CN111423159A - Resource utilization method for high-water-content sludge - Google Patents

Resource utilization method for high-water-content sludge Download PDF

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Publication number
CN111423159A
CN111423159A CN202010145693.9A CN202010145693A CN111423159A CN 111423159 A CN111423159 A CN 111423159A CN 202010145693 A CN202010145693 A CN 202010145693A CN 111423159 A CN111423159 A CN 111423159A
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China
Prior art keywords
sludge
water
content
recycling
water content
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Pending
Application number
CN202010145693.9A
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Chinese (zh)
Inventor
刘坚
苏凡
吴跃东
李旭
陈亮
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Hohai University HHU
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Hohai University HHU
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Priority to CN202010145693.9A priority Critical patent/CN111423159A/en
Publication of CN111423159A publication Critical patent/CN111423159A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/147Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using organic substances
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0418Wet materials, e.g. slurries
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a method for resource utilization of high-water-content sludge, which comprises the following steps: step SS 1: taking a certain amount of sludge with high water content, and adding a flocculating agent into the sludge; step SS 2: after the flocculation phenomenon is generated in the sludge and the sludge is stable, pumping out supernatant liquor by using pumping equipment; step SS 3: putting the water absorbent wrapped by the geotextile into the sludge with the supernatant liquid removed for water absorption until the sludge cannot be further dehydrated; step SS 4: and adding a cementing material into the dewatered sludge, and fully stirring to prepare the filling brick or roadbed filling material. The method overcomes the defects of long time consumption, high cost and insufficient treatment of the traditional high-water-content sludge treatment, and has the characteristics of low cost, high speed, good economic benefit, on-site treatment and the like.

Description

Resource utilization method for high-water-content sludge
Technical Field
The invention relates to a method for resource utilization of high-water-content sludge, and belongs to the technical field of sludge treatment.
Background
Sludge is one of the important sources of urban pollutants. Along with the continuous improvement of the environmental protection consciousness of people, the dredging work of rivers and lakes is also gradually promoted. In the dredging work, how to treat a large amount of sludge becomes a problem to be solved urgently. Such sludges tend to have very high water content and are very difficult to transport outside and require on-site treatment. The existing dehydration treatment technology usually utilizes machinery to compact and drain on the spot, and the method has the disadvantages that firstly, discharged water flows into a river channel and a lake again to bring rework, secondly, in the mechanical compaction process, sludge can not be fixed, the compaction process is actually the process that the sludge is extruded and laterally deformed, the compaction efficiency is low, the time and the labor are consumed in sludge treatment, thirdly, sludge can not be recycled, the treated sludge still needs to be transported outside, the water content is still higher, the strength is lower, and the sludge can not be utilized. Therefore, a new method for resource utilization of the sludge with high water content needs to be found, which can not only avoid rework, but also accelerate the treatment speed and reduce the treatment cost, and can also utilize the treated sludge in a commercialized manner, thereby bringing good economic benefits.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a method for recycling sludge with high water content, which can finally convert sludge with high water content into building material products or building materials for utilization so as to solve the problems of difficult, slow and high cost treatment of sludge with high water content.
In order to solve the technical problem, the invention provides a method for resource utilization of high-water-content sludge, which is characterized by comprising the following steps of:
step SS 1: taking a certain amount of sludge with high water content, and adding a flocculating agent into the sludge;
step SS 2: after the flocculation phenomenon is generated in the sludge and the sludge is stable, pumping out supernatant liquor by using pumping equipment;
step SS 3: putting the water absorbent wrapped by the geotextile into the sludge with the supernatant liquid removed for water absorption until the sludge cannot be further dehydrated;
step SS 4: and adding a cementing material into the dewatered sludge, and fully stirring to prepare the filling brick or the roadbed filling material.
As a preferred embodiment, the moisture content of the sludge in step SS1 exceeds 100%.
As a preferred embodiment, the flocculant in step SS1 is polyacrylamide PAM.
As a preferred embodiment, the addition amount of the flocculating agent is 3-8 per mill of the total mass of the sludge.
As a preferable example, the water absorbing agent in step SS3 is SAP particles of a high molecular water absorbent resin.
As a preferred embodiment, the SAP particles are added in an amount of 5-10kg/m to thin a sludge mass.
In a preferred embodiment, after the SAP particles absorb water and are saturated, the SAP particles are placed in a high ion concentration solution or exposed to sunlight together with geotextile for dehydration, and then are recycled.
In a preferred embodiment, the cement is used as the cementing material in step SS 4.
As a preferred embodiment, the cement is added in an amount of 3-5% of the total mass of the sludge to prepare the roadbed filling material.
As a preferred embodiment, the cement is added in an amount of 10-20% by mass based on the total mass of the sludge.
The invention achieves the following beneficial effects: 1. the method can treat the sludge with high water content, and the traditional treatment method can only treat the sludge with the water content of less than 100 percent, so the method has wider application range. 2. The method simultaneously applies the flocculating agent and the water absorbent to treat the sludge with high water content, compared with a method only using the flocculating agent, the method has the advantages that the treatment is more sufficient, the water content of the obtained sludge is lower, and the mechanical strength is higher; the method of the present invention requires a smaller amount of water-absorbing agent and is less costly than a method using only the water-absorbing agent. 3. Compared with the traditional method for treating by utilizing mechanical in-situ compaction drainage, the method can utilize sludge as resources, and has higher social benefit; compared with the method for preparing the building material product by directly adding cement and lime, the method of the invention needs less cement, and the obtained building material product has higher mechanical strength and higher economic benefit.
Drawings
FIG. 1 is a schematic diagram of a method for resource utilization of high water content sludge according to the present invention.
The method comprises the following steps of 1-beaker, 2-high-water-content sludge, 3-flocculating agent, 4-injector, 5-geotextile, 6-water absorbent, 7-cement, 8-roadbed filling material and 9-filling brick.
Detailed Description
The invention is further described below with reference to the accompanying drawings. The following embodiments are only used to more clearly illustrate the technical solutions of the present invention, and the protection scope of the present invention is not limited thereby.
As shown in fig. 1, the invention provides a method for resource utilization of high-moisture content sludge, which comprises the following steps:
step 1: taking a certain amount of sludge with high water content, and adding a flocculating agent into the sludge;
step 2: after the flocculation phenomenon is generated in the sludge and the sludge is stable, pumping out supernatant liquor by using pumping equipment;
and step 3: putting the water absorbent wrapped by the geotextile into the sludge from which the clear liquid is extracted for water absorption until the sludge cannot be further dehydrated;
and 4, step 4: and adding a cementing material into the dewatered sludge, and fully stirring to prepare the filling brick or roadbed filling material.
Further, the water content of the high water content sludge 2 exceeds 100%, and the sampled high water content sludge is placed in the beaker 1.
Further, the flocculating agent 3 can be selected from polyacrylamide PAM, and the addition amount of the flocculating agent 3 is 3-8 per mill of the total mass of the high-water-content sludge 2.
Further, after the flocculant 3 is added, the flocculant and the high water content sludge 2 are sufficiently stirred by using a glass rod, and after standing for 24 hours, a supernatant liquid is extracted by using an injector 4.
Further, high molecular water absorbent resin SAP particles can be selected as the water absorbent agent 6, the addition amount of the SAP particles is 5-10kg/m high water content sludge 2, the water absorbent agent 6 has the characteristics of water absorption expansion and water loss contraction, in order to reduce cost, the water absorbent agent 6 can be wrapped by the geotextile 5 in advance, the geotextile 5 is put into the sludge 2 filtered out of clear liquid during use, and the sludge is placed in a high ion concentration solution or exposed to the sun for dehydration after full water absorption, so that the reutilization can be realized.
Further, as for the sludge 2 with high water content after the dehydration treatment, cement is selected as a cementing material, and if a roadbed filling material 8 is to be prepared, cement 7 which is about 3-5% of the total mass of the sludge 2 can be added; if the filling brick 9 is to be made, cement 7 may be added thereto in an amount of about 10% to 20% of the total mass of the high water content sludge 2.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (10)

1. A method for resource utilization of high-water-content sludge is characterized by comprising the following steps:
step SS 1: taking a certain amount of sludge with high water content, and adding a flocculating agent into the sludge;
step SS 2: after the flocculation phenomenon is generated in the sludge and the sludge is stable, pumping out supernatant liquor by using pumping equipment;
step SS 3: putting the water absorbent wrapped by the geotextile into the sludge with the supernatant liquid removed for water absorption until the sludge cannot be further dehydrated;
step SS 4: and adding a cementing material into the dewatered sludge, and fully stirring to prepare the filling brick or roadbed filling material.
2. The method for recycling the high-water-content sludge as claimed in claim 1, wherein the water content of the sludge in the step SS1 exceeds 100%.
3. The method for recycling the sludge with the high water content as claimed in claim 1, wherein the flocculant in the step SS1 is Polyacrylamide (PAM).
4. The method for recycling sludge with high water content as claimed in claim 3, wherein the addition amount of the flocculating agent is 3-8 per mill of the total mass of the sludge.
5. The method for recycling sludge with high water content as claimed in claim 1, wherein the water absorbent in the step SS3 is SAP particles.
6. The method for recycling sludge with high water content as claimed in claim 5, wherein the SAP particles are added in an amount of 5-10kg/m during sludge cultivation.
7. The method for recycling sludge with high water content as claimed in claim 5, wherein after the high water-content sludge is saturated by water absorption, the SAP particles with the high water-absorbing resin are placed in a high ion concentration solution along with geotextile or subjected to sun exposure for dehydration, and then are recycled.
8. The method for recycling the high-water-content sludge as claimed in claim 1, wherein the cementing material in the step SS4 is cement.
9. The method for recycling sludge with high water content as claimed in claim 8, wherein the addition amount of the cement used for preparing the roadbed filling material is 3% -5% of the total mass of the sludge.
10. The method for recycling sludge with high water content as claimed in claim 8, wherein the cement used for preparing the filling bricks is added in an amount of 10% -20% of the total mass of the sludge.
CN202010145693.9A 2020-03-05 2020-03-05 Resource utilization method for high-water-content sludge Pending CN111423159A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047676A (en) * 2020-07-31 2020-12-08 河海大学 Light solidified soil for resource utilization of river and lake bottom mud and preparation method and application thereof
CN114105552A (en) * 2021-10-31 2022-03-01 中交隧道工程局有限公司 High-water-content sludge curing agent and application method thereof
WO2022078776A1 (en) * 2020-10-14 2022-04-21 Aprotek Drying composition to facilitate the transportation of salty sludge

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1843987A (en) * 2006-04-26 2006-10-11 江苏聚慧科技有限公司 Construction method by utilizing solidified earth from sludge
CN101941787A (en) * 2010-10-04 2011-01-12 江苏江达生态科技有限公司 Drying treatment method of river and lake sludge
WO2013063774A1 (en) * 2011-11-02 2013-05-10 Empire Technology Development Llc Solidifying sludge
CN103979774A (en) * 2013-07-18 2014-08-13 俞元洪 Slurry dewatering and curing construction process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1843987A (en) * 2006-04-26 2006-10-11 江苏聚慧科技有限公司 Construction method by utilizing solidified earth from sludge
CN101941787A (en) * 2010-10-04 2011-01-12 江苏江达生态科技有限公司 Drying treatment method of river and lake sludge
WO2013063774A1 (en) * 2011-11-02 2013-05-10 Empire Technology Development Llc Solidifying sludge
CN103979774A (en) * 2013-07-18 2014-08-13 俞元洪 Slurry dewatering and curing construction process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047676A (en) * 2020-07-31 2020-12-08 河海大学 Light solidified soil for resource utilization of river and lake bottom mud and preparation method and application thereof
WO2022078776A1 (en) * 2020-10-14 2022-04-21 Aprotek Drying composition to facilitate the transportation of salty sludge
CN114105552A (en) * 2021-10-31 2022-03-01 中交隧道工程局有限公司 High-water-content sludge curing agent and application method thereof

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Application publication date: 20200717

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