CN110840773A - High-viscosity high-foam surfactant composition - Google Patents

High-viscosity high-foam surfactant composition Download PDF

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Publication number
CN110840773A
CN110840773A CN201911066821.4A CN201911066821A CN110840773A CN 110840773 A CN110840773 A CN 110840773A CN 201911066821 A CN201911066821 A CN 201911066821A CN 110840773 A CN110840773 A CN 110840773A
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Prior art keywords
parts
surfactant composition
viscosity
foam
glutamate
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CN201911066821.4A
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Chinese (zh)
Inventor
黄燏斌
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Guangdong Resun Auway Industrial Co Ltd
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Guangdong Resun Auway Industrial Co Ltd
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Priority to CN201911066821.4A priority Critical patent/CN110840773A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Abstract

The invention provides a high-viscosity high-foaming surfactant composition, which comprises the following components in parts by weight: 100 parts of amino acid surfactant, 3-7 parts of alkyl polyglycoside, 2-4 parts of palmitic acid, 2-5 parts of carboxymethyl cellulose, 5-8 parts of pectin, 0.2-0.3 part of foam stabilizer, 0.1-0.2 part of chelating agent, 0.01-0.0.02 parts of bactericide and 1-10 parts of water. The surfactant composition can be used as a tackifying and foaming raw material of a washing and protecting product, and can improve the viscosity and the foam quantity of the washing and protecting product.

Description

High-viscosity high-foam surfactant composition
Technical Field
The invention relates to the technical field of surfactants, in particular to a surfactant composition with high viscosity and high foam quantity.
Background
Surfactants are widely used in our lives, and their use is related to many aspects, such as shampoos, body washes, kitchen cleaners, hand cleaners, and the like. Since amino acid surfactants have excellent detergency and produce small and fine foams, they are increasingly used in washing and care products. However, since the amino acid surfactants are not easily thickened due to high hydrophilicity, it is difficult to thicken by adding amphoteric surfactants and nonionic surfactants only by conventional means, and thus many of the washing products using the amino acid surfactants have low viscosity, and thus, there is a need to solve these problems.
Disclosure of Invention
In order to solve the problems, the invention provides a surfactant composition with high viscosity and high foam quantity, which can be used as a thickening and foam increasing raw material of a washing and caring product and can improve the viscosity and the foam quantity of the washing and caring product.
In order to achieve the purpose, the invention is solved by the following technical scheme:
a high viscosity and high foam surfactant composition comprises the following components in parts by weight: 100 parts of amino acid surfactant, 3-7 parts of alkyl polyglycoside, 2-4 parts of palmitic acid, 2-5 parts of carboxymethyl cellulose, 5-8 parts of pectin, 0.2-0.3 part of foam stabilizer, 0.1-0.2 part of chelating agent, 0.01-0.0.02 parts of bactericide and 1-10 parts of water.
Specifically, the amino acid surfactant is selected from one of sodium cocoyl glutamate, disodium cocoyl glutamate, sodium lauroyl glutamate, sodium cocoyl glycinate, N-acyl sarcosine and N-acyl glutamate.
Specifically, the foam stabilizer is polypropylene glycol.
Specifically, the chelating agent is one selected from ethylenediamine tetraacetic acid, diethylenetriamine pentaacetic acid and N-hydroxyethyl-ethylamine triacetic acid.
Specifically, the bactericide is methylisothiazolinone.
The invention has the beneficial effects that:
the surfactant composition provided by the invention can be used as a thickening and foaming raw material of a washing and protecting product, and can improve the viscosity and the foam quantity of the washing and protecting product.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to provide a further understanding of the nature and technical means of the invention, as well as the specific objects and functions attained by the invention.
Example 1
A high viscosity and high foam surfactant composition comprises the following components in parts by weight: 100 parts of cocoyl sodium glutamate, 4 parts of alkyl polyglycoside, 3 parts of palmitic acid, 2 parts of carboxymethyl cellulose, 8 parts of pectin, 0.2 part of polypropylene glycol, 0.1 part of ethylene diamine tetraacetic acid, 0.01 part of methylisothiazolinone and 5 parts of water.
And (3) testing:
weighing the components according to the mixture ratio, uniformly stirring to obtain a surfactant composition, weighing 10g of the surfactant composition for later use, adding 40g of AES into a 250ml beaker, adding a small amount of water into the beaker, stirring with a stirring device until the AES is dissolved, then adding 10g of the weighed surfactant composition, continuing stirring, adding water while stirring until the scale of the mixture in the 250ml beaker reaches 150ml, continuing stirring until the surfactant composition is completely dissolved, then testing the viscosity and the foam height (5g of sample) at 25 ℃, and recording as shown in the following table 1.
Example 2
A high viscosity and high foam surfactant composition comprises the following components in parts by weight: 100 parts of cocoyl sodium glutamate, 5 parts of alkyl polyglycoside, 2 parts of palmitic acid, 4 parts of carboxymethyl cellulose, 6 parts of pectin, 0.2 part of polypropylene glycol, 0.1 part of ethylene diamine tetraacetic acid, 0.01 part of methylisothiazolinone and 5 parts of water.
And (3) testing:
weighing the components according to the mixture ratio, uniformly stirring to obtain a surfactant composition, weighing 10g of the surfactant composition for later use, adding 40g of AES into a 250ml beaker, adding a small amount of water into the beaker, stirring with a stirring device until the AES is dissolved, then adding 10g of the weighed surfactant composition, continuing stirring, adding water while stirring until the scale of the mixture in the 250ml beaker reaches 150ml, continuing stirring until the surfactant composition is completely dissolved, then testing the viscosity and the foam height (5g of sample) at 25 ℃, and recording as shown in the following table 1.
Comparative example
Weighing 10g sodium cocoyl glutamate for later use, adding 40g AES into a 250ml beaker, adding a small amount of water into the beaker, stirring under a stirring device until the AES is dissolved, then adding 10g of the weighed sodium cocoyl glutamate, continuing stirring, adding water while stirring until the scale of the mixture in the 250ml beaker reaches 150ml, continuing stirring until the sodium cocoyl glutamate is completely dissolved, then testing the viscosity and the foam height (5g sample) at 25 ℃, and recording as in the following table 1.
TABLE 1 test results
Example 1 Example 2 Comparative example
viscosity/mPas 7135 7026 3210
Height/cm of foam 7.3 6.7 5.9
Tests show that the surfactant compositions of examples 1 and 2 produced washing products with AES exhibit greater increases in viscosity and foam height than washing products produced directly with sodium cocoyl glutamate and AES in the same ratio.
The above examples only show 2 embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (5)

1. The high-viscosity high-foam surfactant composition is characterized by comprising the following components in parts by weight: 100 parts of amino acid surfactant, 3-7 parts of alkyl polyglycoside, 2-4 parts of palmitic acid, 2-5 parts of carboxymethyl cellulose, 5-8 parts of pectin, 0.2-0.3 part of foam stabilizer, 0.1-0.2 part of chelating agent, 0.01-0.0.02 parts of bactericide and 1-10 parts of water.
2. A high viscosity, high lathering surfactant composition according to claim 1 wherein said amino acid based surfactant is selected from the group consisting of sodium cocoyl glutamate, disodium cocoyl glutamate, sodium lauroyl glutamate, sodium cocoyl glycinate, N-acyl sarcosine, N-acyl glutamate.
3. A high viscosity, high lathering surfactant composition according to claim 1 wherein said suds stabilizer is polypropylene glycol.
4. A high viscosity high lathering surfactant composition according to claim 1 wherein said chelating agent is selected from the group consisting of ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, N-hydroxyethylethanamine triacetic acid.
5. A high viscosity high lathering surfactant composition in accordance with claim 1 wherein said biocide is methylisothiazolinone.
CN201911066821.4A 2019-11-04 2019-11-04 High-viscosity high-foam surfactant composition Pending CN110840773A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5911981A (en) * 1997-10-24 1999-06-15 R.I.T.A. Corporation Surfactant blends for generating a stable wet foam
CN105902411A (en) * 2016-05-17 2016-08-31 魏春红 Cleansing foam and preparation method thereof
CN107582427A (en) * 2017-09-26 2018-01-16 广州宏度精细化工有限公司 Non-soap base mildy wash and preparation method thereof
CN108309866A (en) * 2018-04-26 2018-07-24 内蒙古伊草恋生物科技有限责任公司 A kind of adult's shower cream containing licorice
CN108567583A (en) * 2018-07-20 2018-09-25 广州天赐高新材料股份有限公司 A kind of amino acid is from thickener composition, system and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5911981A (en) * 1997-10-24 1999-06-15 R.I.T.A. Corporation Surfactant blends for generating a stable wet foam
CN105902411A (en) * 2016-05-17 2016-08-31 魏春红 Cleansing foam and preparation method thereof
CN107582427A (en) * 2017-09-26 2018-01-16 广州宏度精细化工有限公司 Non-soap base mildy wash and preparation method thereof
CN108309866A (en) * 2018-04-26 2018-07-24 内蒙古伊草恋生物科技有限责任公司 A kind of adult's shower cream containing licorice
CN108567583A (en) * 2018-07-20 2018-09-25 广州天赐高新材料股份有限公司 A kind of amino acid is from thickener composition, system and application

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