CN110714327A - 一种书画艺术品阻燃防潮抗菌处理剂及其制备方法 - Google Patents

一种书画艺术品阻燃防潮抗菌处理剂及其制备方法 Download PDF

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CN110714327A
CN110714327A CN201910995312.3A CN201910995312A CN110714327A CN 110714327 A CN110714327 A CN 110714327A CN 201910995312 A CN201910995312 A CN 201910995312A CN 110714327 A CN110714327 A CN 110714327A
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parts
painting
treating agent
flame
moisture
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许平山
陈振
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Anhui Vocational and Technical College
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Anhui Vocational and Technical College
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Abstract

本发明提供一种书画艺术品阻燃防潮抗菌处理剂及其制备方法，涉及艺术品保护领域，包括以下重量份的原料：硅酸镁为5‑10份、三聚磷酸铝为7‑12份、氮化硅为6‑10份、聚对苯二甲酸乙二醇酯2‑7份、硼酸锌为0.5‑3份、藻脘酸盐2‑8份、氯化铝为1‑3份、膨润土4‑8份、碳酸钙6‑12份、高岭土3‑7份，苯乙烯1‑5份、丙烯酸酯3‑6份、甘油4‑9份、磷酸二氢铵3‑10份、苯并咪唑氨基甲酸甲酯5‑13份、2,4,5,6‑四氯‑1,3苯二甲腈6‑10份、聚六亚甲基双胍盐4‑9份、氧化锌0.2‑0.7份、成膜助剂0.03‑0.1份、阴离子表面活性剂0.08‑1.9份、水50‑70份，该处理剂具有优异的阻燃性、防潮性和抗菌性能。

Description

一种书画艺术品阻燃防潮抗菌处理剂及其制备方法
技术领域
本发明涉及艺术品保护技术领域，具体涉及一种书画艺术品阻燃防潮抗菌处理剂及其制备方法。
背景技术
对于书画艺术品来说，因为是用宣纸、绢、绫、帛等为主要原料，保存既怕潮湿又忌干燥，时间久了就很容易被虫蚀，画面酥脆老化、生霉、破损。书画艺术品的收藏保护，受温度、湿度、空气污染、灰尘、光纤、昆虫、微生物等环境因素的影响。潮湿和干燥会引起纸纤维收缩与膨胀等性质的变化，对书画艺术品的破坏性极大。同时，由于书画艺术品本身原料的限制，其不具有阻燃效果，在遇到明火时容易发生燃烧的现象，现有书画艺术品，在保存方面还未对其阻燃效果加以重视。
霉菌、细菌是书画艺术品常见病害之一，对于此类病害，我国上世纪七、八十年代就已经开始研究，并且取得了显著的效果，如环氧乙烷混合气体灭菌、氮气灭菌、冷冻干燥灭菌等灭菌方式，不仅对书画艺术品本体没有伤害，且对环境污染小、操作环境对工作人员无害，特别是环氧乙烷混合气体灭菌，穿透力强，灭菌效果好，但是操作起来却比较复杂，且成本较高。
现有的针对书画艺术品的处理剂，或针对某一方面性能保护比较突出，尚未见对于书画艺术品的阻燃性、防潮性、抗菌性等综合性能比较突出的处理剂的报道。
发明内容
(一)解决的技术问题
针对现有技术的不足，本发明提供了一种书画艺术品阻燃防潮抗菌处理剂及其制备方法，使得经本发明处理过的书画艺术品同时具有良好的阻燃性、防潮性和抗菌性能。
(二)技术方案
为实现以上目的，本发明通过以下技术方案予以实现：
一种书画艺术品阻燃防潮抗菌处理剂，包括以下重量份的原料：硅酸镁为5-10份、三聚磷酸铝为7-12份、氮化硅为6-10份、聚对苯二甲酸乙二醇酯2-7份、硼酸锌为0.5-3份、藻脘酸盐2-8份、氯化铝为1-3份、膨润土4-8份、碳酸钙6-12份、高岭土3-7份，苯乙烯1-5份、丙烯酸酯3-6份、甘油4-9份、磷酸二氢铵3-10份、苯并咪唑氨基甲酸甲酯5-13份、2,4,5,6-四氯-1,3苯二甲腈6-10份、聚六亚甲基双胍盐4-9份、氧化锌0.2-0.7份、成膜助剂0.03-0.1份、阴离子表面活性剂0.08-1.9份、水50-70份。
优选的，包括以下重量份的原料：硅酸镁为6-9份、三聚磷酸铝为8-11份、氮化硅为7-9份、聚对苯二甲酸乙二醇酯4-6份、硼酸锌为1-2份、藻脘酸盐4-7份、氯化铝为1.5-2份、膨润土5-7份、碳酸钙8-11份、高岭土4-6份，苯乙烯2-3份、丙烯酸酯4-5份、甘油6-8份、磷酸二氢铵5-7份、苯并咪唑氨基甲酸甲酯6-10份、2,4,5,6-四氯-1,3苯二甲腈7-9份、聚六亚甲基双胍盐6-8份、氧化锌0.3-0.5份、成膜助剂0.05-0.07份、阴离子表面活性剂0.1-1.5份、水60-70份。
优选的，包括以下重量份的原料：硅酸镁为7份、三聚磷酸铝为9份、氮化硅为8份、聚对苯二甲酸乙二醇酯5份、硼酸锌为1.5份、藻脘酸盐5份、氯化铝为2份、膨润土6份、碳酸钙10份、高岭土5份，苯乙烯2份、丙烯酸酯4份、甘油7份、磷酸二氢铵6份、苯并咪唑氨基甲酸甲酯8份、2,4,5,6-四氯-1,3苯二甲腈8份、聚六亚甲基双胍盐7份、氧化锌0.4份、成膜助剂0.06份、阴离子表面活性剂1份、水65份。
优选的，包括以下重量份的原料：硅酸镁为8份、三聚磷酸铝为10份、氮化硅为8份、聚对苯二甲酸乙二醇酯4份、硼酸锌为2份、藻脘酸盐6份、氯化铝为1.5份、膨润土5份、碳酸钙9份、高岭土4份，苯乙烯2.5份、丙烯酸酯5份、甘油6份、磷酸二氢铵6份、苯并咪唑氨基甲酸甲酯9份、2,4,5,6-四氯-1,3苯二甲腈9份、聚六亚甲基双胍盐7份、氧化锌0.3份、成膜助剂0.05份、阴离子表面活性剂1.2份、水68份。
进一步的，成膜助剂为丙二醇丁醚、丙二醇甲醚醋酸酯、十二碳醇酯、己二醇丁醚醋酸酯中的一种或几种。
进一步的，阴离子表面活性剂为月桂酸、月桂醇硫酸钠、二辛基琥珀酸磺酸钠、十二烷基苯磺酸钠中的一种或几种。
上述书画艺术品阻燃防潮抗菌处理剂的制备方法为：将硅酸镁、三聚磷酸铝、氮化硅、硼酸锌、藻脘酸盐、氯化铝、膨润土、碳酸钙、高岭土、氧化锌进行超微粉碎，粉碎4-5次，过500-600目筛，将聚对苯二甲酸乙二醇酯、苯乙烯、丙烯酸酯、甘油、磷酸二氢铵、苯并咪唑氨基甲酸甲酯、2,4,5,6-四氯-1,3苯二甲腈、聚六亚甲基双胍盐、成膜助剂、阴离子表面活性剂和水与上述粉碎后的原料粉末混合，进行超声高速分散，超声频率为40-50KHz，分散速度为5000-5100r/min，分散时间为30-50min，混合均匀后得处理剂。
(三)有益效果
本发明提供了一种书画艺术品阻燃防潮抗菌处理剂及其制备方法，其具有如下有益效果：
1、本发明以三聚磷酸铝为、氮化硅作为主阻燃剂，同时硅酸镁、聚对苯二甲酸乙二醇酯、硼酸锌、藻脘酸盐、氯化铝作为增效剂，使得该处理剂对书画艺术品的阻燃效果显著。
2、由于书画艺术品本身的材质为纤维素，是由葡萄糖组成的大分子多糖，多糖表面羟基较多，阴离子表面活性剂的亲水基能够与羟基相结合，而阴离子表面活性剂的疏水基一致朝外，疏水基与水的亲和力小，同时配合丙烯酸酯、甘油、成膜助剂等组分，使得该处理剂对书画艺术品的防潮效果显著。
3、苯并咪唑氨基甲酸甲酯、2,4,5,6-四氯-1,3苯二甲腈和聚六亚甲基双胍盐均具有良好的抗菌防霉效果，且三者与氧化锌复配可以起到协同增效的作用，使整个体系的抗菌效果更好。
4、本发明各组分间协同作用，整个体系的组分均匀分布和稳定，使用后在书画艺术品表面快速形成一层保护膜，使各组分能够稳定地附着在书画艺术品表面，有效提高书画艺术品的阻燃性、防潮性和抗菌性等综合性能。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
一种书画艺术品阻燃防潮抗菌处理剂，包括以下重量份的原料：硅酸镁为5份、三聚磷酸铝为11份、氮化硅为6份、聚对苯二甲酸乙二醇酯6份、硼酸锌为0.5份、藻脘酸盐7份、氯化铝为1份、膨润土7份、碳酸钙6份、高岭土6份，苯乙烯1份、丙烯酸酯5份、甘油4份、磷酸二氢铵7份、苯并咪唑氨基甲酸甲酯5份、2,4,5,6-四氯-1,3苯二甲腈9份、聚六亚甲基双胍盐4份、氧化锌0.5份、丙二醇丁醚0.03份、十二烷基苯磺酸钠1.5份、水50份。
上述书画艺术品阻燃防潮抗菌处理剂的制备方法为：将硅酸镁、三聚磷酸铝、氮化硅、硼酸锌、藻脘酸盐、氯化铝、膨润土、碳酸钙、高岭土、氧化锌进行超微粉碎，粉碎5次，过600目筛，将聚对苯二甲酸乙二醇酯、苯乙烯、丙烯酸酯、甘油、磷酸二氢铵、苯并咪唑氨基甲酸甲酯、2,4,5,6-四氯-1,3苯二甲腈、聚六亚甲基双胍盐、成膜助剂、阴离子表面活性剂和水与上述粉碎后的原料粉末混合，进行超声高速分散，超声频率为50KHz，分散速度为5100r/min，分散时间为30min，混合均匀后得处理剂。
实施例2：
一种书画艺术品阻燃防潮抗菌处理剂，包括以下重量份的原料：硅酸镁为10份、三聚磷酸铝为8份、氮化硅为10份、聚对苯二甲酸乙二醇酯4份、硼酸锌为3份、藻脘酸盐4份、氯化铝为3份、膨润土5份、碳酸钙12份、高岭土4份，苯乙烯5份、丙烯酸酯4份、甘油9份、磷酸二氢铵5份、苯并咪唑氨基甲酸甲酯13份、2,4,5,6-四氯-1,3苯二甲腈7份、聚六亚甲基双胍盐9份、氧化锌0.3份、丙二醇甲醚醋酸酯0.1份、二辛基琥珀酸磺酸钠0.05份、水60份。
上述书画艺术品阻燃防潮抗菌处理剂的制备方法为：将硅酸镁、三聚磷酸铝、氮化硅、硼酸锌、藻脘酸盐、氯化铝、膨润土、碳酸钙、高岭土、氧化锌进行超微粉碎，粉碎4次，过500-600目筛，将聚对苯二甲酸乙二醇酯、苯乙烯、丙烯酸酯、甘油、磷酸二氢铵、苯并咪唑氨基甲酸甲酯、2,4,5,6-四氯-1,3苯二甲腈、聚六亚甲基双胍盐、成膜助剂、阴离子表面活性剂和水与上述粉碎后的原料粉末混合，进行超声高速分散，超声频率为40KHz，分散速度为5000r/min，分散时间为50min，混合均匀后得处理剂。
实施例3：
一种书画艺术品阻燃防潮抗菌处理剂，包括以下重量份的原料：硅酸镁为6份、三聚磷酸铝为12份、氮化硅为7份、聚对苯二甲酸乙二醇酯7份、硼酸锌为1份、藻脘酸盐8份、氯化铝为1.5份、膨润土8份、碳酸钙8份、高岭土7份，苯乙烯2份、丙烯酸酯6份、甘油6份、磷酸二氢铵10份、苯并咪唑氨基甲酸甲酯6份、2,4,5,6-四氯-1,3苯二甲腈10份、聚六亚甲基双胍盐6份、氧化锌0.7份、十二碳醇酯0.05份、月桂醇硫酸钠1.9份、水70份。其制备方法同实施例1。
实施例4：
一种书画艺术品阻燃防潮抗菌处理剂，包括以下重量份的原料：硅酸镁为9份、三聚磷酸铝为7份、氮化硅为9份、聚对苯二甲酸乙二醇酯2份、硼酸锌为2份、藻脘酸盐2份、氯化铝为2份、膨润土4份、碳酸钙11份、高岭土3份，苯乙烯3份、丙烯酸酯3份、甘油8份、磷酸二氢铵3份、苯并咪唑氨基甲酸甲酯10份、2,4,5,6-四氯-1,3苯二甲腈6份、聚六亚甲基双胍盐8份、氧化锌0.2份、己二醇丁醚醋酸酯0.07份、月桂酸0.08份、水65份。其制备方法同实施例1。
实施例5：
优选的，包括以下重量份的原料：硅酸镁为7份、三聚磷酸铝为9份、氮化硅为8份、聚对苯二甲酸乙二醇酯5份、硼酸锌为1.5份、藻脘酸盐5份、氯化铝为2份、膨润土6份、碳酸钙10份、高岭土5份，苯乙烯2份、丙烯酸酯4份、甘油7份、磷酸二氢铵6份、苯并咪唑氨基甲酸甲酯8份、2,4,5,6-四氯-1,3苯二甲腈8份、聚六亚甲基双胍盐7份、氧化锌0.4份、十二碳醇酯0.06份、十二烷基苯磺酸钠1份、水65份。其制备方法同实施例1。
实施例6：
优选的，包括以下重量份的原料：硅酸镁为8份、三聚磷酸铝为10份、氮化硅为8份、聚对苯二甲酸乙二醇酯4份、硼酸锌为2份、藻脘酸盐6份、氯化铝为1.5份、膨润土5份、碳酸钙9份、高岭土4份，苯乙烯2.5份、丙烯酸酯5份、甘油6份、磷酸二氢铵6份、苯并咪唑氨基甲酸甲酯9份、2,4,5,6-四氯-1,3苯二甲腈9份、聚六亚甲基双胍盐7份、氧化锌0.3份、己二醇丁醚醋酸酯0.05份、二辛基琥珀酸磺酸钠1.2份、水68份。其制备方法同实施例1。
试验例
采用实施例1-6制得的处理剂分别对同一批次的旧书进行处理，分别进行阻燃性能测试、抗菌性能测试、防潮性能测试，采用未经过处理的一组在相同的条件下测试作为对照组，检测结果如表1所示。
表1：
Figure BDA0002239542470000071
综上，本发明实施例具有如下有益效果：上述测试结果表明，本发明实施例1-6制得的处理剂，其阻燃性能、防潮性能、抗菌性能效果显著。
以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。

Claims (8)

1.一种书画艺术品阻燃防潮抗菌处理剂，其特征在于，包括以下重量份的原料：硅酸镁为5-10份、三聚磷酸铝为7-12份、氮化硅为6-10份、聚对苯二甲酸乙二醇酯2-7份、硼酸锌为0.5-3份、藻脘酸盐2-8份、氯化铝为1-3份、膨润土4-8份、碳酸钙6-12份、高岭土3-7份，苯乙烯1-5份、丙烯酸酯3-6份、甘油4-9份、磷酸二氢铵3-10份、苯并咪唑氨基甲酸甲酯5-13份、2,4,5,6-四氯-1,3苯二甲腈6-10份、聚六亚甲基双胍盐4-9份、氧化锌0.2-0.7份、成膜助剂0.03-0.1份、阴离子表面活性剂0.08-1.9份、水50-70份。
2.如权利要求1所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，包括以下重量份的原料：硅酸镁为6-9份、三聚磷酸铝为8-11份、氮化硅为7-9份、聚对苯二甲酸乙二醇酯4-6份、硼酸锌为1-2份、藻脘酸盐4-7份、氯化铝为1.5-2份、膨润土5-7份、碳酸钙8-11份、高岭土4-6份，苯乙烯2-3份、丙烯酸酯4-5份、甘油6-8份、磷酸二氢铵5-7份、苯并咪唑氨基甲酸甲酯6-10份、2,4,5,6-四氯-1,3苯二甲腈7-9份、聚六亚甲基双胍盐6-8份、氧化锌0.3-0.5份、成膜助剂0.05-0.07份、阴离子表面活性剂0.1-1.5份、水60-70份。
3.如权利要求2所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，包括以下重量份的原料：硅酸镁为7份、三聚磷酸铝为9份、氮化硅为8份、聚对苯二甲酸乙二醇酯5份、硼酸锌为1.5份、藻脘酸盐5份、氯化铝为2份、膨润土6份、碳酸钙10份、高岭土5份，苯乙烯2份、丙烯酸酯4份、甘油7份、磷酸二氢铵6份、苯并咪唑氨基甲酸甲酯8份、2,4,5,6-四氯-1,3苯二甲腈8份、聚六亚甲基双胍盐7份、氧化锌0.4份、成膜助剂0.06份、阴离子表面活性剂1份、水65份。
4.如权利要求2所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，包括以下重量份的原料：硅酸镁为8份、三聚磷酸铝为10份、氮化硅为8份、聚对苯二甲酸乙二醇酯4份、硼酸锌为2份、藻脘酸盐6份、氯化铝为1.5份、膨润土5份、碳酸钙9份、高岭土4份，苯乙烯2.5份、丙烯酸酯5份、甘油6份、磷酸二氢铵6份、苯并咪唑氨基甲酸甲酯9份、2,4,5,6-四氯-1,3苯二甲腈9份、聚六亚甲基双胍盐7份、氧化锌0.3份、成膜助剂0.05份、阴离子表面活性剂1.2份、水68份。
5.如权利要求1所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，所述成膜助剂为丙二醇丁醚、丙二醇甲醚醋酸酯、十二碳醇酯、己二醇丁醚醋酸酯中的一种或几种。
6.如权利要求1所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，所述阴离子表面活性剂为月桂酸、月桂醇硫酸钠、二辛基琥珀酸磺酸钠、十二烷基苯磺酸钠中的一种或几种。
7.如权利要求1-6任一项所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，该处理剂的制备方法为：将硅酸镁、三聚磷酸铝、氮化硅、硼酸锌、藻脘酸盐、氯化铝、膨润土、碳酸钙、高岭土、氧化锌进行超微粉碎，粉碎4-5次，过500-600目筛，将聚对苯二甲酸乙二醇酯、苯乙烯、丙烯酸酯、甘油、磷酸二氢铵、苯并咪唑氨基甲酸甲酯、2,4,5,6-四氯-1,3苯二甲腈、聚六亚甲基双胍盐、成膜助剂、阴离子表面活性剂和水与上述粉碎后的原料粉末混合，进行超声高速分散，混合均匀后得处理剂。
8.如权利要求7所述的书画艺术品阻燃防潮抗菌处理剂，其特征在于，超声高速分散时，超声频率为40-50KHz，分散速度为5000-5100r/min，分散时间为30-50min。
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