CN110934783A

CN110934783A - Dandruff-removing and itching-relieving composition containing Chinese herbal medicines, silicone oil-free amino acid shampoo containing composition, and preparation method and application of silicone oil-free amino acid shampoo

Info

Publication number: CN110934783A
Application number: CN201811105989.7A
Authority: CN
Inventors: 王德友; 周立武; 王石; 方兆华; 刘敬文
Original assignee: Zhuhai Easycare Technology Co Ltd
Current assignee: Zhuhai Easycare Technology Co Ltd
Priority date: 2018-09-21
Filing date: 2018-09-21
Publication date: 2020-03-31
Anticipated expiration: 2038-09-21
Also published as: CN110934783B

Abstract

The invention discloses a dandruff-removing and itching-relieving composition containing Chinese herbal medicines, a silicone-oil-free amino acid shampoo containing the composition, and a preparation method and application thereof. The substances in the anti-dandruff and itching-relieving composition containing the Chinese herbal medicines can be matched with each other to realize synergistic interaction, so that a good anti-dandruff and itching-relieving effect is achieved, and the consumer demand on anti-dandruff and itching-relieving can be met. The silicone-free amino acid shampoo disclosed by the invention has no stimulation to hair and scalp, has good effects of softening hair, improving hair quality, removing dandruff and relieving itching, and can nourish scalp, improve microcirculation of scalp capillaries and achieve the effects of strengthening hair roots and reducing alopecia. The composition provided by the scheme of the invention can be widely applied to the preparation of hair cosmetics and medicines.

Description

Dandruff-removing and itching-relieving composition containing Chinese herbal medicines, silicone oil-free amino acid shampoo containing composition, and preparation method and application of silicone oil-free amino acid shampoo

Technical Field

The invention relates to the technical field of hair care products, in particular to an anti-dandruff and anti-itching composition containing Chinese herbal medicines, a silicone oil-free amino acid shampoo containing the composition, and a preparation method and application of the silicone oil-free amino acid shampoo.

Background

The shampoo is a hair care product with the functions of cleaning, repairing, removing dandruff, treating oil and the like. With the improvement of living standard, the rhythm of life of people is faster and faster, so the problems of irregular work and rest, high mental stress, frequent insomnia and the like are brought, people are more and more easily contacted with various chemical substances in daily life, and the health problem of hair also presents the trend of diversification and complication. The hair conditioner has the advantages that the hair conditioner is high in dandruff, itchy, alopecia, dry and yellow hair and white hair, and is the most common hair problems, and the hair problems are usually not single and are frequently in the phenomenon of complication of multiple hair problems. If not specifically treated by the appropriate method, these problems may occur periodically, recurrently or continuously, and may lead to hair follicle damage on the scalp and permanent hair loss when severe.

The traditional shampoo is added with a plurality of silicon compounds with high molecular weight and high viscosity, and the silicon compounds are attached to the surface of hair during hair washing and hair care to fill the gaps between hair scales to form a smooth film, thereby leading the hair to be soft and smooth. However, since silicone oil is insoluble in water, silicone wrapped on hair and scalp is not easy to be cleaned, and after long-term accumulation, hair becomes thick, hair weight becomes heavy, hair electrostatic action is reduced, hair gradually loses elasticity, and broken hair is generated. In addition, the organic silicon is insoluble in water and surfactant, is difficult to biodegrade after being discharged into the environment, and is very easy to cause environmental pollution.

At present, most of surfactants used in commercially available daily shampoos are sulfate type surfactants, used preservatives generally comprise methylisothiazolinone, methylchloroisothiazolinone, dimethylolhydantoin (2,4-Imidazolidinedione, DMDM hydantoin) and the like, and used anti-dandruff agents are mainly chemical anti-dandruff agents, which can cause great stimulation to scalp to cause inflammation, and the inflammation is a direct cause of itching and dandruff of the head. Therefore, the existing washing and caring products urgently need raw materials such as low-irritation surfactants, low-irritation preservatives and mild plant anti-dandruff agents to meet the market, and gradually develop towards amino acid type surfactants, natural preservatives, or preservatives and plant anti-dandruff agents without adding. When stimulus sources such as sulfate residues, chemical antidandruff agents, flavors and fragrances, chemical preservatives, metabolites of fungi, improper combing and improper hair care cause inflammation, bacterial colony imbalance and damage of scalp metabolic balance, once metabolism is increased or abnormal, excessive scalp cells are peeled off to become seedless and inanimate cuticles, and the scalp cells are peeled off to form dandruff. Maintaining the balance of the bacterial load of malassezia is critical to the treatment of dandruff and head itching.

Shampoo with the function of removing dandruff and relieving itching on the existing market mostly adopts one or two dandruff removing agents, most of the dandruff removing components are chemically synthesized, such as zinc pyrithione, piroctone olamine, clobazole, ketoconazole, hexamidine di (isethionate), selenium sulfide, 17-hydroxy-fold steroid dehydrogenase and the like, and the chemical substances can play a certain positive role, but have large irritation to scalp and side effects, and easily generate drug resistance after long-term use, so that the inhibition effect on malassezia is not ideal, the dandruff removing effect is poor, and particularly for oily hair with more dandruff, the aim of removing dandruff is more difficult to achieve.

Although some shampoos have been developed to be non-irritating, safe and healthy under the trend of gradually returning cosmetics to nature and mild and low irritation in recent years, some commercial products have strong irritation or harm due to the adoption of inferior raw materials or the inclusion of harmful substances, and are still not beneficial to the physiological health of hair, scalp and hair follicle. In conclusion, the shampoo in the prior art cannot meet the comprehensive requirements of modern people. In view of the above, the development of the mild and antiseptic type silicone oil-free amino acid shampoo containing the anti-dandruff and anti-itching composition containing natural Chinese herbal medicines has important significance.

Disclosure of Invention

The technical problem to be solved by the invention is as follows: provides an anti-dandruff and anti-itching composition containing Chinese herbal medicines, which is mild and is beneficial to the physiological health of hair, scalp and hair follicle, a silicone oil-free amino acid shampoo containing the composition, and a preparation method and application thereof.

In order to solve the technical problems, the invention adopts the technical scheme that: a dandruff-removing and itching-relieving composition containing Chinese herbal medicines at least comprises Abies balsamea extract.

The invention has the beneficial effects that: the scheme of the invention adopts fir balsam (ABIES BALSAMA) extract, can be used as a sedative, has the effects of resisting bacteria and diminishing inflammation, is a traditional herbal medicine for relieving respiratory tract infection and inflammation, can prevent and treat halitosis and canker sore, is skillfully applied to the field of hair cosmetics or medicines, and has great creativity. Aiming at the causes of dandruff and head itching, the dandruff removing and itching relieving composition provided by the scheme of the invention applies the traditional Chinese medicine theory, promotes blood circulation on internal causes, improves the activity of scalp cells, regulates the metabolism of the scalp cells, improves the microenvironment of the scalp cells, prolongs the life cycle of the scalp cells, and fundamentally reduces the generation of dandruff and head itching; the external cause radically blocks the external channel of dandruff by killing and inhibiting fungi, resisting the oxidation of fatty acid and decomposing peroxide affecting dandruff generation, thereby effectively radically treating dandruff and relieving scalp itching, and the dandruff removing effect is durable and effective. The scheme of the invention is mild and non-irritant, and can effectively avoid the adverse effect of snowflake-shaped dandruff caused by excessive degreasing and scalp dryness caused by temporary removal of dandruff in an appearance manner by a degreasing mode in the traditional technology.

Further, the anti-dandruff and antipruritic composition containing Chinese herbal medicines further comprises one or more of radix Sophorae Flavescentis (Sophora Angustifolia) root extract, Dictamnus Dasycarpus (Dictamnus Dasycarpus) root extract, Salvia Miltiorrhiza (Salvia miltiorrhizae) root extract, and dipotassium glycyrrhizinate.

The invention also has the following beneficial effects: the five plant extracts of fir balsam, radix sophorae flavescentis, dictamnus dasycarpus, salvia miltiorrhiza and liquorice are reasonably mixed, and mutual synergistic effect among the extracts is ingeniously utilized, so that the tea has the effects of enriching and activating blood, dispelling wind and removing dampness, sterilizing and relieving itching, removing dandruff and the like. The composition in the scheme of the invention contains various natural nutrients and moisturizing components, has no stimulation, toxicity or sensitization on scalp, can provide moisturizing and moisturizing effects for scalp, has conditioning effects of nutrition, smoothness and the like on hair, and does not damage scalp, and does not cause phenomena of alopecia and hair breakage in actual use.

Further, in the composition, the mass percent of the balsam fir extract is 0.1-20%; if yes, the mass percentage of the sophora flavescens root extract is 0.1-40%; if yes, the mass percent of the dittany root extract is 0.1-20%; if the salvia miltiorrhiza root extract exists, the mass percentage of the salvia miltiorrhiza root extract is 0.1-20%; if yes, the weight percentage of the dipotassium glycyrrhizinate is 0.1-20%.

Preferably, in the composition, the mass percentage of the balsam fir extract is 15-20%; if yes, the mass percentage of the sophora flavescens root extract is 20-30%; if yes, the mass percentage of the dictamnus dasycarpus root extract is 10-20%; if yes, the mass percentage of the salvia miltiorrhiza root extract is 10-20%; if yes, the mass percentage of the dipotassium glycyrrhizinate is 5-15%.

The invention also comprises the application of the composition in the preparation of hair washing and/or hair care cosmetics or anti-dandruff and anti-itching medicaments.

The invention has the beneficial effects that: the composition can be widely applied to hair cosmetics such as shampoo, paste shampoo, hair conditioner and the like, and can also be applied to anti-dandruff and anti-itching medicaments.

The invention also comprises silicone oil-free amino acid shampoo containing the composition.

Further, the weight percentage of the composition in the silicone-oil-free amino acid shampoo is 0.05-10%.

Further, the silicone oil-free amino acid shampoo also comprises auxiliary materials and water.

Further, the auxiliary materials comprise one or more of the following components: conditioning agent, chelating agent, surfactant, ester-forming agent, thickening agent, essence, preservative and pH regulator.

Further, if the conditioner exists, the weight percentage content of the conditioner is 0.05-5%; if so, the chelating agent accounts for 0.05-0.3 wt%; if yes, the weight percentage of the surfactant is 15-45%; if so, the weight percentage content of the humectant is 0.1-10%; if yes, the weight percentage content of the ester forming agent is 0.1-10%; if so, the weight percentage content of the thickening agent is 0.05-5%; the essence accounts for 0-1% by weight; if so, the weight percentage content of the preservative is 0.05-5%; if yes, the weight percentage of the pH regulator is 0.01-1%.

Preferably, the conditioning agent comprises polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-37, polyquaternium-47, polyquaternium-67, polyquaternium-74, guar hydroxypropyltrimethylammonium chloride, hydroxypropyl guar hydroxypropyltrimethylammonium chloride, hydroxypropyltrimethylammonium chloride hydrolyzed wheat protein, hydroxypropyltrimethylammonium chloride hydrolyzed keratin, hydroxypropyltrimethylammonium chloride hyaluronic acid, polyglycerol-10 laurate, stearamidopropyl dimethylamine, hydroxypropyl oxidized starch PG-trimethylammonium chloride, palmitamidopropyl trimethylammonium chloride, behenyltrimethylammonium chloride, quaternary ammonium salt-18, quaternary ammonium salt-91, lauryl dimethylammonium hydroxypropylhydrolyzed wheat protein, acrylamidopropyl trimethylammonium chloride/acrylamide copolymer, At least one of cocamidopropyl PG-dimethyl ammonium chloride phosphate.

Preferably, the chelating agent comprises at least one of ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetate, tetrasodium ethylenediaminetetraacetate, trisodium ethylenediaminedisuccinate.

Preferably, the surfactant comprises at least one of sodium lauroyl sarcosinate, cocamidopropyl hydroxysultaine, lauroyl aminopropylbetaine, sodium methylcocoyl taurate, disodium lauryl sulfosuccinate, potassium cocoyl glycinate, sodium lauroyl glutamate, sodium lauroyl amphoacetate, cocoyl glucoside, sodium lauroyl avenamide, sodium cocoyl glycinate, Cocamide-ethanolamine (CMEA), sodium cocoyl isethionate, sodium C14-C16 olefin sulfonate.

Preferably, the humectant comprises at least one of butylene glycol, glycerol, sorbitol, betaine, glycerol glucoside, trehalose, Sodium hyaluronate, fructose, β -dextran, polyamino acid polysaccharide condensate, methyl gluceth-20, Sodium pyrrolidone carboxylate (PCA-Na), allantoin, panthenol, ceramide, bioglycan gum, hydrolyzed keratin, lysine, histidine, arginine, aspartic acid, threonine, serine, glutamic acid, proline, glycine, alanine, valine, isoleucine, leucine, tyrosine, phenylalanine, silk amino acids, polyglutamic acid, hydrolyzed yeast protein, PPG-2-butanol polyether-2.

Preferably, the ester-forming agent comprises at least one of Polyethylene Glycol (PEG-7) glyceryl cocoate, PEG-6 caprylic/capric glycerides, PPG-3 octyl ether, jojoba wax PEG-120 esters, PEG-75 lanolin, C12-13 alcohol lactate, phytosterin macadamia oleate, glyceryl oleate, phytosterol/octyldodecanol lauroyl glutamate, tocopherol (vitamin E), PPG-3 myristyl ether, horse fat, squalane, oleyl polyether-5 phosphate, C12-15 alkanol polyether-10 phosphate.

Preferably, the thickener comprises at least one of PEG-120 methyl glucose dioleate, PEG-150 distearate, PEG-150 pentaerythritol tetrastearate, hydroxypropyl methylcellulose, sodium chloride, xanthan gum, carbomer, acrylic acid (or ester) copolymer, cocamide methyl MEA.

Preferably, the preservative comprises at least one of potassium sorbate, ethylhexylglycerin, 1, 2-pentanediol, 1, 2-hexanediol, caprylyl glycol, gluconolactone, p-hydroxyacetophenone, caprylhydroxamic acid, phenoxyethanol, sodium benzoate, methylchloroisothiazolinone, methylisothiazolinone, DMDM hydantoin.

Preferably, the pH adjusting agent comprises at least one of lactic acid, citric acid, sodium lactate, sodium citrate, sodium hydroxide, potassium hydroxide, aminomethyl propanol, triethanolamine, arginine.

The invention has the beneficial effects that: the shampoo without silicone oil and amino acid has the advantages of being mild, safe, efficient, free of side effects and the like due to the fact that the anti-dandruff and anti-itching composition is remarkable in anti-dandruff and anti-itching effect and free of irritation to scalp. According to the silicone oil-free amino acid shampoo, the anti-dandruff and itching-relieving composition containing the Chinese herbal medicines is added, the mild amino acid type surfactant is selected, the skin moistening grease similar to sebum is adopted to replace the traditional silicone oil, and the low-irritation preservative and other high-quality raw materials are used in a matching manner, so that the overall mildness of the shampoo is improved, the irritation to the scalp is reduced, the safety is improved, and the shampoo can be used by infants and pregnant women without worry. According to the scheme of the invention, the shampoo without silicone oil and amino acid can effectively and deeply clean scalp, nourish scalp and hair, simultaneously strengthen hair roots and reduce alopecia, has good dandruff removing effect, and can keep hair fresh, elegant, smooth and glossy for a long time.

The invention also comprises a preparation method of the silicone oil-free amino acid shampoo, the preparation raw materials of the silicone oil-free amino acid shampoo comprise the composition, auxiliary materials and water, and the auxiliary materials comprise: conditioning agent, chelating agent, surfactant, excipient, thickener, perfume, preservative and pH adjuster, the method comprising the steps of:

s1, adding water and a conditioner, stirring uniformly, starting heating, adding a chelating agent and a surfactant, heating to 80-85 ℃, stopping heating, stirring uniformly, and cooling;

s2, cooling to 65-75 ℃, adding a thickening agent and an ester forming agent, keeping the temperature, stirring uniformly, and then continuously cooling;

s3, cooling to 40-45 ℃, adding the humectant, the anti-dandruff and anti-itching composition, the pH regulator, the essence and the preservative, and uniformly stirring to obtain the silicone oil-free amino acid shampoo.

Preferably, in the step S1, the stirring before heating is performed for 3 to 8min, more preferably 5min at 5 to 20Hz (preferably 15 Hz).

Preferably, in the step S1, the stirring before cooling is performed at 5 to 25Hz (preferably 15Hz) for 5 to 20min, and more preferably 10 min.

Preferably, in the step S2, the stirring at the constant temperature is performed at 5 to 20Hz (preferably 15Hz) for 10 to 25min, and more preferably 15 min.

Preferably, in the step S3, the stirring operation is to stir at 5 to 20Hz (preferably 10Hz) for 5 to 30min, and more preferably 15 min.

The invention has the beneficial effects that: the preparation method is simple, the operation is simple and convenient, the adding sequence and the process parameters of the components in the auxiliary materials are reasonably controlled, the dandruff removing and itching relieving composition is added at a lower temperature, the active ingredients in the dandruff removing and itching relieving composition are prevented from being damaged, and the prepared shampoo can effectively sterilize and relieve itching, balance grease, effectively remove dandruff, prevent alopecia and nourish hair.

Drawings

FIG. 1 is a diagram of the result of the Malassezia bacteriostasis experiment of the embodiment of the present invention.

Detailed Description

In order to explain technical contents, achieved objects, and effects of the present invention in detail, the following description is made with reference to the accompanying drawings in combination with the embodiments.

In the invention, the fir balsam (ABIES BALSAMA) extract can be used as a sedative, has the effects of resisting bacteria and diminishing inflammation, is a traditional herbal medicine for relieving respiratory tract infection and inflammation, and can prevent and treat halitosis and oral ulcer.

Radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) extract mainly contains multiple alkaloids, such as matrine and oxymatrine, and very few bispidines; the majority of flavonoids are flavanone and flavanonol, and the minority of flavonoids are flavone, chalcone and alcohol thereof, wherein only 3 are glycosides; the volatile oil component contains eicosane as main component, olefin as main component, alkane and alcohol as secondary component, and acid, aldehyde, ketone, phenol, etc. as well as fatty acid and unsaturated fatty acid as main component. Radix Sophorae Flavescentis is cold in nature, has effects of clearing heat, eliminating dampness, killing parasite, relieving itching, relieving skin pruritus, and resisting allergy, and can reduce release of allergic medium, and be used as immunosuppressant. The skin care product has the advantages of balancing grease secretion, dredging and astringing pores, removing toxin impurities in skin, enriching herbal nutrition, promoting the growth and repair of damaged vascular nerve cells, recovering the activity of subcutaneous capillary cells, enabling the skin to be compact and smooth, and playing a role in beautifying and protecting the skin.

The extract of Dictamnus DASYCARPUS root has antibacterial, antiinflammatory, antiallergic, antiulcer, parasite killing, coronary atherosclerosis resisting, antitumor, anticancer, liver and nerve protecting, and can be used for treating skin desquamation, rheumatic arthritis, external hemorrhage, urticaria, etc. The chemical components separated and identified from Dictamnus DASYCARPUS root extract mainly include limonoids, alkaloids, flavonoids, lactones, sesquiterpenes and glycosides thereof, wherein limonoids and alkaloids are effective substances. It has inhibitory effect on dermatophytes such as Trichophyton violaceum, Trichophyton schoenleinii, Microsporum ferrugineum, and Epidermophyton rubrum.

Radix Salviae Miltiorrhizae (Salvia Miltiorrhiza) root extract has effects of promoting scalp microcirculation, increasing capillary network opening amount, and accelerating blood flow velocity and flow, so as to improve microcirculation disturbance; has the pharmacological activities of promoting blood circulation, removing blood stasis, diminishing inflammation, resisting virus, resisting ulcer and oxidation, promoting tissue repair and regeneration, protecting liver cells, preventing hepatic fibrosis, liver cirrhosis and the like, and has wide application prospect. The fat-soluble active ingredients of the salvia miltiorrhiza are total tanshinone such as tanshinone, tanshinone IIA, tanshinone IIB and the like, have definite antibacterial action, have very strong inhibiting action on staphylococcus aureus and other drug-resistant strains, have broad-spectrum antibacterial effect, and have the functions of killing bacteria and inhibiting mold; tanshinone IIA is an effective inhibitor for the interaction between intracellular lipid peroxidation products and DNA, achieves the aim of reducing the cytotoxicity of DNA addition products by eliminating the action of lipid free radicals, and can eliminate the lipid free radicals generated in the process of myocardial mitochondrial membrane self-mass peroxidation so as to enable the respiratory function of mitochondria not to be influenced. The water soluble effective components of Saviae Miltiorrhizae radix mainly comprise phenolic acids including protocatechuic aldehyde, caffeic acid, methyl rosmarinate, monophenolic acid A, rosmarinic acid, monophenolic acids C and B, and tanshinol. The functional indications of the fat-soluble active ingredient and the water-soluble active ingredient are consistent. The red sage root plays a role in internally regulating immune response mainly through the action on various cytokines, antibodies, immune complexes and immune cells, and the action has bidirectionality.

Dipotassium glycyrrhizinate is a classic anti-inflammatory raw material and has the effects of resisting inflammation and allergy, inhibiting bacterial reproduction and the like. Can regulate skin immunity, enhance skin disease resistance, eliminate inflammation, prevent allergy, and relieve adverse side effects of cosmetics and other external factors on skin.

According to the scheme of the invention, the five substances exert synergistic effects, so that the composition has extremely strong antibacterial and bactericidal effects, and the plant extract has no stimulation to scalp, and simultaneously has a good moisturizing effect, and can obtain a good anti-dandruff effect.

The embodiment 1 of the invention relates to an anti-dandruff and anti-itching composition containing Chinese herbal medicines and a silicone-oil-free amino acid shampoo containing the composition, wherein the anti-dandruff and anti-itching composition comprises the following components in percentage by weight: 10% of fir balsam (ABIESBALSAMEA) extract, 25% of radix Sophorae Flavescentis (SOPHORA ANGUSTIFOLIA) root extract, 12.5% of cortex Dictamni (DICTAMNUSDASYCARPUS) root extract, 12.5% of radix Salviae Miltiorrhizae (SALVIA MILTIORRHIZA) root extract, 10% of dipotassium glycyrrhizinate, and the balance of water.

The silicone-oil-free amino acid shampoo comprises 1% of the anti-dandruff and itching-relieving composition containing the Chinese herbal medicines and the following auxiliary materials in percentage by weight: 1.5% of conditioner, 0.2% of chelating agent, 35% of surfactant, 1% of humectant, 5% of ester-forming agent, 3% of thickening agent, 0.5% (daily-use) essence, 1% of preservative, 0.3% of pH regulator and the balance of water.

Wherein the conditioner is polyquaternium-6;

the chelating agent is EDTA-2 Na;

the surfactant is sodium lauroyl sarcosinate (15%), cocamidopropyl hydroxysultaine (15%), sodium methyl cocoyl taurate (5%);

the humectant is glycerin;

the ester-forming agent is PEG-7 glycerol cocoate;

the thickening agent is PEG-120 methyl glucose dioleate;

the (daily) essence is an essence for cosmetics;

the preservative is p-hydroxyacetophenone and 1, 2-hexanediol, and preferably the preservative is 0.5% of p-hydroxyacetophenone and 0.5% of 1, 2-hexanediol;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo is prepared by the following method:

1) putting water into a main boiler, adding polyquaternium-6, starting stirring (15HZ) for about 5min to disperse uniformly, starting heating, adding EDTA-2Na, adding sodium lauroyl sarcosinate, cocamidopropyl hydroxysultaine and sodium methyl cocoyl taurate, heating to 80-85 ℃, stopping heating, starting stirring (15HZ) for about 10min to dissolve uniformly, and starting cooling water to circularly cool under stirring (15 Hz);

2) cooling to 65-75 ℃, adding PEG-7 glyceryl cocoate and PEG-120 methyl glucose dioleate, stirring at the temperature of 15Hz for 15min, and continuously starting cooling water circulation to cool under stirring at the temperature of 15 Hz;

3) cooling to 40-45 ℃, adding glycerol, the anti-dandruff and anti-itching composition, citric acid, (daily) essence, p-hydroxyacetophenone and 1, 2-hexanediol, stirring (10HZ) for about 15min, and uniformly mixing to obtain the silicone-oil-free amino acid shampoo.

The second embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 10% fir balsam (ABIES BALSAMA) extract, 25% radix Sophorae Flavescentis (SOPHORAANGUSTIFOLIA) root extract, 12.5% cortex Dictamni (DICTAMNUS DASYCARPUS) root extract, 12.5% radix Salviae Miltiorrhizae (SALVIA MILTIORRHIZA) root extract, 10% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 5 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 0.05% of conditioner, 0.05% of chelating agent, 25% of surfactant, 10% of humectant, 0.5% of excipient, 3% of thickening agent, 0.1% (daily-use) essence, 0.05% of preservative, 0.2% of pH regulator and the balance of water.

Wherein the conditioner is polyquaternium-10;

the chelating agent is tetrasodium ethylene diamine tetraacetate;

the surfactant is cocamidopropyl hydroxysultaine (16%), sodium methyl cocoyl taurate (9%);

the humectant is betaine;

the ester-forming agent is PEG-7 glycerol cocoate;

the thickener is cocamide methyl MEA;

the (daily) essence is an essence for cosmetics;

the preservative is cason (wherein, the content of the methyl chloroisothiazolinone, methyl isothiazolinone, 3:1, the activity thereof is 1.5%);

the pH regulator is lactic acid.

The silicone oil-free amino acid shampoo of example 2 was prepared in the same manner as in example 1.

The third embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 5% fir balsam (ABIES BALSAMA) extract, 25% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 12.5% Dictamnus DASYCARPUS (DICTAMNUS DASYCARPUS) root extract, 12.5% Saviae Miltiorrhizae radix (SALVIA MILTIORRHIZA) root extract, 15% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 6 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 5% of conditioner, 0.1% of chelating agent, 15% of surfactant, 1% of humectant, 0.1% of ester-forming agent, 5% of thickening agent, 0.05% (daily-use) essence, 0.4% of preservative, 0.1% of pH regulator and the balance of water.

Wherein the conditioner is lauryl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein;

the chelating agent is trisodium ethylenediamine disuccinate;

the surfactant is sodium cocoyl isethionate (6%) and sodium methyl cocoyl taurate (9%);

the humectant is sodium PCA;

the ester excipient is PEG-6 caprylic/capric glycerides;

the thickener is cocamide methyl MEA;

the (daily) essence is an essence for cosmetics;

the preservative is DMDM hydantoin;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo of example 3 was prepared in the same manner as in example 1.

The fourth embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 20% fir balsam (ABIES BALSAMA) extract, 20% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 12.5% Dictamnus DASYCARPUS (DICTAMNUS DASYCARPUS) root extract, 12.5% Saviae Miltiorrhizae radix (SALVIA MILTIORRHIZA) root extract, 5% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 6 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 3% of conditioner, 0.3% of chelating agent, 45% of surfactant, 5% of humectant, 10% of excipient, 0.05% of thickening agent, 1% (daily essence), 5% of preservative, 0.1% of pH regulator and the balance of water.

Wherein the conditioner is polyquaternium-7 and polyglycerol-10 laurate;

the chelating agent is trisodium ethylenediamine disuccinate;

the surfactant is sodium cocoyl isethionate (2%), sodium C14-16 olefin sulfonate (20%), potassium cocoyl glycinate (8%), sodium lauroamphoacetate (3%), cocoamidopropyl hydroxysultaine (12%);

the humectant is sorbitol (3%) and polyamino acid polysaccharide condensate (2%);

the ester-forming agent is PEG-7 glyceryl cocoate (6%) and C12-13 alcohol lactate (4%);

the thickening agent is hydroxypropyl methyl cellulose;

the (daily) essence is an essence for cosmetics;

the preservative is 1, 2-pentanediol (4%) and p-hydroxyacetophenone (1%);

the pH regulator is sodium lactate.

The silicone oil-free amino acid shampoo of example 4 was prepared in the same manner as in example 1.

The fifth embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 10% fir balsam (ABIES BALSAMA) extract, 25% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 20% Dictamnus DASYCARPUS (Dictamnus DASYCARPUS) root extract, 5% radix Salviae Miltiorrhizae (Salvia MILTIORRHIZA) root extract, 10% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 6 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 1.5% of conditioner, 0.2% of chelating agent, 35% of surfactant, 1% of humectant, 5% of ester-forming agent, 3% of thickening agent, 1% (daily-use) essence, 0.8% of preservative, 0.3% of pH regulator and the balance of water.

Wherein the conditioner is polyquaternium-7 (1.2 percent), hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride (0.3 percent);

the chelating agent is EDTA-2 Na;

the surfactant is sodium lauroyl sarcosinate (5%), cocamidopropyl hydroxysultaine (15%), sodium methyl cocoyl taurate (10%), sodium lauroamphoacetate (5%);

the humectant is glycerol glucoside;

the ester forming agent is PEG-7 glyceryl cocoate (3%) and Hojoba wax PEG-120 esters (2%);

the thickening agent is PEG-150 pentaerythritol tetrastearate;

the (daily) essence is an essence for cosmetics;

the preservative is phenoxyethanol;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo of example 5 was prepared in the same manner as in example 1.

The sixth embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 10% fir balsam (ABIES BALSAMA) extract, 25% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 5% Dictamnus DASYCARPUS (Dictamnus DASYCARPUS) root extract, 20% radix Salviae Miltiorrhizae (SALVIA MILTIORRHIZA) root extract, 10% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 7 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 1.5% of conditioner, 0.2% of chelating agent, 35% of surfactant, 1% of humectant, 5% of ester-forming agent, 3% of thickening agent, 1% (daily-use) essence, 0.5% of preservative, 0.4% of pH regulator and the balance of water.

Wherein the conditioner is polyquaternium-7 and hydroxypropyl trimethyl ammonium chloride hyaluronic acid (0.1%);

the chelating agent is tetrasodium ethylene diamine tetraacetate;

the surfactant is sodium lauroyl sarcosinate (15%), cocamidopropyl hydroxysultaine (15%), sodium lauroyl avenantamino acid (3%), potassium cocoyl glycinate (2%);

the humectant is silk amino acids;

the excipient is glyceryl oleate;

the thickening agent is acrylic acid (ester) copolymer;

the (daily) essence is an essence for cosmetics;

the preservative is potassium sorbate and phenoxyethanol;

the pH regulator is aminomethyl propanol.

The silicone oil-free amino acid shampoo of example 6 was prepared in the same manner as in example 1.

The seventh embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 10% fir balsam (ABIES BALSAMA) extract, 15% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 17.5% Dictamnus DASYCARPUS (DICTAMNUS DASYCARPUS) root extract, 17.5% Saviae Miltiorrhizae radix (SALVIA MILTIORRHIZA) root extract, 10% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 8 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 1% of conditioner, 0.1% of chelating agent, 40% of surfactant, 2% of humectant, 2% of excipient, 1.5% of thickening agent, 0.5% (daily-use) essence, 0.5% of preservative, 0.2% of pH regulator and the balance of water.

Wherein the conditioner is hydrolyzed wheat protein of hydroxypropyl trimethyl ammonium chloride;

the chelating agent is disodium ethylene diamine tetraacetate;

the surfactant is sodium lauroyl sarcosinate (15%), cocamidopropyl hydroxysultaine (15%), disodium lauryl sulfosuccinate (5%), sodium methyl cocoyl taurate (5%);

the humectant is sorbitol;

the ester excipient is PEG-6 caprylic/capric glycerides;

the thickening agent is PEG-150 distearate;

the (daily) essence is an essence for cosmetics;

the preservative is caprylyl hydroximic acid;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo of example 7 was prepared in the same manner as in example 1.

The eighth embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 5% fir balsam (ABIES BALSAMA) extract, 15% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 10% cortex Dictamni (DICTAMNUS DASYCARPUS) root extract, 10% radix Salviae Miltiorrhizae (SALVIA MILTIORRHIZA) root extract, 5% dipotassium glycyrrhizinate, and balance water.

The silicone-oil-free amino acid shampoo comprises 10 percent of the anti-dandruff and anti-itching composition containing the Chinese herbal medicines and the following components in percentage by weight: 4% of conditioner, 0.15% of chelating agent, 20% of surfactant, 3% of humectant, 1% of excipient, 1% of thickener, 0.3% (daily use) essence, 0.4% of preservative, 0.1% of pH regulator and the balance of water.

Wherein the conditioner is hydrolyzed keratin of hydroxypropyl trimethyl ammonium chloride;

the chelating agent is disodium ethylene diamine tetraacetate;

the surfactant is sodium cocoyl isethionate (3%), cocamidopropyl hydroxysultaine (12%), sodium methyl cocoyl taurate (5%);

the humectant is hydrolyzed yeast protein;

the ester-forming agent is jojoba wax PEG-120 esters;

the thickener is cocamide methyl MEA;

the (daily) essence is an essence for cosmetics;

the preservative is DMDM hydantoin;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo of example 8 was prepared in the same manner as in example 1.

The ninth embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 0.1% fir balsam (ABIES BALSAMA) extract, 15% radix Sophorae Flavescentis (SOPHORA ANGTIFOLIA) root extract, 10% Dictamnus DASYCARPUS (DICTAMNUS DASYCARPUS) root extract, 10% Saviae Miltiorrhizae radix (SALVIA MILTIORRHIZA) root extract, 5% dipotassium glycyrrhizinate, and balance water.

the chelating agent is disodium ethylene diamine tetraacetate;

the humectant is hydrolyzed yeast protein;

the ester-forming agent is jojoba wax PEG-120 esters;

the thickener is cocamide methyl MEA;

the (daily) essence is an essence for cosmetics;

the preservative is DMDM hydantoin;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo of example 9 was prepared in the same manner as in example 1.

Test example 1

The silicone oil-free amino acid shampoo prepared in the examples 1 to 9 is selected for physical and chemical detection, and the obtained detection indexes are as follows.

1. Trait detection

The silicone oil-free amino acid shampoo of examples 1 to 9 is a yellowish to yellow transparent liquid, and has good high and low temperature stability and fragrant smell.

2. pH value detection

The silicone oil-free amino acid shampoo obtained in the embodiments 1 to 9 is sampled, and the pH value of the silicone oil-free amino acid shampoo is measured to be 5.5 to 6.5 according to the measurement of the pH value by the general test method for cosmetics of GBT 13531.1-2008, so that the international requirement is met.

3. Viscosity number detection

According to the viscosity test method of GB-T10247-.

4. Stability detection

Sampling the silicone oil-free amino acid shampoo obtained in the embodiments 1 to 9, packaging the silicone oil-free amino acid shampoo in a transparent cosmetic bottle according to the national standard of GBT 34857-.

5. Centrifugal assay

Sampling the silicone oil-free amino acid shampoo obtained in the embodiments 1 to 9, packaging the shampoo in a centrifugal tube, centrifuging the shampoo at 3000r/min for 30min, and observing whether non-dispersible components appear or not, wherein the detection result shows that the non-dispersible components do not appear, which indicates that the mixture property is good.

6. Stimulus hypersensitivity detection

The shampoo without silicone oil and amino acid in the examples 1-9 is sampled, a proper amount of the shampoo is applied to the backs of hands of volunteers (18-60 years old, 100 people) to observe for 30min, and whether the phenomena of redness, swelling, eruption, blistering and the like appear or not is judged, and the observation result shows that adverse symptoms do not appear in all testers within 30min, which indicates that the shampoo without silicone oil and amino acid is mild and does not cause irritation and anaphylaxis problems to the skin.

7. Malassezia bacteriostasis experimental test

Carrying out malassezia bacteriostasis experiment tests on the anti-dandruff and itching-relieving composition containing the Chinese herbal medicines, which corresponds to the embodiments 1-9;

selecting 0.5% cason water solution as positive control, and measuring the diameter of the inhibition zone to be 19 mm;

deionized water is selected as a negative control, and the diameter of the inhibition zone is measured to be 0 mm;

the anti-dandruff and anti-itching compositions corresponding to examples 1 to 9 are respectively marked as A to I, the aqueous solution of 50% balsam fir extract is marked as J, the bacteriostatic experiment result of malassezia is shown in figure 1, and the diameter information of each colony is as follows:

the diameter of the inhibition zone of A is measured to be 16.4 mm;

the diameter of the inhibition zone of B is measured to be 16.4 mm;

measuring the diameter of the inhibition zone of C to be 15 mm;

d, measuring the diameter of the inhibition zone to be 16 mm;

e, measuring the diameter of the inhibition zone to be 14 mm;

measuring the diameter of the inhibition zone of F to be 14 mm;

measuring the diameter of the inhibition zone of G to be 13 mm;

measuring the diameter of the inhibition zone of H to be 12 mm;

measuring the diameter of the inhibition zone of I to be 9 mm;

the diameter of the inhibition zone of J is measured to be 8.5 mm.

The diameters of the inhibition zones of the experimental results are arranged according to the size: a ═ B > D > C > E ═ F > G > H > I > J

The nine (0.1% balsam fir extract) and the eight (5% balsam fir extract) in the embodiment of the invention are only different in the dosage of the balsam fir (ABIES BALSAMA) extract, but the diameter difference of the inhibition zones forms a dominant difference, which proves that the balsam fir extract has good antibacterial effect and can synergistically inhibit bacteria.

8. Detection of dandruff-removing and itching-relieving effects of silicone oil-free amino acid shampoo

The silicone oil-free amino acid shampoo of examples 1-9 was comprehensively evaluated by asking volunteers to try the product and fill in a test table by adopting a civil investigation and grading method. Volunteers (30 persons in the age range of 18-40 years and 30 persons in the age range of 40-60 years) in different age groups are respectively selected as trial objects, the shampoo is used for washing hair once every two days and is continuously used for two months, a test table is filled for evaluation after trial, and the shampoo prepared by the scheme of the embodiment 1-9 is randomly selected by the volunteers. The evaluation standard of the dandruff removing and itching relieving effect is as follows:

and (3) relieving: after 1-2 months of use, the dandruff is obviously reduced, the scalp is not pruritus any more, and the abnormal alopecia is eliminated.

Obviously improve the following steps: after 1-2 months of use, dandruff is reduced, interval time of scalp itching is prolonged and relieved, and abnormal alopecia is reduced.

And (4) invalidation: neither dandruff nor itching was improved.

The above 60 volunteers were recorded and reviewed, and the specific therapeutic results are shown in table 1 below:

TABLE 1 statistical Table of return visit results

As can be seen from the test results of table 1: after the shampoo without silicone oil and amino acid in the embodiments 1 to 9 is used, the effects of removing dandruff and relieving itching are 100% effective, and no irritation exists, which shows that the shampoo without silicone oil and amino acid in the invention has good effects of removing dandruff and relieving itching.

The tenth embodiment of the invention is as follows: the anti-dandruff and anti-itching composition containing the Chinese herbal medicines comprises the following components in percentage by weight: 20% fir balsam (ABIES BALSAMA) extract, and water in balance.

the chelating agent is disodium ethylene diamine tetraacetate;

the humectant is hydrolyzed yeast protein;

the ester-forming agent is jojoba wax PEG-120 esters;

the thickener is cocamide methyl MEA;

the (daily) essence is an essence for cosmetics;

the preservative is DMDM hydantoin;

the pH regulator is citric acid.

The silicone oil-free amino acid shampoo prepared in the example ten has good itching relieving and dandruff removing effects after use.

It should be noted that the composition or the anti-dandruff and anti-itching composition referred to in the scheme of the invention is a short name for the anti-dandruff and anti-itching composition containing Chinese herbal medicines.

In conclusion, the anti-dandruff and anti-itching composition containing the Chinese herbal medicines, the silicone-oil-free amino acid shampoo containing the composition, and the preparation method and the application of the silicone-oil-free amino acid shampoo provided by the invention have the advantages that the composition can effectively improve the problem of dandruff and itching, all substances in the anti-dandruff and anti-itching composition can be matched with each other to realize a good anti-dandruff and anti-itching effect, and the demands of consumers on anti-dandruff and anti-itching can be met. The silicone-free amino acid shampoo disclosed by the invention has no stimulation to hair and scalp, has good effects of softening hair, improving hair quality, removing dandruff and relieving itching, and can nourish scalp, improve microcirculation of scalp capillaries and achieve the effects of strengthening hair roots and reducing alopecia. The composition provided by the scheme of the invention can be widely applied to the preparation of hair cosmetics and medicines.

The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all equivalent changes made by using the contents of the present specification and the drawings, or applied directly or indirectly to the related technical fields, are included in the scope of the present invention.

Claims

1. An anti-dandruff and antipruritic composition containing Chinese herbal medicines is characterized in that: at least comprises balsam fir extract.

2. The anti-dandruff and antipruritic composition comprising Chinese herbs according to claim 1, wherein: the composition further comprises one or more of a bitter ginseng root extract, a dictamnus root extract, a salvia miltiorrhiza root extract and dipotassium glycyrrhizinate.

3. The anti-dandruff and antipruritic composition comprising Chinese herbs according to claim 2, wherein: in the composition, the mass percentage of the balsam fir extract is 0.1-20%; if yes, the mass percentage of the sophora flavescens root extract is 0.1-40%; if yes, the mass percent of the dittany root extract is 0.1-20%; if yes, the mass percentage of the salvia miltiorrhiza root extract is 0.1-20%; if yes, the weight percentage of the dipotassium glycyrrhizinate is 0.1-20%.

4. Use of a composition according to any one of claims 1 to 3 in the preparation of a cosmetic for washing and/or caring hair or a medicament for removing dandruff and relieving itching.

5. A silicone oil-free amino acid shampoo containing the composition as defined in any one of claims 1 to 3.

6. The silicone oil-free amino acid shampoo as defined in claim 5, wherein: the weight percentage of the composition is 0.05-10%.

7. The silicone oil-free amino acid shampoo as defined in claim 5, wherein: the silicone oil-free amino acid shampoo further comprises auxiliary materials and water, wherein the auxiliary materials comprise one or more of the following components: conditioning agent, chelating agent, surfactant, ester-forming agent, thickening agent, essence, preservative and pH regulator.

8. The silicone oil-free amino acid shampoo as defined in claim 7, wherein: if yes, the conditioner accounts for 0.05-5 wt%; if so, the chelating agent accounts for 0.05-0.3 wt%; if yes, the weight percentage of the surfactant is 15-45%; if so, the weight percentage content of the humectant is 0.1-10%; if yes, the weight percentage content of the ester forming agent is 0.1-10%; if so, the weight percentage content of the thickening agent is 0.05-5%; the essence accounts for 0-1% by weight; if so, the weight percentage content of the preservative is 0.05-5%; if yes, the weight percentage of the pH regulator is 0.01-1%.

9. The silicone oil-free amino acid shampoo as defined in claim 7, wherein: the surfactant comprises at least one of sodium lauroyl sarcosinate, cocamidopropyl hydroxysultaine, lauroamidopropyl betaine, sodium methyl cocoyl taurate, disodium lauryl sulfosuccinate, potassium cocoyl glycinate, sodium lauroyl glutamate, sodium lauroyl amphoacetate, cocoyl glucoside, sodium lauroyl avenamide, sodium cocoyl glycinate, cocamide-ethanolamine, sodium cocoyl isethionate, and sodium C14-C16 olefin sulfonate.

10. A preparation method of silicone oil-free amino acid shampoo is characterized by comprising the following steps: the preparation raw materials of the silicone-oil-free amino acid shampoo comprise the composition as defined in any one of claims 1 to 3, auxiliary materials and water, wherein the auxiliary materials comprise: conditioning agent, chelating agent, surfactant, excipient, thickener, perfume, preservative and pH adjuster, the method comprising the steps of: