CN110752420B - 一种镁空气电池缓蚀电解液 - Google Patents
一种镁空气电池缓蚀电解液 Download PDFInfo
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- CN110752420B CN110752420B CN201911073752.XA CN201911073752A CN110752420B CN 110752420 B CN110752420 B CN 110752420B CN 201911073752 A CN201911073752 A CN 201911073752A CN 110752420 B CN110752420 B CN 110752420B
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- parts
- electrolyte
- polymer monomer
- air battery
- plasticizer
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- 238000005260 corrosion Methods 0.000 title claims abstract description 43
- 230000007797 corrosion Effects 0.000 title claims abstract description 42
- 239000003792 electrolyte Substances 0.000 title claims abstract description 27
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 19
- 239000011777 magnesium Substances 0.000 title claims abstract description 19
- 230000005764 inhibitory process Effects 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 32
- 239000003112 inhibitor Substances 0.000 claims abstract description 25
- 239000000178 monomer Substances 0.000 claims abstract description 24
- 239000000945 filler Substances 0.000 claims abstract description 18
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 18
- 239000003999 initiator Substances 0.000 claims abstract description 16
- 239000004014 plasticizer Substances 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 claims description 16
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 8
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims description 8
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 claims description 6
- 229940079864 sodium stannate Drugs 0.000 claims description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 claims description 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 4
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 2
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 16
- 239000011245 gel electrolyte Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- HKVFISRIUUGTIB-UHFFFAOYSA-O azanium;cerium;nitrate Chemical compound [NH4+].[Ce].[O-][N+]([O-])=O HKVFISRIUUGTIB-UHFFFAOYSA-O 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0085—Immobilising or gelification of electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
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CN201911073752.XA CN110752420B (zh) | 2019-11-06 | 2019-11-06 | 一种镁空气电池缓蚀电解液 |
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CN201911073752.XA CN110752420B (zh) | 2019-11-06 | 2019-11-06 | 一种镁空气电池缓蚀电解液 |
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CN110752420A CN110752420A (zh) | 2020-02-04 |
CN110752420B true CN110752420B (zh) | 2023-04-07 |
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Families Citing this family (1)
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CN111416139A (zh) * | 2020-03-06 | 2020-07-14 | 中科院过程工程研究所南京绿色制造产业创新研究院 | 一种电解液缓蚀剂、铝空气电池、碱性电解液及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1630127A (zh) * | 2003-12-16 | 2005-06-22 | 中国电子科技集团公司第十八研究所 | 电池用复合型聚合物电解质膜及其制造方法 |
JP2015028896A (ja) * | 2013-06-25 | 2015-02-12 | 一徳 清家 | 半導体を用いた二次電池の負電極 |
JP2015046403A (ja) * | 2014-10-24 | 2015-03-12 | トヨタ自動車株式会社 | 空気電池用空気極及び空気電池 |
CN109401693A (zh) * | 2018-10-31 | 2019-03-01 | 清华大学深圳研究生院 | 醇酸树脂改性的聚合物电解质及其制备方法和应用 |
CN109643807A (zh) * | 2016-08-30 | 2019-04-16 | 罗地亚经营管理公司 | 用于电池中的固-液电解质 |
CN110364787A (zh) * | 2019-07-24 | 2019-10-22 | 易航时代(北京)科技有限公司 | 一种复合缓蚀剂电解液及其应用、镁空气电池 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5633630B2 (ja) * | 2011-02-22 | 2014-12-03 | トヨタ自動車株式会社 | 非水電解質空気電池 |
-
2019
- 2019-11-06 CN CN201911073752.XA patent/CN110752420B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1630127A (zh) * | 2003-12-16 | 2005-06-22 | 中国电子科技集团公司第十八研究所 | 电池用复合型聚合物电解质膜及其制造方法 |
JP2015028896A (ja) * | 2013-06-25 | 2015-02-12 | 一徳 清家 | 半導体を用いた二次電池の負電極 |
JP2015046403A (ja) * | 2014-10-24 | 2015-03-12 | トヨタ自動車株式会社 | 空気電池用空気極及び空気電池 |
CN109643807A (zh) * | 2016-08-30 | 2019-04-16 | 罗地亚经营管理公司 | 用于电池中的固-液电解质 |
CN109401693A (zh) * | 2018-10-31 | 2019-03-01 | 清华大学深圳研究生院 | 醇酸树脂改性的聚合物电解质及其制备方法和应用 |
CN110364787A (zh) * | 2019-07-24 | 2019-10-22 | 易航时代(北京)科技有限公司 | 一种复合缓蚀剂电解液及其应用、镁空气电池 |
Non-Patent Citations (2)
Title |
---|
Rahman,MA等.High energy density metal-air batteries:A review.《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》.2013,第160卷(第10期), * |
李慧明.镁空气电池电解液缓蚀剂的研究.《中国优秀硕士学位论文全文数据库(电子期刊)工程II辑》.2018,(第1期), * |
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Address after: 226000 No. 1, Xiangjiang Road, Chengbei street, Rugao City, Nantong City, Jiangsu Province Applicant after: Jiangsu Yushi Energy Group Co.,Ltd. Address before: 226000 No. 1, Xiangjiang Road, Chengbei street, Rugao City, Nantong City, Jiangsu Province Applicant before: Yushi energy (Nantong) Co.,Ltd. |
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CP03 | Change of name, title or address |
Address after: No. 99, Lane 255, Sizhuan South Road, Xinqiao Town, Songjiang District, Shanghai, 201600 Patentee after: Shanghai Yushi Energy Group Co.,Ltd. Country or region after: China Address before: 226000 No. 1, Xiangjiang Road, Chengbei street, Rugao City, Nantong City, Jiangsu Province Patentee before: Jiangsu Yushi Energy Group Co.,Ltd. Country or region before: China |