CN104070741A - Highly elastic plastic alloy composite board and manufacturing method thereof - Google Patents
Highly elastic plastic alloy composite board and manufacturing method thereof Download PDFInfo
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- CN104070741A CN104070741A CN201410246666.5A CN201410246666A CN104070741A CN 104070741 A CN104070741 A CN 104070741A CN 201410246666 A CN201410246666 A CN 201410246666A CN 104070741 A CN104070741 A CN 104070741A
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Abstract
The invention provides a highly elastic plastic alloy composite plate and a manufacturing method thereof, and belongs to the field of plastic plates. The plate is of a three-layer composite structure which is respectively provided with a transparent elastic plastic alloy surface layer, a figure film layer and an elastic plastic bottom layer from top to bottom. The plate provided by the invention has the advantages of good anti-aging weather resistance property, light mass, high wear resistance, flexibility, impact strength and elasticity, noise reduction, good oxygen barrier property and antibacterial, antistatic and antiflaming properties, convenience and quickness in installation, energy conservation, sanitation, environmental protection, long service life and the like by improving burdening in each layer.
Description
Technical field
The invention belongs to plastic plate technical field, relate generally to a kind of elastomer alloy composite plate material and manufacture method thereof.
Background technology
Plastic plate is popular a kind of Novel light body ornament materials in the world today, also referred to as " light board ".A kind of at the very popular product of the Japan and Korea S in America and Europe and Asia, fashionable external, since the beginning of the eighties, enter Chinese market, so far big and medium-sized cities at home have obtained general approval, use very extensive, such as various places such as indoor family, hospital, school, office building, factory, public place, supermarket, business, stadiums.
At present, in the world plastic plate have that intensity is low, not sound insulation, not wear-resisting, etc. shortcoming, therefore need to manufacture a kind of plastic plate with characteristics such as high strength, high tenacity, fire-retardant, antistatic, high abrasion, anti-aging, hygienic environment-protectings.
Summary of the invention
The object of the invention is to overcome weak point of the prior art, provide a kind of elastomer alloy composite plate material effectively to strengthen the performances such as the ageing resistance of plastic plate, resistance oxygen biocidal property, weatherability, toughness, wearability, noise reduction, its comprehensive technical performance and economic indicator are far superior to other like product, especially the performance such as antibacterial, antistatic, fire-retardant, wear-resisting, heat-resisting, the noise reduction of the resistance oxygen of its brilliance, long service life, product has environmentally-friendly sanitary, energy-saving and cost-reducing and economic dispatch advantage.
The present invention is achieved in that and the invention provides a kind of elastomer alloy composite plate material, it is characterized in that this composite board adopts 3 layers of hot roll extrusion composite construction, above-mentioned three layers are respectively transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom.
In the present invention, polyvinyl chloride (PVC) resin, chliorinated polyvinyl chloride (CPVC) resin, ethylene-vinyl acetate copolymer (EVA), Vingon (PVDC), liquid calcium zinc complex stabilizer, cyclohexane 1 have been used in transparent elastic plastic alloy top layer, 2-dioctyl phthalate diisononyl esters (DINCH), phosphate flame retardant, concrete component and weight portion are:
In the present invention, decorative pattern rete comprises decorative pattern rete bed material, this decorative pattern rete bed material has been used polyvinyl chloride (PVC) resin, calcium-zinc composite stabilizing agent, silane coupler, cyclohexane 1,2-dioctyl phthalate diisononyl esters (DINCH), nano TiO 2, nano-calcium carbonate, flexibilizer, phosphate flame retardant, concrete component and weight portion are:
Elastic plastic bottom layer of the present invention has been used polyvinyl chloride (PVC) resin, calcium-zinc composite stabilizing agent, carbon fiber (CF), cyclohexane 1,2-dioctyl phthalate diisononyl esters (DINCH), haloflex (CPE), nano-calcium carbonate, phosphate flame retardant, concrete component and weight portion are:
The present invention has used polyvinyl chloride (PVC) resin, is the universal SG5 type of suspension method Corvic.
It is the low molecule organo-silicon compound that a class has special construction that the present invention has used silane coupler, and its general formula is RSiX3, and in formula, R representative and polymer molecule have the active function groups of affinity or respond,
In the present invention, decorative pattern rete comprises decorative pattern rete bed material, this decorative pattern rete bed material has been used polyvinyl chloride (PVC) resin, calcium-zinc composite stabilizing agent, silane coupler, cyclohexane 1,2-dioctyl phthalate diisononyl esters (DINCH), nano TiO 2, nano-calcium carbonate, flexibilizer, phosphate flame retardant, concrete component and weight portion are:
Elastic plastic bottom layer of the present invention has been used polyvinyl chloride (PVC) resin, calcium-zinc composite stabilizing agent, carbon fiber (CF), cyclohexane 1,2-dioctyl phthalate diisononyl esters (DINCH), haloflex (CPE), nano-calcium carbonate, phosphate flame retardant, concrete component and weight portion are:
The present invention has used polyvinyl chloride (PVC) resin, is the universal SG5 type of suspension method Corvic.
It is the low molecule organo-silicon compound that a class has special construction that the present invention has used silane coupler, its general formula is RS iX3, in formula, R representative and polymer molecule have the active function groups of affinity or respond, as oxygen base, sulfydryl, vinyl, epoxy radicals, amide groups, aminopropyl etc.; The alkoxyl that X representative can be hydrolyzed, as halogen, alkoxyl, acyloxy etc.Improve interface cementitiousness between formula each component, improve the bond strength of each layer.
The present invention has used carbon fiber, is that a kind of phosphorus content is at the tencel material of more than 95% high strength, high modulus fibre.After it will comprise that the organic fibers such as flake graphite crystallite are piled up along fiber axial direction, then through carbonization and graphitization processing and obtain.
The manufacture method of elastomer alloy composite plate material of the present invention is: after weighing according to each layer formula ratio, add together high-speed mixer to stir after 8-10 minute and add extruder to plasticate, calendering, cooling, batch and prepare respectively transparent elastic plastic alloy top layer, decorative pattern rete bed material, elastoplast bottom, decorative pattern rete bed material is prepared decorative pattern rete through printing, pressing order is up and down transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom is through the hot roll extrusion of hot roll extrusion unit, cooling, tempering, cooling, cutting preparation has the elastomer alloy composite plate material of space pattern.Extrusion temperature is: 170-190 ℃; Rolling temperature 150-170 ℃; Hot roll extrusion temperature 140-175 ℃; Temperature 110-150 ℃; When cooling, use water quench, wherein cooling water temperature≤40 ℃.
The invention has the beneficial effects as follows: relatively have with existing plastic plate that excellent mechanical performance, anti-wear performance, ageing resistace, good toughness, epistasis are high, antistatic, resistance oxygen is antibacterial, a long service life, energy-saving clean environmental protection.Can be widely used in: dalle and field, indoor and outdoor floor.
Accompanying drawing explanation
For content of the present invention is more likely to be clearly understood, below according to a particular embodiment of the invention and by reference to the accompanying drawings, the present invention is further detailed explanation, wherein
Fig. 1 is the structural representation of elastomer alloy composite plate material.
In figure: 1-transparent elastic plastic alloy top layer, 2-decorative pattern rete, 3-elastoplast bottom.
The specific embodiment
embodiment 1:
A kind of elastomer alloy composite plate material, it adopts 3 layers of hot roll extrusion composite construction, above-mentioned three layers are respectively transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom, wherein elastoplast alloy surface is filled a prescription: 100 parts of polyvinyl chloride (PVC) resins, 50 parts of chliorinated polyvinyl chloride (CPVC) 40 parts of ethylene-vinyl acetate copolymers of resin (EVA), 20 parts of Vingon (PVDC), 7 parts of liquid calcium zinc complex stabilizers, cyclohexane 1,30 parts of 2-dioctyl phthalate diisononyl esters (DINCH), 5 parts of phosphate flame retardants; Decorative pattern rete comprises decorative pattern rete bed material, this decorative pattern rete backing material formula: 100 parts of polyvinyl chloride (PVC) resins, 4 parts of calcium-zinc composite stabilizing agents, cyclohexane 1,20 parts of 2-dioctyl phthalate diisononyl esters (DINCH), 0.8 part of silane coupler, 4 parts of nano TiO 2s, 10 parts of nano-calcium carbonates, 5 parts of flexibilizer, 5 parts of phosphate flame retardants; Elastoplast bottom formula: 50 parts of polyvinyl chloride (PVC) resins, 30 parts of haloflexes (CPE), 2 parts of calcium-zinc composite stabilizing agents, cyclohexane 1,10 parts of 2-dioctyl phthalate diisononyl esters (DINCH), 5 parts, carbon fiber (CF), 30 parts of nano-calcium carbonates, 5 parts of phosphate flame retardants.By above-mentioned manufacture method, produce sheet material, after testing, surface resistivity 2.61 * 108 Ω, antibiotic rate 99.9%, heating size changing rate≤0.08%, abrasion resistance properties≤0.1g/100 turns, mar-proof performance >=2000g, limits of harmful substances meets standard GB/T/T18586.The advantages such as sheet material has that anti-aging weather resistance is excellent, quality is light, wear-resisting, pliability good, impact strength is high, good springiness, reduction noise, resistance oxygen are antibacterial, antistatic, fire-retardant, quick and easy for installation, energy-saving clean environmental protection, long service life.
embodiment 2:
A kind of elastomer alloy composite plate material, it adopts 3 layers of hot roll extrusion composite construction, above-mentioned three layers are respectively transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom, wherein fill a prescription in sheet material transparent elastic plastic alloy top layer: 100 parts of polyvinyl chloride (PVC) resins, 60 parts of chliorinated polyvinyl chloride (CPVC) 50 parts of ethylene-vinyl acetate copolymers of resin (EVA), 30 parts of Vingon (PVDC), 8 parts of liquid calcium zinc complex stabilizers, cyclohexane 1,50 parts of 2-dioctyl phthalate diisononyl esters (DINCH), 8 parts of phosphate flame retardants; Decorative pattern rete formula: 100 parts of polyvinyl chloride (PVC) resins, 6 parts of calcium-zinc composite stabilizing agents, cyclohexane 1,30 parts of 2-dioctyl phthalate diisononyl esters (DINCH), 1.6 parts of silane couplers, 6 parts of nano TiO 2s, 20 parts of nano-calcium carbonates, 8 parts of flexibilizer, 10 parts of phosphate flame retardants; Elastoplast bottom formula: 50 parts of polyvinyl chloride (PVC) resins, 50 parts of haloflexes (CPE), 3 parts of calcium-zinc composite stabilizing agents, cyclohexane 1,20 parts of 2-dioctyl phthalate diisononyl esters (DINCH), 10 parts, carbon fiber (CF), 50 parts of nano-calcium carbonates, 10 parts of phosphate flame retardants.By above-mentioned manufacture method, produce sheet material, after testing, surface resistivity 2.61 * 108 Ω, antibiotic rate 99.9%, heating size changing rate≤0.08%, abrasion resistance properties≤0.1g/100 turns, mar-proof performance >=2000g, limits of harmful substances meets standard GB/T/T18586.The advantages such as sheet material has that anti-aging weather resistance is excellent, quality is light, wear-resisting, pliability good, impact strength is high, good springiness, reduction noise, resistance oxygen are antibacterial, antistatic, fire-retardant, quick and easy for installation, energy-saving clean environmental protection, long service life.
embodiment 3:
A kind of manufacture method of elastomer alloy composite plate material is: after weighing according to the formula rate of each layer in embodiment 1 or 2, add together high-speed mixer to stir after 8-10 minute and add extruder to plasticate, calendering, cooling, batch and prepare respectively transparent elastic plastic alloy top layer, decorative pattern rete bed material, elastoplast bottom, decorative pattern rete bed material is prepared decorative pattern rete through printing, pressing order is up and down transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom is through the hot roll extrusion of hot roll extrusion unit, cooling, tempering, cooling, cutting preparation has the elastomer alloy composite plate material of space pattern, wherein extrusion temperature is: 170-190 ℃, rolling temperature 150-170 ℃, hot roll extrusion temperature 140-175 ℃, temperature 110-150 ℃, when cooling, use water quench, wherein cooling water temperature≤40 ℃.
Claims (3)
1. an elastomer alloy composite plate material, it comprises 3 layers of composite construction, is respectively transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom from top to bottom; It is characterized in that described transparent elastic plastic alloy top layer prescription quality part consists of:
Described decorative pattern rete prescription quality part consists of:
Described elastoplast bottom prescription quality part consists of:
2. a kind of elastomer alloy composite plate material according to claim 1, it is characterized in that: the phosphorus content in carbon fiber is more than 95%, it obtains through carbonization and graphitization processing after organic fiber that comprises flake graphite crystallite is piled up along fiber axial direction.
3. by the manufacture method of the described a kind of elastomer alloy composite plate material of one of claim 1-2, it is characterized in that: after weighing according to each layer formula ratio, add together high-speed mixer to stir after 8-10 minute and add extruder to plasticate, calendering, cooling, batch and prepare transparent elastic plastic alloy top layer, decorative pattern rete bed material, elastoplast bottom, decorative pattern rete bed material is prepared decorative pattern rete through printing, pressing order is up and down transparent elastic plastic alloy top layer, decorative pattern rete, elastoplast bottom is through the hot roll extrusion of hot roll extrusion unit, cooling, tempering, cooling, cutting preparation has the elastomer alloy composite plate material of space pattern, wherein extrusion temperature is: 170-190 ℃, rolling temperature 150-170 ℃, hot roll extrusion temperature 140-175 ℃, temperature 110-150 ℃, for cooling cooling water temperature≤40 ℃.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105113443A (en) * | 2015-09-07 | 2015-12-02 | 界首市鑫豪塑胶有限公司 | Plastic floor |
| CN105256967A (en) * | 2015-09-07 | 2016-01-20 | 界首市鑫豪塑胶有限公司 | Imitation marble decorative plate |
| CN105295256A (en) * | 2015-12-03 | 2016-02-03 | 江苏普奥新型装饰材料有限公司 | Novel PVC board and manufacturing method thereof |
| CN106243550A (en) * | 2016-07-28 | 2016-12-21 | 缪琼华 | A kind of inorganic material-modified polrvinyl chloride and preparation method thereof |
| CN106977836A (en) * | 2017-03-16 | 2017-07-25 | 浙江三和塑料有限公司 | A kind of PVC sheet alloys and preparation method thereof |
| CN109159522A (en) * | 2018-07-17 | 2019-01-08 | 江苏富华新型材料科技有限公司 | A kind of compound plastic plate and its manufacturing method |
| CN110303698A (en) * | 2019-05-29 | 2019-10-08 | 惠州伟康新型建材有限公司 | A kind of EPC composite-structure floor manufacture craft of high resistance to deformation lower shrinkage |
| CN114103304A (en) * | 2021-11-04 | 2022-03-01 | 安徽九牛塑业科技有限公司 | Anti-aging steel-plastic composite material and preparation method thereof |
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| US20010041256A1 (en) * | 1998-11-09 | 2001-11-15 | Heilmayr Peter F. | Composite panel |
| CN203373926U (en) * | 2013-05-02 | 2014-01-01 | 泰州市华丽塑料有限公司 | Antibacterial pvc composite wall panel |
| CN103628652A (en) * | 2013-11-06 | 2014-03-12 | 安徽圣源橡塑科技有限公司 | Functional co-extrusion composite alloy material floor-heating floor and manufacturing method thereof |
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| US20010041256A1 (en) * | 1998-11-09 | 2001-11-15 | Heilmayr Peter F. | Composite panel |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105113443A (en) * | 2015-09-07 | 2015-12-02 | 界首市鑫豪塑胶有限公司 | Plastic floor |
| CN105256967A (en) * | 2015-09-07 | 2016-01-20 | 界首市鑫豪塑胶有限公司 | Imitation marble decorative plate |
| CN105295256A (en) * | 2015-12-03 | 2016-02-03 | 江苏普奥新型装饰材料有限公司 | Novel PVC board and manufacturing method thereof |
| CN105295256B (en) * | 2015-12-03 | 2017-11-24 | 江苏普奥新型装饰材料有限公司 | A kind of PVC board and its manufacture method |
| CN106243550A (en) * | 2016-07-28 | 2016-12-21 | 缪琼华 | A kind of inorganic material-modified polrvinyl chloride and preparation method thereof |
| CN107459740A (en) * | 2016-07-28 | 2017-12-12 | 缪琼华 | A kind of inorganic material changes polyvinyl chloride and preparation method thereof |
| CN107522978A (en) * | 2016-07-28 | 2017-12-29 | 缪琼华 | A kind of modified inorganic material polyvinyl chloride and preparation method thereof |
| CN106977836A (en) * | 2017-03-16 | 2017-07-25 | 浙江三和塑料有限公司 | A kind of PVC sheet alloys and preparation method thereof |
| CN106977836B (en) * | 2017-03-16 | 2020-09-29 | 浙江三和塑料有限公司 | PVC alloy plate and manufacturing method thereof |
| CN109159522A (en) * | 2018-07-17 | 2019-01-08 | 江苏富华新型材料科技有限公司 | A kind of compound plastic plate and its manufacturing method |
| CN110303698A (en) * | 2019-05-29 | 2019-10-08 | 惠州伟康新型建材有限公司 | A kind of EPC composite-structure floor manufacture craft of high resistance to deformation lower shrinkage |
| CN114103304A (en) * | 2021-11-04 | 2022-03-01 | 安徽九牛塑业科技有限公司 | Anti-aging steel-plastic composite material and preparation method thereof |
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Application publication date: 20141001 |