CN111423924B - 一种改进拉丝油及其制备方法 - Google Patents

一种改进拉丝油及其制备方法 Download PDF

Info

Publication number
CN111423924B
CN111423924B CN202010260595.XA CN202010260595A CN111423924B CN 111423924 B CN111423924 B CN 111423924B CN 202010260595 A CN202010260595 A CN 202010260595A CN 111423924 B CN111423924 B CN 111423924B
Authority
CN
China
Prior art keywords
parts
oil
improved
drawing oil
mixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202010260595.XA
Other languages
English (en)
Other versions
CN111423924A (zh
Inventor
何友德
姚华强
刘安荣
何瞻
王振杰
彭伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUIZHOU INSTITUTE OF METALLURGY AND CHEMICAL ENGINEERING
Guizhou Shuigang Metal Technology Co ltd
Original Assignee
GUIZHOU INSTITUTE OF METALLURGY AND CHEMICAL ENGINEERING
Guizhou Shuigang Metal Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUIZHOU INSTITUTE OF METALLURGY AND CHEMICAL ENGINEERING, Guizhou Shuigang Metal Technology Co ltd filed Critical GUIZHOU INSTITUTE OF METALLURGY AND CHEMICAL ENGINEERING
Priority to CN202010260595.XA priority Critical patent/CN111423924B/zh
Publication of CN111423924A publication Critical patent/CN111423924A/zh
Application granted granted Critical
Publication of CN111423924B publication Critical patent/CN111423924B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C10M2207/243—Epoxidised acids; Ester derivatives thereof used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Metal Extraction Processes (AREA)

Abstract

本发明涉及润滑剂技术领域，尤其是一种改进拉丝油及其制备方法，以环氧大豆油和绵羊油为基础油所具有的优良润滑性能和相比矿物油更为环保安全等特性的基础上，对拉丝油中的各原料成分的相对含量进行调整，实现基础油用量减少，微晶蜡适量增加，2‑辛基十二烷醇、丙二醇苯醚适当减少，十八烷醇基聚氧乙烯醚、松香酸聚氧乙烯酯、助剂适当增加，有效改善了拉丝油的性能，提高了拉丝油的润滑效果，降低了模具与线材间的摩擦系数，降低了能耗。

Description

一种改进拉丝油及其制备方法
技术领域
本发明涉及润滑剂技术领域，尤其是一种改进拉丝油及其制备方法。
背景技术
拉丝油是重要的工业助剂，在金属线拉丝、拉拔工艺中用作高效润滑油，具有润滑、清洗、冷却、防锈等功效，提高金属流动顺畅性，避免模具拖花拉线，提高成品率，降低生产损耗。目前，拉丝油分为油性拉丝油和水性拉丝油，而这两类拉丝油在实际使用过程中，各具利弊，例如：油性拉丝油存在散热性能差，清洗排屑困难，废液降解难等问题；水性拉丝油相较油性拉丝油来说，其散热性能优良，但润滑效果却难以满足多种金属线的拉丝拉拔工艺要求，故而为了提高加工企业的生产水平，降低生产成本，需要对拉丝油配方以及制备工艺进行改进，使得拉丝油的润滑性能得到提高。
基于此，本研究者在实际生产过程中，于2017年9月开展了技术引进，引入了专利号为201410169999.2的清净减磨高效拉丝油，以微晶蜡、绵羊油、环氧大豆油、2-辛基十二烷醇、三乙醇胺硼酸酯、十二烷基三甲基氯化铵、十八烷醇基聚氧乙烯醚、丙二醇苯醚、松香酸聚氧乙烯酯、硫化棉籽油、助剂，其中助剂是石墨烯、硅烷偶联剂KH560、异硬脂酸、黄原胶、司盘80、去离子水配制而成，经过混合搅拌而成，使得以绵羊油和环氧大豆油作为基础油，提高了环保性和使用的安全性，并且与金属表面具有较强的吸附力，能够降低模具与线材的摩擦系数，走线顺畅，拉丝效果好，清净分散性良好，使用寿命长。
发明内容
本研究者对引进的专利技术进行产业化生产试验，以φ5.63mm，抗拉强度为84.12kg/mm2的中碳钢丝为原料进行拉丝拉拔时，采用引进专利技术文献的原料成分配制成相应的拉丝油作为润滑剂使用，发现：现有原料配比的拉丝油与线材表面的摩擦系数依然较大，能耗较高，致使拉拔出口温度较高，导致拉丝油润滑效果依然不理想。
为了解决现有技术中存在的上述技术问题，本发明创造的目的之一是提供一种改进拉丝油，由以重量份计的以下原料配制而成：环氧大豆油78份，微晶蜡13份，绵羊油7份，2-辛基十二烷醇2份，三乙醇胺硼酸酯1-3份，十二烷基三甲基氯化铵1-2份，十八烷醇基聚氧乙烯醚9份，丙二醇苯醚0.5份，松香酸聚氧乙烯酯11份，硫化棉籽油1-2份，助剂4份。采用的助剂是按照现有技术(参照所引进的专利技术文献：实施例)中所公开的技术方案配制而成的。
为了提高拉丝油的润滑效果，优选，所述的硫化棉籽油为1.3份。更优选，所述的三乙醇胺硼酸酯2份。进一步优选，所述的十二烷基三甲基氯化铵1.5份。
本发明创造的目的之二在于提供一种上述的改进拉丝油制备方法，包括以下步骤：先将环氧大豆油、微晶蜡、绵羊油混合，加热至80-90℃，恒温；再依次加入助剂和2-辛基十二烷醇、三乙醇胺硼酸酯、十二烷基三甲基氯化铵，以1000-1500r/min的搅拌速度搅拌混合25-30min；随后将其它剩余物料一起加入，继续搅拌40-50min，自然冷却至室温，即得成品。
与现有技术相比，本发明创造的技术效果体现在：
①充分利用了现有技术中，以环氧大豆油和绵羊油为基础油所具有的优良润滑性能和相比矿物油更为环保安全等特性的基础上，对拉丝油中的各原料成分的相对含量进行调整，实现基础油用量减少，微晶蜡适量增加，2-辛基十二烷醇、丙二醇苯醚适当减少，十八烷醇基聚氧乙烯醚、松香酸聚氧乙烯酯、助剂适当增加，有效改善了拉丝油的性能，提高了拉丝油的润滑效果，降低了模具与线材间的摩擦系数，降低了能耗。
②经过对各原料成分混合顺序控制，使得各原料成分相互之间参与物混的环境发生变化，使得拉丝油的综合性能得到改善，增强了拉丝油在金属表面的吸附力，提高成膜效果，确保走线更为顺畅，拉丝效果更好，清净分散性增强，延长了使用寿命。
具体实施方式
下面结合具体的实施方式来对本发明的技术方案做进一步的限定，但要求保护的范围不仅局限于所作的描述。
实施例1
改进拉丝油，由以重量(kg)计的以下原料配制而成：环氧大豆油78，微晶蜡13，绵羊油7，2-辛基十二烷醇2，三乙醇胺硼酸酯2，十二烷基三甲基氯化铵1.5，十八烷醇基聚氧乙烯醚9，丙二醇苯醚0.5，松香酸聚氧乙烯酯11，硫化棉籽油1.3，助剂4。
制备方法1：按照专利号为201410169999.2的清净减磨高效拉丝油混合配制而成，得到成品A；
制备方法2：先将环氧大豆油、微晶蜡、绵羊油混合，加热至80-90℃，恒温；再依次加入助剂和2-辛基十二烷醇、三乙醇胺硼酸酯、十二烷基三甲基氯化铵，以1000-1500r/min的搅拌速度搅拌混合25-30min；随后将其它剩余物料一起加入，继续搅拌40-50min，自然冷却至室温，即得成品B。
实施例2
改进拉丝油，由以重量(kg)计的以下原料配制而成：环氧大豆油78，微晶蜡13，绵羊油7，2-辛基十二烷醇2，三乙醇胺硼酸酯1，十二烷基三甲基氯化铵1，十八烷醇基聚氧乙烯醚9，丙二醇苯醚0.5，松香酸聚氧乙烯酯11，硫化棉籽油1，助剂4。
制备方法同实施例1。
实施例3
改进拉丝油，由以重量(kg)计的以下原料配制而成：环氧大豆油78，微晶蜡13，绵羊油7，2-辛基十二烷醇2，三乙醇胺硼酸酯3，十二烷基三甲基氯化铵2，十八烷醇基聚氧乙烯醚9，丙二醇苯醚0.5，松香酸聚氧乙烯酯11，硫化棉籽油2，助剂4。
制备方法同实施例1。
实施例4
改进拉丝油，由以重量(kg)计的以下原料配制而成：环氧大豆油78，微晶蜡13，绵羊油7，2-辛基十二烷醇2，三乙醇胺硼酸酯3，十二烷基三甲基氯化铵2，十八烷醇基聚氧乙烯醚9，丙二醇苯醚0.5，松香酸聚氧乙烯酯11，硫化棉籽油1，助剂4。
制备方法同实施例1。
实施例5
改进拉丝油，由以重量(kg)计的以下原料配制而成：环氧大豆油100，微晶蜡10，绵羊油40，2-辛基十二烷醇5，三乙醇胺硼酸酯1，十二烷基三甲基氯化铵2，十八烷醇基聚氧乙烯醚8，丙二醇苯醚1，松香酸聚氧乙烯酯10，硫化棉籽油1，助剂3。
制备方法同实施例1。
将实施例1-5配制得到的拉丝油，在室温条件下，稳定存放15个月，未见有沉淀、分层现象，其具体指标性能如下表1所示：
表1：拉丝油具体指标性能(取10次测试平均值)
Figure BDA0002439144880000051
采用上述实施例1-5配制的拉丝油进行拉拔性能测试试验：采用钢材为φ5.63mm，抗拉强度为84.12kg/mm2的中碳钢丝为原料进行拉丝拉拔，拉拔机为链式拉拔机，在同等条件下，拉拔参数控制以及拉拔性能测试结果如下表2所示：
表2：拉拔性能测试(测试数据取10次测试结论平均值)
Figure BDA0002439144880000052
备注：N1拉拔时电机功率；N0空载时电机功率；出口温度是钢丝拉拔至最后模具出口时的钢丝温度。
由表2的数据显示可见，本发明创造的拉丝油应用于钢材为φ5.63mm，抗拉强度为84.12kg/mm2的中碳钢丝为原料进行拉丝拉拔时，拉丝拉拔出口温度得到了降低，相较于现有技术来说，大幅度的节约了能耗，降低了模具与线材的摩擦系数，有助于降低拉拔成本。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (5)

1.一种改进拉丝油，其特征在于，由以重量份计的以下原料配制而成：环氧大豆油78份，微晶蜡13份，绵羊油7份，2-辛基十二烷醇2份，三乙醇胺硼酸酯1-3份，十二烷基三甲基氯化铵1-2份，十八烷醇基聚氧乙烯醚9份，丙二醇苯醚0.5份，松香酸聚氧乙烯酯11份，硫化棉籽油1-2份，助剂4份；
所述的改进拉丝油制备方法，包括以下步骤：先将环氧大豆油、微晶蜡、绵羊油混合，加热至80-90℃，恒温；再依次加入助剂和2-辛基十二烷醇、三乙醇胺硼酸酯、十二烷基三甲基氯化铵，以1000-1500r/min的搅拌速度搅拌混合25-30min；随后将其它剩余物料一起加入，继续搅拌40-50min，自然冷却至室温，即得成品；
所述助剂由以下重量份的原料制成：石墨烯1份，硅烷偶联剂KH560 0.2份，异硬脂酸15份，黄原胶10份，司盘80 4份，去离子水适量；制备方法为：先将石墨烯与硅烷偶联剂混合研磨15min，得到的粉末与异硬脂酸、司盘80混合，在1500转/分钟的转速下搅拌20min，制成乳化液备用，再将黄原胶与适量的去离子水混合，配制成质量浓度为 60%的黄原胶水溶液，最后将水溶液、乳化液混合，继续以1500转/分钟转速搅拌15min，搅拌结束后静置2h，即得；
所述的改进拉丝油用于以φ5.63mm、抗拉强度为84.12kg/mm2的中碳钢丝为原料进行拉丝拉拔时作润滑剂。
2.如权利要求1所述的改进拉丝油，其特征在于，所述的硫化棉籽油为1.3份。
3.如权利要求1所述的改进拉丝油，其特征在于，所述的三乙醇胺硼酸酯2份。
4.如权利要求1所述的改进拉丝油，其特征在于，所述的十二烷基三甲基氯化铵1.5份。
5.一种将如权利要求1-4任一项所述的改进拉丝油用于以φ5.63mm、抗拉强度为84.12kg/mm2的中碳钢丝为原料进行拉丝拉拔时作润滑剂。
CN202010260595.XA 2020-04-03 2020-04-03 一种改进拉丝油及其制备方法 Active CN111423924B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010260595.XA CN111423924B (zh) 2020-04-03 2020-04-03 一种改进拉丝油及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010260595.XA CN111423924B (zh) 2020-04-03 2020-04-03 一种改进拉丝油及其制备方法

Publications (2)

Publication Number Publication Date
CN111423924A CN111423924A (zh) 2020-07-17
CN111423924B true CN111423924B (zh) 2022-06-28

Family

ID=71557824

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010260595.XA Active CN111423924B (zh) 2020-04-03 2020-04-03 一种改进拉丝油及其制备方法

Country Status (1)

Country Link
CN (1) CN111423924B (zh)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103992867B (zh) * 2014-04-25 2016-05-18 蚌埠市正园电子科技有限公司 一种含牛至油的抗氧化拉丝油
CN103992855B (zh) * 2014-04-25 2016-02-10 蚌埠市时代电子有限公司 一种清净减磨高效拉丝油

Also Published As

Publication number Publication date
CN111423924A (zh) 2020-07-17

Similar Documents

Publication Publication Date Title
CN103602376B (zh) 一种复合纳米抗磨剂及其制备方法
CN104450120A (zh) 一种半合成金属拉丝润滑液及制备方法
CN102559351B (zh) 一种汽车子午线轮胎钢帘线湿拉润滑剂
CN103045335A (zh) 一种适应于软水的水性金属加工切削液
CN104745280B (zh) 一种环保易分解的植物油基润滑油及其生产工艺
CN103992853A (zh) 一种不锈钢拉丝用拉丝油
CN105316094A (zh) 一种环保型齿轮润滑油及其制备方法
CN104818103B (zh) 汽车用低碳钢件冷挤压成形润滑剂及其制备方法
CN106590907A (zh) 一种含石墨烯的金属切削液及其制备方法
CN108949288A (zh) 高抗磨极压及抗磨减摩性润滑油制备工艺
CN105950268A (zh) 一种含石墨烯添加剂的金属加工多功能润滑剂及其制备方法
CN111423924B (zh) 一种改进拉丝油及其制备方法
CN103992855B (zh) 一种清净减磨高效拉丝油
CN109370722A (zh) 一种切割钢丝湿拉润滑剂及其制备方法
CN103992838A (zh) 一种含纳米银的拉丝油
CN116987543A (zh) 一种钢帘线湿拉润滑剂组合物
CN104120017A (zh) 一种渗透力强防锈性能好的水基切削液及其制备方法
CN108456585B (zh) 一种钢管拉拔反应油组合物
CN115820332A (zh) 一种水基全合成切削液及其制备方法和应用
CN109233965A (zh) 一种钢帘线湿拉润滑剂及其制备方法
CN109097167A (zh) 高耐磨自修复性润滑油
CN109913300B (zh) 一种可生物降解的环保型润滑剂及其制备方法
CN115678654B (zh) 一种低模耗低磨损量的钢帘线拉丝液及其制备方法
CN112605322A (zh) 一种航空航天用铝合金紧固件螺纹滚压成形的冷却方法
CN108300539A (zh) 一种新型润滑油的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: 553000 Guizhou Shuigang tongxinsheng metal products Co., Ltd. Hongqiao Industrial Park, Zhongshan Economic Development Zone, Liupanshui City, Guizhou Province

Applicant after: Guizhou Shuigang Metal Technology Co.,Ltd.

Applicant after: Guizhou Institute of metallurgy and chemical industry

Address before: 553000 Guizhou Shuigang tongxinsheng metal products Co., Ltd. Hongqiao Industrial Park, Zhongshan Economic Development Zone, Liupanshui City, Guizhou Province

Applicant before: GUIZHOU SHUIGANG TONGXINSHENG METAL PRODUCTS CO.,LTD.

Applicant before: Guizhou Institute of metallurgy and chemical industry

GR01 Patent grant
GR01 Patent grant