CN110862876A - 一种高效去污的凝胶型洗涤剂及其制备方法 - Google Patents
一种高效去污的凝胶型洗涤剂及其制备方法 Download PDFInfo
- Publication number
- CN110862876A CN110862876A CN201911076948.4A CN201911076948A CN110862876A CN 110862876 A CN110862876 A CN 110862876A CN 201911076948 A CN201911076948 A CN 201911076948A CN 110862876 A CN110862876 A CN 110862876A
- Authority
- CN
- China
- Prior art keywords
- gel
- type detergent
- surfactant
- preparation
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 37
- 238000005202 decontamination Methods 0.000 title claims abstract description 19
- 230000003588 decontaminative effect Effects 0.000 title claims abstract description 19
- 239000004094 surface-active agent Substances 0.000 claims abstract description 28
- 102000004190 Enzymes Human genes 0.000 claims abstract description 18
- 108090000790 Enzymes Proteins 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002738 chelating agent Substances 0.000 claims abstract description 13
- 239000003755 preservative agent Substances 0.000 claims abstract description 12
- 230000002335 preservative effect Effects 0.000 claims abstract description 12
- 150000007529 inorganic bases Chemical class 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 30
- 239000004115 Sodium Silicate Substances 0.000 claims description 18
- -1 alkyl glycoside Chemical class 0.000 claims description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 18
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 18
- 229940088598 enzyme Drugs 0.000 claims description 17
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 14
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 14
- 239000002736 nonionic surfactant Substances 0.000 claims description 12
- 229930182470 glycoside Natural products 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 108091005804 Peptidases Proteins 0.000 claims description 9
- 239000004365 Protease Substances 0.000 claims description 9
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 8
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 7
- 102000004882 Lipase Human genes 0.000 claims description 7
- 108090001060 Lipase Proteins 0.000 claims description 7
- 239000004367 Lipase Substances 0.000 claims description 7
- 235000019421 lipase Nutrition 0.000 claims description 7
- 239000000176 sodium gluconate Substances 0.000 claims description 7
- 235000012207 sodium gluconate Nutrition 0.000 claims description 7
- 229940005574 sodium gluconate Drugs 0.000 claims description 7
- 235000019864 coconut oil Nutrition 0.000 claims description 6
- 239000003240 coconut oil Substances 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 4
- 239000004382 Amylase Substances 0.000 claims description 3
- 102000013142 Amylases Human genes 0.000 claims description 3
- 108010065511 Amylases Proteins 0.000 claims description 3
- 102100032487 Beta-mannosidase Human genes 0.000 claims description 3
- 108010059892 Cellulase Proteins 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 108010029541 Laccase Proteins 0.000 claims description 3
- 102000004316 Oxidoreductases Human genes 0.000 claims description 3
- 108090000854 Oxidoreductases Proteins 0.000 claims description 3
- 102000003992 Peroxidases Human genes 0.000 claims description 3
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 claims description 3
- 235000019418 amylase Nutrition 0.000 claims description 3
- 108010055059 beta-Mannosidase Proteins 0.000 claims description 3
- 108010089934 carbohydrase Proteins 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 229940106157 cellulase Drugs 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000002808 molecular sieve Substances 0.000 claims description 3
- 108010087558 pectate lyase Proteins 0.000 claims description 3
- 108040007629 peroxidase activity proteins Proteins 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 3
- 235000019419 proteases Nutrition 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- 229960001790 sodium citrate Drugs 0.000 claims description 3
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000004851 dishwashing Methods 0.000 abstract description 15
- 238000005406 washing Methods 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 6
- 229920002125 Sokalan® Polymers 0.000 abstract description 6
- 239000013543 active substance Substances 0.000 abstract description 6
- 229960001631 carbomer Drugs 0.000 abstract description 6
- 239000006260 foam Substances 0.000 abstract description 6
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
- 239000000047 product Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007794 irritation Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000009924 canning Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- OHOTVSOGTVKXEL-WJXVXWFNSA-K trisodium;(2s)-2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)[C@H](C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-WJXVXWFNSA-K 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 229940079919 digestives enzyme preparation Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- XFLNVMPCPRLYBE-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XFLNVMPCPRLYBE-UHFFFAOYSA-J 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
本发明属于日化产品技术领域，具体涉及一种高效去污的凝胶型洗涤剂及其制备方法。本申请的高效去污的凝胶型洗涤剂，由下列组分按质量百分数组成，表面活性剂1.0‑12％，螯合剂8‑20％，酶制剂0.5‑1.0％，无机碱制剂10‑15％，pH调节剂1‑5％，防腐剂0.05‑0.1％，其余含量为水，实现通过加入特定结构的鳌合分散剂，调节体系pH值至特定范围，从而自形成凝胶体系，一方面可以明显降低洗碗机洗涤过程中的泡沫状况；另一方面相比传统卡波姆体系，简化了生产工艺，降低了生产成本，并提高了配方自身活性物的稳定性，有效地提高了活性物的用量，具有广泛的工业应用前景。
Description
技术领域
本发明属于日化产品技术领域，具体涉及一种高效去污的凝胶型洗涤剂及其制备方法。
背景技术
随着生活水平的提高和环保意识的日益增强，自动洗碗机逐渐的在我国年轻一代的家庭中实现普及，消费者对洗涤产品的要求也日益提高，如要求洗涤剂对人体健康无损伤、方便使用、去污力强、价格便宜。
在自动餐具洗涤剂领域，洗碗粉、洗碗片、凝胶型洗碗剂最为普遍，近几年如水溶性膜包裹的凝珠型免计量定投洗涤产品也渐渐流行。传统洗碗粉一般通过提供一定的碱性，维持洗涤液在一定的pH值以起去油污效果，但碱性较强容易对手部皮肤造成一定的刺激损伤，后来出现一些洗碗粉新产品，通过加入表面活性剂和酶等，其中往往含有较多的三聚磷酸钠，其洗涤效果优异，但含磷的洗涤废液排放后容易导致严重的富营养化，且洗碗粉一般通过喷雾干燥而制成，制作工艺相对复杂，成本也比较高，开封后易吸潮和变质。而洗碗片是最早推出的免计量定投产品，便于携带和使用方便是片剂最为突出的优点，但其制作过程中需要高温以将水分蒸发，极易导致酶出现变性失活，生产设备要求高，工艺复杂决定了片剂洗涤剂拥有比粉剂高出一倍的制造成本和售价。传统液体洗涤剂一般是多种表面活性剂与40％～80％的水复配而成，温和、使用方便，但由于受溶解度、表面活性剂的配伍及酶制剂的稳定性等问题的限制，优良助剂的添加量受到了限制，同时也减弱了其洗涤效果，而后推出的卡波类凝胶型的洗涤剂，虽一定程度提高了配方体系的稳定性，但卡波类增稠剂本身具有良好的稳泡性，洗涤时会因为泡沫难以消除影响自动洗碗机的洗涤效果，另外其挂壁特性会影响自动分配器液位测量***，无法很好的配合现代洗碗机的洗涤程序。
发明内容
为了解决上述洗涤剂不稳定，易产泡而影响洗涤效果，生产工艺复杂、成本高等问题，本发明提供一种高效去污的凝胶型洗涤剂及其制备方法。
为实现上述目的，本发明所采用的技术方案是：一种高效去污的凝胶型洗涤剂，由下列组分按质量百分数组成，表面活性剂1.0-12％，螯合剂8-20％，酶制剂0.5-1.0％，无机碱制剂10-15％，pH调节剂1-5％，防腐剂0.05-0.1％，其余含量为水。
进一步的，表面活性剂包括阴离子表面活性剂、非离子表面活性剂中的一种或多种。
进一步的，阴离子表面活性剂包括磺酸盐型表面活性剂、羧酸盐型表面活性剂、硫酸盐型表面活性剂中的一种或多种。
进一步的，非离子表面活性剂包括C12-C18的脂肪醇聚氧乙烯醚、C12-C14的烷基糖苷、环氧乙烷与环氧丙烷嵌段共聚物和C12-C18的醇的缩合物、椰子油脂肪酸二乙醇酰胺、椰子油脂肪酸单乙醇酰胺、C8-C20的支链醇聚氧乙烯醚中的一种或多种。
进一步的，C12-C18的脂肪醇聚氧乙烯醚包括月桂醇聚氧乙烯醚。
进一步的，螯合剂包括次氨基三亚甲基五钠、葡萄糖酸钠、柠檬酸钠、乙二胺四乙酸四钠、甲基甘氨酸二乙酸三钠盐、4A分子筛、聚丙烯酸盐、丙烯酸-马来酸共聚物中的一种或多种。
进一步的，无机碱制剂包括偏硅酸钠、层状硅酸钠、硅酸钠中的一种或多种。
进一步的，酶制剂包括蛋白酶、淀粉酶、脂肪酶、纤维素酶、氧化酶、糖酶、漆酶、过氧化物酶、果胶酸裂合酶、甘露聚糖酶中的一种或多种。
一种高效去污的凝胶型洗涤剂的制备方法，
步骤一：往配料锅内加入水，并加热搅拌，再加入螯合剂、无机碱制剂搅拌均匀；
步骤二：继续往配料锅内加入阴离子表面活性剂、非离子表面活性剂，搅拌均匀后，接着加入pH调节剂调节溶液pH值；
步骤三：继续在搅拌下往配料锅内加入酶制剂、防腐剂，恒温反应，获得凝胶型洗涤剂。
进一步的，步骤一中的加热温度为40-65℃。
进一步的，步骤二中pH值为6.5-8.5。
进一步的，恒温反应的温度为30-45℃。
本发明提供一种高效去污的凝胶型洗涤剂，该洗涤剂由下列组分按质量百分数组成，表面活性剂1.0-12％，螯合剂8-20％，酶制剂0.5-1.0％，无机碱制剂10-15％，pH调节剂1-5％，防腐剂0.05-0.1％，其余含量为水，实现通过加入特定结构的鳌合分散剂，调节体系pH值至特定范围，从而自形成凝胶体系，一方面可以明显降低洗碗机洗涤过程中的泡沫状况；另一方面相比传统卡波姆体系，简化了生产工艺，降低了生产成本，并提高了配方自身活性物的稳定性，有效地提高了活性物的用量，具有广泛的工业应用前景。
附图说明
图1为高效去污的凝胶型洗涤剂的制备方法流程图。
具体实施方式
下面将结合本发明实施例中的附图，对本发明中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。
一种高效去污的凝胶型洗涤剂，由下列组分按质量百分数组成，表面活性剂1.0-12％，螯合剂8-20％，酶制剂0.5-1.0％，无机碱制剂10-15％，pH调节剂1-5％，防腐剂0.05-0.1％，其余含量为水。
表面活性剂包括阴离子表面活性剂、非离子表面活性剂中的一种或多种。
阴离子表面活性剂包括磺酸盐型表面活性剂、羧酸盐型表面活性剂、硫酸盐型表面活性剂中的一种或多种，如磺酸盐型表面活性剂包括十二烷基苯磺酸钠；硫酸盐型表面活性剂包括月桂醇聚氧乙烯醚硫酸钠；
非离子表面活性剂包括C12-C18的脂肪醇聚氧乙烯醚、C12-C14的烷基糖苷、环氧乙烷与环氧丙烷嵌段共聚物和C12-C18的醇的缩合物、椰子油脂肪酸二乙醇酰胺、椰子油脂肪酸单乙醇酰胺、C8-C20的支链醇聚氧乙烯醚中的一种或多种，该C12-C18的脂肪醇聚氧乙烯醚包括月桂醇聚氧乙烯醚，该月桂醇聚氧乙烯醚具有优良的洗涤、乳化、分散、润湿、增溶等功能，且起泡力强，易漂洗，去污力优异；是表面活性剂中对皮肤刺激性最低的品种之一。它能与各种表面活性剂复配，降低它们的刺激性，改善产品的性能，可代替AES，既能降低产品的刺激性又不增加成本；它还可以作为乳化剂、柔软剂、润湿剂、发泡剂等。
C12-C14的烷基糖苷，Alkyl Polyglucoside(简称APG)，它是由葡萄糖的半缩醛羟基和脂肪醇羟基在催化作用下脱水而成，属于非离子表面活性剂，并兼具非离子和阴离子种表面活性剂的性能(可以抗酸碱，配伍性能好，稳定性高，并具有较好的去污、发泡、分散、乳化、润湿等特性)。它是新型高效、无毒、可生物降解的非离子表面活性剂，表面活性很好，复配后可形成目前最好的表面活性剂，烷基糖苷具有十分优异的性能，表面张力低、起泡力强、泡沫稳定、润湿性好、配伍性能极好，对人体刺激性小。由于烷基糖苷的生产原料都来自可再生的农产品，主要有淀粉水解产物葡萄糖、植物油氢化产物高级脂肪醇，所以能迅速生物降解，是目前世界上唯一可被称为无毒级的品种，被誉为“世界级”表面活性剂。
螯合剂包括次氨基三亚甲基五钠、葡萄糖酸钠、柠檬酸钠、乙二胺四乙酸四钠、甲基甘氨酸二乙酸三钠盐、4A分子筛、聚丙烯酸盐、丙烯酸-马来酸共聚物中的一种或多种，本实施例的洗涤剂通过多种性能优异的螯合剂混合搭配，如硅酸盐类能与金属离子生成不溶性的盐，有良好的软化硬水、抑制泡沫、消除泡沫的性能，使产品具有优异去污力和洗涤性能。
无机碱制剂包括偏硅酸钠、层状硅酸钠、硅酸钠中的一种或多种，其中硅酸钠、偏硅酸钠、层状硅酸钠等硅酸盐在该体系中，中和后有自成凝胶的特性，并且具有很好的悬浮性和稳定悬浮***的能力，较好地缓解了酶制剂在高无机盐体系中不稳定的问题。
酶制剂包括蛋白酶、淀粉酶、脂肪酶、纤维素酶、氧化酶、糖酶、漆酶、过氧化物酶、果胶酸裂合酶、甘露聚糖酶中的一种或多种。
pH调节剂包括柠檬酸；防腐剂包括卡松。
如图1所示，一种高效去污的凝胶型洗涤剂的制备方法，具体如下：
S101：往配料锅内加入水，并加热搅拌，加热温度为40-65℃，再加入螯合剂、无机碱制剂搅拌均匀；
S102：继续往配料锅内加入阴离子表面活性剂、非离子表面活性剂，搅拌均匀后，接着加入pH调节剂调节溶液pH值，pH值为6.5-8.5；
S103：继续在搅拌下往配料锅内加入酶制剂、防腐剂，在30-45℃温度下反应，获得凝胶型洗涤剂。
实施例一
一种高效去污的凝胶型洗涤剂，由下列组分按质量百分数组成：
月桂醇聚氧乙烯醚5％；柠檬酸钠8％；葡萄糖酸钠5％；硅酸钠2％；蛋白酶0.1％；柠檬酸3.0％；卡松0.1％；水为76.8％。
该高效去污的凝胶型洗涤剂采用以下的工艺制得：在配料锅中加入去离子水，加热至50℃～60℃，启动搅拌，并加入8％柠檬酸钠、5％葡萄糖酸钠、2％硅酸钠，搅拌均匀；
在搅拌下向配料锅中加入5％月桂醇聚氧乙烯醚，搅拌均匀；
在搅拌下加入3.0％柠檬酸，并将pH值调节至7.5-8.5；
在搅拌下加入0.1％蛋白酶和0.1％防腐剂卡松，温度达到35℃-40℃即可取样化验；储存，罐装即得凝胶型洗涤剂。
上述获得的凝胶型洗涤剂的外观为透明凝胶状，粘度为1500cps；酶制剂月衰减率小于1％；高低温条件下稳定性测试：未发现分层与沉淀。
实施例二
一种高效去污的凝胶型洗涤剂，由下列组分按质量百分数组成：
烷基糖苷5％；十二烷基苯磺酸钠5％；偏硅酸钠5％；甲基甘氨酸二乙酸三钠盐5％；聚丙烯酸钠5％；蛋白酶0.5％；脂肪酶0.5％；柠檬酸5.0％；卡松0.1％；水68.9％。
该高效去污的凝胶型洗涤剂采用以下的工艺制得：在配料锅中加入去离子水，加热至50℃～60℃，启动搅拌，并加入5％甲基甘氨酸二乙酸三钠盐、5％聚丙烯酸钠、5％偏硅酸钠，搅拌均匀；
在搅拌下向配料锅中加入5％十二烷基苯磺酸钠、5％烷基糖苷，搅拌均匀；
在搅拌下加入3.0％柠檬酸，并将pH值调节至7.5-8.5；
在搅拌下加入0.5％蛋白酶、0.5％脂肪酶和0.1％防腐剂卡松，温度达到35℃-40℃即可取样化验；储存，罐装即得凝胶型洗涤剂。
上述获得的凝胶型洗涤剂的外观为透明凝胶状，粘度为1400cps；酶制剂月衰减率小于1％，高低温条件下稳定性测试未发现分层与沉淀。
实施例三
一种高效去污的凝胶型洗涤剂，由下列组分按质量百分数组成：
烷基糖苷5％；月桂醇聚氧乙烯醚硫酸钠5％；偏硅酸钠5％；乙二胺四乙酸四钠5％；葡萄糖酸钠5％；蛋白酶0.5％；脂肪酶0.5％；柠檬酸5.0％；卡松0.1％；水68.9％。
该高效去污的凝胶型洗涤剂采用以下的工艺制得：在配料锅中加入去离子水，加热至50℃～60℃，启动搅拌，并加入5％乙二胺四乙酸四钠、5％葡萄糖酸钠、5％偏硅酸钠，搅拌均匀；
在搅拌下向配料锅中加入5％月桂醇聚氧乙烯醚硫酸钠、5％烷基糖苷，搅拌均匀；
在搅拌下加入5.0％柠檬酸，并将pH值调节至7.5-8.5；
在搅拌下加入0.5％蛋白酶、0.5％脂肪酶和0.1％防腐剂卡松，温度达到35℃-40℃即可取样化验；储存，罐装即得凝胶型洗涤剂。
上述获得的凝胶型洗涤剂的外观为透明凝胶状，粘度为1600cps；酶制剂月衰减率小于1％；高低温条件下稳定性测试：未发现分层与沉淀。
本发明提供一种高效去污的凝胶型洗涤剂，通过往配料锅内加入表面活性剂1.0-12％，螯合剂8-20％，酶制剂0.5-1.0％，无机碱制剂10-15％，pH调节剂1-5％，防腐剂0.05-0.1％，水，从而自形成凝胶体系，一方面可以明显降低洗碗机洗涤过程中的泡沫状况；另一方面相比传统卡波姆体系，简化了生产工艺，降低了生产成本，并提高了配方自身活性物的稳定性，有效地提高了活性物的用量，具有广泛的工业应用前景。
上述仅为本发明的优选具体实施方式，但本发明的设计构思并不局限于此，凡利用此构思对本发明进行非实质性的改动，均应属于侵犯本发明保护范围的行为。
Claims (12)
1.一种高效去污的凝胶型洗涤剂，其特征在于：由下列组分按质量百分数组成，表面活性剂1.0-12％，螯合剂8-20％，酶制剂0.5-1.0％，无机碱制剂10-15％，pH调节剂1-5％，防腐剂0.05-0.1％，其余含量为水。
2.根据权利要求1所述的高效去污的凝胶型洗涤剂，其特征在于：所述表面活性剂包括阴离子表面活性剂、非离子表面活性剂中的一种或多种。
3.根据权利要求2所述的高效去污的凝胶型洗涤剂，其特征在于：所述阴离子表面活性剂包括磺酸盐型表面活性剂、羧酸盐型表面活性剂、硫酸盐型表面活性剂中的一种或多种。
4.根据权利要求2所述的高效去污的凝胶型洗涤剂，其特征在于：所述非离子表面活性剂包括C12-C18的脂肪醇聚氧乙烯醚、C12-C14的烷基糖苷、环氧乙烷与环氧丙烷嵌段共聚物和C12-C18的醇的缩合物、椰子油脂肪酸二乙醇酰胺、椰子油脂肪酸单乙醇酰胺、C8-C20的支链醇聚氧乙烯醚中的一种或多种。
5.根据权利要求4所述的高效去污的凝胶型洗涤剂，其特征在于：所述C12-C18的脂肪醇聚氧乙烯醚包括月桂醇聚氧乙烯醚。
6.根据权利要求1所述的高效去污的凝胶型洗涤剂，其特征在于：所述螯合剂包括次氨基三亚甲基五钠、葡萄糖酸钠、柠檬酸钠、乙二胺四乙酸四钠、甲基甘氨酸二乙酸三钠盐、4A分子筛、聚丙烯酸盐、丙烯酸-马来酸共聚物中的一种或多种。
7.根据权利要求1所述的高效去污的凝胶型洗涤剂，其特征在于：所述无机碱制剂包括偏硅酸钠、层状硅酸钠、硅酸钠中的一种或多种。
8.根据权利要求1所述的高效去污的凝胶型洗涤剂，其特征在于：所述酶制剂包括蛋白酶、淀粉酶、脂肪酶、纤维素酶、氧化酶、糖酶、漆酶、过氧化物酶、果胶酸裂合酶、甘露聚糖酶中的一种或多种。
9.一种高效去污的凝胶型洗涤剂的制备方法，其特征在于：
步骤一：往配料锅内加入水，并加热搅拌，再加入螯合剂、无机碱制剂搅拌均匀；
步骤二：继续往配料锅内加入阴离子表面活性剂、非离子表面活性剂，搅拌均匀后，接着加入pH调节剂调节溶液pH值；
步骤三：继续在搅拌下往配料锅内加入酶制剂、防腐剂，恒温反应，获得凝胶型洗涤剂。
10.根据权利要求9所述的高效去污的凝胶型洗涤剂的制备方法，其特征在于：所述步骤一中的加热温度为40-65℃。
11.根据权利要求9所述的高效去污的凝胶型洗涤剂的制备方法，其特征在于：所述步骤二中pH值为6.5-8.5。
12.根据权利要求9所述的高效去污的凝胶型洗涤剂的制备方法，其特征在于：所述恒温反应的温度为30-45℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911076948.4A CN110862876A (zh) | 2019-11-06 | 2019-11-06 | 一种高效去污的凝胶型洗涤剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911076948.4A CN110862876A (zh) | 2019-11-06 | 2019-11-06 | 一种高效去污的凝胶型洗涤剂及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110862876A true CN110862876A (zh) | 2020-03-06 |
Family
ID=69653843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911076948.4A Pending CN110862876A (zh) | 2019-11-06 | 2019-11-06 | 一种高效去污的凝胶型洗涤剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110862876A (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111394206A (zh) * | 2020-04-02 | 2020-07-10 | 周栋 | 一种具有缓释功能的洗碗片及其制备方法 |
| CN111575121A (zh) * | 2020-05-15 | 2020-08-25 | 珠海格力电器股份有限公司 | 一种水溶性浓缩凝胶清洁剂、制备方法及冲洗清洁方法 |
| CN114540825A (zh) * | 2021-03-15 | 2022-05-27 | 广东多创新材料科技有限公司 | 一种除油除蜡粉及制备方法 |
| CN114540427A (zh) * | 2020-11-25 | 2022-05-27 | 山东蓝星东大有限公司 | 聚氧乙烯醚类的非离子表面活性剂的制备方法 |
| CN114891570A (zh) * | 2021-06-08 | 2022-08-12 | 北京市家荣保洁服务有限公司 | 一种温和高效污渍去除剂及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055760A (zh) * | 1990-08-15 | 1991-10-30 | 柏绿山 | 高效无磷杀菌洗涤膏 |
| CN1948151A (zh) * | 2006-10-23 | 2007-04-18 | 李永兆 | 一种除油专用硅胶的制造方法及其用途 |
| CN101402901A (zh) * | 2008-11-12 | 2009-04-08 | 江门市蓬江区海润化工有限公司 | 一种具有消毒功能的二氧化硅膏状去污剂及其制备方法 |
| CN101649258A (zh) * | 2009-08-31 | 2010-02-17 | 广州立白企业集团有限公司 | 一种含酶餐具洗涤剂及其制备方法 |
| CN107384599A (zh) * | 2017-06-16 | 2017-11-24 | 广东红日星实业有限公司 | 一种胶体环保洗涤剂及其制备方法 |
-
2019
- 2019-11-06 CN CN201911076948.4A patent/CN110862876A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055760A (zh) * | 1990-08-15 | 1991-10-30 | 柏绿山 | 高效无磷杀菌洗涤膏 |
| CN1948151A (zh) * | 2006-10-23 | 2007-04-18 | 李永兆 | 一种除油专用硅胶的制造方法及其用途 |
| CN101402901A (zh) * | 2008-11-12 | 2009-04-08 | 江门市蓬江区海润化工有限公司 | 一种具有消毒功能的二氧化硅膏状去污剂及其制备方法 |
| CN101649258A (zh) * | 2009-08-31 | 2010-02-17 | 广州立白企业集团有限公司 | 一种含酶餐具洗涤剂及其制备方法 |
| CN107384599A (zh) * | 2017-06-16 | 2017-11-24 | 广东红日星实业有限公司 | 一种胶体环保洗涤剂及其制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 任洪波等译: "<<气凝胶手册>>", 31 December 2014 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111394206A (zh) * | 2020-04-02 | 2020-07-10 | 周栋 | 一种具有缓释功能的洗碗片及其制备方法 |
| CN111394206B (zh) * | 2020-04-02 | 2022-09-13 | 芊碟净智能家居科技(广东)有限公司 | 一种具有缓释功能的洗碗片及其制备方法 |
| CN111575121A (zh) * | 2020-05-15 | 2020-08-25 | 珠海格力电器股份有限公司 | 一种水溶性浓缩凝胶清洁剂、制备方法及冲洗清洁方法 |
| CN114540427A (zh) * | 2020-11-25 | 2022-05-27 | 山东蓝星东大有限公司 | 聚氧乙烯醚类的非离子表面活性剂的制备方法 |
| CN114540427B (zh) * | 2020-11-25 | 2024-05-03 | 中化东大(淄博)有限公司 | 聚氧乙烯醚类的非离子表面活性剂的制备方法 |
| CN114540825A (zh) * | 2021-03-15 | 2022-05-27 | 广东多创新材料科技有限公司 | 一种除油除蜡粉及制备方法 |
| CN114891570A (zh) * | 2021-06-08 | 2022-08-12 | 北京市家荣保洁服务有限公司 | 一种温和高效污渍去除剂及其制备方法 |
| CN114891570B (zh) * | 2021-06-08 | 2023-08-22 | 北京市家荣保洁服务有限公司 | 一种温和污渍去除剂及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110862876A (zh) | 一种高效去污的凝胶型洗涤剂及其制备方法 | |
| CN107955743B (zh) | 一种高效洗衣液及其制备方法 | |
| CN103642602B (zh) | 一种洗洁精 | |
| CN107287046B (zh) | 婴幼儿衣物生物酶清洗液及其制备方法 | |
| CN102876483A (zh) | 一种低泡易漂型洗衣液组合物及其制备方法 | |
| EP2598625A2 (de) | Stabilisierte flüssige enzymhaltige tensidzubereitung | |
| CN103484265A (zh) | 一种绿色抗菌高效洗洁精及其制备方法 | |
| DE102007039655A1 (de) | Reinigungsmittel | |
| CN103881845A (zh) | 含有海洋生物成分的羽绒服专用洗涤剂及其制备方法 | |
| CN107937171A (zh) | 一种低泡绿色cip杀菌浓缩型清洗剂 | |
| CN106367216A (zh) | 一种茶皂素洗洁精 | |
| CN103725439B (zh) | 一种洗洁精的制备方法 | |
| CN111575121B (zh) | 一种水溶性浓缩凝胶清洁剂、制备方法及冲洗清洁方法 | |
| CN102517160B (zh) | 生物环保抗氧化洗洁剂及其制备方法 | |
| CN113604296B (zh) | 一种兼具低刺激性、高清洁力和低温稳定性的洗涤剂组合物 | |
| CN103695189A (zh) | 一种无泡餐具洗涤剂 | |
| CN103194338B (zh) | 一种洗手液及其制备方法 | |
| CN107312658A (zh) | 一种易漂洗的手工洗衣皂粉 | |
| CN1354238A (zh) | 婴幼儿衣物洗涤剂 | |
| EP2692843A1 (en) | Use of C1-oxidised starch hydrolysates | |
| WO2011110593A1 (en) | Stabilised enzyme-containing liquid detergent composition | |
| CN101816625B (zh) | 一种温和低刺激的洗手液及其制备方法 | |
| CN101514314B (zh) | 一种含有高浓度螯合剂的透明中性衣物洗涤剂及其制备方法 | |
| CN104031782A (zh) | 一种洗碗机专用餐具洗涤剂及其制备方法 | |
| CN110484379A (zh) | 一种手机玻璃清洗剂组合物及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200306 |
|
| RJ01 | Rejection of invention patent application after publication |