest, the total lithium reserve in the ores is small, the energy consumption is large, and high-quality resources are nearly exhausted after being mined for hundreds of years, so that the production cost is high, the lithium resources of salt lake brine account for 71 percent of the lithium resource reserve in China, and the process for extracting lithium from brine is relatively simple and relatively low in cost, so that the process for extracting lithium from brine becomes a mainstream research process.
The lithium content in salt lakes of Qinghai Tibet and other places is high, in the current lithium extraction method, the salt lake of Tibet mainly uses a solar pond method to extract lithium industrially, the production period from salt lake brine to lithium resource products is long, statistics is generally carried out by taking years as units, the consumed time is long, and the lithium extraction efficiency is seriously influenced. The Qinghai salt lake is mainly used for industrially extracting lithium by using an aluminum adsorption method, the method needs to carry out pretreatment such as temperature rise on salt lake brine, more power consumption is inevitably increased by the pretreatment such as temperature rise in a high-altitude low-temperature environment, the concentration of a lithium-containing solution extracted by the method is low, and a multi-step purification process is needed subsequently, so that the whole extraction process is time-consuming and labor-consuming.
Meanwhile, the lithium-rich solution extracted from the salt lake brine contains more metal impurity ions, and in order to change the lithium-rich solution into lithium carbonate, a plurality of precipitants or impurity extracting agents are required to be added to remove the impurity ions, so that the process is complicated, the consumed time is long, and the final yield of the lithium carbonate cannot be ensured. In order to simplify the lithium extraction process of salt lake brine, a method for preparing lithium carbonate suitable for high altitude areas such as Qinghai Tibet and areas with relatively poor industrial foundation needs to be found.
Disclosure of Invention
The invention aims to provide a method for preparing lithium carbonate by adopting salt lake brine, which can effectively remove impurity ions without introducing new impurities by adopting calcium oxide, has simple whole process and convenient operation, and effectively improves the preparation efficiency and the purity of the lithium carbonate.
In order to achieve the purpose, the invention adopts the following technical scheme: a method for preparing lithium carbonate by adopting salt lake brine comprises the following steps:
s01: concentrating the lithium-rich solution I to obtain a lithium-rich solution II;
s02: adding calcium oxide into the lithium-rich solution II to adjust the pH value to 10-13, and performing solid-liquid separation to obtain filtrate and filter residue;
s03: adding sodium carbonate into the filtrate, filtering and washing with water to obtain lithium carbonate;
s04: and after the filter residue is placed and dried, performing carbon burning at a high temperature to obtain calcium oxide and sulfur dioxide gas.
Further, the lithium concentration in the lithium-rich solution I in the step S01 is 1-5g/L, and the lithium concentration in the lithium-rich solution II is 10-20 g/L.
Further, in the step S01, the lithium-rich solution i may be concentrated by one or more of reverse osmosis, nanofiltration, multiple-effect evaporation, mechanical vapor recompression, solar heat collection, and solar pond methods.
Further, the step S03 specifically includes:
s031: adding sodium carbonate with the molar ratio of Na/Li being 1-1.5 into the filtrate to separate out lithium carbonate crystals;
s032: and filtering the filtrate from which the lithium carbonate crystals are precipitated, and washing the filtered solid with deionized water to obtain the lithium carbonate.
Further, in the step S032, the filter residue is washed with deionized water at 60-90 ℃.
Further, the filter residue is calcium sulfate.
Further, the step S04 specifically includes:
s041: after the filter residue is placed and dried, carbon burning is carried out at 800-1600 ℃ to obtain calcium oxide and sulfur dioxide gas;
s042: the sulfur dioxide gas is converted into sulfur trioxide under the action of a vanadium pentoxide catalyst and is absorbed by concentrated sulfuric acid, so that the recycling of calcium oxide and concentrated sulfuric acid is realized.
Further, the lithium-rich solution I is obtained by extracting from salt lake brine through an adsorbent, and the specific extraction method comprises the following steps:
t01: allowing the filtered salt lake brine to pass through a manganese-based lithium ion sieve adsorbent so that lithium ions in the salt lake brine are adsorbed on the manganese-based lithium ion sieve adsorbent;
t02: cleaning impurity ions in the manganese-based lithium ion sieve adsorbent by using a cleaning solution;
t03: and washing the manganese-based lithium ion sieve adsorbent by using an eluent to enable lithium ions adsorbed in the manganese-based lithium ion sieve adsorbent to be separated into the eluent, so as to obtain a lithium-rich solution I.
Further, the pH value of the salt lake brine is 5-12, and the lithium ion concentration is more than or equal to 1 ppm.
Further, the temperature range of extracting the lithium-containing solution in the step T01-step T03 is between-20 ℃ below zero and-80 ℃.
The invention has the following beneficial effects: compared with a solar pond method, the method can shorten the production period of extracting lithium from salt lake brine from year to hour, and greatly improves the production efficiency; according to the invention, calcium oxide with low cost is used as an additive, so that not only can cationic impurities such as manganese, magnesium and the like be effectively removed, but also the concentration of anionic impurities such as sulfate radicals and the like can be reduced, the mirabilite is prevented from being separated out in the concentration process, and new impurities are prevented from being introduced; the whole process is simple, the operation is convenient, and the preparation efficiency and the purity of the lithium carbonate are effectively improved.
Drawings
FIG. 1 is a flow chart of a method for preparing lithium carbonate by using salt lake brine.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention are described in detail below with reference to the accompanying drawings.
As shown in the attached figure 1, the method for preparing lithium carbonate by using salt lake brine provided by the invention is characterized by comprising the following steps:
s01: concentrating the lithium-rich solution I to obtain a lithium-rich solution II; wherein the lithium concentration in the lithium-rich solution I is 1-5g/L, and the lithium concentration in the lithium-rich solution II is 10-20 g/L. The lithium-rich solution i can be concentrated by one or more methods, such as, but not limited to, reverse osmosis, nanofiltration, multiple-effect evaporation, MVR (Mechanical Vapor Recompression), solar heat collection, solar cells, and the like. Wherein, the reverse osmosis process adopts an acid-resistant reverse osmosis membrane for concentration, and the acid-resistant reverse osmosis membrane can be suitable for the environment with the pH value of 0.5-8.
S02: and adding calcium oxide into the lithium-rich solution II to adjust the pH value to 10-13, and performing solid-liquid separation to obtain filtrate and filter residue. The solid-liquid separation can be realized by suction filtration, centrifugation, plate-frame filter pressing and other modes. The calcium oxide can be added in the form of calcium oxide solid, or the calcium oxide can be dissolved in water to form calcium hydroxide solution to be added, or the calcium hydroxide can be diluted and then added, and only the effect of pH adjustment can be achieved.
According to the invention, calcium oxide with low cost is used as an additive, so that not only can cationic impurities such as manganese, magnesium and the like be effectively removed, but also the concentration of anionic impurities such as sulfate radicals and the like can be reduced, the mirabilite is prevented from being separated out in the concentration process, and meanwhile, new impurities are prevented from being introduced. The mirabilite is sodium sulfate decahydrate, and the lithium-rich solution II containing sulfate ions can separate out the mirabilite in a low-temperature environment, such as an environment at a temperature of-2 to-12 ℃, so that the yield of lithium carbonate is reduced.
S03: adding sodium carbonate into the filtrate, filtering and washing with water to obtain lithium carbonate; the method specifically comprises the following steps:
s031: adding sodium carbonate with the molar ratio of Na/Li being 1-1.5 into the filtrate to separate out lithium carbonate crystals;
s032: and filtering the filtrate from which the lithium carbonate crystals are precipitated, and washing the filtered solid with deionized water to obtain the lithium carbonate. Wherein, the filtration can be realized by suction filtration, centrifugation, plate-and-frame filter pressing and the like, and the washing can adopt deionized water with the temperature of 60-90 ℃ to drip wash the filter residue for 1-5 times, thus obtaining the industrial grade lithium carbonate.
S04: after the filter residue is placed and dried, carbon burning is carried out at high temperature to obtain calcium oxide and sulfur dioxide gas; the components of the filter residue are closely related to the preparation process of the lithium-rich solution i, and as described later, if a sulfuric acid solution is used as an eluent in step T03, the corresponding filter residue is calcium sulfate. The treatment method for the calcium sulfate filter residue specifically comprises the following steps:
s041: after the filter residue is placed and dried, carbon burning (preferably sulfur-containing carbon) is carried out at 800-1600 ℃ to obtain calcium oxide and sulfur dioxide gas; the carbon burning refers to burning the filter residue by using carbon as a heat source, furnace gas, namely burning gas in the carbon burning process can be introduced into the filter residue, and preferably, a sulfur-containing carbon source is used as a heat source for burning, so that the filter residue can better form calcium oxide and sulfur dioxide gas.
S042: the sulfur dioxide gas is converted into sulfur trioxide under the action of a vanadium pentoxide catalyst, and the sulfur trioxide is absorbed by concentrated sulfuric acid to prepare concentrated sulfuric acid with better concentration, so that the recycling of calcium oxide and the concentrated sulfuric acid is realized. The recovered calcium oxide is used as a pH regulator in step S02, and the recovered concentrated sulfuric acid is used to prepare an eluent in the extraction of the lithium-rich solution I.
It is worth to say that the lithium-rich solution I is obtained by extracting from salt lake brine through an adsorbent, and the extraction method can be applied to the temperature ranging from minus 20 ℃ to minus 80 ℃, and can be directly applied to high-altitude areas such as Qinghai Tibet and the like. The preparation method specifically comprises the following steps:
t01: and (3) passing the filtered salt lake brine through a manganese-based lithium ion sieve adsorbent, so that lithium ions in the salt lake brine are adsorbed on the manganese-based lithium ion sieve adsorbent.
The invention is suitable for any lithium-containing salt lake with the pH value of the salt lake brine in the range of 5-12, and the concentration of lithium ions in the salt lake brine is more than or equal to 1 ppm. Preferably, the salt lake brine is derived from salt lakes in Tibet or Qinghai regions. The manganese-based lithium ion sieve adsorbent can adopt any manganese-based lithium ion sieve adsorbent in the prior art, and specifically can be but not limited to one or more of a porous manganese-based lithium ion sieve adsorbent, a hexagonal flaky manganese-based lithium ion sieve adsorbent and a hexagonal dendritic manganese-based lithium ion sieve adsorbent.
T02: and cleaning the impurity ions in the manganese-based lithium ion sieve adsorbent by using a cleaning solution.
The cleaning solution in this step is deionized water or distilled water or filtered river water, and the purpose of cleaning is to remove impurity ions, such as iron ions, sodium ions, and the like, in the manganese-based lithium ion sieve adsorbent. In the manganese-based lithium ion sieve adsorbent, about 99% of hydrogen ions in the manganese-based lithium ion sieve adsorbent are subjected to ion exchange with lithium ions in salt lake brine, and the rest about 1% of hydrogen ions are subjected to ion exchange with impurity ions in the salt lake brine, wherein the impurity ions have the radius or charge distribution close to that of the lithium ions. Through the reasonable volume that sets up manganese system lithium ion sieve adsorbent, can ensure that the lithium ion in salt lake brine is basically all adsorbed in manganese system lithium ion sieve adsorbent, at this moment, adopt the washing liquid to wash, can get rid of most other impurity ions except the lithium ion.
T03: and (3) cleaning the manganese-based lithium ion sieve adsorbent by using an eluent to enable lithium ions adsorbed in the manganese-based lithium ion sieve adsorbent to be separated into the eluent, so as to obtain a lithium-rich solution I.
The eluent in the invention can be but is not limited to 0.1-2mol/L hydrochloric acid solution or 0.1-2mol/L nitric acid solution or 0.1-2mol/L oxalic acid solution or 0.05-1mol/L phosphoric acid solution or 0.05-1mol/L sulfuric acid solution. In the process of cleaning the manganese-based lithium ion sieve adsorbent by the eluent, the lithium ions adsorbed in the manganese-based lithium ion sieve adsorbent are replaced, and the lithium ions are discharged along with the eluent, wherein the eluent containing the lithium ions is the lithium-enriched solution I.
T04: and cleaning the manganese-based lithium ion sieve adsorbent by using a cleaning solution, and cleaning the eluent in the manganese-based lithium ion sieve adsorbent.
The cleaning solution in this step may be, but is not limited to, deionized water, distilled water, or filtered river water, and the purpose of cleaning is to remove the eluent in the manganese-based lithium ion sieve adsorbent, so as to facilitate the next use.
Compared with a solar pond method, the method can shorten the production period of extracting lithium from salt lake brine from year to hour, and greatly improves the production efficiency; according to the invention, calcium oxide with low cost is used as an additive, so that not only can cationic impurities such as manganese, magnesium and the like be effectively removed, but also the concentration of anionic impurities such as sulfate radicals and the like can be reduced, the mirabilite is prevented from being separated out in the concentration process, and new impurities are prevented from being introduced; the whole process is simple, the operation is convenient, and the preparation efficiency and the purity of the lithium carbonate are effectively improved.
The above description is only a preferred embodiment of the present invention, and the embodiment is not intended to limit the scope of the present invention, so that all equivalent structural changes made by using the contents of the specification and the drawings of the present invention should be included in the scope of the appended claims.
Claims (10)
1. A method for preparing lithium carbonate by adopting salt lake brine is characterized by comprising the following steps:
s01: concentrating the lithium-rich solution I to obtain a lithium-rich solution II;
s02: adding calcium oxide into the lithium-rich solution II to adjust the pH value to 10-13, and performing solid-liquid separation to obtain filtrate and filter residue;
s03: adding sodium carbonate into the filtrate, filtering and washing with water to obtain lithium carbonate;
s04: and after the filter residue is placed and dried, performing carbon burning at a high temperature to obtain calcium oxide and sulfur dioxide gas.
2. The method for preparing lithium carbonate from salt lake brine as claimed in claim 1, wherein the lithium concentration in the lithium-rich solution i in step S01 is 1-5g/L, and the lithium concentration in the lithium-rich solution ii is 10-20 g/L.
3. The method of claim 1, wherein the lithium-rich solution I is concentrated by one or more of reverse osmosis, nanofiltration, multiple-effect evaporation, mechanical vapor recompression, solar heat collection, and solar pond methods in step S01.
4. The method for preparing lithium carbonate from salt lake brine according to claim 1, wherein the step S03 specifically comprises:
s031: adding sodium carbonate with the molar ratio of Na/Li being 1-1.5 into the filtrate to separate out lithium carbonate crystals;
s032: and filtering the filtrate from which the lithium carbonate crystals are precipitated, and washing the filtered solid with deionized water to obtain the lithium carbonate.
5. The method of claim 3, wherein the filter residue is washed with deionized water at 60-90 ℃ in the step S032.
6. The method for preparing lithium carbonate from salt lake brine according to claim 1, wherein the filter residue is calcium sulfate.
7. The method for preparing lithium carbonate from salt lake brine according to claim 6, wherein the step S04 specifically comprises:
s041: after the filter residue is placed and dried, carbon burning is carried out at 800-1600 ℃ to obtain calcium oxide and sulfur dioxide gas;
s042: the sulfur dioxide gas is converted into sulfur trioxide under the action of a vanadium pentoxide catalyst and is absorbed by concentrated sulfuric acid, so that the recycling of calcium oxide and concentrated sulfuric acid is realized.
8. The method for preparing lithium carbonate from salt lake brine according to claim 1, wherein the lithium-rich solution I is obtained by extracting from salt lake brine through an adsorbent, and the specific extraction method comprises the following steps:
t01: allowing the filtered salt lake brine to pass through a manganese-based lithium ion sieve adsorbent so that lithium ions in the salt lake brine are adsorbed on the manganese-based lithium ion sieve adsorbent;
t02: cleaning impurity ions in the manganese-based lithium ion sieve adsorbent by using a cleaning solution;
t03: and washing the manganese-based lithium ion sieve adsorbent by using an eluent to enable lithium ions adsorbed in the manganese-based lithium ion sieve adsorbent to be separated into the eluent, so as to obtain a lithium-rich solution I.
9. The method for preparing lithium carbonate from salt lake brine according to claim 8, wherein the salt lake brine has a pH value of 5-12 and a lithium ion concentration of 1ppm or more.
10. The method for preparing lithium carbonate from salt lake brine according to claim 8, wherein the temperature range of the lithium-containing solution extracted in the steps T01-T03 is from-20 ℃ below zero to-80 ℃.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112777614A (en) * | 2021-02-02 | 2021-05-11 | 江苏久吾高科技股份有限公司 | Method and device for adsorbing and extracting lithium from salt lake brine |
CN115029564A (en) * | 2022-08-12 | 2022-09-09 | 矿冶科技集团有限公司 | Co-production process for extracting lithium from salt lake brine and preparing acid from sulfur-containing material and application |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1141983A (en) * | 1995-07-28 | 1997-02-05 | 李保民 | Method for comprehensive control and treatment of black liquor from alkali paper-making |
CN1454843A (en) * | 2003-03-21 | 2003-11-12 | 钟辉 | Magnesium sulfate hypotype salt lake brine magnesium lithium separation method |
US20040005267A1 (en) * | 1998-07-16 | 2004-01-08 | Boryta Daniel Alfred | Production of lithium compounds directly from lithium containing brines |
CN103318926A (en) * | 2012-03-22 | 2013-09-25 | 日铁矿业株式会社 | Method for producing lithium carbonate |
CN103898341A (en) * | 2014-03-06 | 2014-07-02 | 中国科学院青海盐湖研究所 | Method for separating and extracting lithium from lithium sulfate coarse ore |
CN106045113A (en) * | 2016-07-08 | 2016-10-26 | 徐愿坚 | Technological method for recycling high-salinity wastewater from sodium carbonate manufacturing factories |
CN106241841A (en) * | 2016-08-29 | 2016-12-21 | 江苏海普功能材料有限公司 | A kind of salt lake bittern prepares the method for lithium carbonate |
CN206308030U (en) * | 2016-12-13 | 2017-07-07 | 宜春银锂新能源有限责任公司 | Byproduct collecting apparatus in a kind of lithium carbonate preparation process |
CN107089673A (en) * | 2017-06-09 | 2017-08-25 | 北京矿冶研究总院 | Method for preparing lithium carbonate by two-stage conversion of lithium ore |
CN110563009A (en) * | 2019-09-29 | 2019-12-13 | 华东理工大学 | Method for preparing battery-grade lithium carbonate from fly ash by carbonization decomposition method |
-
2020
- 2020-07-13 CN CN202010669364.4A patent/CN111792657A/en active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1141983A (en) * | 1995-07-28 | 1997-02-05 | 李保民 | Method for comprehensive control and treatment of black liquor from alkali paper-making |
US20040005267A1 (en) * | 1998-07-16 | 2004-01-08 | Boryta Daniel Alfred | Production of lithium compounds directly from lithium containing brines |
CN1454843A (en) * | 2003-03-21 | 2003-11-12 | 钟辉 | Magnesium sulfate hypotype salt lake brine magnesium lithium separation method |
CN103318926A (en) * | 2012-03-22 | 2013-09-25 | 日铁矿业株式会社 | Method for producing lithium carbonate |
CN103898341A (en) * | 2014-03-06 | 2014-07-02 | 中国科学院青海盐湖研究所 | Method for separating and extracting lithium from lithium sulfate coarse ore |
CN106045113A (en) * | 2016-07-08 | 2016-10-26 | 徐愿坚 | Technological method for recycling high-salinity wastewater from sodium carbonate manufacturing factories |
CN106241841A (en) * | 2016-08-29 | 2016-12-21 | 江苏海普功能材料有限公司 | A kind of salt lake bittern prepares the method for lithium carbonate |
CN206308030U (en) * | 2016-12-13 | 2017-07-07 | 宜春银锂新能源有限责任公司 | Byproduct collecting apparatus in a kind of lithium carbonate preparation process |
CN107089673A (en) * | 2017-06-09 | 2017-08-25 | 北京矿冶研究总院 | Method for preparing lithium carbonate by two-stage conversion of lithium ore |
CN110563009A (en) * | 2019-09-29 | 2019-12-13 | 华东理工大学 | Method for preparing battery-grade lithium carbonate from fly ash by carbonization decomposition method |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112777614A (en) * | 2021-02-02 | 2021-05-11 | 江苏久吾高科技股份有限公司 | Method and device for adsorbing and extracting lithium from salt lake brine |
CN112777614B (en) * | 2021-02-02 | 2023-09-15 | 江苏久吾高科技股份有限公司 | Method and device for extracting lithium from salt lake brine through adsorption |
CN115029564A (en) * | 2022-08-12 | 2022-09-09 | 矿冶科技集团有限公司 | Co-production process for extracting lithium from salt lake brine and preparing acid from sulfur-containing material and application |
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