CN111016365A - Composite fabric with waterproof performance - Google Patents

Composite fabric with waterproof performance Download PDF

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Publication number
CN111016365A
CN111016365A CN201911086641.2A CN201911086641A CN111016365A CN 111016365 A CN111016365 A CN 111016365A CN 201911086641 A CN201911086641 A CN 201911086641A CN 111016365 A CN111016365 A CN 111016365A
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CN
China
Prior art keywords
parts
cloth layer
composite fabric
layer
waterproof performance
Prior art date
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Pending
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CN201911086641.2A
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Chinese (zh)
Inventor
张子睿
姜亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunshan Huayang New Material Co ltd
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Kunshan Huayang New Material Co ltd
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Priority to CN201911086641.2A priority Critical patent/CN111016365A/en
Publication of CN111016365A publication Critical patent/CN111016365A/en
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof

Abstract

The invention discloses a waterproof composite fabric which comprises a base cloth layer, an outer cloth layer and a film layer, wherein two sides of the film layer are respectively attached to the base cloth layer and the outer cloth layer through adhesives, the film layer is obtained by extruding, forming, heating, stretching and annealing a film material, and the film material comprises the following components in parts by weight: 85-100 parts of polytetrafluoroethylene resin, 10-20 parts of tetrafluoroethylene/perfluoroalkyl vinyl ether copolymer, 5-15 parts of 1, 4-trans polyisoprene rubber, 8-12 parts of polymer of bis (4-fluorophenyl) ketone and 1, 4-benzenediol, 2-10 parts of 1, 4-benzenediol, 0.5-3 parts of potassium peroxodisulphate, 0.5-5 parts of nano titanium dioxide dispersion slurry, 0.3-2 parts of 2-methyl-2-pentanol-4-ketone, 0.5-5 parts of dioctyl sulfosuccinate, 0.2-3 parts of chlorofluorocarbon oil, 1-5 parts of silane coupling agent and 15-30 parts of N, N-dimethylformamide. The composite fabric has good heat resistance, slows down the heat conduction time and has wide application prospect.

Description

Composite fabric with waterproof performance
Technical Field
The invention relates to a polytetrafluoroethylene film, in particular to a composite fabric with waterproof performance.
Background
With the change of consumption concept and the continuous improvement of life quality of people, people pay more and more attention to the functional requirements of textiles such as clothes, and increasingly pursue that the same textile has multiple practical functions as much as possible so as to adapt to and improve living environment, working environment and self health. The fabric plays a crucial role as the first element of the garment.
For the clothes used in special working environment, because various extreme environments need to be faced, the clothes are generally required to have heat insulation and waterproof functions, while the traditional fabric is mostly woven in a knitting or weaving mode, the air permeability is good, but the waterproof performance is poor, a waterproof polyurethane coating is coated on the fabric, although the characteristic of poor waterproof performance is improved, the waterproof performance is generally reduced along with the increase of washing times, and the service life of the clothes is shortened. Therefore, how to provide a composite fabric which not only meets the requirements of heat insulation and water resistance, but also is resistant to washing becomes an effort for those skilled in the art.
Disclosure of Invention
The invention aims to provide the waterproof composite fabric which has good heat resistance, slows down the heat conduction time and has a wide application prospect.
In order to achieve the purpose, the invention adopts the technical scheme that: the composite fabric with the waterproof performance comprises a base fabric layer, an outer fabric layer and a film layer, wherein two sides of the film layer are respectively attached to the base fabric layer and the outer fabric layer through adhesives, the film layer is obtained by extruding, forming, heating, stretching and annealing a film material, and the film material comprises the following components in parts by weight:
85-100 parts of polytetrafluoroethylene resin,
10-20 parts of tetrafluoroethylene/perfluoroalkyl vinyl ether copolymer,
5-15 parts of 1, 4-trans-polyisoprene rubber,
8-12 parts of a polymer of bis (4-fluorophenyl) ketone and 1, 4-benzenediol,
2-10 parts of 1, 4-benzenediol,
0.5 to 3 parts of potassium peroxodisulphate,
0.5-5 parts of nano titanium dioxide dispersion slurry,
0.3-2 parts of 2-methyl-2-pentanol-4-ketone,
0.5 to 5 parts of dioctyl sulfosuccinate,
0.2 to 3 parts of chlorofluorocarbon oil,
1-5 parts of a silane coupling agent,
15-30 parts of N, N-dimethylformamide.
The technical scheme of further improvement in the technical scheme is as follows:
1. in the above embodiment, the silane coupling agent is at least one selected from γ (2,3 glycidoxy) propyltrimethoxysilane, 3-aminopropyltriethoxysilane, and aminopropylmethyldimethoxysilane.
2. In the scheme, the number average molecular weight of the polytetrafluoroethylene resin is 3000000-8000000.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
according to the waterproof composite fabric, the film material is prepared by adding 0.5-3 parts of potassium peroxodisulfate and 0.5-5 parts of nano titanium dioxide dispersed slurry on the basis of 10-20 parts of tetrafluoroethylene/perfluoroalkyl vinyl ether copolymer and 5-15 parts of 1, 4-trans polyisoprene rubber, so that the heat resistance of the prepared film is improved, the heat conduction time is shortened, and the waterproof composite fabric has good heat insulation performance and wide application prospect; in addition, 0.5-5 parts of dioctyl sulfosuccinate is further added based on 0.5-3 parts of potassium peroxodisulphate and 0.5-5 parts of nano titanium dioxide dispersion slurry in a formula system of the film material, and the water washing resistance and waterproof performance of the prepared film are enhanced, so that the composite fabric adopting the film is durable in use, and the service life of the fabric is prolonged.
Drawings
FIG. 1 is a schematic structural diagram of a composite fabric with waterproof performance according to the invention.
In the above drawings: 1. a base cloth layer; 2. an outer cloth layer; 3. a thin film layer.
Detailed Description
The invention is further described below with reference to the following examples:
examples 1 to 4: the composite fabric with the waterproof performance comprises a base fabric layer 1, an outer fabric layer 2 and a film layer 3, wherein two sides of the film layer 3 are respectively attached to the base fabric layer 1 and the outer fabric layer 2 through adhesives, the film layer 3 is obtained by extruding, forming, heating, stretching and annealing a film material, and the film material comprises the following components in parts by weight:
TABLE 1
Components Example 1 Example 2 Example 3 Example 4
Polytetrafluoroethylene resin 100 95 90 88
Tetrafluoroethylene/perfluoroalkyl vinyl ether copolymer 14 13 17 20
1, 4-trans polyisoprene rubber 9 7 13 10
Polymers of bis (4-fluorophenyl) methanone and 1, 4-benzenediol 9 11 8.5 10
1, 4-benzenediol 8 5 10 3
Potassium peroxodisulphate 1.5 2 0.8 2.5
Nano titanium dioxide dispersion slurry 1.0 3.9 5 2.8
2-methyl-2-pentanol-4-one 0.8 1.5 1.3 0.7
Dioctyl ester of sodium sulfosuccinic acid 0.5 3 2 1
Fluorocarbon oil 0.6 2.5 1.8 1.0
Silane coupling agent 2.5 4 3 0.5
N, N-dimethylformamide 20 15 28 25
The silane coupling agent in example 1 was 3-aminopropyltriethoxysilane;
the silane coupling agent in example 2 was a mixture of 3-aminopropyltriethoxysilane and aminopropylmethyldimethoxysilane;
the silane coupling agent in example 3 was gamma (2,3 glycidoxy) propyltrimethoxysilane;
the silane coupling agent in example 4 was aminopropylmethyldimethoxysilane;
the polytetrafluoroethylene resin in examples 1 to 4 had a number average molecular weight of 8000000.
The preparation method of the composite fabric with the waterproof performance comprises the following steps:
s1, unwinding the film layer 3, coating hot melt adhesive on the surface of the film layer, and compounding the film layer with the outer cloth layer 2 through a lamination process;
s2, curling the semi-finished product of the composite fabric prepared in the S1, stacking and ripening;
s3, unwinding the semi-finished product of the composite fabric, coating hot melt adhesive on the film surface of the semi-finished product of the composite fabric, and compounding the semi-finished product of the composite fabric with the base fabric layer 1 through a laminating process;
and S4, curling the finished product of the composite fabric prepared in the S3, stacking and curing.
Comparative examples 1 to 2: a polytetrafluoroethylene film comprises the following components in parts by weight:
TABLE 2
Components Comparative example 1 Comparative example 2
Polytetrafluoroethylene resin 100 95
Tetrafluoroethylene/perfluoroalkyl vinyl ether copolymer 13 14
1, 4-trans polyisoprene rubber 9 13
Polymers of bis (4-fluorophenyl) methanone and 1, 4-benzenediol 11 8.5
1, 4-benzenediol 8 5
Potassium peroxodisulphate - 2.5
Nano titanium dioxide dispersion slurry - 5
2-methyl-2-pentanol-4-one 1.5 5
Dioctyl ester of sodium sulfosuccinic acid 3 -
Fluorocarbon oil 2.5 1.8
Silane coupling agent 4 3
N, N-dimethylformamide 15 28
The silane coupling agent in comparative example 1 was gamma (2,3 glycidoxy) propyltrimethoxysilane;
the silane coupling agent in comparative example 2 was 3-aminopropyltriethoxysilane;
the polytetrafluoroethylene resins in comparative examples 1 and 2 both had a number average molecular weight of 8000000.
The preparation process is the same as the embodiment.
The properties of the polytetrafluoroethylene thin film layer 3 in the above examples 1 to 4 and comparative examples 1 to 3 are shown in table 3:
TABLE 3
Figure 892620DEST_PATH_IMAGE001
In the above test, the fabric with the polytetrafluoroethylene film layer is cleaned by a honeycomb drum washing machine for 48min each time, as shown in table 3, comparative example 1 lacks components potassium peroxodisulphate and nano titanium dioxide dispersion slurry compared with examples 1-4, and it can be known from data that the polytetrafluoroethylene film prepared in comparative example 1 has increasingly smaller water contact angles after being washed for many times, that is, the prepared fabric has increasingly poor hydrophobicity and water resistance; compared with the examples 1-4, the comparative example 2 lacks the component dioctyl sodium sulfosuccinate, and the data show that the contact angle of water of the polytetrafluoroethylene film prepared in the comparative example 2 is smaller and smaller after the polytetrafluoroethylene film is washed for many times, namely the hydrophobicity and the waterproof performance of the prepared fabric are also poorer and poorer;
as shown in the evaluation results of Table 3, the polytetrafluoroethylene films prepared in the embodiments of the invention have the advantages of better parameters than the comparative examples, high heat resistance, slow heat conduction time, and heat conductivity coefficient reduced to 0.19-0.26W/mk, and the composite fabric adopting the film has good heat insulation performance and wide application prospect, and the composite fabric adopting the film is durable and the service life of the fabric is prolonged.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.

Claims (3)

1. The utility model provides a compound surface fabric with waterproof performance which characterized in that: including base cloth layer (1), outer cloth layer (2) and thin layer (3), the two sides of thin layer (3) are laminated with base cloth layer (1) and outer cloth layer (2) through the adhesive respectively, thin layer (3) are extruded, are formed, are heated, are stretched, are annealed by film material and obtain, film material comprises the component of following part by weight:
85-100 parts of polytetrafluoroethylene resin,
10-20 parts of tetrafluoroethylene/perfluoroalkyl vinyl ether copolymer,
5-15 parts of 1, 4-trans-polyisoprene rubber,
8-12 parts of a polymer of bis (4-fluorophenyl) ketone and 1, 4-benzenediol,
2-10 parts of 1, 4-benzenediol,
0.5 to 3 parts of potassium peroxodisulphate,
0.5-5 parts of nano titanium dioxide dispersion slurry,
0.3-2 parts of 2-methyl-2-pentanol-4-ketone,
0.5 to 5 parts of dioctyl sulfosuccinate,
0.2 to 3 parts of chlorofluorocarbon oil,
1-5 parts of a silane coupling agent,
15-30 parts of N, N-dimethylformamide.
2. The composite fabric with waterproof performance according to claim 1, characterized in that: the silane coupling agent is selected from at least one of gamma (2,3 epoxypropoxy) propyl trimethoxy silane, 3-aminopropyl triethoxy silane or aminopropyl methyl dimethoxy silane.
3. The composite fabric with waterproof performance according to claim 1, characterized in that: the polytetrafluoroethylene resin has a number average molecular weight of 3000000-8000000.
CN201911086641.2A 2019-11-08 2019-11-08 Composite fabric with waterproof performance Pending CN111016365A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112237322A (en) * 2020-10-16 2021-01-19 张家港市海易五金工具有限公司 Waterproof and breathable draw-bar bag and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693414A (en) * 2008-12-01 2010-04-14 中山市坦洲镇银峰服装鞋材厂 Vamp material and method for preparing same
CN101811384A (en) * 2009-02-24 2010-08-25 苏州中来太阳能材料技术有限公司 Medium surface energy teflon backing plate and processing technique thereof
CN102205681A (en) * 2011-03-21 2011-10-05 科德宝宝翎衬布（南通）有限公司 Composite lining fabric with functions of wind resistance, moisture permeability and heat preservation, and production method thereof
CN107434944A (en) * 2016-05-25 2017-12-05 三菱铅笔株式会社 The non-aqueous dispersoid of fluorine resin, using its containing the thermally curable resin composition of fluorine resin and its solidfied material
CN109983088A (en) * 2016-12-01 2019-07-05 科慕埃弗西有限公司 Fluorocarbon polymer coating composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693414A (en) * 2008-12-01 2010-04-14 中山市坦洲镇银峰服装鞋材厂 Vamp material and method for preparing same
CN101811384A (en) * 2009-02-24 2010-08-25 苏州中来太阳能材料技术有限公司 Medium surface energy teflon backing plate and processing technique thereof
CN102205681A (en) * 2011-03-21 2011-10-05 科德宝宝翎衬布（南通）有限公司 Composite lining fabric with functions of wind resistance, moisture permeability and heat preservation, and production method thereof
CN107434944A (en) * 2016-05-25 2017-12-05 三菱铅笔株式会社 The non-aqueous dispersoid of fluorine resin, using its containing the thermally curable resin composition of fluorine resin and its solidfied material
CN109983088A (en) * 2016-12-01 2019-07-05 科慕埃弗西有限公司 Fluorocarbon polymer coating composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112237322A (en) * 2020-10-16 2021-01-19 张家港市海易五金工具有限公司 Waterproof and breathable draw-bar bag and preparation method thereof

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