CN111685111A - Water-based environment-friendly auxiliary agent special for smoke cooling machine and application thereof - Google Patents

Water-based environment-friendly auxiliary agent special for smoke cooling machine and application thereof Download PDF

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Publication number
CN111685111A
CN111685111A CN202010486401.8A CN202010486401A CN111685111A CN 111685111 A CN111685111 A CN 111685111A CN 202010486401 A CN202010486401 A CN 202010486401A CN 111685111 A CN111685111 A CN 111685111A
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water
based environment
auxiliary agent
friendly
agent
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Inventor
江杨
宋洪允
崔郭勤
罗金仁
卢瑞
万远见
陈冠
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Guangxi Yasheng Environmental Technology Co ltd
Guangxi Tianyuan Biochemical Co Ltd
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Guangxi Yasheng Environmental Technology Co ltd
Guangxi Tianyuan Biochemical Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants

Abstract

The invention relates to the technical field of pesticide preparations, and particularly discloses a special water-based environment-friendly auxiliary agent for a smoke cooling machine, which comprises the following components in percentage by mass: 1-15% of surfactant, 40-90% of smoke agent, 0.1-0.5% of defoaming agent and 5-50% of water. The invention also provides the application of the water-based environment-friendly auxiliary agent in preventing and treating plant diseases and insect pests. The water-based environment-friendly auxiliary special for the cold tobacco machine is directly added with a pesticide preparation, is supplemented with water, can generate a cold tobacco effect to control plant diseases and insect pests through the cold tobacco machine, does not need to be added with harmful organic solvents such as benzene, dimethylbenzene, cyclohexanone and the like, is environment-friendly, is supplemented with water, is supplemented with organic solvents and the like, reduces the cost and has small taste; can be used together with pesticide, bactericide or disinfectant in the form of suspension, emulsion in water, microemulsion, etc., and is suitable for preventing and treating plant diseases and insect pests in closed space and non-closed space, and has wide application range.

Description

Water-based environment-friendly auxiliary agent special for smoke cooling machine and application thereof
Technical Field
The invention belongs to the technical field of pesticide preparations, and particularly relates to a special water-based environment-friendly auxiliary agent for a smoke cooling machine and application thereof.
Background
The pesticide hot fogging concentrate is prepared by dissolving a solid or liquid pesticide raw material in a solvent meeting certain viscosity and flash point conditions, and adding other auxiliary components to prepare a preparation with certain specification. In the using process, a certain amount of hot fogging agent is pressed into the firework tube by using a hot fogging machine, so that the hot fogging agent is mixed with high-speed and high-temperature hot air and is sprayed out of a conduit of the hot fogging machine to form micron-sized fog or smoke, and the preparation is called as the hot fogging agent. In hills and mountainous areas, the local crops mainly comprise high-stem crops such as corns, cassava, sugarcanes and the like, and also comprise fruit trees such as oranges, pear trees, apples and the like, economic forests and the like, and when the traditional pesticide application mode meets the problems of complex terrain, water shortage and the like, the pesticide application efficiency is generally low. The use of the hot fogging concentrate can obviously overcome the defects, and firstly, the hot fogging concentrate is hardly required to be mixed with water for application; secondly, the formed hot fog can be diffused naturally, and the spraying process can be carried out only by walking according to a specified route without considering the problems of the direction of a spray head, whether the route is repeated, whether the medicine is in place and the like; thirdly, the atomized fog drops of the hot fogging concentrate have good prevention effect and extremely strong penetrating power, greatly increase the contact probability with a target and more fully exert the prevention and treatment effect of the medicament.
The hot fogging agent commonly used in the market is heated and fogged by a hot fogging machine, which is called a smoke sprayer and a thermal fogger, and is also called a pulse fogger because the power of the hot fogging machine is pulse. The working principle of the hot fogging machine is as follows: the air and the gasoline form mixed gas in the carburetor, and under the condition of ignition, the mixed gas is explosively combusted to generate high-pressure high-temperature gas, so that the pesticide and the carrier thereof at the nozzle are instantly atomized and diffused to a target part under the drive of high-pressure airflow, and the purpose of protection and prevention is achieved. Most pesticide preparations cannot be directly applied to a hot fogging machine and need to be matched with a hot fogging machine auxiliary agent for use, and a solvent used by a traditional hot fogging machine auxiliary agent generally contains an organic solvent, for example, a pesticide auxiliary agent in patent document CN200510081634.5, which consists of vegetable oil, a cosolvent and a surfactant, wherein the cosolvent is an organic solvent; patent document CN201610845990.8 discloses a functional aid for a thermal spraying machine, and a preparation method and a use method thereof, wherein the functional aid for the thermal spraying machine comprises paraffin oil, a surfactant and a thermal spraying density regulator, wherein the paraffin oil is used as a solvent, and an organic solvent can cause certain harm to a human body and pollute the air environment.
The water-based environment-friendly auxiliary agent special for the smoke cooling machine is matched with a multi-nozzle adjustable electric smoke device for use, and the machine is similar to a hot fog machine commonly used in the market, but is different. The atomization principle of the machine is as follows: the equipment is powered by electricity, and a heating and atomizing device in the equipment is heated to a certain temperature under the control of an electronic circuit board; after the infusion pump is started, the liquid medicine is conveyed into the heating device from the medicine pot, is quickly vaporized by the heating device to form smoke, and is sprayed out from the smoke outlet by the pressure generated inside, the atomization temperature of the machine is between 90 ℃ and 310 ℃, the smoke can be quickly cooled to the temperature of the outside air 20cm to 30cm away from the outlet, the machine is safe to crops and operators, and scalding cannot occur.
The special water-based environment-friendly auxiliary agent for the smoke cooling machine is composed of a surfactant, a smoke agent, a defoaming agent and water, greatly reduces the use of organic solvents, is very environment-friendly, saves precious environmental resources, improves the prevention and treatment effect, and is a green auxiliary agent system.
Disclosure of Invention
The invention aims to provide a special water-based environment-friendly auxiliary agent for a smoke cooling machine, which reduces the use of harmful organic solvents and improves the control effect of pesticide preparations.
In order to achieve the purpose, the invention provides a special water-based environment-friendly auxiliary agent for a smoke cooling machine, which comprises the following components in percentage by mass: 1-15% of surfactant, 40-90% of smoke agent, 0.1-0.5% of defoaming agent and 5-50% of water.
Preferably, in the above water-based environment-friendly auxiliary agent, the surfactant is one or a mixture of several of alkylphenol ethoxylates, phenethylphenol ethoxylates, sodium dodecylbenzenesulfonate, sodium laurylsulfate, anionic sodium alkylsulfate (sodium dodecyl sulfate), EO-PO block copolymer (ethylene oxide-propylene oxide block copolymer), sorbitan monooleate, fatty alcohol polyoxyethylene ether, alkylaryl polyoxypropylene polyoxyethylene ether, fatty alcohol polyoxyethylene ether phosphate, alkylphenol polyoxyethylene ether phosphate, and calcium dodecylbenzenesulfonate.
Preferably, in the above water-based environment-friendly auxiliary, the smoke agent is one or a mixture of more of ethylene glycol, propylene glycol, glycerol, polyvinyl alcohol, n-butanol, isobutanol, butanediol, butanetriol, erythritol, soybean oil, peanut oil and mineral oil.
Preferably, in the above water-based environment-friendly auxiliary agent, the defoamer is one or a mixture of more of emulsified silicone oil, a higher alcohol fatty acid ester compound, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether and polydimethylsiloxane.
Preferably, in the above water-based environment-friendly auxiliary agent, the water is deionized water.
Preferably, in the above water-based environment-friendly auxiliary, the water-based environment-friendly auxiliary is prepared by the following method: and pumping water, a surfactant and a defoaming agent into the reaction kettle in sequence, stirring for 10min at a speed of 100r/min, pumping a smoke agent, continuously stirring for 20min, and stirring the system uniformly to obtain the water-based environment-friendly auxiliary agent.
The water-based environment-friendly auxiliary agent is applied to prevention and treatment of plant diseases and insect pests.
Preferably, in the application, the water-based environment-friendly auxiliary agent is uniformly mixed with a suspending agent, a water emulsion or a microemulsion pesticide, a bactericide or a disinfectant, and is heated and atomized at constant temperature by a cold tobacco machine to prevent and treat the plant diseases and insect pests.
Preferably, in the application, the water-based environment-friendly auxiliary agent is added in an amount of 7-63 ml/250m for controlling pests in a closed space3(ii) a The water-based environment-friendly auxiliary agent is added in an amount of 5-100 ml/667m for preventing and treating diseases and insect pests in non-closed space2
In the application, the atomization principle of the cold-smoke machine is as follows: the equipment is powered by electricity, and a heating and atomizing device in the equipment is heated to a certain temperature under the control of an electronic circuit board; after the infusion pump is started, the liquid medicine is conveyed into the heating device from the medicine pot, is quickly vaporized by the heating device to form smoke, and is sprayed out from the smoke outlet by the pressure generated inside, the atomization temperature of the machine is between 90 ℃ and 310 ℃, the smoke can be quickly cooled to the temperature of the outside air 20cm to 30cm away from the outlet, the machine is safe to crops and operators, and scalding cannot occur.
Compared with the prior art, the invention has the following beneficial effects:
1. the water-based environment-friendly auxiliary agent special for the cold smoke machine is directly added with a pesticide preparation, is supplemented with water, can generate a hot fog effect to control plant diseases and insect pests through a cold smoke machine, does not need to be added with harmful organic solvents such as benzene, dimethylbenzene and cyclohexanone, is environment-friendly, is supplemented with water, is supplemented with relatively organic solvents, and the like, reduces the cost, has small taste, is convenient for public acceptance, and can widen the application scene. Can be used together with pesticide, bactericide or disinfectant in the form of suspension, emulsion in water, microemulsion, etc., and is suitable for preventing and treating plant diseases and insect pests in closed space and non-closed space, and has wide application range.
2. The common hot-fogging oil-based auxiliary agent on the market can only be mixed with missible oil products, and water-based pesticides such as suspending agent aqueous emulsion, microemulsion and the like can not be mixed and dissolved.
3. Compared with the traditional hot fogging concentrate, the water-based auxiliary agent for the cold smoke machine disclosed by the invention has the advantages that the outlet temperature is lower, the water-based auxiliary agent is used, the outlet temperature is within 30cm, the water-based auxiliary agent can be rapidly cooled to the ambient temperature in the air, and the safety of crops and users is ensured.
4. The water-based environment-friendly auxiliary agent for the smoke cooler is matched with a multi-nozzle adjustable electric smoke machine (trade name is a smoke cooler), can quickly smoke, has large smoke quantity, can quickly diffuse smoke in the air, and has the retention time of 4-6 hours, thereby achieving the purpose of higher prevention effect.
Detailed Description
The following detailed description of specific embodiments of the invention is provided, but it should be understood that the scope of the invention is not limited to the specific embodiments.
Example 1
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 3% of EO-PO block copolymer, 4% of fatty alcohol-polyoxyethylene ether, 5% of calcium dodecyl benzene sulfonate, 20% of ethylene glycol, 30% of glycerol, 0.5% of higher alcohol fatty acid ester compound and deionized water to make up to 100%.
The preparation method of the special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following steps:
sequentially pumping deionized water, 3% of EO-PO block copolymer, 4% of fatty alcohol-polyoxyethylene ether, 5% of calcium dodecyl benzene sulfonate and 0.3% of higher alcohol fatty acid ester compound into a reaction kettle, and stirring for 10min at the speed of 100r/min to obtain a component A;
secondly, adding a smoke agent of 20 percent of glycol and 30 percent of glycerol into the component A, and continuously stirring for 20min at the speed of 100r/min to obtain the special water-based environment-friendly auxiliary agent for the cold-smoke machine.
Comparative example 1
The additive provided in this comparative example differs from the additive of example 1 in that: xylene was used instead of deionized water, and the other ingredients were the same as in example 1. The procedure and parameters for the preparation of the auxiliaries are the same as in example 1.
Example 2
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 5% of alkylphenol polyoxyethylene, 5% of sodium dodecyl benzene sulfonate, 40% of n-butanol, 44.8% of propylene glycol, 0.2% of polydimethylsiloxane and deionized water to make up to 100%.
The preparation steps of the special water-based environment-friendly auxiliary agent for the smoke cooling machine are the same as those of the example 1.
Comparative example 2
The additive provided in this comparative example differs from the additive of example 2 in that: paraffin oil was used instead of deionized water, and the other ingredients were the same as in example 2. The procedure and parameters for the preparation of the auxiliaries are the same as in example 2.
Example 3
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 4% of EO-PO block copolymer, 6% of anionic alkyl sodium sulfate, 5% of fatty alcohol polyoxyethylene ether phosphate, 20% of soybean oil, 20% of peanut oil, 0.3% of polyoxyethylene polyoxypropylene pentaerythritol ether and deionized water which are added to make up to 100%.
Comparative example 3
The additive provided in this comparative example differs from the additive of example 3 in that: cyclohexanone was used instead of deionized water and the other ingredients were the same as in example 3.
Example 4
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 6% of phenethyl phenol polyoxyethylene ether, 3% of alkylphenol polyoxyethylene ether phosphate, 30% of butanediol, 30% of n-butyl alcohol, 0.3% of emulsified silicone oil and deionized water which are complemented to 100%.
Comparative example 4
The additive provided in this comparative example differs from the additive of example 4 in that: the deionized water was replaced with 0# diesel and the other ingredients were the same as in example 4.
Example 5
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 3% of sodium lauryl sulfate, 2% of sorbitan monooleate, 3% of alkylaryl polyoxypropylene polyoxyethylene ether, 20% of glycerol, 21.7% of isobutanol, 0.3% of polyoxyethylene polyoxypropylene amine ether and the balance of deionized water to 100%.
Comparative example 5
The additive provided in this comparative example differs from the additive of example 5 in that: cyclohexanone was used instead of deionized water and the other ingredients were the same as in example 5.
Example 6
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 6% of calcium dodecyl benzene sulfonate, 2% of EO-PO block copolymer, 3% of alkylaryl polyoxypropylene polyoxyethylene ether, 20% of polyvinyl alcohol, 25% of butanetriol, 0.3% of polyoxypropylene polyoxyethylene glycerol ether and deionized water to make up to 100%.
Comparative example 6
The additive provided in this comparative example differs from the additive of example 6 in that: dimethyl sulfoxide was used instead of deionized water, and the other ingredients were the same as in example 6.
Example 7
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 6% of calcium dodecyl benzene sulfonate, 2% of EO-PO block copolymer, 3% of fatty alcohol-polyoxyethylene ether, 20% of polyvinyl alcohol, 25% of butyl tetrol, 0.3% of polyoxypropylene glycerol ether and the balance of deionized water to 100%.
Comparative example 7
The additive provided in this comparative example differs from the additive of example 7 in that: xylene was used instead of deionized water, and the other ingredients were the same as in example 7.
Example 8
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 60% of polyvinyl alcohol, 25% of butyl tetrol, 5% of EO-PO block copolymer, 0.2% of polyoxypropylene glycerol ether and deionized water which are complemented to 100%.
Comparative example 8
The additive provided in this comparative example differs from the additive of example 8 in that: dimethyl sulfoxide was used instead of deionized water, and the other ingredients were the same as in example 8.
Example 9
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 6% of calcium dodecyl benzene sulfonate, 2% of EO-PO block copolymer, 3% of alkylaryl polyoxypropylene polyoxyethylene ether, 20% of polyvinyl alcohol, 25% of butanetriol, 0.1% of polyoxypropylene polyoxyethylene glycerol ether, 0.2% of polydimethylsiloxane and deionized water which are added to make up to 100%.
Comparative example 9
The additive provided in this comparative example differs from the additive of example 9 in that: the deionized water and deionized water were replaced with cyclohexanone, and the other ingredients were the same as in example 9.
Example 10
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 2% of EO-PO block copolymer, 6% of phenethyl phenol polyoxyethylene ether, 3% of alkylphenol polyoxyethylene ether phosphate, 30% of soybean oil, 30% of n-butyl alcohol, 0.3% of silicone emulsion and the balance of deionized water to 100%.
Comparative example 10
The additive provided in this comparative example differs from the additive of example 10 in that: xylene was used instead of deionized water, and the other ingredients were the same as in example 10.
Example 11
The special water-based environment-friendly auxiliary agent for the smoke cooling machine comprises the following components in percentage by mass: 6% of calcium dodecyl benzene sulfonate, 2% of EO-PO block copolymer, 3% of fatty alcohol-polyoxyethylene ether, 20% of glycerol, 25% of butyl tetrol, 0.3% of polyoxypropylene glycerol ether and the balance of deionized water to 100%.
Comparative example 11
The additive provided in this comparative example differs from the additive of example 11 in that: the deionized water was replaced with 0# diesel and the other ingredients were the same as in example 11.
Test example 1 efficacy test for field control of citrus red mites
Test site: in the orchard of double bridge ballast hole and village-ballast orange in Wuming district of south-Guangxi
The test method comprises the following steps: the experiment was set up for 24 treatments: 22 groups of drug application groups, 1 group of clear water and abamectin controlThe group and the group 1 clear water control group, the 22 groups of drug application groups comprise 11 groups of example groups and 11 groups of comparative group, the example groups are formed by compounding the auxiliary agent and the corresponding medicament in the embodiment of the invention, the comparative group is formed by compounding the auxiliary agent and the corresponding medicament in the comparative example, each group is treated three times, each group treats 2 trees, and the drug application is carried out according to the ratio of 40mL/667m2The dosage of the auxiliary agent is equal to 60ml/667m21.5% Avermectin ULV (registered as PD20171507, available from Guangxi rural Biochemical Co., Ltd.) was made up with water to 600ml/667m2Carrying out hot mist pesticide application; the clear water and abamectin control group is 60ml/667m21.5% abamectin ULV is made up to 600ml/667m with water2Application is carried out. The number of red spiders per leaf before medicine is 18.54-50.43. Randomly selecting 8 spring shoots by adopting a fixed-point survey method, hanging a small label at the mature leaves at the base part of each spring shoot, selecting 10 leaves from the branches with the small labels, photographing the front and back sides of the leaves by using a camera, and amplifying and calculating the number of live/dead insects on a computer. Investigating 1 day, 3 days and 7 days after the pesticide application respectively, and calculating the population reduction rate and the prevention and treatment effect, wherein the specific calculation formula is as follows:
the oral cavity decline rate is (number of living insects before the drug-number of living insects after the drug)/number of living insects before the drug x 100%;
the control effect is (the oral cavity decline rate of the treated area-the oral cavity decline rate of the control area)/(100-the oral cavity decline rate of the control area) × 100%.
And (3) test results: the effect of preventing citrus red spiders by matching the auxiliary agent and the pesticide preparation is shown in table 1, and the prevention and treatment effect can be seen from table 1 by mixing the auxiliary agent and the pesticide preparation, the insect population reduction rate reaches over 90 percent after the pesticide is applied for 7 days, the prevention and treatment effect is over 88 percent, the prevention and treatment effect is obviously higher than that of a comparative example group, the prevention effect can be improved by 13 percent to the maximum extent, the effect can be effectively improved and the prevention and treatment effect can be enhanced by the aid of the auxiliary agent, the auxiliary agent is a water-based auxiliary agent, is green and environment-friendly, is supplemented with water when matched with the pesticide preparation, is small in taste and wide in application scene, and can.
TABLE 1 Effect of adjuvant and pesticide preparation for preventing and treating citrus red spider
Figure BDA0002519223840000081
Figure BDA0002519223840000091
Figure BDA0002519223840000101
Test example 2 test of the efficacy of indoor cockroach control
Test site: dormitory building of Guangxi professional technical institute
The test method comprises the following steps: the experiment was set up with 12 treatments: 10 groups of application medicines, 1 group of clear water and beta-cypermethrin control group and 1 group of clear water control group, wherein the 10 groups of application medicines comprise 5 groups of example groups and 5 groups of comparative proportion groups, the example groups are formed by compounding the auxiliary agents and the corresponding medicines in the examples of the invention, the comparative proportion groups are formed by compounding the auxiliary agents and the corresponding medicines in the comparative proportion, each treatment is repeated three times, each dormitory is treated by one time, and the application is carried out according to the ratio of 40mL/250m3The dosage of the auxiliary agent is equal to 80ml/250m34.5% of beta-cypermethrin EC (registered as PD20092168, available from Guangxi rural Biochemical Co., Ltd.) and water to 220ml/250m3Carrying out hot mist pesticide application; the clear water and beta-cypermethrin control group is 80ml/250m34.5% beta-cypermethrin EC is complemented with water to 220ml/250m3Application is carried out. The method is characterized in that a drug stimulation method is adopted, 0.5% of dichlorokresoxim-methyl alcohol liquid is sprayed on the breeding and inhabiting place of the cockroaches to excite and expel the cockroaches, the number of nymphs of the cockroaches which climb out or knock down within 15min is calculated respectively, and the killing rate is calculated according to the average density (only/15 min). Investigating once in 3 days, 15 days and 30 days respectively, and calculating the killing rate and the control effect, wherein the specific calculation formula is as follows:
the killing rate (%) (pre-extinction density-post-extinction density)/pre-extinction density x 100%
Control effect (%) × (density after extinction-density of control area)/(density of 100-density of control area) × 100%.
And (3) test results: the table 2 shows that the effect of the auxiliary agent and the pesticide preparation on preventing and treating indoor cockroaches is achieved, the killing rate is over 90% after the auxiliary agent and the pesticide preparation are mixed for preventing and treating, the prevention and treatment effect is over 95%, the prevention and treatment effect is improved by over 5% compared with a proportional group, and the prevention and treatment effect is improved by 10% to the maximum extent, so that the auxiliary agent can effectively improve the pesticide effect and strengthen the prevention and treatment effect.
TABLE 2 Effect of adjuvant and pesticide preparation for preventing and treating indoor cockroach
Figure BDA0002519223840000111
The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.

Claims (9)

1. The special water-based environment-friendly auxiliary agent for the smoke cooling machine is characterized by comprising the following components in percentage by mass: 1-15% of surfactant, 40-90% of smoke agent, 0.1-0.5% of defoaming agent and 5-50% of water.
2. The water-based environment-friendly auxiliary agent as claimed in claim 1, wherein the surfactant is one or a mixture of more of alkylphenol ethoxylate, phenethylphenol ethoxylate, sodium dodecylbenzene sulfonate, sodium laurylsulfate, anionic sodium alkylsulfate, EO-PO block copolymer, sorbitan monooleate, fatty alcohol ethoxylate, alkylaryl polyoxypropylene ethoxylate, fatty alcohol ethoxylate phosphate, alkylphenol ethoxylate phosphate, and calcium dodecylbenzene sulfonate.
3. The water-based environment-friendly additive according to claim 1, wherein the smoke agent is one or a mixture of more of ethylene glycol, propylene glycol, glycerol, polyvinyl alcohol, n-butanol, isobutanol, butanediol, butanetriol, butanetetraol, soybean oil, peanut oil and mineral oil.
4. The water-based environment-friendly additive as claimed in claim 1, wherein the defoaming agent is one or more of silicone emulsion, higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
5. The water-based environment-friendly additive according to claim 1, wherein the water is deionized water.
6. The water-based environment-friendly additive according to claim 1, wherein the water-based environment-friendly additive is prepared by the following method: and pumping water, a surfactant and a defoaming agent into the reaction kettle in sequence, stirring for 10min at a speed of 100r/min, pumping a smoke agent, continuously stirring for 20min, and stirring the system uniformly to obtain the water-based environment-friendly auxiliary agent.
7. The application of the water-based environment-friendly auxiliary agent as defined in any one of claims 1 to 6 in pest control.
8. The application of the water-based environment-friendly auxiliary agent as claimed in claim 7, wherein the water-based environment-friendly auxiliary agent is uniformly mixed with a pesticide, a bactericide or a disinfectant in a suspension, water emulsion or microemulsion form, and is heated and atomized at a constant temperature by a cold tobacco machine to prevent and treat pests.
9. The application of the water-based environment-friendly auxiliary agent as claimed in claim 8, wherein the water-based environment-friendly auxiliary agent is added in an amount of 7-63 ml/250m for pest control in the closed space3(ii) a The water-based environment-friendly auxiliary agent is added in an amount of 5-100 ml/667m for preventing and treating diseases and insect pests in non-closed space2
CN202010486401.8A 2020-06-01 2020-06-01 Water-based environment-friendly auxiliary agent special for smoke cooling machine and application thereof Pending CN111685111A (en)

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CN101773113A (en) * 2010-02-09 2010-07-14 安徽农业大学 Hot fogging concentrate containing propiconazole and chlorpyrifos and preparation method thereof
CN101779625A (en) * 2010-02-09 2010-07-21 安徽省农业科学院植物保护研究所 Functional smoke agent for hot fogging machine and preparation method thereof
CN102165949A (en) * 2011-03-03 2011-08-31 安徽农业大学 Dedicated additive for hot fog machine and preparation method thereof
CN103404540A (en) * 2013-07-29 2013-11-27 安徽农业大学 Hot fogging concentrate containing arasan and azoxystrobin and preparation method of hot fogging concentrate
CN104322509A (en) * 2014-10-20 2015-02-04 贵州大学 Emulsion containing bactericide methanesulfonylazole
CN204552994U (en) * 2015-01-26 2015-08-12 广西田园生化股份有限公司 A kind of hot mist machine device for preventing oil spilling
CN111149799A (en) * 2020-02-19 2020-05-15 中国日用化学研究院有限公司 Multifunctional pesticide aqueous suspension dispersant, preparation method and use method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101773113A (en) * 2010-02-09 2010-07-14 安徽农业大学 Hot fogging concentrate containing propiconazole and chlorpyrifos and preparation method thereof
CN101779625A (en) * 2010-02-09 2010-07-21 安徽省农业科学院植物保护研究所 Functional smoke agent for hot fogging machine and preparation method thereof
CN102165949A (en) * 2011-03-03 2011-08-31 安徽农业大学 Dedicated additive for hot fog machine and preparation method thereof
CN103404540A (en) * 2013-07-29 2013-11-27 安徽农业大学 Hot fogging concentrate containing arasan and azoxystrobin and preparation method of hot fogging concentrate
CN104322509A (en) * 2014-10-20 2015-02-04 贵州大学 Emulsion containing bactericide methanesulfonylazole
CN204552994U (en) * 2015-01-26 2015-08-12 广西田园生化股份有限公司 A kind of hot mist machine device for preventing oil spilling
CN111149799A (en) * 2020-02-19 2020-05-15 中国日用化学研究院有限公司 Multifunctional pesticide aqueous suspension dispersant, preparation method and use method thereof

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Application publication date: 20200922