CN110628132A - 一种聚丙烯用阻燃母粒、其制备方法及应用 - Google Patents

一种聚丙烯用阻燃母粒、其制备方法及应用 Download PDF

Info

Publication number
CN110628132A
CN110628132A CN201911034445.0A CN201911034445A CN110628132A CN 110628132 A CN110628132 A CN 110628132A CN 201911034445 A CN201911034445 A CN 201911034445A CN 110628132 A CN110628132 A CN 110628132A
Authority
CN
China
Prior art keywords
parts
flame
polypropylene
retardant
master batch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911034445.0A
Other languages
English (en)
Inventor
刘春晓
张雪
刘平平
车雪梅
从文韬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yantai Geruien Polymer Materials Co Ltd
Original Assignee
Yantai Geruien Polymer Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yantai Geruien Polymer Materials Co Ltd filed Critical Yantai Geruien Polymer Materials Co Ltd
Priority to CN201911034445.0A priority Critical patent/CN110628132A/zh
Publication of CN110628132A publication Critical patent/CN110628132A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34928—Salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/10—Encapsulated ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种聚丙烯用阻燃母粒，按重量份数计，包括如下组分：载体10‑30份、阻燃剂60‑80份、阻燃协效剂10‑20份、硅烷偶联剂0.5‑2份、抗氧剂0.1‑0.2份和增韧剂1‑2份，该聚丙烯用阻燃母粒可应用于制备阻燃型聚丙烯。本发明的有益效果是：本发明阻燃母粒成炭性好、阻燃效率高且能遏制玻纤增强聚丙烯材料燃烧时的“烛芯效应”，当材料燃烧时，可形成致密的壳核结构的炭层，避免了熔滴现象，可有效降低材料燃烧时的热释放速率，从而提高材料的阻燃效率。

Description

一种聚丙烯用阻燃母粒、其制备方法及应用
技术领域
本发明涉及阻燃剂应用领域，尤其涉及一种聚丙烯用阻燃母粒、其制备方法及应用。
背景技术
随着科技进步，诸多方面都开始要求轻质材料，金属材料由于不适合成型复杂的形状，且重量较重、价格昂贵，限制了它在很多零件中的应用。而聚丙烯材料由于重量轻、价格便宜、可任意注塑成型，经玻纤增强改性后，逐步取代金属材料、ABS树脂等，多用于产品的结构零件上。
聚丙烯材料属易燃材料，氧指数为17％左右。玻纤的加入可以提高聚丙烯的热稳定性，使增强后的材料氧指数可达21.0％，但玻纤增强材料一旦燃烧，由于玻纤的“烛芯效应”，传热快、燃烧速度快、火苗大，较非玻纤增强聚丙烯更难于阻燃。
卤系阻燃剂由于燃烧时易产生有毒、腐蚀性气体，且生烟量大，目前，用于玻纤增强聚丙烯材料的阻燃剂多为无机金属氢氧化物和膨胀体系阻燃剂。金属氢氧化物的添加量多、阻燃效率低，所以单独应用较少；膨胀体系阻燃剂添加量相对较少，应用越来越多，但大多膨胀阻燃剂用于玻纤增强聚丙烯中成炭性仍不够，易产生滴落现象。
发明内容
本发明针对现有玻纤增强聚丙烯材料用阻燃剂的阻燃效果差的问题，提供一种聚丙烯用阻燃母粒、其制备方法及应用。
本发明解决上述技术问题的技术方案如下：一种聚丙烯用阻燃母粒，按重量份数计，包括如下组分：载体10-30份、阻燃剂60-80份、阻燃协效剂10-20份、硅烷偶联剂0.5-2份、抗氧剂0.1-0.2份和增韧剂1-2份。
所述载体为共聚聚丙烯、均聚聚丙烯、低密度聚乙烯或超低密度聚乙烯中的一种或多种。
所述阻燃剂由以下重量分数的物质组成：密胺包覆聚磷酸铵30-50％、三聚氰胺氰尿酸盐10-30％、双季戊四醇10-20％、氢氧化镁5-15％和二氧化硅8-10％。
所述阻燃协效剂为蒙脱土、有机蒙脱土、滑石粉、水滑石、针状硅灰石中的一种或多种。上述聚丙烯用阻燃母粒的制备方法为：按重量份依次称取各组分，将载体加入到高速搅拌机中，开动高搅机，转速为200r/min，温度为180℃，加入硅烷偶联剂、抗氧剂和增韧剂，继续搅拌3-8min；再加入剩余组分，保持温度继续搅拌10min，转移至双螺杆挤出机料斗中，挤出后造粒即得。
本发明聚丙烯用阻燃母粒可用于制备纤维增强型阻燃聚丙烯，其中各组分所占重量份数如下：聚丙烯用阻燃母粒份10-30份、聚丙烯基材40-70份、长玻璃纤维20-40份。
所述长玻璃纤维长度为10-15mm。
本发明的有益效果是：本发明阻燃母粒成炭性好、阻燃效率高且能遏制玻纤增强聚丙烯材料燃烧时的“烛芯效应”，当材料燃烧时，可形成致密的壳核结构的炭层，避免了熔滴现象，可有效降低材料燃烧时的热释放速率，从而提高材料的阻燃效率。
具体实施方式
以下结合实例对本发明进行描述，所举实例只用于解释本发明，并非用于限定本发明的范围。
实施例1
一种聚丙烯用阻燃母粒，按重量份数计，包括如下组分：共聚聚丙烯10份、阻燃剂80份、蒙脱土20份、硅烷偶联剂KH550 2份、抗氧剂168 0.1份和增韧剂乙烯-丙烯共聚物2份。
阻燃剂由以下重量分数的物质组成：密胺包覆聚磷酸铵30％、三聚氰胺氰尿酸盐30％、双季戊四醇20％、氢氧化镁12％和二氧化硅8％。
本实施例聚丙烯用阻燃母粒的制备方法的步骤为：按重量份依次称取各组分，将载体加入到高速搅拌机中，开动高搅机，转速为200r/min，温度为180℃，加入硅烷偶联剂、抗氧剂和增韧剂，继续搅拌3-8min；再加入剩余组分，保持温度继续搅拌10min，转移至双螺杆挤出机料斗中，挤出后造粒即得。
采用本实施例制备的纤维增强型阻燃聚丙烯，包括以下组分：聚丙烯用阻燃母粒份10份、聚丙烯基材40份、长度为10mm的长玻璃纤维40份；其制备方法为：将各组分混合均匀后采用双螺杆挤出机挤出，冷却成型。
实施例2
一种聚丙烯用阻燃母粒，按重量份数计，包括如下组分：均聚聚丙烯20份、阻燃剂70份、滑石粉15份、硅烷偶联剂KH560 1.2份、抗氧剂1010 0.15份和增韧剂乙烯-辛烯共聚物1.5份。
阻燃剂由以下重量分数的物质组成：密胺包覆聚磷酸铵50％、三聚氰胺氰尿酸盐10％、双季戊四醇20％、氢氧化镁10％和二氧化硅10％。
本实施例聚丙烯用阻燃母粒的制备方法的步骤为：按重量份依次称取各组分，将载体加入到高速搅拌机中，开动高搅机，转速为200r/min，温度为180℃，加入硅烷偶联剂、抗氧剂和增韧剂，继续搅拌3-8min；再加入剩余组分，保持温度继续搅拌10min，转移至双螺杆挤出机料斗中，挤出后造粒即得。
采用本实施例制备的纤维增强型阻燃聚丙烯，包括以下组分：聚丙烯用阻燃母粒份20份、聚丙烯基材55份、长度为11mm的长玻璃纤维30份；其制备方法为：将各组分混合均匀后采用双螺杆挤出机挤出，冷却成型。
实施例3
一种聚丙烯用阻燃母粒，按重量份数计，包括如下组分：低密度聚乙烯30份、阻燃剂60份、水滑石10份、硅烷偶联剂KH550 0.5份、抗氧剂168 0.2份和增韧剂乙烯-丁烯共聚物1份。
阻燃剂由以下重量分数的物质组成：密胺包覆聚磷酸铵40％、三聚氰胺氰尿酸盐20％、双季戊四醇15％、氢氧化镁15％和二氧化硅10％。
本实施例聚丙烯用阻燃母粒的制备方法的步骤为：按重量份依次称取各组分，将载体加入到高速搅拌机中，开动高搅机，转速为200r/min，温度为180℃，加入硅烷偶联剂、抗氧剂和增韧剂，继续搅拌3-8min；再加入剩余组分，保持温度继续搅拌10min，转移至双螺杆挤出机料斗中，挤出后造粒即得。
采用本实施例制备的纤维增强型阻燃聚丙烯，包括以下组分：聚丙烯用阻燃母粒份30份、聚丙烯基材70份、长度为13mm的长玻璃纤维20份；其制备方法为：将各组分混合均匀后采用双螺杆挤出机挤出，冷却成型。
实施例4
一种聚丙烯用阻燃母粒，按重量份数计，包括如下组分：共聚聚丙烯5份、均聚聚丙烯10份、阻燃剂80份、针状硅灰石17份、硅烷偶联剂KH560 1份、抗氧剂1010 0.1份和增韧剂乙烯-辛烯共聚物1.5份。
阻燃剂由以下重量分数的物质组成：密胺包覆聚磷酸铵47％、三聚氰胺氰尿酸盐30％、双季戊四醇10％、氢氧化镁5％和二氧化硅8％。
本实施例聚丙烯用阻燃母粒的制备方法的步骤为：按重量份依次称取各组分，将载体加入到高速搅拌机中，开动高搅机，转速为200r/min，温度为180℃，加入硅烷偶联剂、抗氧剂和增韧剂，继续搅拌3-8min；再加入剩余组分，保持温度继续搅拌10min，转移至双螺杆挤出机料斗中，挤出后造粒即得。
采用本实施例制备的纤维增强型阻燃聚丙烯，包括以下组分：聚丙烯用阻燃母粒份20份、聚丙烯基材60份、长度为15mm的长玻璃纤维25份；其制备方法为：将各组分混合均匀后采用双螺杆挤出机挤出，冷却成型。
对比例
一种纤维增强型聚丙烯，包括70重量份的聚丙烯基材和30重量份长度为11mm的长玻璃纤维，采用双螺杆挤出机挤出、冷却成型制得。
将实施例1-4玻纤增强型阻燃聚丙烯和对比例玻纤增强型聚丙烯进行相关测试，结果如表1所示。
表1.实施例1-4和对比例聚丙烯材料检测结果
备注：
1、“√”表示通过测试；“×”表示未通过测试。
2、测试方法
材料的成炭情况及热分析：锥形量热仪；
垂直燃烧测试：ANSI/UL-94-1985；
材料的灼热丝可燃性试验：GB/T 5169.12-2013；
材料的灼热丝起燃性试验：GB/T 5169.13-2013。
由表1测试数据对比分析可以看出，本发明的阻燃母粒用于玻纤增强聚丙烯材料中后可使材料达到UL94 V-0(1.0mm)，同时可通过GWIT 750℃(1.5mm)、GWFI 850℃(1.5mm)灼热丝测试。材料燃烧后的炭层致密，具有壳核结构，且明显降低了热释放速率。
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (7)

1.一种聚丙烯用阻燃母粒，其特征在于，按重量份数计，包括如下组分：载体10-30份、阻燃剂60-80份、阻燃协效剂10-20份、硅烷偶联剂0.5-2份、抗氧剂0.1-0.2份和增韧剂1-2份。
2.根据权利要求1所述的聚丙烯用阻燃母粒，其特征在于，所述载体为共聚聚丙烯、均聚聚丙烯、低密度聚乙烯或超低密度聚乙烯中的一种或多种。
3.根据权利要求1所述的聚丙烯用阻燃母粒，，其特征在于，所述阻燃剂由以下重量分数的物质组成：密胺包覆聚磷酸铵30-50％、三聚氰胺氰尿酸盐10-30％、双季戊四醇10-20％、氢氧化镁5-15％和二氧化硅8-10％。
4.根据权利要求1所述的聚丙烯用阻燃母粒，其特征在于，所述阻燃协效剂为蒙脱土、有机蒙脱土、滑石粉、水滑石、针状硅灰石中的一种或多种。
5.一种如权利要求1-4任一项所述的聚丙烯用阻燃母粒的制备方法，其特征在于，包括以下步骤：按重量份依次称取各组分，将载体加入到高速搅拌机中，开动高搅机，转速为200r/min，温度为180℃，加入硅烷偶联剂、抗氧剂和增韧剂，继续搅拌3-8min；再加入剩余组分，保持温度继续搅拌10min，转移至双螺杆挤出机料斗中，挤出后造粒即得。
6.一种纤维增强型阻燃聚丙烯，其特征在于，由权利要求1-4任一项所述的聚丙烯用阻燃母粒、聚丙烯基材和长玻璃纤维组成，各组分所占重量份数如下：聚丙烯用阻燃母粒10-30份、聚丙烯基材40-70份、长玻璃纤维20-40份。
7.根据权利要求1所述的纤维增强型阻燃聚丙烯，其特征在于，所述长玻璃纤维长度为10-15mm。
CN201911034445.0A 2019-10-29 2019-10-29 一种聚丙烯用阻燃母粒、其制备方法及应用 Pending CN110628132A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911034445.0A CN110628132A (zh) 2019-10-29 2019-10-29 一种聚丙烯用阻燃母粒、其制备方法及应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911034445.0A CN110628132A (zh) 2019-10-29 2019-10-29 一种聚丙烯用阻燃母粒、其制备方法及应用

Publications (1)

Publication Number Publication Date
CN110628132A true CN110628132A (zh) 2019-12-31

Family

ID=68978009

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911034445.0A Pending CN110628132A (zh) 2019-10-29 2019-10-29 一种聚丙烯用阻燃母粒、其制备方法及应用

Country Status (1)

Country Link
CN (1) CN110628132A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114031844A (zh) * 2021-10-25 2022-02-11 浙江旭森非卤消烟阻燃剂有限公司 连续长玻纤增强聚丙烯用无卤阻燃母粒及其制备方法
CN114736461A (zh) * 2022-05-05 2022-07-12 清远市一丞阻燃材料有限公司 一种高容量的阻燃母粒

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212228A (zh) * 2010-08-17 2011-10-12 扬州大学 一种无卤阻燃聚丙烯母料
CN107964167A (zh) * 2017-12-14 2018-04-27 江苏万纳普新材料科技有限公司 一种高加工温度阻燃长玻纤增强聚丙烯材料及其制备方法
CN108752732A (zh) * 2018-04-27 2018-11-06 苏州银禧新能源复合材料有限公司 一种玻璃纤维改性无卤阻燃聚丙烯材料、电池外壳及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212228A (zh) * 2010-08-17 2011-10-12 扬州大学 一种无卤阻燃聚丙烯母料
CN107964167A (zh) * 2017-12-14 2018-04-27 江苏万纳普新材料科技有限公司 一种高加工温度阻燃长玻纤增强聚丙烯材料及其制备方法
CN108752732A (zh) * 2018-04-27 2018-11-06 苏州银禧新能源复合材料有限公司 一种玻璃纤维改性无卤阻燃聚丙烯材料、电池外壳及其制备方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
于守武 等: "《高分子材料改性—原理及技术》", 31 May 2015, 知识产权出版社 *
徐勇 等: "《高分子科学与工程实验》", 31 May 2019, 东南大学出版社 *
杨明山等: "《现代工程塑料改性 理论与实践》", 31 July 2009, 中国轻工业出版社 *
欧育湘 等: "《塑料助剂系列丛书 阻燃剂》", 30 September 2009, 国防工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114031844A (zh) * 2021-10-25 2022-02-11 浙江旭森非卤消烟阻燃剂有限公司 连续长玻纤增强聚丙烯用无卤阻燃母粒及其制备方法
CN114031844B (zh) * 2021-10-25 2023-10-03 浙江旭森阻燃剂股份有限公司 连续长玻纤增强聚丙烯用无卤阻燃母粒及其制备方法
CN114736461A (zh) * 2022-05-05 2022-07-12 清远市一丞阻燃材料有限公司 一种高容量的阻燃母粒

Similar Documents

Publication Publication Date Title
Fu et al. Synergistic flame retardant mechanism of fumed silica in ethylene-vinyl acetate/magnesium hydroxide blends
CN101293983B (zh) 一种膨胀阻燃聚丙烯组合物及其制备方法
CN108250572B (zh) 一种可过ul94-5va高阻燃耐光热老化无卤环保阻燃聚丙烯材料及其制备方法
CN102585322B (zh) 一种易加工低烟无卤阻燃热收缩标识套管及制备与应用
CN102477184B (zh) 一种高光泽阻燃聚丙烯复合材料及其制备方法
CN101293984B (zh) 一种膨胀成炭阻燃聚丙烯组合物及其制备方法
CN109627567A (zh) 一种b1级阻燃辐照交联低烟无卤绝缘电缆料及其制备方法
CN110628132A (zh) 一种聚丙烯用阻燃母粒、其制备方法及应用
CN105482240B (zh) 一种无卤阻燃线性低密度聚乙烯材料的制备方法
CN1709968A (zh) 无卤膨胀型阻燃聚烯烃复合物
CN103183901A (zh) 无卤阻燃蓄电池壳体材料及其制备方法
CN103102593A (zh) 负载型金属氧化物催化协效无机阻燃聚丙烯复合材料及其制备方法
CN102492231B (zh) 一种无卤阻燃聚苯乙烯复合材料及其制备方法
CN105778281B (zh) 一种高灼热丝、低烟阻燃聚丙烯复合材料及其制备方法
CN102229719B (zh) 纳米介孔分子筛协效膨胀阻燃剂阻燃聚丙烯
CN110734608A (zh) 一种阻燃母粒及其在阻燃型聚丙烯材料中的应用
CN112745549A (zh) 一种无卤膨胀型的陶瓷化聚烯烃组合物及其制备方法和应用
CN112210161A (zh) 一种无卤隔氧层电缆料及其制备方法和用途
CN114933773B (zh) 一种耐寒无卤阻燃聚丙烯材料及其制备方法和应用
CN115873293B (zh) 制备阻燃发泡聚丙烯材料的组合物和阻燃发泡聚丙烯材料及其制备方法
Di et al. A novel EVA-based composite via ceramization toward excellent flame retardance performance and high-temperature resistance
CN112251019B (zh) 一种聚酰胺无卤阻燃剂组合物及其应用
CN108219427A (zh) 生物级透明阻燃聚碳酸酯复合物及其制备方法
CN108003607A (zh) 一种阻燃型导热尼龙复合材料及其制备方法
CN103333365A (zh) 复合无机阻燃剂及其在阻燃eva复合材料中的应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination