CN110621769A - Laundry detergent compositions - Google Patents
Laundry detergent compositions Download PDFInfo
- Publication number
- CN110621769A CN110621769A CN201880027340.XA CN201880027340A CN110621769A CN 110621769 A CN110621769 A CN 110621769A CN 201880027340 A CN201880027340 A CN 201880027340A CN 110621769 A CN110621769 A CN 110621769A
- Authority
- CN
- China
- Prior art keywords
- surfactant
- laundry detergent
- linear alkylbenzene
- detergent composition
- aqueous liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 239000003599 detergent Substances 0.000 title claims abstract description 42
- -1 alkyl ether carboxylic acid Chemical class 0.000 claims abstract description 71
- 239000004094 surface-active agent Substances 0.000 claims abstract description 48
- 239000007788 liquid Substances 0.000 claims abstract description 26
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 18
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 150000001298 alcohols Chemical class 0.000 claims abstract description 11
- 239000004753 textile Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 8
- 239000011574 phosphorus Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims abstract description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 238000005008 domestic process Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 description 19
- 239000000975 dye Substances 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 229920002873 Polyethylenimine Polymers 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 11
- 150000004996 alkyl benzenes Chemical class 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 238000007046 ethoxylation reaction Methods 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 108091005804 Peptidases Proteins 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 239000013522 chelant Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000007850 fluorescent dye Substances 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 3
- 108010065511 Amylases Proteins 0.000 description 3
- 102000013142 Amylases Human genes 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- 235000019418 amylase Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003752 hydrotrope Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 2
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 108090000787 Subtilisin Proteins 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 229940025131 amylases Drugs 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 239000000987 azo dye Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001860 citric acid derivatives Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- 238000004453 electron probe microanalysis Methods 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- KJPHTXTWFHVJIG-UHFFFAOYSA-N n-ethyl-2-[(6-methoxypyridin-3-yl)-(2-methylphenyl)sulfonylamino]-n-(pyridin-3-ylmethyl)acetamide Chemical compound C=1C=C(OC)N=CC=1N(S(=O)(=O)C=1C(=CC=CC=1)C)CC(=O)N(CC)CC1=CC=CN=C1 KJPHTXTWFHVJIG-UHFFFAOYSA-N 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 229960004063 propylene glycol Drugs 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- WWUZIQQURGPMPG-UHFFFAOYSA-N (-)-D-erythro-Sphingosine Natural products CCCCCCCCCCCCCC=CC(O)C(N)CO WWUZIQQURGPMPG-UHFFFAOYSA-N 0.000 description 1
- SFLSHLFXELFNJZ-QMMMGPOBSA-N (-)-norepinephrine Chemical compound NC[C@H](O)C1=CC=C(O)C(O)=C1 SFLSHLFXELFNJZ-QMMMGPOBSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 229940035437 1,3-propanediol Drugs 0.000 description 1
- KZYAYVSWIPZDKL-UHFFFAOYSA-N 1,4-diamino-2,3-dichloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=C(Cl)C(Cl)=C2N KZYAYVSWIPZDKL-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 1
- DRLIOHVXDBLHQM-UHFFFAOYSA-N 1-amino-3-(2-methoxyethoxy)propan-2-ol Chemical compound COCCOCC(O)CN DRLIOHVXDBLHQM-UHFFFAOYSA-N 0.000 description 1
- KODLUXHSIZOKTG-UHFFFAOYSA-N 1-aminobutan-2-ol Chemical compound CCC(O)CN KODLUXHSIZOKTG-UHFFFAOYSA-N 0.000 description 1
- NPEIGRBGMUJNFE-UHFFFAOYSA-N 1-aminohexan-1-ol Chemical compound CCCCCC(N)O NPEIGRBGMUJNFE-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- GPPXJGVECOPHES-UHFFFAOYSA-N 2-[2-methoxyethyl(methyl)amino]ethanol Chemical compound COCCN(C)CCO GPPXJGVECOPHES-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- ZULPATVQDRLYAC-UHFFFAOYSA-N 2-methyl-4-(methylamino)butan-2-ol Chemical compound CNCCC(C)(C)O ZULPATVQDRLYAC-UHFFFAOYSA-N 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
- REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical class OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
- SUTWPJHCRAITLU-UHFFFAOYSA-N 6-aminohexan-1-ol Chemical compound NCCCCCCO SUTWPJHCRAITLU-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
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- HUYWAWARQUIQLE-UHFFFAOYSA-N Isoetharine Chemical compound CC(C)NC(CC)C(O)C1=CC=C(O)C(O)=C1 HUYWAWARQUIQLE-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
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- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
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- OKBJQVCCZCGZHD-UHFFFAOYSA-M disodium;9-amino-5-anilino-7-phenylbenzo[a]phenazin-7-ium-4,10-disulfonate Chemical compound [Na+].[Na+].C12=CC(NC=3C=CC=CC=3)=C3C(S([O-])(=O)=O)=CC=CC3=C2N=C2C=C(S([O-])(=O)=O)C(N)=CC2=[N+]1C1=CC=CC=C1 OKBJQVCCZCGZHD-UHFFFAOYSA-M 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- DLNKOYKMWOXYQA-UHFFFAOYSA-N dl-pseudophenylpropanolamine Natural products CC(N)C(O)C1=CC=CC=C1 DLNKOYKMWOXYQA-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical group 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229960001268 isoetarine Drugs 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229960002748 norepinephrine Drugs 0.000 description 1
- SFLSHLFXELFNJZ-UHFFFAOYSA-N norepinephrine Natural products NCC(O)C1=CC=C(O)C(O)=C1 SFLSHLFXELFNJZ-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 125000001791 phenazinyl group Chemical class C1(=CC=CC2=NC3=CC=CC=C3N=C12)* 0.000 description 1
- DLNKOYKMWOXYQA-APPZFPTMSA-N phenylpropanolamine Chemical compound C[C@@H](N)[C@H](O)C1=CC=CC=C1 DLNKOYKMWOXYQA-APPZFPTMSA-N 0.000 description 1
- 229960000395 phenylpropanolamine Drugs 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003138 primary alcohols Chemical group 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 1
- RBYJOOWYRXEJAM-UHFFFAOYSA-M sodium;5,9-dianilino-7-phenylbenzo[a]phenazin-7-ium-4,10-disulfonate Chemical compound [Na+].C=1C=CC=CC=1[N+]1=C2C=C(NC=3C=CC=CC=3)C(S(=O)(=O)[O-])=CC2=NC(C2=CC=CC(=C22)S([O-])(=O)=O)=C1C=C2NC1=CC=CC=C1 RBYJOOWYRXEJAM-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- WWUZIQQURGPMPG-KRWOKUGFSA-N sphingosine Chemical compound CCCCCCCCCCCCC\C=C\[C@@H](O)[C@@H](N)CO WWUZIQQURGPMPG-KRWOKUGFSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical class OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
An aqueous liquid laundry detergent composition comprising: (i)5-19 wt% of LAS, (ii)0.5-8 wt% of alkyl ether carboxylic acid of the structureSurfactant (b): r2‑(OCH2CH2)n‑OCH2-COOH, wherein R2Is C16‑C18A linear alkyl chain; n is 10 to 25 and the ratio of (ii) to (i) is 0.05 to 1; (iii) at least 60% by weight of water; (iv)0-2 wt% of an ethoxylated alcohol nonionic surfactant, wherein the ratio of (iv) to (i) is 0-0.2; and (v)0-1 wt% of a phosphorus-containing chemical; wherein the composition optionally comprises an additional anionic surfactant, wherein the ratio of additional surfactant to (i) is from 0 to 0.55. A method of treating a textile, comprising: a) treating a textile with 1g/L of an aqueous solution of the composition; and b) contacting the solution for 10 minutes to 2 days, followed by rinsing and drying.
Description
Technical Field
The present invention provides laundry detergent compositions. In particular, the present invention relates to aqueous liquid laundry detergent compositions for use in domestic laundry.
Background
Aqueous household laundry detergent formulations comprising alkyl ether carboxylates in combination with other anionic surfactants as the primary surfactant are known. The alkyl ether carboxylates enhance the cleaning performance of the detergent and it is desirable to maximize this enhancement.
WO2016/180552(Unilever) discloses an enzymatic dispersant formulation for home laundry comprising an alkyl ether carboxylic acid, a protease, an anionic surfactant and optionally a nonionic surfactant. Exemplified are formulations comprising alkyl ether carboxylate and a surfactant system comprising linear alkylbenzene sulfonate, a nonionic surfactant and sodium lauryl ether sulfate in a weight ratio of 4:1: 5.
DE102013218614(Henkel) discloses liquid detergent formulations comprising a surfactant mixture comprising at least one ether carboxylate with improved cleaning performance, especially against greasy stains and/or at low temperatures. Exemplified are formulations comprising alkyl ether carboxylate and a surfactant system comprising linear alkylbenzene sulfonate, nonionic surfactant and lauryl ether sulfate in a weight ratio of 4:2: 5.
Disclosure of Invention
We have found that aqueous laundry detergent formulations with high ratios of linear alkylbenzene sulphonate to other non-alkyl ether carboxylate surfactants give much greater benefit from the addition of specific alkyl ether carboxylate surfactants.
In one aspect, the present invention provides an aqueous liquid laundry detergent composition comprising:
(i)5-19 wt% of a linear alkylbenzene sulphonate anionic surfactant,
(ii)0.5 to 8 wt% of an alkyl ether carboxylic acid anionic surfactant of the structure:
R2-(OCH2CH2)n-OCH2-COOH,
wherein:
R2is selected from C16-C18A linear alkyl chain; wherein n is selected from 10 to 25 and wherein the weight ratio of alkyl ether carboxylic acid to linear alkylbenzene sulfonate surfactant is from 0.05 to 1;
(iii) at least 60% by weight of water;
(iv)0-2 wt% of an ethoxylated alcohol nonionic surfactant, wherein the weight ratio of ethoxylated alcohol nonionic surfactant to linear alkylbenzene sulfonate surfactant is 0-0.2; and
(v)0-1 wt% of a phosphorus-containing chemical;
wherein the composition optionally comprises an additional anionic surfactant, wherein the weight ratio of additional surfactant to linear alkylbenzene sulphonate is from 0 to 0.55, preferably from 0 to 0.1.
In a second aspect, the present invention provides a domestic method of treating a textile, the method comprising the steps of:
a) treating the textile with at least 1g/L of an aqueous solution of a laundry detergent composition as defined in the first aspect; and the combination of (a) and (b),
b) the aqueous laundry detergent solution is left in contact with the textile for a period of time from 10 minutes to 2 days, and then the textile is rinsed and dried.
Detailed Description
Weight percentages (wt.%) summarized herein are weight percentages based on the total composition, unless otherwise specified.
The indefinite articles "a" and "an" as used herein mean at least one or more unless otherwise indicated.
Preferably, the laundry contains 0.3-3 wt.% of human sebum.
In the method aspect of the invention, the surfactant used is preferred as is preferred in the composition aspect of the invention.
The domestic method is preferably carried out in a domestic washing machine or by hand washing. The washing temperature is preferably 280-320K. The main wash time is preferably 10 to 60 minutes.
The textile product is preferably an item of clothing, bedding or tablecloth. Preferred articles of clothing are shirts, pants, undergarments and pullovers containing polyester cotton.
The pH of the composition is preferably 7 to 11, preferably 7 to 10. The pH may suitably be measured so that a dilution of 5g/L of the aqueous liquid laundry detergent in demineralised water has the pH indicated.
The compositions of the present invention may contain 0-1% by weight of a phosphorus-containing chemical. Thus, the formulations may (and preferably do) be free of phosphorous-containing chemicals, but when present, they may only be present at levels up to 1 wt% based on the total formulation.
The surfactants of the present invention can be neutralized with any suitable base. Typical amines used for neutralizing surfactants are monoethanolamine, triethanolamine, diisopropanolamine, triisopropanolamine, monoaminohexanol, 2- [ (2-methoxyethyl) methylamino ] ethanol, propanolamine, N-methylethanolamine, diethanolamine, monobutanolamine, isobutanol amine, monopentanolamine, 1-amino-3- (2-methoxyethoxy) -2-propanol, 2-methyl-4- (methylamino) -2-butanol, 6-amino-1-hexanol, heptanediol, isotataline (isoetarine), norepinephrine, sphingosine, phenylpropanolamine and mixtures thereof.
The surfactants of the present invention are preferably neutralized with aqueous sodium hydroxide.
Preferably, the aqueous liquid laundry detergent composition comprises less than or equal to 5 wt% (i.e. 0-5 wt%), more preferably less than or equal to 0.2 wt% (i.e. 0-0.2 wt%) of a hydrotrope (hydrotrope) selected from the group consisting of: ethylene glycol; 1, 3-propanediol; 1, 2-propanediol; 1, 4-butanediol; 1, 5-pentanediol; 1, 6-hexanediol; 2, 3-butanediol; 1, 3-butanediol; diethylene glycol; triethylene glycol; polyethylene glycol; glycerol formaldehyde dipropylene glycol; polypropylene glycol dipropylene glycol n-butyl ether; and mixtures thereof. Preferably, the low level of hydrotrope is selected from 1, 2-propanediol; dipropylene glycol; polypropylene glycol; 2, 3-butanediol; dipropylene glycol n-butyl ether; and mixtures thereof.
The detergent is preferably blue, green or violet in colour. The detergent is preferably transparent and has a maximum optical density (1cm) of 1.5 in the range of 400-700 nm.
The weight of the anionic surfactant is calculated as its protonated form.
Alkyl ether carboxylic acids
The liquid laundry compositions comprise from 0.5 to 8 wt%, preferably from 0.5 to 6 wt%, more preferably from 1 to 6 wt%, most preferably from 2 to 6 wt% of alkyl ether carboxylic acid anionic surfactant.
Weight of alkyl ether carboxylic acid in protonated form R2-(OCH2CH2)n-OCH2COOH calculation. They may be used as salts, for example sodium or amine salts.
The alkyl chain may be linear or branched, preferably it is linear.
The alkyl chain may be aliphatic or contain one cis or trans double bond.
Alkyl chain (R)2) Is selected from C16-C18A linear alkyl chain.
The alkyl ether carboxylic acids have n selected from 10 to 25, preferably 10 to 20.
The weight ratio of alkyl ether carboxylic acid to linear alkylbenzene sulphonate surfactant is from 0.05 to 1, preferably from 0.1 to 0.6.
Alkyl ether carboxylic acids are available from KaoHuntsmanAnd ClariantMost preferred are the sodium salts of alkyl ether carboxylates.
Alkyl ether carboxylic acid synthesis is discussed in the International Surfactants Organic Chemistry, edited by H.W.Stache (Marcel Dekker, New York 1996).
They can be synthesized by reaction of the corresponding alcohol ethoxylates with chloroacetic acid or sodium monochloroacetate in the presence of NaOH:
R2-(OCH2CH2)n-OH+NaOH+ClCH2COONa→R2-(OCH2CH2)n-OCH2COOH+NaCl+H2O
in this synthesis, residual R may be present2-(OCH2CH2)n-OH, preferably R in alkyl ether carboxylic acids2-(OCH2CH2)nThe content of-OH is from 0 to 10% by weight. Low levels of diethanoic acid and glycolic acid may be present as by-products.
NaCl from synthesis may be present in an aqueous liquid laundry detergent composition. Additional NaCl may be added to the composition.
Their alkyl ether carboxylic acids can also be synthesized by oxidation reactions:
R2-(OCH2CH2)n-O CH2CH2OH→R2-(OCH2CH2)n-OCH2COOH
the oxidation is usually carried out under basic conditions, using oxygen as oxidant in the presence of a metal catalyst such as Pd/Pt, as described in DE3135946, DE2816127 and EP 0304763.
Straight chain alkyl benzene sulfonate
The linear alkylbenzene sulphonate is present in an amount of from 5 to 19 wt%, preferably from 6 to 19 wt%, more preferably from 7 to 19 wt%, even more preferably from 8 to 19 wt%, most preferably from 9 to 19 wt%.
The linear alkyl benzene sulfonate is a neutralized form of linear alkyl benzene sulfonic acid. Neutralization can be carried out with any suitable base. Most preferred is the sodium salt.
Linear alkyl benzene sulphonic acids have the following structure:
wherein x + y is 7, 8, 9 or 10.
Preferably, x + y ═ 8 is present at a weight content greater than 28% by weight of the total linear alkylbenzene anionic surfactant content.
Preferably, x + y ═ 9 is present at a weight content greater than 28% by weight of the total linear alkylbenzene anionic surfactant content. Weight is expressed as protonated form.
Surfactants can be produced by a number of different routes. Synthesis is discussed in International Surfactants Organic Chemistry, edited by H.W.Stache (Marcel Dekker, New York 1996).
The linear alkyl benzene sulphonic acid may be prepared by sulphonation of linear alkyl benzene. Sulfation can be carried out with concentrated sulfuric acid, oleum or sulfur trioxide. Preferably linear alkyl benzene sulphonic acid produced by reacting linear alkyl benzene with sulphur trioxide.
Linear alkylbenzenes can be produced by a variety of routes. Examples include:
benzene may be alkylated with n-olefins using an HF catalyst.
Benzene can be alkylated with n-olefins in a fixed bed reactor using a solid acidic catalyst (DETAL process), such as an aluminosilicate.
Benzene may be alkylated with n-olefins using an aluminum chloride catalyst. Benzene may be alkylated with n-chlorinated paraffins using an aluminum chloride catalyst.
The weight percentage of linear alkylbenzene sulphonate surfactant relative to the total non-alkyl ether surfactant is preferably from 50 to 100 wt%, preferably from 60 to 100 wt%, more preferably from 70 to 10 wt%, most preferably from 80 to 100 wt%.
Water (W)
The liquid detergent composition is aqueous. Which comprises at least 60% by weight of water.
Preferably it comprises at least 65 wt.%, more preferably at least 70 wt.%, most preferably at least 75 wt.% water. Exemplary preferred weight ranges for the water content include 60 to 94.5 weight percent, preferably 62.5 to 92.5 weight percent, more preferably 65 to 90 weight percent.
Ethoxylated alcohol nonionic surfactant
Ethoxylated alcohol nonionic surfactants may be absent or present in the formulation. If present, it is present in an amount of up to 2% by weight.
The weight ratio of ethoxylated alcohol nonionic surfactant to linear alkylbenzene sulphonate surfactant is from 0 to 0.2. This means that the ethoxylated alcohol nonionic surfactant may not be present (so the weight ratio of ethoxylated alcohol nonionic surfactant to linear alkylbenzene sulphonate surfactant is 0); or if present, at most one fifth the weight content of the linear alkylbenzene sulphonate surfactant.
The nonionic surfactant is preferably a fatty alcohol ethoxylate nonionic surfactant.
The ethoxylated nonionic surfactant is preferably a primary alcohol ethoxylate, more preferably C ethoxylated with an average of 1 to 20 moles of ethylene oxide per mole of alcohol8-C20An aliphatic alcohol. Most preferably, the ethoxylated alcohol nonionic surfactant is selected from the group consisting of C having 7-9 moles of ethylene oxide per mole of alcohol12-C15An aliphatic primary alcohol; r2-(OCH2CH2)n-OH and R2-(OCH2CH2)n+1-OH。
Preferably, the alkyl chain is linear.
Additional surfactants
Aqueous liquid laundry detergents may contain additional surfactants, as described, for example, in "Surface Active Agents", Vol.1, Schwartz & Perry, Interscience 1949; volume 2, Schwartz, Perry & Berch, Interscience 1958; current versions of "McCutcheon's emulsifiers and Detergents", published by Manufacturing conditioners Company, or "Tenside-Taschenbuch", H.Stache, 2 nd edition, Carl Hauser Verlag, 1981, or International Surfactants, edited by Helmut W.Stache, Organic chemistry (Marcel Dekker 1996).
Preferably the weight ratio of additional surfactant (total) to linear alkylbenzene sulphonate is from 0 to 0.55. This means that no additional surfactant may be present (hence a weight ratio of additional surfactant to linear alkylbenzene sulphonate surfactant of 0); or if present, the additional surfactant, in an amount of up to 55% by weight of the linear alkylbenzene sulphonate surfactant.
Preferably the weight ratio of additional surfactant to linear alkylbenzene sulphonate is from 0 to 0.55, more preferably from 0 to 0.1. Exemplary preferred weight ratios of additional surfactant (when present) to linear alkylbenzene sulfonate include 0.01 to 0.55, more preferably 0.01 to 0.1.
The additional surfactant is preferably an anionic surfactant.
Therefore, it is preferred that the weight ratio of additional anionic surfactant to linear alkylbenzene sulphonate is from 0 to 0.55, more preferably from 0 to 0.1. Exemplary preferred weight ratios of additional anionic surfactant (when present) to linear alkylbenzene sulphonate comprise from 0.01 to 0.55, more preferably from 0.01 to 0.1.
Examples of suitable additional anionic detergent compounds are: alkyl ether sulfates, especially lauryl ether sulfate having 1-3 moles of ethoxylation; alkyl sulfates, especially by reacting straight or branched chain C8-C18Those obtained by alcohol sulphation; soap; alkyl (preferably methyl) ester sulfonates, and mixtures thereof. Alkyl ether sulfates and alkyl sulfates are particularly preferred.
Alkoxylated polyethyleneimines
The formulation may comprise an alkoxylated polyethyleneimine comprising a polyethyleneimine backbone, wherein the modification of the polyethyleneimine backbone is intended to render the polymer non-quaternized. Such materials may be represented as PEI (X) YAO, where X represents the molecular weight of unmodified PEI and Y represents the average moles of Alkoxylation (AO) per available NH in the unsubstituted polyethyleneimine backbone. Y is preferably from 7 to 40, more preferably from 16 to 26, most preferably from 18 to 22. X is selected to be about 300 to about 10000 weight average molecular weight, and is preferably about 600.
The alkoxylation is preferably selected from ethoxylation or propoxylation, or a combination of both, most preferably ethoxylation. The alkoxy chain may be terminated by a group selected from: h; CH (CH)3;SO3 -;CH2COO-;PO3 2-;C2H5(ii) a N-propyl, isopropyl; n-butyl; a tertiary butyl group; and sulfosuccinates, most preferably H.
Most preferably, the alkoxylated PEI is PEI (600)20 EO.
The alkoxylated polyethyleneimine may be contained in an amount of 0.1 to 10 wt%.
In certain embodiments, it is preferred that the aqueous liquid laundry detergent composition does not comprise from 1 to 8 wt% of alkoxylated polyethyleneimine.
Polymer and method of making same
The composition may comprise one or more additional polymers.
Examples are carboxymethylcellulose, poly (ethylene glycol), poly (vinyl alcohol), polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers, lauryl methacrylate/acrylic acid copolymers, and terephthalate polyester soil release polymers including polymers of aromatic dicarboxylic acids and alkylene glycols (including polymers containing polyalkylene glycols), as described in WO2009/153184, EP2692842 and WO 2014/019903. Copolymers as described in WO2014/082955(Unilever) may be present.
Polymers for preventing dye deposition may be present, for example poly (vinylpyrrolidone), poly (vinylpyridine-N-oxide) and poly (vinylimidazole).
Such polymers are most preferably present in an amount of less than 0.4 wt.%.
The composition is preferably free of silicone polymers and polymers with quaternized N groups.
When the polymer is considered to be a builder and/or a chelant, then the level of polymer is included in the total level of builder and chelant.
Builders and chelating agents
The detergent composition may also optionally comprise relatively low levels of organic detergent builder or chelant materials. Examples include alkali metals, citrates, succinates, malonates, carboxymethylsuccinates, carboxylates, polycarboxylates and polyacetylcarboxylates. Specific examples include sodium, potassium and lithium salts of oxydisuccinic acid, trimellitic acid, benzene polycarboxylic acids, ethylene diamine tetraacetic acid, diethylene triamine pentaacetic acid, alkyl or alkenyl succinic acids, nitrilotriacetic acid and citric acid.
Aqueous liquid laundry detergent formulations, if used, contain 0.1 wt% to 3.0 wt% of builder and chelant materials. Citrate salts are most preferred.
Phosphorus-containing chemicals
The phosphorus-containing chemical is an inorganic or organic chemical containing phosphorus.
Examples are sodium tripolyphosphate, DEQUESTTMOrganic phosphonate type chelants sold by Monsanto, and alkane hydroxy phosphonates.
The aqueous liquid laundry detergent composition comprises 0-1 wt% of a phosphorus-containing chemical.
Shading dye
Dyes are described in Color Chemistry Synthesis, Properties and Applications of Organic Dyes and Pigments (H Zollinger, Wiley VCH, Z ü rich, 2003) and Industrial dye Chemistry, Properties Applications (K Hunger (ed), Wiley-VCH Weinheim 2003).
Hueing dyes for laundry detergents preferably have more than 5000L mol at the absorption maximum in the visible range (400-700nm)-1cm-1Preferably greater than10000L mol-1cm-1The extinction coefficient of (a). The color of the dye is blue or violet.
Preferred shading dye chromophores are azo, azine and anthraquinone.
Preferred examples of azo dyes are direct violet 9, direct violet 99, direct violet 35 and the dyes indicated below:
the azo dyes are preferably selected from sulfonated phenazine dyes. A preferred example is acid blue 98, acid Violet 50, CAS-No 72749-80-5 dye, acid blue 59.
The preferred anthraquinone dyes are disperse violet 28, and a reactive blue anthraquinone dye covalently attached to an alkoxylated polyethyleneimine. The alkoxylation is preferably selected from ethoxylation and propoxylation, most preferably propoxylation. Preferably, 80 to 95 mol% of the NH groups in the polyethyleneimine are replaced by isopropanol groups by propoxylation. Preferably, the molecular weight of the polyethyleneimine prior to reaction with the dye and propoxylation is 600-1800.
Mixtures of hueing dyes may be used.
The hueing dye is preferably present in the composition in an amount of from 0.0001 to 0.5 wt%, more preferably from 0.001 to 0.1 wt%. Depending on the nature of the hueing dye, there is a preferred range depending on the efficacy of the hueing dye, which depends on the class and the specific efficacy within any particular class.
Enzyme
Preferably, each enzyme is present in the laundry compositions of the present invention at a level of from 0.0001 wt% to 0.1 wt% protein.
The protease is preferably present in an aqueous liquid laundry detergent composition. Proteases hydrolyze the peptides and bonds within the protein, which results in enhanced removal of protein or peptide containing stains in the context of laundry.
Most preferably, the protease is subtilisin (EC 3.4.21.62).
The lipase is preferably present in an aqueous liquid detergent composition. Preferred commercially available lipases include LipolaseTMAnd Lipolase UltraTM,LipexTMAnd LipocleanTM(Novozymes A/S)。
Suitable amylases (alpha and/or beta) include those of bacterial or fungal origin. Chemically modified or protein engineered mutants are included. Amylases include, for example, alpha-amylases obtained from Bacillus, such as particular strains of Bacillus licheniformis described in more detail in GB1,296,839, or strains of Bacillus disclosed in WO95/026397 or WO 00/060060. The commercially available amylase is DuramylTM,TermamylTM,Termamyl UltraTM,NatalaseTM,StainzymeTM,FungamylTMAnd BANTM(Novozymes A/S),RapidaseTMAnd PurastarTM(from Genencor International Inc.).
Fluorescent agent
The composition preferably comprises a fluorescent agent (brightener). Fluorescent agents are well known, and many such fluorescent agents are commercially available. Typically, these fluorescent agents are provided and used in the form of their alkali metal salts, e.g., sodium salts.
Preferred classes of fluorescers are: distyrylbiphenyl compounds, such as Tinopal (trade mark) CBS-X, diaminostilbene disulfonic acid compounds, such as Tinopal DMS pure Xtra and Blankophor (trade mark) HRH, and pyrazoline compounds, such as Blankophor SN.
Preferred fluorescent agents are: sodium 2- (4-styryl-3-sulfophenyl) -2H-naphtho (napthol) [1,2-d ] triazole, disodium 4,4' -bis { [ (4-anilino-6- (N-methyl-N-2-hydroxyethyl) amino-1, 3, 5-triazin-2-yl) ] amino } stilbene-2-2 ' -disulfonate, disodium 4,4' -bis { [ (4-anilino-6-morpholinyl-1, 3, 5-triazin-2-yl) ] amino } stilbene-2-2 ' -disulfonate, and disodium 4,4' -bis (2-sulfostyryl) biphenyl.
The total amount of fluorescent agent or agents used in the composition is preferably 0.0001 to 0.5 wt%, more preferably 0.005 to 2 wt%, most preferably 0.05 to 0.25 wt%.
Perfume
The composition preferably comprises a perfume.
The perfume is preferably comprised in 0.01-2 wt%, more preferably 0.05-0.5 wt%, most preferably 0.1-1 wt%. Many suitable examples of fragrances are provided in CTFA (Cosmetic, Toiletry and Fragrance Association)1992International layers Guide, published by CFTA Publications, and OPD1993Chemicals layers Directory 80th annular Edition, published by Schnell Publishing Co.
The international daily-use perfumery association has issued a list of fragrance ingredients (fragrances) in 2011. (http:// www.ifraorg.org/en-us/ingredients #. U7Z4 hPldWzk).
The international daily fragrance institute provides a database of fragrances (fragrances) with safety information.
Some or all of the perfume may be encapsulated, typical perfume components which facilitate encapsulation include those having a relatively low boiling point, preferably a boiling point of less than 300 ℃, preferably 100 ℃ and 250 ℃. It is also advantageous to encapsulate perfume components having a low Clog P (i.e. those that will have a higher tendency to partition into water), preferably having a Clog P of less than 3.0.
Preferably, the laundry treatment composition does not comprise a peroxygen bleach, such as sodium percarbonate, sodium perborate and peracids.
The liquid laundry detergent composition may be present in a water-soluble unit dose article. In such embodiments, the water-soluble unit dose article comprises at least one water-soluble film shaped such that the unit dose article comprises at least one interior compartment surrounded by the water-soluble film. At least one compartment contains a liquid laundry detergent composition. The water-soluble film is sealed so that the liquid laundry detergent composition does not leak out of the compartment during storage. However, when the water-soluble unit dose article is added to water, the water-soluble film dissolves and releases the contents of the internal compartment into the wash liquor.
Examples
An aqueous liquid laundry detergent was prepared having the following formulation:
surfactants other than AEC are Linear Alkylbenzene Sulfonate (LAS), sodium lauryl ether sulfate with 3 moles of ethoxylation (SLES), and nonionic with 7 moles of ethoxylation (NI) C12-C15A straight chain alcohol. The surfactant levels given in the table are the sum of LAS, SLES and NI. The ratios of the three are given in the table of results below. The formulations were prepared with and without the addition of 4 wt% of an Alkyl Ether Carboxylate (AEC). The AEC used had 10 moles of ethoxylated and oleyl alkyl chains.
The formulation was used to wash 8 pieces of 5 x 5cm EMPA 117 stain monitor (blood/milk/ink stain on polyester cotton) in a tergitometer set at 200 rpm. A60 minute wash was carried out with 2.3g/L of the formulation in 800ml of 26o French hard water at room temperature (293K). To simulate oily soil, SBL2004 soil strips (from WarwickEquest) of (7.5g) were cut into 4 aliquots and added to the wash liquor.
Once the wash was complete, the cotton monitor was rinsed once in 400ml of clear water, removed, dried, and the color measured on a reflectometer as% reflectance at R460, i.e. 460nm (excluding UV).
The greater the Δ of the R460 value, the cleaner the fabric compared to the control.
The Δ R460 value is thus calculated:
Δ R460 ═ L (AEC) -L (control without AEC)
The greater the Δ R460 value, the greater the formulation performance improvement brought about by the introduction of the Alkyl Ether Carboxylate (AEC). The 95% confidence limits were calculated based on 8 individual EMPA 117 blocks.
The results are shown below:
comparative example A, which is believed to fairly reflect the disclosure of prior art WO2016/180552 (example 1) and DE 102013218614A (example B), discloses exemplary formulations of LAS: NI: SLES in a weight ratio of 4:1:5(WO2016/180552) and 4:2:5(DE 102013218614A).
The inventive formulations with a high proportion of LAS relative to other surfactants (e.g., NI and SLES surfactants) show much greater benefit from AEC addition than formulations with a much lower proportion of LAS.
Claims (8)
1. An aqueous liquid laundry detergent composition comprising:
(i)5-19 wt% of a linear alkylbenzene sulphonate anionic surfactant,
(ii)0.5 to 8 wt% of an alkyl ether carboxylic acid anionic surfactant of the structure:
R2-(OCH2CH2)n-OCH2-COOH,
wherein:
R2is selected from C16-C18A linear alkyl chain; wherein n is selected from 10 to 25 and wherein the weight ratio of alkyl ether carboxylic acid to linear alkylbenzene sulfonate surfactant is from 0.05 to 1;
(iii) at least 60% by weight of water;
(iv)0-2 wt% of an ethoxylated alcohol nonionic surfactant, wherein the weight ratio of ethoxylated alcohol nonionic surfactant to linear alkylbenzene sulfonate surfactant is 0-0.2; and
(v)0-1 wt% of a phosphorus-containing chemical;
wherein the composition optionally comprises an additional anionic surfactant, wherein the weight ratio of additional surfactant to linear alkylbenzene sulphonate is from 0 to 0.55, preferably from 0 to 0.1.
2. An aqueous liquid laundry detergent composition according to claim 1, wherein the composition comprises an additional anionic surfactant, wherein the weight ratio of additional surfactant to linear alkylbenzene sulphonate is from 0.01 to 0.55, preferably from 0.01 to 0.1.
3. An aqueous liquid laundry detergent composition according to claim 1 or claim 2 wherein the composition comprises from 0.5 to 6 wt%, preferably from 1 to 6 wt%, more preferably from 2 to 6 wt% of alkyl ether carboxylic acid anionic surfactant.
4. An aqueous liquid laundry detergent composition according to any preceding claims wherein the weight ratio of alkyl ether carboxylic acid to linear alkylbenzene sulphonate surfactant is from 0.1 to 0.6.
5. An aqueous liquid laundry detergent composition according to any preceding claims wherein the linear alkylbenzene sulphonate surfactant is present in an amount of from 6 to 19 wt%, preferably from 7 to 19 wt%, more preferably from 8 to 19 wt%, most preferably from 9 to 19 wt%.
6. An aqueous liquid laundry detergent composition according to any preceding claims wherein the weight percentage of linear alkylbenzene sulphonate surfactant to total non-alkyl ether surfactant is from 50 to 100 wt%, preferably from 60 to 100 wt%, more preferably from 70 to 10 wt%, most preferably from 80 to 100 wt%.
7. An aqueous liquid laundry detergent composition according to any preceding claim having a pH of from 7 to 11, preferably from 7 to 10.
8. A domestic method of treating a textile, the method comprising the steps of:
a) treating a textile with at least 1g/L of an aqueous solution of a laundry detergent composition as defined in any preceding claim; and
b) the aqueous laundry detergent solution is left in contact with the textile for a period of time from 10 minutes to 2 days, and then the textile is rinsed and dried.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP17170419 | 2017-05-10 | ||
EP17170419.0 | 2017-05-10 | ||
PCT/EP2018/058431 WO2018206197A1 (en) | 2017-05-10 | 2018-04-03 | Laundry detergent composition |
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CN (1) | CN110621769A (en) |
AR (1) | AR111780A1 (en) |
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CN1234854C (en) | 1999-03-31 | 2006-01-04 | 诺维信公司 | Polypeptides having alkaline alpha-amylase activity and uncleic acids encoding same |
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DE102013218614A1 (en) | 2013-09-17 | 2015-03-19 | Henkel Ag & Co. Kgaa | Detergent containing ether carboxylates |
-
2018
- 2018-04-03 CN CN201880027340.XA patent/CN110621769A/en active Pending
- 2018-04-03 EP EP18713978.7A patent/EP3622045B1/en active Active
- 2018-04-03 WO PCT/EP2018/058431 patent/WO2018206197A1/en active Search and Examination
- 2018-05-09 AR ARP180101208A patent/AR111780A1/en active IP Right Grant
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2019
- 2019-09-27 ZA ZA2019/06405A patent/ZA201906405B/en unknown
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EP0178006A2 (en) * | 1984-10-12 | 1986-04-16 | Unilever N.V. | Liquid detergent compositions |
CN1533426A (en) * | 2001-07-17 | 2004-09-29 | Liquid conditioner and method for washing textiles | |
CN106574208A (en) * | 2014-08-07 | 2017-04-19 | 宝洁公司 | Laundry detergent composition |
WO2016180552A1 (en) * | 2015-05-08 | 2016-11-17 | Unilever Plc | Laundry detergent composition |
WO2016198262A1 (en) * | 2015-06-11 | 2016-12-15 | Unilever Plc | Laundry detergent composition |
WO2017054983A1 (en) * | 2015-10-01 | 2017-04-06 | Unilever Plc | Liquid laundry detergent composition |
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AR111780A1 (en) | 2019-08-21 |
WO2018206197A1 (en) | 2018-11-15 |
EP3622045A1 (en) | 2020-03-18 |
EP3622045B1 (en) | 2021-03-10 |
ZA201906405B (en) | 2021-01-27 |
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